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Article history: Among various lead-free piezoelectric materials, (K,Na)NbO3 is a very promising candidate. In this study, (K,Na)
Received 23 June 2009 NbO3 ceramics were sintered from mixed KNbO3 and NaNbO3 powders prepared by hydrothermal reaction. These
Accepted 6 October 2009 two powders were mixed with distilled water in a KNbO3/NaNbO3 molar ratio of 1. After sintering the mixed
Available online 12 October 2009
powder, the solid solution of (Na,K)NbO3 ceramics was obtained. The electrical properties such as the
electromechanical coupling factors kp and k33, the mechanical quality factor, Qm, and the piezoelectric constant
Keywords:
d33 of the sintered (K,Na)NbO3 ceramics were 0.32, 0.48, 71 (radial mode), 118 ((33)mode), and 107 pC/N,
Lead-free piezoelectric material
(K,Na)NbO3 ceramics
respectively.
Sintering solid solution © 2009 Elsevier B.V. All rights reserved.
Piezoelectric properties
0167-577X/$ – see front matter © 2009 Elsevier B.V. All rights reserved.
doi:10.1016/j.matlet.2009.10.012
126 T. Maeda et al. / Materials Letters 64 (2010) 125–128
washed sufficiently with 1 L of distilled water. Fig. 1 shows SEM 2.2. Sintering process
photographs of the obtained powders. The powder sizes were
approximately 1 μm for KNbO3 and 3 μm for NaNbO3 powders, To synthesize (K,Na)NbO3 ceramics, KNbO3 and NaNbO3 powders
respectively. Fig. 2 shows an XRD pattern for each powder. From these were mixed in distilled water. The amounts were 1.500 g and 1.366 g,
results, it was confirmed that the powders had no impurity or secondary in order to obtain a molar ratio between potassium and sodium of 1 in
phases, such as niobium oxide or pyrochlore. the ceramics. The mixed powder was filtered and dried for 10 min at
Fig. 2. XRD patterns of hydrothermally produced powders: (a) KNbO3 and (b) NaNbO3.
Fig. 3. XRD patterns: (a) powder mixtures and (b) (K,Na)NbO3 ceramic.
T. Maeda et al. / Materials Letters 64 (2010) 125–128 127
mode. Poling treatments were carried out using a high voltage supply
(Matsusada HARb-10P10) at 2.0 kV/mm in 100 °C silicone oil for
30 min. The admittance results for the radial vibration mode and (33)
mode are shown in Fig. 5(a) and (b). The electromechanical coupling
factors kp and k33 were calculated from the resonant–antiresonant
T
method. The relative free permittivity ε33 was determined from the
capacitance value at 1 kHz of the poled specimen. The stiffness cEij was
calculated from the resonant frequency. With these parameters, the
piezoelectric factors dij were calculated from the equation,
qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
dij = kij εT33 = cEij ð2:3:1Þ
150 °C. After drying, this powder was ground with alumina mortar
3. Conclusion
and alumina pestle, and filtered with sieve (mesh size 425 μm). From
this powder, a disk-shaped pellet was obtained using cold isostatic
In this study, potassium niobate and sodium niobate powders were
pressing (CIP) at 200 MPa. The pellet was then sintered at 1100 °C for
synthesized using a hydrothermal method. These two powders were
two hours in an air environment. The heating rate was 230 °C/h and
sintered into a solid solution of (K,Na)NbO3. This solid solution process
the cooling rate was 100 °C/h.
was confirmed by XRD measurements. Compared to non-doped KNbO3,
Fig. 3 shows a comparison of XRD patterns between mixed powder
the poling process was easier [1,2]. The sintering temperature also
and sintered ceramics. This figure indicates that in the sintering
became wider, from 1050 °C to 1150 °C. As a result, the piezoelectric
process, KNbO3 and NaNbO3 powders resulted in the solid solution of
properties k33 = 0.48, d33 = 107 pC/N, and Qm = 118 were obtained.
(K,Na)NbO3. Note that the three peaks around 22° of the powder XRD
became two peaks after sintering. SEM photographs of the ceramics
Acknowledgements
verified that the grain size was 3 ~ 20 μm as shown in Fig. 4. The
density of the sintered (K,Na)NbO3 ceramic was measured to be
This research was supported by the New Energy and Industrial
4.09 × 103 kg/m3 by density meter (Alfamirage SD-200 L), which
Technology Development Organization (NEDO). We would like to
corresponds to a relative density of 90.7%.
appreciate Dr. Daeyong Jeong for fruitful discussion.
References
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