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fRT E
its measurement. the useual units of heat are calorie E= and Cv =
2 T
or kilocalorie
Rf
1. SPECIFIC HEAT CV =
2
This is also called ' Heat Inertia' of a substance (8) Amount of heat needed to increase the
1.1 Specific Heat of solid & Liquid (s) : If a solid or a temperature of n moles of gas by dT at constant
liquid is heated till the change of the state, there is volume is
no change in their volume hence the work done is d = ncv dT.
zero. Hence there is only one specific heat of solids (9) Amount of heat needed to increase the
and liquids which is constant. temperature of 1gm of gas by 1 0C at constant
1. Definition : The amount of heat needed for an volume is called gram specific heat at constant
unit increase in the temperature of unit mass of volume.
a solid or liquid is called it's specific heat
(C v ) molar
Unit : kilocalorie / kg-ºC or calorie/g-ºC (10) (Cv)gram =
M
1 Kcal / Kg-ºC = 1 Cal/g-ºC
or (Cv)molar = M(Cv)gram
2. If mass of the body is 'm' and specific heat is 's'
then amount of heat needed to increases it's where M = molecules wt . of gas
temperature by dT is given by Q = msdT (11) Amount of heat needed to increases temperature
3. Specific heat of water = 1 kcal / kg-ºC = 1 of 'm' gm of gas by dT at constant volume is
Cal/ g-ºC = 4.18 × 103 J/kg-ºC m
4. Kelvin can also be used instead of ºC is size of dQ = m (Cv)gram dT = (C ) dT
M v molar
both uints is same.
(12) Amount of heat needed to increase temperature
1.2 Specific heat of gas (C) of 1mole of gas by 10C at constant pressure is
(1) There are many processes possible to give heat called molar specific heat at constant pressure.
to a gas. A specific heat can be associated to (13) Cp = Cv + R, for one mole.
each such process which depends on the nature where R = universal gas constant
of process. (14) Amount of heat needed to increase temperature
(2) The number of possible specific heats for a gas of n moles of gas by dT is at constant pressure
is infinite and the value of specific heats can dQ = nCp dT
very from zero (0) to infinity ( ).
Note : If gas is heated at constant pressure, then C v can
(3) Generally two types of specific heat are
be replaced by Cp in above discussion. Hence
mentioned for a gas -
CP
(a) specific heat at constant volume (Cv) (a) (Cp)gram =
M
(b) specific heat at constant pressure (Cp) or Cp = M (Cp)gram
(4) These specific heats can be molar or gram, (15) Specific heat for other processes
depending on the amount of gas considered to Q
define it S
mT
(5) The molar heat capacities of a gas are defined as (a) adiabatic s = 0, as Q = 0 but T has some
the heat given per mole of the gas per unit rise value
in the temperature
(b) isothermal s = , as T = 0 but Q has some
(6) The molar heat capacity at constant volume, value
Q
denoted by Cv is Cv = (16) Specific heat for any process is given by
nT
pdV pdV
(7) If, at absolute temperature T , total energy of a C = Cv + = Cp – R +
ndT ndT
gas E , degree of freedom of gas = f
(for the n mole of gas)
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Example : 4. LATENT HEAT
(1) If process is isochoric , then dV = 0
Latent heat of fusion of a substance is the quantity
C = Cv of heat (in kilocalories) required to change its 1 kg
(2) If process is isobaric , then pV = nRT mass from solid to liquid state at its melting point
(For ice latent heat of fusion = 80 kilocal/kg).
pdV
= nR Latent heat of vaporization of a substnce is the
dT quantity of heat required to change its 1 kg mass
from liquid to vapour state at its boiling point.
C = Cv + R = Cp (for one mole)
For water latent heat of vaporisation = 536 kilocal/kg
2 THERMAL CAPACITY
Specific heat, thermal capacity &
(1) Amount of heat needed to increase the latent heat
temperature of a substance (any amount) by 1ºC
is called thermal capacity of that substance. Ex.1 The amount of heat necessary to raise the
temperature of 0.2 mol of N2 at constant pressure
(2) Thermal capacity = ( mass of body ) x (specific from 37º to 337º C will be -
heat) Hc = ms (A) 1764 Joule (B) 764 Joule
(3) Unit = calorie /ºCor Kcal/ºC (C) 1764 Calorie (D) 1764 erg
Sol.[A] dQ = nCPdT
1
Heat capacity at point 'p' = = cot dQ = 0.2 × 7 × 300
tan
dQ = 420 Calorie
(4) Thermal capacity is given by reciprocal of slope dW = 420 × 4.2
of heat temperature curve.as dW = 1764 Joule
Q Ex.2 (Cp – Cv) will be -
Hc = mS = (A) Maximum for oxygen
dT
(B) Maximum for nitrogen
(5) Heat capacity in an isothermal process is infinite
(C) Maximum for carbon di oxide
(). e.g. process of melting and vaporisation
(D) Same for all gases
(6) If heat capacity of a body is Hc, then heat needed Sol.[D] (Cp – Cv) = R, where R is gas constant which is
to rise it's temperature by d is, dQ = Hc d same for all gases. So (Cp – Cv) is same for all
gases.
3. WATER EQUIVALENT OF A BODY
Ex.3 The ratio of radii of two copper spheres is
(1) If m gram of a substance is given Q amount of 2 : 1 and they are kept at same temperature. The
heat which rises its temperature by T . Now if ratio of their heat capacities will be -
on giving same amount of heat temperature of w (A) 2 : 1 (B) 1 : 1
gram of water is also increased by T then w is (C) 8 : 1 (D) 4 : 1
called water equivalent of body of mass m.
(2) The value of water equivalent of a body is same dQ 1
4
3
r13 S FG IJ
r1
3
2FG IJ
3 8
as it's heat capacity. The difference is only in
units. e.g If heat capacity of a body is m calorie/
Sol.[C] dQ =
2 4
r2 3 S
=
r2H K =
1 HK =
1
3
0C then it's water equivalent will be m gram.
Ex.4 5 g of ice at 0°C is dropped ina beaker containing
20 g of water at 40°C, then
(3) Physical meaning : The same amount of heat (A) All the ice will not melt into water
has to be given to a body for increasing
(B) All the ice will melt and the resulting
it'stemperature by dT as needed for quantity of temperature of water will be 0°C
water equal to it's water equivalent by same (C) All the ice will melt and the resulting
temperature range. temperature of water will be 25°C
(D) All the ice will melt and the resulting
temperature of water will be 16°C
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Sol.[D] Heat required to melt 5 g ice = 5 × 80 = 400 cal. Heat (viii) If n1 moles of first gas at a temperarure T 1 are
available with 20 g water at 40°C = 20 × 1× 40 mixed with n 2 moles of the other gas at a
= 800 cal out of this, 400 cal heat will be used to temperature T 2, the temperature of the mixture
melt the ice and remaining heat will raise the will be
temperature. Thus Heat given by water = Heat
taken by ice n 1T1 n 2 T2
T= n1 n 2
20 × 1 × (40 – ) = 5 × 80 + 5 × 1 × ( – 0)
800 – 20 = 400 + 5 Gaseous mixture
25 = 400
Ex.5 n 1 and n 2 moles of two ideal gases of the
400 thermodynamics constants 1 and 2 respectively
or = =16°C
25 CP
are mixed C for the mixture is -
5. GASEOUS MIXTURE v
1 2
(i) Suppose two non - reactive gases are enclosed (A)
2
in a vessel of volume V. In the mixture n1 moles
of one gas are mixed with n2 moles of another n1 1 n 2 2
(B) n1 n 2
gas. If NA is Avogadro's number then number of
molecules of first gas will be N1 = n1 NA and n1 2 n 2 1
number of molecules of second gas will be (C) n1 n 2
N2 = n2A2.
n1 1 ( 2 1) n 2 2 ( 1 1)
(ii) Total mole fraction n = (n1 + n2). (D) n1 ( 2 1) n 2 ( 1 1)
(iii) If M1 is molecular weight of first gas and M 2
that of second gas the molecular weight of the Sol.[D] At constant temperature U = U1 + U2
mixture will be nCv = n1 Cv1 + n2 Cv2
Total number of mols. in the mixture
n1M1 n2 M2
M= n = n1 + n2
n1 n2
R R
(iv) Specific heat of the mixture at constant volume nCv = n1 + n2
1 1 2 1
will be
CP = C v
n 1C v n 2 c v 2 R R
1
Cv = nCP = n1 1 + n2 2
n1 n 2 1 1 2 1
(v) Specific heat of the mixture at constant pressure R R
will be n1 1 n2 2
CP 1 1 2 1
= C =
n 1C p n 2 c p 2 R R
v
n1 n1
1 1 2 1
1
Cp =
n1 n 2
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