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FORM TP 2019005 JANUARY ]019

CARIBBEAIi. E\AMTNATIONS COUNCIL

CARIBBEAN SECO\DARY EDUCATION CERTIF'ICATE@
ELA.MINATION

CHEMISTRY

Paper 02 - General Proficiency

2 hours and 30 minutes

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READ THE FOLLOWING INSTRUCTIONS CAREFTILL}"

1 . This paper consists of SIX questions in TWO sections"

2. Arsr.r,er ALL questions.

3. Write your answ-ers in rhe spaces provided in this booklet.

4. Do NOT rvdte in rhe margins.

5" Where appropriate. -{LL WORKING MUST BE SHOUN in this 5r.r,_r},1g1.

6" You may use a silent. non-programmable calculator to ansrr er Juesrr,rns.

7 " Ifyou need to reurii: an\ answer and there is not enough space :l,iir so o1 the
original page, you l-itlist use the extra lined page(s) provided at :h,- back of this
o
booklet. Remember to draw a line through your original ans* er.
o
8. If you use the extra page(s) you MUST write the question number clear.ly in
the box provided at the top of the extra page(s) ando where reler ant. include
the question part beside the answer-.

DO NOT TL R\ THIS P..\GE UNTIL YOTI ..l.RE TOLD TO DO SO.

Copyri$ C 2018 Caribbean Examinations Council

- All rights reserved.
A1?1)fi'{\/IANIIIAI?\."N1O TIEIilETilUHTSUHI I
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SECTIOI A

\nsrr er -\lL questions in this section.

Do NOT spend nlore than *10 minutes on Question 1'

salnple'
1. An experiment was carrie.l ,-,iit tc detenl',ir: the percentage of iron in an iron salt
mL of dilute sulfuric acid"
a O.SdO g sample of iron sa,r * as placed ,n a conical flask. To it. 25"0
10 mL oiphosphoric acid anC 8 drops oian indicator were added. The
contents of the flask were
rnixed ani titrated against a r-r.ul0 mo1 ,jm.' ...1Lrtion of potassium dictu"omate
until the end point
u,as reached. 'Ihe ionic equatiritl tbr the reaction is given beloll'

CrrO.,2'* + i4H- 6Fer- * 2Crr- -;H-O

6Fe2*
-
titration.
Figure 1 shows the burette readings of the initial and final voluntes of EACH
@ @
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:Ffi

Initial Final Initial FinaI Initial Final

a
Titration 1 Titration 2 Titration 3

fRough)

Figure 1. Burette readings

(a) , List the apparatus that would be necessar-v to carry out the experiment.

a O
c) o

1 (2 marks)

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(b) Use the information in Fr:*:e I to complete'lable 1.

TABLE 1: TITRATIO\ \.{LUES OBTAINED F'ROM EXPBRT]VIENT

Burctte Readings (cm'' r Titration 1 Titration 2 Titration 3

Final volume

Initial volume

Volume of solution used

(9 marks)

(c) (i) Use an asterisk t * ) to indicate the titration data tirat should be r-rsed to obtain the
average titration \ L-,lume of,potassium dichromate used in the experiment.
(1 mark)

(ii) Hence, calculate the avemge volume ofpotassium dichromate used in the experiment
and record the r alue to two decimal places.

(2 marks)

(d) Using the information from (c) (ii). calculate the average number of moles of potassium
dichromate used in the experiment.

(1 mark)

(e) From the equation grr en on page 4, determine the number of moles of iron ions (Fe2')
that react rr,,ith 1 rnc,i; cf dichromate ions (Cr,O_r-).

(1 mtrt)

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-a-

Calculate the number of moles of iron in the iron salt sample-

(l rnark)

(g) Calculate the mass of iron in the iron salt sample.

[Molar mass of Fe is 55.8 g moli-]

LS
(o co

(1 mark)

(h) Calculate the percentage of iron in the iron salt sample.

(1mark)

(il The reaction between iron and dichromate is considered a reduction-oxidation reaction.
Define the term 'reduction'in tenms of electrons.

'J O
.r!.
O
o ,"""""'-""' """"':""""'
(1 mark)

() In the reaction, Fe2* acts as a re&rcing agent. Define the &mr 'reducing agent'-

(2 marks)

01212020/JANUARY20r9
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(k) Calculate the oxidation state of Cr in CrrOrz-.

(2 marks)

(1) State ONE precaution that sirould be taken u,hen carn,ing out the erperiment.

(1 mark)

Total25 marks

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012120201JANUARY 201e

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the scent of curry coming from her mom's

.,, (a) Jamelia is in her IOom Sudyitrg and smells ..Ah! Diffusion at work!,,
to herself,
cooking in the kitphen afea. ste oinr<s

(1) Define *re term 'diffirsion''

(2 marks)

(ii)ExplainhowthediffisionofthescentofthecurrySupportsthepj{i*lI"theo1
of matter.
@
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i;;;;*j
S"a:e h'''\\' tire arrangernent
(iii) Diffusion is a proeess that can also occur in liquids'
soliC and a gas
of ponl"f". in a liquid differs from that in a

.t

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(ir') Apart from diffsion, identify ONE process that supports the particulate theory of
matter and state OlriE example of such a process.

Example

(2 marks)

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(b).Jamelia,smomshowedhefthatinordertocookwithcurqyshefirsthadtomixthecurry
mixture resembled a chalk and water
mixture
that the
powder with water. Jamelia ob-served
she had seen in class, exceptthe
curry mixture was brown in colour'
,--r^- ^-,{water is a suspensro n or colloid'
(i) State whether the mi$rre of curry powder and

(1 mark)

..atetechniquethatcouldbeusedinaschoollaboratory
(ii) State the MOST aPProPil
to seParate this mixture'
. ". " ".......... i......
(1 mark)

;Dr
@

C)
O
4O
-o

.i

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0r212020/JANUARY 2019
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(ii| Draw a cleartlr hbelled diagram of the apparatus that could be set up in the school
laboratory to seprde the mixture of curry powder and water. In your diagram,
show the localn of the separated'cbmpone-ntr----

(4 marks)

Totdii5 marks

.t

CrO ONTO THENEXTPAGE

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3. (a) Compound-\isastrargh:-;h;'i''1\Jr'carbonwiththemolecularfomiulaC'Ht''
of
s':;:;e ll hydrooarbons and T\\-o possible uses
(i) State O\ E 1l'f i'..;ir
Con-rPcun'3 -\

Source

Uses

sffucturo of Compound
A'
(ii) Draw the FULLY DISPLAYED

CO
@

Structure of ComPound -t t 2 nrarks)

.!

]-:,',. rr lr) :{ \ll.' i P\uF

a
01212020IJANUARY 2019
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Therrnai and cataivtic Cr:-:. - - j:e \ ery useful processes in the petrocher-nical industrr.

(i) Define the ter: - tr.i '.-tc cracking'.

(2 marks)

(ii) state the imporare of catalytic cracking in petroleum refineries-

(1 rnark)

CO O'r TO THE \EXf P.\t -

I I l, -T{\l ,\RY lr,rt-
flt ffi,illt il1ilIilililt tr
 r (c) Another hydrocarbon. comp.ound
-i4-

B-with the formula CrH,o' can be

converted to

Co*po""iA T u simple one-step reaction"

Compound B'
(i) D:r.',";.tt-a-
-' - -
-
1'-
triSPLAYED structiral lbmruia of

€
co

Structure of ComPou.nd B
(2 marks)

and Compound B'

O
o (ii) State ONE physical p'op"ny common to borh Compound A
O

(1 mark)

GO ON TO THE NEXT PAGE

I

rI ffill lllll llll llll

 r (c)
\-.-...-:--,-. r: -.-.----
\ . - ,.-!
-l+-

,- -.:--:ld B \\tith the formula C-H,.,

can be converted to

C.-::--:.1 -:lj \ ':'. t S'il-l ; --;-: ':;33f,1-1o11'

B'
(ii Dr:ri
Ppjrr ita Pt-ss-r-- IISPLAYI strucftiral forrnuia of Compound
- - ' IISPLAYED
p.:i l.:- ' - ---'

Structure of ComPound B (2 marks)

B'
physical ptop"ny common to both Compound A and Compound
C
O
(ii) State ONE

ii *;;i

CIO ON TOTHENEXTPAGE
(

0I2I?020/]ANUARY 2019
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(d) CompoundA anc t : :-.:': -:. r B can be distinguished by reacting them u'ith bromine strlutlon
in the dark.

(i) State u hrci: - - -: e rvo compounds, A or B, reacts with bromine.

(1 mark)

(ii) State the colorn change that is observed when ttre reaction occurs.

(1 mark)

(iii) \liite a balan;eci chemical equation for the reaction.

(2 marks)

Total 15 marks

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Sf,CTION B

' A-nsrer AII qrc!$tfr)ns in this section'

ir ttc spaees provided in this booklet'

Write your reslxlns

4. (a) Define E\Cli -' lr.; -- - ;' -' :i-':

(t Atomicaumber

C
O

Go a,\ r,-, ^ I-.i \F\T PAGE

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 -17 -

(b) Sodir-rm is a metal i'. .-. :r. ,-,:nic number of i I and lilass number oi Ii.
(i) Draw a dia!r': ,- ':t,ru-the arrangement of electrons in a sodiurn atom.

(2 marks)

(ii) State the period to which the element sodium belongs in the periodic table.

(L mark)

(iii) Describe the type of bonding in sodium metal.

(2 mark,

L(-) o\ lt) iHE \l \

(-)ll1:(,)10 -lA\LrAR\- l. -

Il llt ll ll Il I llll Ill I ll il

 - 18 -

(c)Sc..li,.ri:..;i1,.-::.::.:]]-:::.].-isodiummetai'-A'C.-i-t;c:li;::eJs..cliurnclrloridesolution
. :'i':::lrte in an e1ectrol1''tic cell
(Lriir:: i a ':- *lr-1-:-- ; :. ' ''s lr'hett it is tlsed as "'l''
Lt't:.-.:';a i --'- ---

ll' De-:-l:-' '::-- ': ;---- rsis"

(2 marks)

(ii)Writethehalfequations,includingstatesymbols,forthereactionthatoccursat
of concentrated sodium chloride
the anode and cathode during the electxoiysis
solution (brine)-

Anode i""""""""" """""""""""'""

Cathode """""':"""

(6 marl ';

Total 15 mar'' tj

o
O

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NOTHING HAS BEEN OMITTED.

GL-) O\ , ,..

IITITIIIIIIII
 r
t. (a)
-20-

CompormdD,CIIG{,GLCOOH,hasaveryunpleasantsmellandbittertaste'
D belongs'
(, Name the homologous series to which Compound

(1 mark)

formula of compound D and write its

(i1) Draw the FULLY DISPLAYED structural
name'

@
.D

' Structure of ComPound D

O
o (2 marks)

Name of ConlPt'ur'i ) (1 marh)

(b)CompoundDt.ea;1...'..---.:.-:..']:clbnrrthesr,veet-sileliinsConrpotrtldE.

tii]I-r':,.'.':-.]..:-]-':.:euuationfortlrere:::-..:.:e:..'eel.i.L-rlTlpLrundDa:1.:
-:E

rl mlrL-.

i-: '. . *l' tillr' ' P\uL

0 1 I :.010 JA\I-\F.\-
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u r*r u ff r{ r [Ir I lll llillllllli

 l1

(ii) Suggest the cmditims for the reaction between Compound D and ethanol.

......--............................
.........,...-..4.. ...............,..

(2 marks)

(iii) State the type ofreaction that occurs between Compound D and ethanol.

]l-j-,-,-.------
.... i.............
ft ---t!+r
(1mark)
li--:*--,
-ll:'A-l
il::11:{--.
lL---\rr-: (c) Compound D reacts with sodium metal to produce a sah of Compound D afld a gas.
][.F{i
Ia:--_-'-l:
(r) Write a balarced chemical equation for the reaction between Compound D and
rl- -- --
,l l: -:-_-_--- sodium metal.
I r-:. -'._-l
.trll _ _

'T!:: .: -:
tr-_-:_:
t--
l_ l_-',
ilf: !) L

ifrf -:.+1-
!i 1-
'!l- _ J..ll (2 marks)
i, - :-:i
-it-. +.
:li:i': (i i1 Describe O\--E test that could be used to identifl the gas.
!:.:
.lf li'.r
:Li: u .**
li.:,'.:-
:i r'l'"'
(2 marks)
-.i!-.r ':
;l -?ri-
-.

lln-f=
l--'s*
(iii) State whether the salt formed will be soluble in water, grving a reason for your
t+l
-li--a5-
-'lt-:!-qt
answer"

.l!------
. l:-,_-_---:

'll---

-ri - .-

-+ rj.l

.t _-i ',
(2 marks)

t.- . :
Total L5 marks

'i.'li.
il'i.-,, .
...

'[. ,;] '

-tjj-,."''
l-..' '
-.'.,1!
-1'rrf.ir
lt..
-'1,, i,,
jrl -,r'
'li', '
.. lf.- .,
-r-.Ul:
- ii- 'Y_1
'-rl ::-l
r- ,,..'a
'.,] GO O\ TO THE \-E\I . '
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--l-

r (a)
' _^!- -

' rmoncl and graphite and is a main compouent in

dioxide gas
-1
many
6.
:;,',:.]'ii'i.:x::= ,:-,. - -- -l"Jl'il.":;'-"; 'I;;'; 'u'bon
Ciamonci differs physicalh
irom -eraphire'
rlt .,rr. Q\E "' ;. . "'-----''

(ii)StateoNEsirnilaritlbenrgendianrr,lc].anderaphiteotherthantlre-vlrotlrcontain
cartron.

@
co
ii;;;-;
monoxide' whicl, can
silpply of ox-veen to form carbon
(b) Carboir call react sith a liuiteci
ne gativel,v affect hltrnal-r
health'
formatioi,l
a balancecl c}remicat eqttation,
rnclucling state s-vmboIs. to shou,.tlre
(i) Write
of carbon monoxide'

(3 marks)

(ii) StateTwoe.ffectsofcarbonmonoxideinhalationonthehumanbody.

- .. ..-. !......,....'.'.-.......""."""'
O ,
o

(2 marks)

sr-:, r r\ TO TH: \E\T P\GE

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