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"The equilibrium constant, Kc for the reaction H2(g) + CO2(g) <==> H2O(g) + CO(g) is
4.2. Initially 0.80 mole of H2 and 0.80 mole CO2 are placed in a 5.0 L flask. The concentration of
H2 at equilibrium is _____."
Selected Answer:
Correct 0.054 M
"The equilibrium constant, Kc for the reaction H2(g) + CO2(g) <==> H2O(g) + CO(g) is
4.2. Initially 0.80 mole of H2 and 0.80 mole CO2 are placed in a 5.0 L flask. The concentration of
CO at equilibrium is _____."
Answers:
Correct 0.11 M
The number of faradays required to deposit one mole of Cr metal from Cr2O72- is
Selected Answer:
Correct 6
How many grams of copper will be deposited at an electrode if a current of 1.5 A is supplied for 2
hours to a CuSO₄?
Correctd.
3.6 g
The reaction shown occurs in a gaseous phase. Once equilibrium has been achieved in a
particular reaction vessel, additional HI gas is injected directly into the reaction vessel.
Compared to the initial conditions, which of the following statements is correct after the new
equilibrium has been achieved?
Correctc.
The amount of I2 will have increased.
"When the concentrations of reactant molecules are increased, the rate of reaction increases.
The best explanation for this phenomenon is that as the reactant concentration increases,"
Correct
Kp = RT × Kc
Correct 3600 C
"A certain reaction A --> products is second order in A. If this reaction is 10.% complete after 20.
s, how long would it take for the reaction to be 90.% complete?"
Selected Answer:
Answers:
Correct 1600 s
0 0.85
2 0.67
6 0.41
8 0.33
12 0.20
14 0.16
Correct
0.049 mol L-1s-1
"The half-life of radioactive carbon is approximately 5700 years. If a sample is found to have
7000 atoms after 6000 years, how many atoms were presents initially?"
Selected Answer:
Correctb.
14500 atoms
"The decay of U-238 to Pb-206 can be used to estimate the age of inorganic matter. The half-life
of U-238 is 4.5 x 10^9 years. In a particular rock sample, the ratio of the numbers of Pb-206 to
U-238 atoms is 0.66. Assume all of the Pb-206 present is due to the decay of U-238. What is the
age of the rock?"
Correctd.
3.3x 109 yr
What is the half-life of a substance that decays to 25% of its original amount in six days?
Selected Answer:
Correctc.
3 days
A first-order reaction has a rate constant of 7.5 x10^-3 /s. The time [sec] required for the
reaction to be 60% complete is
Answers:
Correct 120
The two equilibrium constants for the same reaction, Kc and Kp, will always equal one another
when
Correct
in the reaction equation, the number of moles of gaseous products equals the number of moles
of gaseous reactants.
Correct
-0.020 mol L-1 s-1
The addition of He to the equilibrium 2CO(g) + O2(g) <==> 2 CO2(g) at constant volume _____.
Selected Answer:
Answers:
Correct Has no effect
"Kp is 158 for the equilibrium 2NO2(g) <==> 2 NO(g) + O2(g) Starting with NO2 (g) only, the
partial pressure of O2 at equilibrium is 0.25 atm. Calculate the partial pressure [atm] of NO2 at
equilibrium."
Correct 0.02
Which of the following will shift the equilibrium to the right? CaCO3(s) <==> CaO(s) + CO2(g)
Selected Answer:
Correct Addition of NaOH solution
Gamma-rays cause radiation damage when they interact with matter by producing
Selected Answer:
Correct ions and free radicals
"A certain reaction A --> products is second order in A. If this reaction is 10.% complete after 20.
s, how long would it take for the reaction to be 90.% complete?"
Answers:
Correct 1600 s
A given sample of radioactive material has 80% of the original substance remaining after 10
years. How much will remain after 90 additional years?
Answers:
Correcta.
0.11
Gamma-rays cause radiation damage when they interact with matter by producing
Answers:
Correct ions and free radicals
The equilibrium constant Kc for the equilibrium A + B <==> C + D is X. The equilibrium constant
for the reaction 1/2 A + 1/2 B <==> 1/2 C + 1/2 D is
Answers:
Correct X^(1/2)
The kinetics of the decomposition of dinitrogen pentaoxide is studied at 50°C and at 75°C. Which
of the following statements concerning the studies is correct?
Correct
The rate at 75°C will be greater than the rate at 50°C because the number of molecules with
enough energy to react increases with increasing temperature.
The first-order reaction SO2Cl2 --> SO2 + Cl2 is 10% complete in 80. min. How long would it take
for the reaction to be 95% complete?
Answers:
Correct 2300 min
"The solubility constant of stronyium sulfate, SrSO4, is 2.8 x 10-7. How many grams of SrSO4
must be dissolved in water to produce 1 L saturated solution?"
Selected Answer:
Correcta.
0.1 g
"The decay of U-238 to Pb-206 can be used to estimate the age of inorganic matter. The half-life
of U-238 is 4.5x109 years. In a particular rock sample, the ratio of the numbers of Pb-206 to U-
238 atoms is 0.66. Assume all of the Pb-206 present is due to the decay of U-238.What is the age
of rock?"
Selected Answer:
Correctb.
3.3x109 yr
The addition of He to the equilibrium 2CO(g) + O2(g) <==> 2 CO2(g) at constant volume _____.
Selected Answer:
Incorrect Shifts the equilibrium to the right
Answers:
Correct Has no effect
For the reaction N2(g) + 3H2(g) <==> 2NH3(g) Kc = 1.2 at 375 C. Kc for the reverse reaction is
Answers:
Correct 0.83
A certain first-order reaction A --> B is 25% complete in 42 min at 25°C. What is the half-life
[min] of the reaction?
Selected Answer:
Correct 101
A first-order reaction has a rate constant of 3.00 x 10^-3 s-1. The time [sec] required for the
reaction to be 75.0% complete is
Selected Answer:
Correct 462
Which isotope, when bombarded with nitrogen-15, yields the artificial isotope dubnium-260 plus
4 neutrons?
Selected Answer:
Correct
californium-249
The first-order reaction SO2Cl2 --> SO2 + Cl2 is 10% complete in 80. min. How long would it take
for the reaction to be 95% complete?
Answer: 2300 min
The half-life of a first-order reaction does not depend on the initial concentration of reactant.
Answer: True
A radioisotope decays to give an alpha particle and Pb-208. What was the original element?
Selected Answer:
Correct Po
The reaction of nitric oxide to form dinitrogen oxide and nitrogen dioxide is exothermic.
What effect will be seen if the temperature of the system at equilibrium is raised by 25°C?
Selected Answer:
Correct
The partial pressure of NO will increase.
The greater the energy of activation, Ea, the faster will be the reaction.
Answer: False
Sodium hydrogen carbonate decomposes above 110°C to form sodium carbonate, water, and
carbon dioxide.
One thousand grams of sodium hydrogen carbonate are added to a reaction vessel, the
temperature is increased to 200°C, and the system comes to equilibrium. What happens in this
system if another 50 g of sodium carbonate are now added? Answer: The partial pressure of
carbon dioxide will be unchanged.
"A certain reaction A --> products is second order in A. If this reaction is 10.% complete after 20.
s, how long would it take for the reaction to be 90.% complete?"
Answer: 1600 s
The reaction A → B is first-order overall and first-order with respect to the reactant A. The result
of doubling the initial concentration of A will be to,
Answer: double the initial rate
"What is the value of Kc for the reaction CO2(g) + H2(g) <==> H2O(g) + CO(g) when the
equilibrium concentrations of CO, H2, CO2, and H2O are 0.050 M, 0.045 M, 0.086 M and 0.040 M
respectively?"
Answer: 0.52
What is the half-life of a substance that decays to 25% of its original amount in six days?
Answer: 3 days
The value of Kc for the equilibrium 2SO2(g) + O2(g) <==> 2SO3(g) is 5.6x10^4 at 350 C. The
initial pressures of SO2 and O2 are 0.35 and 0.762 atm. The total pressure at equilibrium will be
"Kp is 158 for the equilibrium 2NO2(g) <==> 2 NO(g) + O2(g) Starting with NO2 (g) only, the
partial pressure of NO at equilibrium is 0.25 atm. Calculate the partial pressure [atm] of NO2 at
equilibrium."
Correct 0.5
Consider the following mechanism for the oxidation of bromide ions by hydrogen peroxide in
aqueous acid solution.
H+ + H2O2 H2O+-OH (rapid equilibrium)
H2O+-OH + Br- → HOBr + H2O (slow)
HOBr + H+ + Br- → Br2 + H2O (fast)
Which of the following rate laws is consistent with the mechanism?
Correct Rate = k[H2O2][H+][Br-]
Which one of the following statements about fission and fusion is false?
Correct "For a fission reaction the mass defect (Dm) is negative, whereas for fusion Dm is
positive."
"Kp is 158 for the equilibrium 2NO2(g) <==> 2 NO(g) + O2(g) Starting with NO2 (g) only, the
partial pressure of NO at equilibrium is 0.25 atm. Calculate the partial pressure [atm] of NO2 at
equilibrium."
Correct 0.5
A solution is adjusted from pH 8 to pH 9. The relative concentration of the hydrogen [H?] ion has
changed by a factor of what?
Correct 110
For what order reaction does the half-life get longer as the initial concentration increases?
Correct HI
A solution is prepared by adding 0.10 mol of sodium fluoride, NaF, to 1.00 L of water. Which
statement about the solution is correct?
Correct The solution is basic.
Changing the amount of reactant or product in an equilibrium reaction will always change the
equilibrium position, regardless of the physical state of the substance involved.
Correct TRUE
The reaction quotient, Qc, for a reaction has a value of 75 while the equilibrium constant, Kc, has
a value of 195. Which of the following statements is accurate?
Correct the reaction must proceed to the right to establish equilibrium.
Correct 0.37V
"The equilibrium constant, Kc for the reaction H2(g) + CO2(g) <==> H2O(g) + CO(g) is 4.2.
Initially 0.80 mole of H2 and 0.80 mole CO2 are placed in a 5.0 L flask. At equilibrium, the
concentration of H2 is equal to the concentration of _____."
Correct C02
Which one of the following substances will give an aqueous solution of pH < 7?
Correct NH4Br
The equilibrium pressure of NO2 in the equilibrium N2O4(g) <==> 2 NO2(g) is 1.56 atm. Its pressure
on the addition of a catalyst will be _____.
The equilibrium constant Kc for the equilibrium A + B <==> C + D is X. The equilibrium constant for
the reaction 2C + 2D <==> 2A + 2B is
Correct X^(-2)
Which statement is correct with respect to the above equilibrium when 0.30 moles of CO and 0.30
moles of H2O are heated to 700°C and allowed to reach equilibrium.
Correct Cl2(g)
Correct 0.035V
is at equilibrium. Which of the following statements describes the behavior of the system if the partial
pressure of carbon disulfide is reduced?
Correct Cl-
Ammonium chloride is used as an electrolyte in dry cells. Which of the following statements about a
0.10M solution of NH4Cl, is correct?
For a gas-phase equilibrium, a change in the pressure of any single reactant or product will affect the
amounts of other substances involved in the equilibrium.
Correct TRUE