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h i g h l i g h t s
< Usability of two different vegetable oils in a coated diesel engine was experimentally investigated.
< A diesel engine was coated with ZrO2 layer to make the combustion chamber insulated.
< Test results showed significant improvements in performance parameters.
< While only minor reductions were observed in emissions with coated engine operation.
a r t i c l e i n f o a b s t r a c t
Article history: The possibility of using pure vegetable oils in a thermally insulated diesel engine has been experi-
Received 5 June 2012 mentally investigated. Initially, the standard diesel fuel was tested in the engine, as base experiment for
Accepted 21 October 2012 comparison. Then the engine was thermally insulated by coating some parts of it, such as piston, exhaust
Available online 30 October 2012
and intake valves surfaces with zirconium oxide (ZrO2). The main purpose of engine coating was to
reduce heat rejection from the walls of combustion chamber and to increase thermal efficiency and thus
Keywords:
to increase performance of the engine that using vegetable oil blends. Another aim of the study was to
LHR engine
improve the usability of pure vegetable oils in diesel engines without performing any fuel treatments
Coating
Cottonseed oil
such as pyrolysis, emulsification and transesterification. Pure inedible cottonseed oil and sunflower oil
Sunflower oil were blended with diesel fuel. Blends and diesel fuel were then tested in the coated diesel engine.
Diesel engine Experimental results proved that the main purpose of this study was achieved as the engine performance
parameters such as power and torque were increased with simultaneous decrease in fuel consumption
(bsfc). Furthermore, exhaust emission parameters such as CO, HC, and Smoke opacity were decreased.
Also, sunflower oil blends presented better performance and emission parameters than cottonseed oil
blends.
Ó 2012 Elsevier Ltd. All rights reserved.
1. Introduction occurs when using pure vegetable oils in diesel engines. Direct use
of crude vegetable oils in diesel engines causes some damage to
Vegetable oils are considered as alternative fuel for internal parts of the engine and also, the performance is negatively affected
combustion engines and they are derived from renewable biolog- [5,6]. Besides, using these kinds of fuel in diesel engines result in
ical sources. Also they emit far less regulated pollutants than the worse performance parameters than that of diesel fuel. It has been
standard diesel fuel [1e3]. Among the vegetable oils, sunflower, reported by many researchers that when crude vegetable oils are
canola, hemp, cotton, corn and safflower oils are the most known used as diesel engine fuel, declines can be seen in performance
fuel candidates for diesel engines. The usage of vegetable oils, as parameters with reductions in emission values [7e13]. Importantly,
alternative diesel engine fuel, has been increased rapidly. However, it was reported that the use of vegetable oils and their blends with
due to technical deficiencies, they are rarely used in pure form or diesel fuel helps in controlling air pollution to a great extent [14].
with high percentages in unmodified diesel engines [4]. Without Engine coating with a ceramic thermal barrier can be applied to
engine or oil modification some problems such as poor atomiza- improve reliability and durability of engine performance and effi-
tion, injector sticking and blocking which prevent engine operation ciency in diesel engines. Because in-combustion chamber temper-
atures of coated engines are higher than those of uncoated engines,
it may be possible to use a fuel with a large distillation range and
E-mail address: huseyyinaydin@gmail.com. lower quality fuels such as pure vegetable oils.
1359-4311/$ e see front matter Ó 2012 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.applthermaleng.2012.10.030
624 H. Aydin / Applied Thermal Engineering 51 (2013) 623e629
Table 3 Table 5
Technical specifications of the dynamometer control unit. Chemical and physical properties of test fuels.
Model PC101BMS Fuel type Heat value Viscosity Density Flash Flow Cloud
Accuracy 0.2% kJ/kg mm2/sn (15 C) point C point C point
Precision 1 Digit (40 C)
Response time 600 ms Test method TS 1740 TS 1451 TS 1013 TS EN EN ISO TS 2834
Weight measurement Linear (load-cell) EN ISO EN ISO EN ISO ISO 2719 2719 EN ISO
Speed measurement Sensor 1928 3104 3675 23015
Screen type 3 6 unit, 7-region LED Diesel fuel 42,800 2.5e4.5 0.82e0.86 >55 33 16
2 16 character LCD Cottonseed oil 39,173 27.02 0.8830 218 17 1
Power 16 W Sunflower oil 39,827 31.52 0.9060 262 18 7
Operation temperature 0e50 C CSO15 41,754 3.75 0.842 70 28 12
Operation voltage 220 5% V AC CSO35 40,640 5.6 0.854 120 24 8
Output Printer SFO15 42,600 3.8 0.850 76 28 15
SFO35 41,120 5.6 0.866 134 26 14
3. Experimental results
Table 4
Technical properties of the gas analyzing device.
6,9
6,4
Fig. 5. Curves of engine power variation with speed for test fuels.
Fig. 3. The combustion chamber and piston surface after 100 h of engine operation.
and CFO35 fuels have presented quite similar values with the
remaining test fuels.
decreased again for all test fuels. At lower engine speeds, the main Mean effective pressure values were calculated for each tests
reason for decreased power values is considered to be longer cycle and are presented in Fig. 7. The engine coating can be seen to have
duration due to lower mean piston speed. As for higher engine increased mean effective pressure. It is considered that the pressure
speed, two main reasons can be presented for power reduction: the increase is mainly due to the increased temperature inside cylinder
decreased volumetric efficiency at higher speed and increased thanks to insulation coatings applied to the combustion chamber
mechanical losses. walls.
The torque variations with the use of D2 and blends fuels are Brake specific fuel consumption (Bsfc) values for various test
illustrated in Fig. 6. Generally, when engine speed was increased fuels and engine speeds are given in Fig. 8. Generally, as anticipated,
the torque values for almost all the test fuels showed minor Bsfc values for entire test fuels were decreased when engine speed
increases. However, after 2500 rpm engine speed torque values was increased until the medium speeds and then increased again
were sharply decreased for all the test fuels. This considerable with speed increase. Average Bsfc decrease for D2 operation in
decrease can be attributed to the combined effects of lowered coated engine was 5.56% in comparison to normal D2 operation.
volumetric efficiency and more importantly increased mechanical The similar reductions can be expected for vegetable oils use in
and friction losses. coated engine according to the normal uncoated operation. The
When test fuels were compared, generally coated engine D2 lowest average Bsfc was obtained from the coated engine using D2
operation supplied higher torque values than the remaining fuels. fuel. The highest average Bsfc values were obtained from the usage
This result of torque is consistent with power values at corre- of CSO35 in coated engine operation. It can clearly be seen from the
sponding engine operation conditions. SFO15 and SFO35 fuel power, torque and Bsfc experiments that SFO15 and SFO35 that are
blends had usually better torque and power values when compared the blends of sunflower oilediesel fuel achieved a better perfor-
with CFO15 and CFO35 fuels. The lowest average torque and power mance than the blends of CSO15 and CSO35 which derived from
values were obtained from the engine operation with CFO35. cottonseed oilediesel fuel. Generally, petroleum diesel fuel per-
However, at the lower engine speed the torque values for coated D2 formed a better performance than the vegetable oil blends prob-
ably due to the lower calorific values of vegetable oils. Even though
vegetable oils and their blends with diesel fuel have not been tested
in the coated engine, in this study, the performance of vegetable oil
usage can be said to be improved by engine coating since
20
Engine Torque (NM)
18
16
14
12
10
500 1000 1500 2000 2500 3000
Engine speed (rpm)
Fig. 4. The valves surface after 100 h of engine operation. Fig. 6. Engine torque values for test fuels at different engine speeds.
H. Aydin / Applied Thermal Engineering 51 (2013) 623e629 627
Normal D2 D2 CSO15 CSO35 SFO15 SFO35 Normal D2 D2 CSO15 CSO35 SFO15 SFO35
900 3,5
850 3
800
CO emissions (%)
2,5
750
MEP (kPa)
2
700
650 1,5
600 1
550
0,5
500
500 1000 1500 2000 2500 3000 0
Engine speed (rpm) 1000 1500 2000 2500 3000
Engine speed (rpm)
Fig. 7. Calculated mean effective pressure values for test fuels at different engine
speeds. Fig. 9. CO emission results in different engine speeds for test fuels.
performance parameters of coated engine diesel fuel operation observed from Fig. 10 that HC emissions were considerably
have been increased when compared with uncoated diesel fuel decreased when using vegetable oil blends fuel in diesel engine.
operation. The higher oxygen contented in the vegetable oilediesel blend
fuels take part in combustion and make the combustion environ-
3.2. Emission results ment enriched with oxygen. Hence, the surplus oxygen content
helps to achieve more complete combustion thus results in
When petroleum based fuels are used in an engine the main decreased in-complete combustion products such as HC and CO
toxic substances present in the waste exhaust gases are incomplete emissions. When both coated and uncoated diesel engine experi-
oxides of hydrocarbon containing CO, NOx, HC, soot containing SO2 ments were compared, average HC emissions were found slightly
emissions, particulates and smoke emissions. CO emission is the lower for coated diesel engine operation. Flame ionization detec-
most toxic substance found in exhaust gases and is colorless, tors (FID’s) have been commonly used for sensitive monitoring of
tasteless and odorless. HC and CO emissions are main products of mixtures of hydrocarbon. It has also been stated that their carbon
incomplete combustion. Curves of engine CO emissions with counting ability to integrate, for example, total unburned hydro-
engine speed are presented in Fig. 9. CO emissions were consider- carbon emissions from a source, now is accepted without question
ably decreased for vegetable oil usage in diesel engine. It is one of [22]. On the other hand, as presented in the literature, the FID’s that
the most important and beneficial results of using vegetable oils in are conventionally used for measuring these emissions may have
diesel engines as fuel. This crucial result is achieved thanks to the a lower sensitivity of detecting oxygenated compounds, such as the
oxygen amount inherently contained in the vegetable oils chemical ones that might be present in the exhaust gas when using
construction. When the engine coating is taken into consideration oxygenated fuels like vegetable oils [23e25]. However, the forma-
both two diesel fuel experiments should be analyzed. When both tion of HC emissions is described including both oxygenated and
coated and uncoated diesel engine experiments were compared non-oxygenated compounds [26]. In the meantime, the oxygen
with each other, average CO emissions were found slightly lower contained in the vegetable oils leads to a more complete and
for coated diesel engine operation even though the main purpose of cleaner combustion [23,27]. For this reasons, the measured THC
insulation of the engine was to improve the performance and emissions may be exceedingly low for vegetable oils and blend
usability of vegetable oils in diesel engines. fuels. Therefore, it is generally known that the HC emissions
This surplus benefit can also be seen in HC emission values as decrease in the case of vegetable oil usage in diesel engines similar
they were also decreased for coated engine operation. HC emissions to the results of this study.
results, for all test fuels, can be seen in Fig. 10. It can clearly be
Normal D2 D2 CSO15 CSO35 SFO15 SFO35 Normal D2 D2 CSO15 CSO35 SFO35 SFO15
900
550
800
500
700
HC emissions (ppm)
450
600
Bsfc (g/kWh)
400
500
350
400
300
300
250 200
200 100
150 0
500 1000 1500 2000 2500 3000 1000 1500 2000 2500 3000
Engine speed (rpm) Engine speed (rpm)
Fig. 8. Variation of bsfc values for testing fuels and specified speeds. Fig. 10. Emissions of HC for all the test fuels and different conditions.
628 H. Aydin / Applied Thermal Engineering 51 (2013) 623e629
Normal D2 D2 CSO15 CSO35 SFO15 SFO35 Normal D2 D2 CSO15 CSO35 SFO15 SFO35
250 90
80
NOx emissions (ppm)
200
70
100 40
30
50
20
10
0
1000 1500 2000 2500 3000 0
Engine speed (rpm) 1000 1500 2000 2500 3000
Engine speed (rpm)
Fig. 11. NOx’s emitted by using specified test fuels and at different engine speeds.
Fig. 13. Smoke emissions resulted from test engine with different test fuels.
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