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ALL INDIA TEST SERIES


OPEN TEST

JEE (Advanced)-2019
PAPER – 2

TEST DATE: 03-02-2019

ANSWERS, HINTS & SOLUTIONS


Physics PART – I

SECTION – A

1. B, D
Sol. Distance of image of fish as seen by bird only after refraction is Bird
 2
  (x  h)  (h  y) 2
1
z
1 x image
  (x  h)  (h  y) 1 h
4/3
Fish
Differentiate w.r.t. time y
d 3 17
 ( 6  2)  ( 2  4)   cm/sec
dt 4 2
Similarly we can calculate for 2nd case.

2. C, D
Sol. Collision takes place in ideal gases are elastic hence total kinetic energy will be conserved.

3. A, C, D
2u sin 
Sol. T  2 sin15
g
Horizontal component of velocity will reverse in each collision.
u2 sin2
R 5 m
g

4. A, C
1 2
Sol. In time interval (0 to 3) sec, S  ut  at = 30 m
2

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AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19 2

 30
v average   10 m/s
3
In time interval (0 to 6) sec
v  u  at  40 m/s
 
 v f  vi (5  40)  5 5   20 2
aaverage    m/s
t 6 3

5. A, C
Sol. Deviation Normal
1
1    2 (Clockwise)
50°
2    2  50    (Anti-clockwise)
40°
  1   2
40°

50°
2

6. A
Sol. Ball moves very slowly hence it is in equilibrium at each instant.

7. D
 hC 
N  x
Sol. Intensity is given by I     , where
(A cos  )t  y
N  total number of photons and  
wavelength of photons  90

Px IA cos   sin 


(A) Fx  
t C P Q
Py IA cos  cos 
Fy  
t C
Fy Icos2 
pr  
A C
(B) Fx = 0
2IA cos2 
Fy 
C
2Icos2 
pr 
C
(C) and (D)
IA cos  sin 
Fx  (1  r)
C
IA cos2 
Fy  (1  r)
C
Icos2 
pr  (1  r)
C

8. C
Sol. Circuit can be solved by using Phasor diagram.

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3 AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19

9. A
Sol. By using concept of motional emf induced in the circuit.

10. A
y
Sol.  v 0  2gh  5 m/s …(i) Jy
 Jy = Py = 2  80  5 = 800 N-s …(ii)
 Jx = Px
Jy = mv x Jx x
v0
v x = 1 m/s …(iii) f
 MvC = Jx
Jx f
vC = 0.4 m/s …(iv)
25 Cart
 t0   1 sec …(v)
10
 Lmin = 2(1 + 0.4) 1 = 2.8 m …(vi)
 At the time of second collision
R  1 = 0.4
 = 7 rad/s …(vii)

 J  L
JxR  I(  0 )
0  19.5 rad/sec …(viii)
1
 WmM  Mv C2  16J …(ix)
2
1 1 1
 WMm  I()2  mv 2x  I02  172 J
2 2 2

SECTION – D
11. 00006.92
x normal
Sol. tan 60  Y
2
x2 3m
60
Hence total length = 4 3 m. M2 3030 M1
O

man x x-axis

12. 00035.20
Sol. To reach at ‘B’ it should crosses the point ‘A’. Now from work energy theorem
W = K
W g + W f = K f  Ki
mg(4H)  (0.4)mgH = 0  ki
Ki = 44 mH = 35.20

13. 00002.40
   
Sol. L  Icm   (r  pcm )
 m(2R)2
L  0  R(2m)(R0 )
2

L  4mR2 0 = 2.40

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AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19 4

14. 00016.64
Sol. dsin   (  1)t  x
 3  3
d   x
 2d  2
x = 3
Hence maximum intensity will occur at ‘O’.
I = 4I0 = 16.64 W/m2

15. 00002.67
2E0
Sol. (Mg)  1 = 2
tc
2  20  2 8
M 3 8
=  103 kg
10  0.01 10  3  10 3

16. 00000.74
Sol. pitch = 0.2 mm
Total division = 200
Least count = 0.001 mm
ve zero error = 40  L.C. = 0.04 mm
Reading = 0.6 mm + 100  L.C. = 0.7 mm
Thickness = 0.7 mm + 0.04 mm = 0.74 mm

17. 00002.25
Sol. In time dt shift in centre of mass of system (ball + liquid)
m ds  m2 ds2  b V  vdt    V  vdt
d SCM  1 1  …(i)
M M
dS
Momentum of system = M. cm …(ii)
dt
= (bV) v – (V ) v
Therefore momentum of liquid = (V )v
= 2.25 gm/cm 3.

18. 00002.33
2GM
Sol. Speed of projection  v 0   ...(1)
R
1 GMm 1 GMm
mv 2   mv 2  …(2)
2 R 2 r
2GM
v
r
4R t

 rdr  2GM  dt
R 0
3
7 2R
t .
3 GM

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5 AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19

Chemistry PART – II

SECTION – A
19. A, C
Sol. Main hexagonal unit cell (figure A) consists of three identical smaller unit cells (B).
20. A, C, D
Sol. H3C H3C
Cl Cl
CH3 CH3

Cl Cl
H3C
Cl B 
A
21. B, C, D

22. B, C
Sol. Weight of pay load = 80 × 103 g
Let, the number of balloons required be x.
nRT
80  103  0  100x  x  1.25
P
x = 26.8

23. A, B, D
Sol. O
O O
O3
CH3  CH  CH  CH2  CH3 
 H3C CH CH CH2 CH3

O O
H3 C CH CH CH2 CH3
O

Zn / H2O

CH3  CHO  CH3  CH2  CHO

24. A, B, D
Sol. Cl Cl

Br
 
Mg 1 eqvt int ramolecular nucleophilic substitution

ether
  N
N N
H MgBr

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AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19 6

O O O OH
H
Br
H 
 Br  Br

 

Tautomerism


NH NH2 NH2 NH2

25. A
26. C
Sol. NaCl type solid CsCl type solid
a 3a
1st nearest distance
2 2
a
2nd nearest distance a
2
3a
3rd nearest distance 2a
2
11a
4th nearest distance a
2
5a
5th nearest distance 3a
2
3a
6th nearest distance 2a
2
27. C
Sol. General property trends.
28. A
Sol. O O

OH
i MCPBA
  OH
ii dil. H2SO4
O
O
H 
dil. OH
  
O
O
O

+  3
C OH
NK 
i CH Cl
  CH3NH2
ii  Dil. H
C OH

O O
Na/C2H5 OH
CH3NC  CH3  NH  CH3

SECTION – D
29. 00002.50

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7 AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19

 n2a 
Sol.  P  2   V  nb   nRT
 V 
n=1
 a 
 P  V 2   V  b   RT
 
If ‘b’ is negligible, then
 a  RT a
 P  V 2  V  RT , P  V  V 2
 
The equation is quadratic in ‘V’, thus
RT  R2 T 2  4aP
V
2P
‘V’ has one value at a given P and T, thus numerical value of discriminant = 0
So, R2 T 2  4aP
2 2
R2 T 2  0.08    300 
P   40
4a 4  3.6
30. 00000.50
 2x 
Sol.   x   A sin  
  
d  x  2  2x 
 A cos  
dx    
d2  x   2 
2
 2x 
2
    A sin   So, n = 2, m = -4, p = 2, q = 2
dx      
d2  x  4 2   x 

dx 2 2

31. 00015.05
Sol. Complex Magnetic moment
2
 Cu NH3 4  3  1.73 B.M.
3
Fe  CN6  3  1.73 B.M.
 
2
NiCl4  2 2  2.82 B.M.
3
CoF6  24  4.90 B.M.

Fe H2O 5 NO   SO 4 15  3.87 B.M.

32. 00054.50
Sol. x = 22.5; y = 30; z = 2
In parallel reactions the activation energy of the overall path is given by
k1Ea1  k 2Ea2
Ea net 
k1  k 2

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AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19 8

33. 00007.50
 2
Sol. 2  Au  CN2   Zn  2Au  Zn  CN4 
Eo  0.60   1.26   0.66 V
o + +
Since E value for the reduction of complexed Ag ion to Ag is higher than that of complexed Au
+
ion into Au. So, Ag ion will be reduced first.
78
Moles of Zn added   1.2
65

Moles of [Ag(CN)2] = 0.003 × 500 = 1.5
Moles of [Au(CN)2]– = 0.002 × 500 = 1.0

Moles of Zn used to reduce 1.5 moles of [Ag(CN)2] = 0.75

Moles of [Au(CN)2] reduced by remaining 0.45 moles of Zn = 0.90
Moles of [Au(CN)2]– left in the solution = 0.10
– 0.10
Concentration of [Au(CN)2] left in the solution   2  10 4 M  x
500



  Au  CN2  , K f  4  10
Also, Au  2CN 
28


 Au  CN2  90  Au 
Kf    4  10 28
  2   2
 Au  CN  10  Au  CN 
CN   1.5  1014 M  y
y 1.5  10 14
So,   7.50  10 11
x 2  10 4
So, A = 7. 50

34. 00367.50
Sol. Let, the moles of KClO3 required to be ‘x’. Assuming 50% yield in each step.
x
Moles of O2 formed in step (i)  .
2
x
Moles of each of K2MnO4 and Cl2 formed in (i) 
4
x
Moles of O2 formed in step (ii) =
8
x x 5x
Total moles of O2 formed  
2 8 8
5x 60

8 32
x=3

35. 00000.80
Sol. Tf  i  K f  m
0.00558 = i × 1.86 × 0.001 i  3
i  1   y  1  1  3 y  3
So, formula of the complex Pt NH3 4 Cl2  Cl2

36. 00004.50
Sol. x = 3, y = 15, z = 10

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9 AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19

Mathematics PART – III

SECTION – A

37. A, B, C, D
Sol. A + B = ABAB = A2 + A
2
B=A
BAB = A5 = A + I  A(A4 – I) = I
B5 – A5 = (A5)2 – A5 = (A + I)2 – (A + I) = A2 + A = A + B

38. A, D
x
Sol. Let f(a) = 0 and F  x    f  t  dt
0
F(x) = –f(x) 0  x < a, F(x) = f(x) a  x  1
2 2
1
x  F 1   F a 2 =  S1  S2   S 2  7
  f  x    f  t  dt  dx 
  2
   2
 2
0 0 

39. B, C
b b b
tan  
tan  1 1
Sol. tan   a = a  a  ab
b b
1  tan2  cot   tan  2 b 2 ab
a a a
A(a cos , a sin )

B(–a sin , a cos ) P(a cos , b sin )



Q 

Q(a sin , –b cos )

b b 2b
tan   cot 
a a  2ab 
tan   2
 a 2  2 2 
b b  a b 
1 2 1 2
a a

40. A, C
393  n  5 
Sol. n2  5  2n  5    n2  25
5
 73.6  n  83.6, n = 80 is only possible value

41. B, C
 x  x
1  x 2 tan  2
  2 1  x sin  3x
 2
 1 x  1 x2
Sol. lim
x 0 xp
Using expansion

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AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19 10

 
 x x3 2 x5 
1  x2   3
 5
.....  
 1  x 2 15 
 
3 1  x2  2
1 x2 2  
 
 2x x3 x5 
2 1 x   3
 5
.....   3x
 1  x 2 
lim  
3! 1  x 2  2

5! 1  x 2 2  
x 0 xp
 
 2  2 1

2  x5
 3 15 2 2 

lim 

1 x2  
5! 1  x 2  

x 0 xp
2 2 2 31
 p = 5 and limit =    
3 15 5! 60

42. A, B, D
Sol. All the values of |A| = 4, 0 and determinant is 0 when two rows/columns are proportional

43. B
Sol. (P) d2 3
(Q) These lines are skew and O lies on shortest distance
(R) Lines are parallel and O lies mid way between them (1, 1, –1)  (A, B)
(S) Lines are coplanar and perpendicular
O

44. D
Sol. We can consider 9 cells as 9 different boxes and we have to fill these boxes by 3 identical balls
(2 written on them), 4 identical balls (3 written on them) and 7 identical balls (5 written on them)
as per given conditions

45. A
Sol. (P) x2 – a = x
x2 – x – a = 0
D<0
1 + 4a < 0
1
a
4

(Q)  a  a
a a
a > a2
2
a –a<0
a(a – 1) < 0
0<a<1 (–a, 0)
One real
 a,0   a,0 
1
a (0, –a) One real
4

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11 AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19

(R) x2 – x – a = 0
1 + 4a > 0, –a > 0
1
a ,a<0
4
1
 a0
 a, 0 
4 (–a, 0) Two real
a   a One real
a  a , a2 > a (–a, 0)
a(a – 1) > 0, a  1

46. A
Sol. For regular quadrilateral n must be multiple of 4. Perpendiculars dropped from a plane
5
C 8C
circumcentre to side is always collinear. For one of the side to be diameter P  E   101 1 and
C3
9
C1 4 C2 5
orthocentre is inside for acute angled triangle P  E   1  9

C3 14

SECTION – D
47. 00021.00
a d 1 a d 1
Sol. b e 1  5 b e 2  3
c f 1 c f 3
a d 1 a d 1
2 b e 2  3 b e 1  21
c f 3 c f 1
a d 1
b e 1  21
c f 3

48. 00009.00
1 a1
Sol. Take an  n
, on solving, we get an  ,
 2  tn  2   2 n  n 1
a1     2 
 6 
 
 2   2 n 
for periodicity a1     2 n1  1 ,
 6 
 
n
 2   2  
for undefined a1     2 n 1  0 ,
 6 
 
lim an  0
n 

49. 01600.00
6 3
Sol. x – 2x – 8 = (x – 1)(x – 2) .....(x – 6)
6 3
(2) – 2(2) – 8 = (2 – 1)(2 – 1) ..... (2 – 6)
((2 ) – 2(22)3 – 8) = (22 – 1) ..... (2 – 6)
2 6

On multiplying (40)2 = g(1)g(2) ..... g(6)

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AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19 12

50. 00062.00
2014 r 2014
k
Sol.    1  k  1k  2  2019 Cr k   2 2016 Cr  22017  4034
r 0 k 0 r 0

51. 00061.25
dx  x 1  x 1
Sol. e  e  3
dy y y
d x 1 1
dy
 
e y   2 , e x y   c
y y

52. 00018.00
Sol. Area PRST = PQR – QST
1 1 1 

P 3, 2 3 
= 8  2 3    4  4 sin150º 
2 2 2  T
= 8 3 2 3  6 3
30º
Q S R

53. 00009.00
y y
2 y3
Sol.   
x 4   y  3  y   dx   x 2  y  3  y  dx 
3
 y2 3  y 
0 0
3
y
f  y   y2 3  y 
3
f(y) = y2 + 6y – 3y2 = 2y(3 – y) > 0 for 0  y  3 so maximum occurs at y = 3

54. 00056.25
Sol. Given expression is r1r2 + r2r3 + r1r3 = s2 = (7.5)2

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