Beruflich Dokumente
Kultur Dokumente
PRESENTED BY
MD. SHAHJALAL
SAMUDA CHEMICAL COMPLEX LTD,
BANGLADESH.
PROPERTIES OF CHLORINE
.
▪ Liquid chlorine is 1.5 times heavier than water.
Gaseous chlorine is 2.5 times heavier than air. And tends settle down near ground
level.
Neither liquid nor gaseous chlorine is explosive or flammable but both react
chemically with many organic and inorganic substance such as either turpentine,
ammonia, Hydrocarbon etc.
Chlorine does not burn but supports combustion. The volume of liquid chlorine
increase with increase the temperature. Precaution must be taken to build up of
excessive pressure in containers by ensuring vapor space for expansion of liquid
chlorine.
One volume of liquid chlorine vaporizes into about 458 volume of gas at 0º C and
1 atmospheric pressure.
Chlorine gas is highly corrosive to the most metal in the presence of moisture due
to formation of Hydrochloric acid and Hypo-chlorus acid.
Cl2 + H2O = HCl +HOCl
CHLORINE GAS BURNING WITH HYDROGEN GAS
HANDLING AND TRANSPORTATION OF CONTAINERS
Ton containers should be handled with suitable lifting or chain slings in combination
with a hoist or crane having at least 3 Ton capacity. Chlorine cylinders should not be
lifted with rope slings, chain or magnetic device or by fork lift.
Container should not be permitted to drop and no object should be allowed to strike
them with force.
The vehicle carrying filled or partially filled chlorine cylinders should be covered by
tarpaulins as direct exposure to sun can raise temperature much beyond the safe limits.
The vehicle in which container are kept should not carry flammable items including oil,
Paints, grease etc.
Do not roll container on the rough surface to avoid damage to the paint or surface of
the container.
Both valve of cylinders should be tightened by jam nuts and valve protection hood
should be secured in right position.
In case the driver of the vehicle detected any leakage on the way. He must take the
vehicle to an open and isolated area to minimize the hazardous of chlorine gas leakage.
An emergency kit should be available in every vehicle used for transportation
containers. As a minimum requirement, an emergency must contain one set of valves
and surface leak arrestor assembly and personal protection equipment such as Gas
mask, Oxygen Cylinders, Safety hand Gloves and safety Goggles .
CHLORINE CYLINDER HANDLING PROCEDURE
Proper handling of
Improper Handling of
chlorine cylinder
chlorine cylinders
STORAGE OF CONTAINERS
Operator handling filled or empty chlorine cylinders must wear face mask, hand gloves and
gum boots.
Check and clean coupling threads thoroughly and replace gaskets before fitting plugs or
valves with the containers. Also avoid over tightening of valves or plugs as this may cause
damage to the threads.
The external surface of the container should be inspected to check any dents, heavy pitting
or leaks and exposure to fire.
To be continued
OPERATING CONTAINER
Container should be emptied in the gas phase and set in a horizontal portion. Valves
in a vertical plane will deliver gas from the upper valve and liquid from the lower
valves.
Ensure that water or any other liquid is not sucked back due to pressure gradient. At
least 5 kg of volume of chlorine should be left in the container before sending it for a
refilling and inside pressure of the container should be 0.5 kg/cm2 of chlorine in the
container is recommended to avoid the back flow of any liquid from the system.
The rate of delivery of gases chlorine should not be increased by spraying hot water
for increasing discharge rate. Use force circulation of room temperature air around
the container.
Every cylinders must be emptied of its residual gas by venting. Venting gas must be
neutralized by absorption in lime water.
Use of pipe wrench or improper size spanner should be avoided as this would cause
damaged in the valve spindle leading to leakage.
When the container is empty, the valves of the container should be closed by rotating
the spindle clockwise and tested the leaks.
The container valves should not be used for maintaining chlorine flow as frequent
operation may damage the valves spindle.
To find the leak a small cloth to the end of a stick soak the cloth with strong ammonia
solution to hold it to the suspected area. A white cloud of ammonia chloride will result
if there is any chlorine leakage. All chlorine user must ensure that they have ammonia
Torch ready and handy.
MARKING AND LABELING
Each container of chlorine shall be marked legibly. The marking shall include the following
Certificate of analysis with indications of country of origin shall accompany all delivers for the chemical and being given to
the end users.
The content of the certification of analysis shall include the following
Chlorine content, % v/v.
Water content % W/W
Residual on evaporation, mg/kg
Nitrogen tri-chloride (NCl3), mg/kg.
Circulation tower
ATTACHED DURING DELIVERY WITH CHLORINE CYLINDERS
Thickness
Mask meter
3 ton capacity over Head crane Checking leak test with ammonia torch along
with oxygen cylinder
CHLORINE CYLINDERS HYDRAULIC TEST PROCEDURE
Checking
thickness
DIFFERENT PARTS OF LIQUID CHLORINE STORAGE TANKS AND
SPECIFICATION OF CHLORINE STORAGE TANKS :
Specification of liquid chlorine storage tanks :
Thickness of chlorine storage tanks = 20 mm
Corrosion allowance = 4.50 mm.
Operating pressure = 12 kg/cm2
Design Pressure = 18 kg/cm2.
Test pressure = 23.40 kg/cm2
Liquid chlorine filling ratio = 1 : 1.19.
Volume of the chlorine storage tank= 40 M3.
Safety valve pressure released to Hypo = 17.50 kg/Cm2
Re-testing after two years.
Average life 20-25 years.
❖ Low and High level alarm ,10% low and 75% high.
❖ High and low pressure alarm ,2.5 kg/cm2 low and 12.0 kg/cm2 is high.
❖ Double safety valves open at 17.50 kg/cm2.
❖ Double valve of each line of international standards.
❖ One tank is always empty.
❖ Each tank is connected emergency release line to neutralization line or to Hypo.
❖ Chlorine detector installed in the storage area.
❖ Adequate distance between two storage tanks.
❖ Tanks location at sufficient distance from the hazards chemicals.
LIQUID CHLORINE TRANSFER OPERATION FROM FILLED
STORAGE TANKS TO CHLORINE TONNER / CYLINDERS
LEAK DETECTION & PREVENTION.
Leak detection : There is any indication of the presence of chlorine in the air, skilled person
equipped with personal protective equipment should investigate promptly. All other person
should be kept away from the affected area.
Identifying and stopping the leakage :
▪ Valve steam Packing (3.0.1)
▪ Through valve seat (3.0.1)
▪ Valve inlet threads. (3.0.1)
LEAK DETECTION AND PREVENTION