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1000
PBMA
10
1
-3 -2
10 10
Water evaporation at Annealing at
q (A-1)
TgPBMA <T<TgPS T >TgPS
Schema 1: Description of the experimental procedure. Figure1. Evolution of the scattering intensity at different
annealing times of 80 nm dPS in 10% crosslinled PBMA
(□) before annealing; (■) 4 min, (∆) 17 min and (▲) 37
min. The films were annealed at 140 °C.
900 4
3
Intensity (arb. unit)
Log(aT)
600 2
1
300
0
0 10 20 30 40 -1
0.9 0.92 0.94 0.96 0.98
time (min)
Tg/T
Figure 2. The evolution of the scattering intensity at q = 0.0054 Å-1 as a Figure 3. The time-temperature shift factor aT
function of the annealing time for 80 nm dPS in PBMA matrix. The plot calculated from the decays at different temperatures
is fitted to a single exponential (continuous line) with a τ = 5.4 minutes using 140°C as the reference temperature, plotted vs.
the temperature.
References
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