1.

      At 460 °C, the reaction

SO2(g ) + NO2(g ) NO(g ) + SO3( g)

has K c = 85.0. If 0.0255 mol of SO2, 0.0600 mol of NO2, 0.0800 mol of NO, and 0.0446 mol of SO3 are placed in a 10.0 L
container at this temperature, how many grams of each gas will be present when the mixture reaches equilibrium? What
will the total pressure of the system be at equilibrium? S = 32; O = 16; N= 14.

SO2(g ) + NO2(g ) NO(g ) + SO3( g)

I 0.00255 0.006 0.008 0.00446 Q= 2.332026 < Kc
C -x -x x x
E (.00255-x) (0.006-x) (0.008+x) (0.00446+x)

85 x^2 -0.00855 1.53E-05 = x^2 0.01246 x 3.568E-05

ax^2+bx+c=0
a= 84 x= 0.0023256577
b= -0.73921
c= 0.001265
SO2 NO2 NO SO3
E (M) 0.000224 0.003674 0.010326 0.006786 Q= 85 = Kc
Mr 64 46 30 80
E(mol) 0.0022 0.0367 0.1033 0.0679
E(g) 0.144 1.690 3.098 5.429

Mol total= 0.2101

P=nRT/V V= 10 L P= 1.265 atm
n= 0.2101 mol
T= 733 K
R= 0.08215 L atm/mol K
2)
If 0.3902 g of fluoroacetic acid (FCH2COOH, HFA, pKa = 2.66; BM 78.04 g / mol) is dissolved with water to 500.0 mL, what is
the pH of the solution? What is the concentration of [HFA] on equilibrium and percent dissociation of HFA?

Massa HFA 0.3902 M Mr= 78.04 g/mol Vol= 500 mL

C_HFA= 0.01 M
pKa= 2.66
Ka= 2.19E-03
H-FA+ H2O ============== H3O+ + FA-

ax^2+bx+c=0
a= 1 x= 0.0037 atau 3.71E-03 %Dis= 37.10%
b= 2.19E-03 [H3O+]= 0.0037 atau 3.71E-03 M
c= -2.19E-05 [HFA]= 0.0063 atau 6.29E-03 M
[FA-]= 0.0037 atau 3.71E-03
pH= 2.43 2.43
3)
1.    Tris buffer (tris (hydroxymethyl) aminomethane, Mr = 121.14 g mol-1} is prepared by reacting the basic tris with HCl solution
as follows:
OH OH

HO OH Tris + HClTris·HCl. HO OH
NH2 NH3+Cl-

If 6.057 g of Tris base is dissolved in 900 mL water then 42.0 ml of HCl 0.1 M and water is added to 1 L volume. What is the pH
of the buffered solution obtained? Given pKa for Tris HCl = 8,07.

Diketahui=
pKa= 8.07
massa Tris= 6.057 g Mr= 121.14 g/mol
Tris= = 0.05 mol
HCl= 42 mL 0.1 M = 0.0042 mol
[Tris]= mol Tris - mol HCl = 0.0458 mol
[Tris-HCl]= mol HCl = 0.0042 mol

pH=pKa + log [Tris]/[Tris-HCl]

pH= 9.11