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ETOOS Comprehensive Study Material

For JEE- Main & Advanced
 REDOX REACTION AND EQUIVALENT CONCEPT

Oxidation & Reduction

Let us do a comparative study of oxidation and reduction :

Oxidation Reduction
1. Addition of Oxygen 1. Removal of Oxygen
Ex. 2Mg + O2  2MgO Ex. CuO + C  Cu + CO

2. Removal of Hydrogen 2. Addition of Hydrogen

Ex. H2S + Cl2  2HCl + S Ex. S + H2  H2S
3. Increase in positive charge 3. Decrease in positive charge
Ex. Fe2+  Fe3+ + e– Ex. Fe3+ + e–  Fe2+

4. Increase in oxidation number 4. Decrease in oxidation number

(+2) (+4) (+7) (+2)
Ex. SnCl2  SnCl4 Ex. MnO4–  Mn2+
5. Removal of electron 5. Addition of electron
Ex. Sn2+  Sn4+ + 2e– Ex. Fe3+ + e–  Fe2+

Oxidation Number
It is an imaginary or apparent charge developed over atom of an element when it goes from its elemental free state
to combined state in molecules.
It is calculated on basis of an arbitrary set of rules.
It is a relative charge in a particular bonded state.
In order to keep track of electron-shifts in chemical reactions involving formation of compounds, a more practical
method of using oxidation number has been developed.
In this method, it is always assumed that there is a complete transfer of electron from a less electronegative atom to
a more electronegative atom.

Rules governing oxidation number

The following rules are helpful in calculating oxidation number of the elements in their different compounds. It is to
be remembered that the basis of these rule is the electronegativity of the element .

Fluorine atom
Fluorine is most electronegative atom (known). It always has oxidation number equal to –1 in all its compounds
Oxygen atom
In general and as well as in its oxides , oxygen atom has oxidation number equal to –2.
In case of (I) peroxide (e.g. H2O2, , Na2O2 ) is –1,
(II) super oxide (e.g. KO2) is –1/2
(III) ozonide (e.g. KO3) is –1/3
(IV) in OF2 is + 2 & in O2F2 is +1

Hydrogen atom
In general, H atom has oxidation number equal to +1. But in metallic hydrides ( e.g. NaH, KH), it is –1.

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CHEMISTRY FOR JEE MAIN & ADVANCED

6 + (–2)
Now, you can also calculate Average Oxidation number of S = = + 2 (as we have calculated before)
2
ETOOS KEY POINTS
Miscellaneous Examples
In order to determine the exact or individual oxidation number we need to take help from the structures of the
molecules. Some special cases are discussed as follows:
O O
(i) The structure of CrO5 is Cr
||
O O O

From the structure, it is evident that in CrO5 there are two peroxide linkages and one double bond. The contribution
of each peroxide linkage is –2. Let the oxidation number of Cr is x.
 x + (–2)2 + (–2) = 0 or x = 6
 Oxidation number of Cr = + 6 Ans
O
(ii) The structure of H2SO5 is H O O S
O
H O
From the structure, it is evident that in H2SO5, there is one peroxide linkage, two sulphur-oxygen double bonds
and one OH group. Let the oxidation number of S = x.
 (+ 1) + (– 2) + x + (–2) 2+ (–2) + 1 = 0
or x+ 2–8=0 or x–6 =0 or x= 6
 Oxidation number of S in H2SO5 is + 6 Ans.

Paradox of fractional oxidation number

Fractional oxidation number is the average of oxidation state of all atoms of element under examination and the
structural parameters reveal that the atoms of element for whom fractional oxidation state is realised a
actually present in different oxidation states. Structure of the species C3O2, Br3O8 and S4O62– reveal the following
bonding situations :
The element marked with asterisk (*) in each species is exhibiting different oxidation number from rest of the atoms
of the same element in each of the species. This reveals that in C3O2, two carbon atoms are present in +2 oxidation
state each whereas the third one is present in zero oxidation state and the average is + 4/3. However, the realistic
picture is +2 for two terminal carbons and zero for the middle carbon.
2 0 2
O  C C*  C O
Structure of C3O2
(Carbon suboxide)
Likewise in Br3O8, each of the two terminal bromine atoms are present in +6 oxidation state and the middle bromine
is present in +4 oxidation state. Once again the average, that is different from reality, is + 16/3.

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 REDOX REACTION AND EQUIVALENT CONCEPT

wt. in g
1. Number of moles of molecules =
Mol. wt.
wt. in g
Number of moles of atoms =
Atomic mass
Volume at STP
Number of moles of gases =
Standard molar volume
Number of particles
Number of moles of particles, e.g. atoms, molecular ions etc. =
Avogadro No.
Moles of solute in solution = M × V(L)

Atomic wt.
2. Equivalent wt. of element =
Valence
Mol.wt.
Equivalent wt. of compound =
Total charge on cation or anion
Mol wt.
Equivalent wt. of acid =
Basicity

Mol wt.
Equivalent wt. of base =
Acidity

Formula wt.
Equivalent wt. of an ion =
Charge on ion

Molecular wt.
Equivalent wt. of acid salt =
Replaceable H atom in acid salt
Mol.wt.
Equivalent wt. of oxidizing or reducing agent =
Change in oxidation number per mole
wt.in g
No. of equivalent = N × V(L) =
Eq.wt.

Ws ×1000 x × d ×10
3. Molarity (M) = =
Ms × V Ms
where
Ws = wt. of solute in g
Ms = Mol. wt. of solute
x = % by mass of solute
d = density of solution in g/ml
V = volume of solution in ml

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 REDOX REACTION AND EQUIVALENT CONCEPT

SOLVED EXAMPLES
Ex. 1 The weight of sodium bromate required to prepare 55.5 mL of 0.672 N solution for cell reaction,
BrO3– + 6H+ + 6e–  Br– + 3H2O, is
(A) 1.56 g (B) 0.9386 g (C) 1.23 g (D) 1.32 g
Sol. Meq. of NaBrO3 = 55.5 × 0.672 = 37.296
Let weight of NaBrO3 = W
W
 × 6 × 1000 = 37.296 (equivalent weight = M/6) of n-factor = 6
M NaBrO3
M
 × 6 × 1000 = 37.296
151
 W = 0.9386 g
Hence, (B) is the correct answer.

Ex. 2 NaIO3 reacts with NaHSO3 according to equation

IO3– + 3HSO3–  I – + 3H+ + 3SO42–
The weight of NaHSO3 required to react with 100 mL of solution containing 0.68 g of NaIO3 is
(A) 5.2 g (B) 0.2143 g (C) 2.3 g (D) none of the above
0.68
Sol. Meq. of NaHSO3 = Meq. of NaIO3 = N × V = × 6 × 1000 (I 5+ + 6e–  I –)
198
WNaHSO3 0.68
 × 2 × 1000 = × 6 × 100
M NaHSO3 198
0.68 × 6 × 100 × 104
WNaH SO 3 = = 0.2143
198 × 1000
Hence (B) is the correct answer.

Ex. 3 If 0.5 moles of BaCl2 is mixed with 0.1 moles of Na3PO4, the maximum amount of Ba3(PO4)2 that can be formed is
(A) 0.7 mol (B) 0.5 mol (C) 0.2 mol (D) 0.05 mol
Sol. Let us first solve this problem by writing the complete balanced reaction.
3BaCl2 + 2Na3PO4  Ba3(PO4)2  + 6NaCl
3
We can see that the moles of BaCl 2 used are times the moles of Na 3PO 4. Therefore, to react with
2
3
0.1 mol of Na3PO4, the moles of BaCl2 required would be 0.1 × = 0.15. Since BaCl2 is 0.5 mol, we can conclude that
2
3
Na3PO4 is the limiting reagent. Therefore, moles of Ba3(PO4)2 formed is 0.1 × = 0.05 mol.
2
Hence, (D) is the correct answer.

Ex. 4 A 0.1097 g sample of As2O3 required 36.10 mL of KMnO4 solution for its titration. The molarity of KMnO4 solution is.
(A) 0.02 (B) 0.04 (C) 0.0122 (D) 0.3

Sol. n-factor = 5

As2O3 + MnO4– 2AsO43– + Mn2+

n-factor = 4

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 REDOX REACTION AND EQUIVALENT CONCEPT

Exercise # 1 [Single Correct Choice Type Questions]

1. Which reaction does not represent autoredox or disproportionation :-
(A) Cl2 + OH–  Cl– + ClO3– + H2O (B) 2H2O2  H2O + O2
(C) 2Cu+  Cu+2 + Cu (D) (NH4)2Cr2O7  N2 + Cr2O3 + 4H2O

2. Match List-I (Compounds) with List-II (Oxidation states of nitrogen) and select answer using the codes given below
the lists :-
List-I List-II
(A) NaN3 1. +5
(B) N2H2 2. +2
(C) NO 3. –1/3
(D) N2O5 4. –1
Code : (A) (B) (C) (D)
(A) 3 4 2 1
(B) 4 3 2 1
(C) 3 4 1 2
(D) 4 3 1 2

3. Which of the following is a redox reaction :-

(A) 2 CrO42– + 2H+  Cr2O72– + H2O (B) CuSO4 + 4 NH3  [Cu(NH3)4] SO4
(C) Na2S2O3 + I2  Na2S4O6 + NaI (D) Cr2O72– + 2OH–  2 CrO42– + H2O

4. 50 mL of 0.1 M solution of a salt reacted with 25 mL of 0.1 M solution of sodium sulphite. The half reaction for the
oxidation of sulphite ion is :-
SO32– (aq) + H2O ()  SO2– +
4 (aq) + 2H (aq) + 2e
–

If the oxidation number of metal in the salt was 3, what would be the new oxidation number of metal :
(A) zero (B) 1 (C) 2 (D) 4

5. An element A in a compound ABD has oxidation number An–. It is oxidised by Cr2O72– in acid medium. In the
experiment 1.68 × 10–3 moles of K2Cr2O7 were used for 3.26 × 10–3 moles of ABD. The new oxidation number of A after
oxidation is
(A) 3 (B) 3 – n (C) n – 3 (D) +n

6. The incorrect order of decreasing oxidation number of S in compounds is :-

(A) H2S2O7 > Na2S4O6 > Na2S2O3 > S8 (B) H2SO5 > H2SO3 > SCl2 > H2S
(C) SO3 > SO2 > H2S > S8 (D) H2SO4 > SO2 > H2S > H2S2O8

7. In which of the following reaction is there a change in the oxidation number of nitrogen atoms :-
(A) 2 NO2  N2O4 (B) NH3 + H2O  NH4+ + OH–
(C) N2O5 + H2O  2HNO3 (D) none

8. In the reaction
xHI + yHNO3 NO + I2 + H2O
(A) x = 3, y = 2 (B) x = 2, y = 3 (C) x = 6, y = 2 (D) x = 6, y = 1

9. For the redox reaction :

MnO4– + C2O42– + H+ Mn2+ + CO2 + H2O
the correct stoichiometric coefficients of MnO4–, C2O42– and H+ are respectively
(A) 2,5,16 (B) 16,5,2 (C) 5,16,2 (D) 2,16,5

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CHEMISTRY FOR JEE MAIN & ADVANCED

Exercise # 2 Part # I [Multiple Correct Choice Type Questions]

1. In the titration of K2Cr2O7 and ferrous sulphate , following data is obtained :

V1 mL of K2Cr2O7 solution of molarity M1 requires V2 mL of FeSO4 solution of molarity M2.
Which of the following relations is/are true for the above titration :
(A) 6 M1V1 = M2V2 (B) M1V1 = 6 M2V2 (C) N1V1 = N2V2 (D) M1V1 = M2V2

2. Choose the correct statement(s) :

(A) 1 mole of MnO4– ion can oxidise 5 moles of Fe2+ ion in acidic medium.
(B) 1 mole of Cr2 O72– ion can oxidise 6 moles of Fe2+ ion in acidic medium.
(C) 1 mole of Cu2S can be oxidised by 1.6 moles of MnO4– ion in acidic medium.
(D) 1 mole of Cu2S can be oxidised by 1.33 moles of Cr2O72– ion in acidic medium.

3. Which of the following samples of reducing agents is /are chemically equivalent to 25 mL of 0.2 N KMnO4 to be
reduced to Mn2+ and water :
(A) 25 mL of 0.2 M FeSO4 to be oxidized to Fe3+
(B) 50 mL of 0.1 M H3AsO3 to be oxidized to H3AsO4
(C) 25 mL of 0.1 M H2O2 to be oxidized to H+ and O2
(D) 25 mL of 0.1 M SnCl2 to be oxidized to Sn4+

4. 0.1 M solution of KI reacts with excess of H2SO4 and KO3 solutions, according to equation
5– + O3– + 6H+  32 + 3H2O ; which of the following statements is/are correct :
(A) 200 mL of the K solution react with 0.004 mole KIO3.
(B) 100 mL of the K solution reacts with 0.006 mole of H2SO4.
(C) 0.5 litre of the K solution produced 0.005 mole of I2.

 Molecular Weight 
(D) Equivalent weight of KO3 is equal to  .
 5 

5. Consider the redox reaction 2S2O32– + 2  S4O62– + 2 – :

(A) S2O32– gets reduced to S4O62– (B) S2O32– gets oxidised to S4O62–
(C) 2 gets reduced to – (D) 2 gets oxidised to –

6. There are two sample of HCl having molarity 1N and 0.25 N. Find volume of these sample taken in order to prepare
0.75 N HCl solution. (Assume no water is used) :
(A) 20 mL, 10 mL (B) 100 mL, 50 mL (C) 40 mL, 20 mL (D) 50 mL, 25 mL

7. To a 25 ml H2O2 solution excess acidified solution of KI was added. The iodine liberated 20 ml of 0.3 N sodium
thiosulphate solution. Use these data to choose the correct statements from the following :
(A) The weight of H2O2 present in 25 ml solution is 0.102 g
(B) The molarity of H2O2 solution is 0.12 M
(C) The weight of H2O2 present in 1 L of the solution is 0.816 g
(D) The volume strength of H2O2 is 1.344 L

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CHEMISTRY FOR JEE MAIN & ADVANCED

Exercise # 3 Part # I [Matrix Match Type Questions]

1. Column-I Column-II
Molecular weight
(A) Eq. wt. = (p) When CrI3 oxidises into Cr2O72– and IO4–
33
Molecular weight
(B) Eq. wt. = (q) When Fe(SCN)2 oxidises into Fe3+, SO42–, CO32–
27
and NO3–
Molecular weight
(C) Eq. wt. = (r) When NH4SCN oxidizes into SO42–, CO32– and
28
NO3–
Molecular weight
(D) Eq. wt. = (s) When As2S3 oxidises into AsO3– and SO42–
24

2. Column-I Column-II
(A) When Bi2S3 converted into Bi5+ and S (p) 18
(B) When Al2(Cr2O7)3 reduced into Cr3+ in (q) 11
acidic medium
(C) When FeS2 converted into Fe2O3 and (r) 2
SO2
(D) When Mn(NO3)2 converted into (s) 10
MnO42–and NO

3. Column-I Column-II
3M
(A) P2H4 →PH3 + P4H2 (p) E=
4

3M
(B) I2 →I – + IO3– (q) E=
5

15M
(C) MnO4– + Mn2+ + H2O →Mn3O4 + H+ (r) E=
26

5M
(D) H3PO2 →PH3 + H3PO3 (s) E=
6

4. Column-I Column-II
(A) Molarity (p) Dependent on temperature
MA × n A
(B) Molality (q) x 100
n A M A + n BM B
(C) Mole fraction (r) Independent of temperature
XA
(D) Mass % (s) XBMB × 1000
Where MA , MB are molar masses, nA , nB are no of moles & XA , XB are mole fractions of solute and solvent
respectively.

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 REDOX REACTION AND EQUIVALENT CONCEPT

Exercise # 4 [Subjective Type Questions]

1. KMnO4 oxidizes Xn+ ion to XO3–, itself changing to Mn 2+ in acid medium. 2.68 × 10–3 mole of Xn+ requires
–3 –
1.61 × 10 mole of MnO4 . What is the value of n? Also calculate the atomic mass of X, if the weight of 1g equivalent
of XCln is 56.

2. In a quantitative determination of iron in an ore, an analyst converted 0.40 g, of the ore into its ferrous. This required
40.00 mL of 0.1 N solution of KMnO4 for titration.

(i) How many milliequivalents of KMnO4 does 40.00 mL of 0.1 N solution represent?

(ii) How many equivalents of iron were present in the sample of the ore taken for analysis?

(iii) How many grams of iron were present in the sample?

(iv) What is the percentage of iron in the ore?
(v) What is the molarity of KMnO4 solution used?
(vi) How many moles of KMnO4 were used for titration ? (Fe = 56)
3. The mixture of CuS (molar weight = M1) and Cu2S (molecular weight = M2) oxidised by KMnO4 (molecular weight = M3)
in acidic medium, the product obtained are Cu2+, SO2. Find the equivalent weight of CuS, Cu2S and KMnO4
respectively.
4. Calculate the oxidation number of underlined elements in the following compounds :
(a) K[ Co(C2O4)2.(NH3)2] (b) K4 P2O7 (c) CrO2Cl2
(d) Na2[ Fe(CN)5NO+] (e) Mn3O4 (f) Ca(ClO2)2
(g) [ Fe(NO)(H2O)5]SO4 (h) ZnO 2–
2
(c) Fe0.93O
5. Write balanced net ionic equation for the following reactions in acidic solution.
(a) S4O62– (aq) +Al (s)  H2S (aq) + Al3+ (aq)
(b) S2O32– (aq) + Cr2O72– (aq)  S4O62– (aq) + Cr3+ (aq)
(c) ClO3– (aq) + As2S3 (s)  Cl– (aq) + H2AsO4– (aq) + HSO4– (aq)
(d) IO3– (aq) + Re (s)  ReO4– (aq) + I– (aq)
(e) HSO4– (aq) + As4 (s) + Pb3O4 (s)  PbSO4 (s) + H2AsO4– (aq)
(f) HNO2 (aq)  NO3– + NO (g)
6. Write balanced net ionic equations for the following reactions in basic solution :
(a) C4H4O62–(aq) + ClO3– (aq)  CO32– (aq) + Cl– (aq)

(b) Al (s) + BiONO3 (s)  Bi (s) + NH3 (aq) + Al (OH)4–(aq)

(c) H2O2 (aq) + Cl2O7 (aq)  ClO2– (aq) + O2 (g)

(d) Tl2O3 (s) + NH2OH (aq)  TlOH (s) + N2 (g)

(e) Cu(NH3)42+ (aq) + S2O42– (aq)  SO32– (aq) + Cu (s) + NH3 (aq)

(f) Mn(OH)2 (s) + MnO4– (aq)  MnO2 (s)

149
 REDOX REACTION AND EQUIVALENT CONCEPT

Exercise # 5 Part # I [Previous Year Questions] [AIEEE/JEE-MAIN]

1. MnO4– is good oxidising agent in different medium changing to - [AIEEE-02]

MnO4– Mn2+
MnO42–
MnO2
Mn2O3
Changes in oxidation number respectively are -
(1) 1, 3, 4, 5 (2) 5, 4, 3, 2 (3) 5, 1, 3, 4 (4) 2, 6, 4, 3

2. Oxidation number of Cl in CaOCl2 (bleaching powder is ) [AIEEE-02]

(1) Zero, since it contains Cl2
(2) –1, since it contains Cl–
(3) +1, since it contains ClO–
(4) +1 and –1 since it contains ClO– and Cl–

3. Which of the following is a redox [AIEEE-02]

(1) 2NaAg(CN)2 + Zn  Na2Zn (CN)4 + 2 Ag (2) BaO2 + H2SO4  BaSO4 + H2O2

(3) N2O5 + H2O  2HNO3 (4) AgNO3 + KI  AgI + KNO3

4. In the coordination compound, K4[Ni (CN)6], the oxidation state of nickel is [AIEEE-03]
(1) +1 (2) +2 (3) –1 (4) 0
5. The oxidation state of Cr in [Cr(NH3)4Cl2]+ is - [AIEEE-05]
(1) +2 (2) +3 (3) 0 (4) +1
6. The oxidation state of chromium in the final product formed by the reaction between Kl and acidified potassium
dichromate solution is - [AIEEE-05]
(1) +6 (2) +4 (3) +3 (4) +2
7. Which of the following chemical reaction depicts the oxidizing behaviour of H2SO4 ? [AIEEE-06]
(1) Ca(OH)2 + H2SO4 CaSO4 + 2H2O (2) NaCl + H2SO4  NaHSO4 + HCl

(3) 2PCl5 + H2SO4  2POCl3 + 2HCl + SO2Cl2 (4) 2HI + H2SO4 I2 + SO2 + 2H2O

Part # II [Previous Year Questions][IIT-JEE ADVANCED]

1. The oxidation number of phosphorus in Ba(H2PO2)2 is : [JEE 1990]

(A) +3 (B) +2 (C) +1 (D) –1
2. The number of electrons to balance the following equation :- [JEE 1991]
– + –
NO3 + 4H + e  2H2O + NO is
(A) 5 (B) 4 (C) 3 (D) 2
3. What is the volume strength of 1.5 N H2O2 : [JEE 1991]
(A) 4.8 (B) 8.4 (C) 3.0 (D) 8.0

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CHEMISTRY FOR JEE MAIN & ADVANCED

MOCK TEST

SECTION - I : STRAIGHT OBJECTIVE TYPE

1. The number of moles of KMnO4 that will be needed to react completely with one mole of ferrous oxalate in acid
solution is
(A) 3/5 (B) 2/5 (C) 4/5 (D) 1

2. The number of moles of KMnO4 that will be needed to react with one mole of sulphite ions in acidic solution is
(A) 2/5 (B) 3/5 (C) 4/5 (D) 1

3. The normality of 0.3 M phosphorus acid (H3PO3) is

(A) 0.1 (B) 0.9 (C) 0.3 (D) 0.6

4. An aqueous solution of 6.3 gm of oxalic acid dihydrate is made upto 250 ml. The volume of 0.1 N NaOH required to
completely neutralize 10 ml of this solution is
(A) 40 ml (B) 20 ml (C) 10 ml (D) 4 ml

5. Consider a titration of potassium dichromate solution with acidified Mohr’s salt solution using diphenylamine as
indicator. The number of moles of Mohr’s salt required per mole of dichromate is
(A) 3 (B) 4 (C) 5 (D) 6

SECTION - II : MULTIPLE CORRECT ANSWER TYPE

6. Consider the redox reaction 2S2O32– + 2  S4O62– + 2 – :
(A) S2O32– gets reduced to S4O62– (B) S2O32– gets oxidised to S4O62–
(C) 2 gets reduced to – (D) 2 gets oxidised to –

7. There are two sample of HCl having molarity 1N and 0.25 N. Find volume of these sample taken in order to prepare
0.75 N HCl solution. (Assume no water is used) :
(A) 20 mL, 10 mL (B) 100 mL, 50 mL (C) 40 mL, 20 mL (D) 50 mL, 25 mL

8. To a 25 ml H2O2 solution excess acidified solution of KI was added. The iodine liberated 20 ml of 0.3 N sodium
thiosulphate solution. Use these data to choose the correct statements from the following :
(A) The weight of H2O2 present in 25 ml solution is 0.102 g
(B) The molarity of H2O2 solution is 0.12 M
(C) The weight of H2O2 present in 1 L of the solution is 0.816 g
(D) The volume strength of H2O2 is 1.344 L

SECTION - III : ASSERTION AND REASON TYPE

Each question has 5 choices (A), (B), (C), (D) and (E) out of which only one is correct.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
(E) Statement-1 and Statement-2 both are False.

9. Statement-1 : In the redox reaction 8 H+ (aq) + 4 NO3– + 6 Cl– + Sn(s)  SnCl62– + 4 NO2 + 4 H2O, the reducing
agent is Sn(s).
Statement-2 : In balancing half reaction, S2O32–  S(s), the number of electrons added on the left is 4.

158
 11th Class Modules Chapter Details

Physics Chemistry Mathematics

5 5 5
Modules Modules Modules

PHYSICS CHEMISTRY MATHEMATICS

Module-1 Module-1(PC) Module-1

1. Physical World and Units 1. Mole Concept 1. Basic Maths and Logarithm
& Dimensions 2. Atomic Structure 2. Quadratic Equation
2. Basic Maths & Vector 3. Chemical Bonding 3. Sequence and Series
3. Kinematics 4. Gaseous State
Module-2
Module-2 Module-2(PC) 1. Trigonometric Ratio and
1. Thermodynamics Identities
1. Newton’s Law of Motion 2. Trigonometric Equation
& Friction 2. Thermochemistry
3. Chemical Equilibrium 3. Properties & Solution
2. Work, Energy & Power of Triangle
4. Ionic Equilibrium
Module-3 Module-3
Module-3(IC)
1. Centre of Mass & Collisions 1. Periodic Table & Its Properties 1. Permutation & Combination
2. Rotational Motion 2. Redox Reaction & Equivalent 2. Binomial Theorum
3. Gravitation Concepts 3. Complex Number
3. Hydrogen & Its Components
Module-4 4. S-Block Module-4
1. Straight Line
1. Mechanical Properties 2. Circle
of Matter Module-4(OC)
1. Nomenclature of 3. Conic Section
2. Thermal Properties of Matter (Parabola,Ellipse & Hyperbola)
Organic Compounds
Module-5 2. Isomerism
3. General Organic Chemistry Module-5
1. Simple Harmonic Motion 1. Mathematical Induction
2. Wave Motion Module-5(OC) 2. Mathematical Reasoning
3. Measurement Error 1. Reaction Mechanism 3. Statistics
& Experiment 2. Hydrocarbon
3. Aromatic Hydrocarbon
4. Environmental Chemistry

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 12th Class Modules Chapter Details

Physics Chemistry Mathematics

5 5 5
Modules Modules Modules

PHYSICS CHEMISTRY MATHEMATICS

Module-1 Module-1(PC) Module-1

1. Solid State 1. Sets & Relation
1. Electrostatics
2. Solutions and 2. Function
2. Capacitance
Colligative Properties 3. Inverse Trigonometric Function
3. Electro Chemistry 4. Probability
Module-2
1. Current Electricity Module-2(PC) Module-2
2. Magnetic Effect of Current 1. Chemical Kinetics and
and Magnetism Nuclear Chemistry 1. Limit
2. Surface Chemistry 2. Continuity
Module-3 3. Differentiability
Module-3(IC) 4. Method of Differentiation
1. Electromagnetic Induction
2. Alternating Current 1. Metallurgy
2. P- Block Module-3
Module-4 3. Transition Elements 1. Indefinite Integration
(d & f block) 2. Definite Integration
1. Geometrical Optics 4. Co-ordination Compound 3. Area Under the Curve
2. Wave Optics 5. Salt Analysis & Qualitative
Analysis Module-4
Module-5
Module-4(OC) 1. Application of Derivative
1. Modern Physics
1. Alkyl Halides & Aryl Halides 2. Matrix
2. Nuclear Physics
2. Alcohol, Phenol & Ether 3. Determinant
3. Solids & Semiconductor
Devices 3. Carbonyl Compound
Module-5
4. Electromagnetic Waves
5. Principle of Communication Module-5(OC) 1. Differential Equation
1. Carboxylic Acid & Their 2. Vector & 3-Dimensional
Derivatives
2. Biomolecules & Polymers
3. Chemistry in Everyday Life

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