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Article history: There are several factors and test methods for evaluating the durability of concrete. In recent years a great
Received 15 June 2010 deal of attention has been paid to research and development of relationships of these parameters for pro-
Received in revised form 17 October 2010 duction of sustainable concretes: water penetration and Rapid Chloride Penetration Test (RCPT) methods
Accepted 13 November 2010
which are most commonly used to evaluate the permeability of concrete are two of the most famous
Available online 28 December 2010
methods specified by BS EN-12390-8:2000 and ASTM C1202 respectively. Concrete surface resistivity
(SR) test is also a suitable indicator for concrete penetration and chloride ion permeability. It is a non-
Keywords:
destructive, simple, rapid and economical method that can also be used on site.
Water penetration
Electrical resistivity
The present study is an exploratory research concerned with the relationship of these methods. Based
RCPT on the correlation of concrete resistivity with water penetration and Rapid Chloride Penetration Test
Permeability (RCPT) results, two new models for relating these parameters are presented.
Pozzolans Ó 2010 Elsevier Ltd. All rights reserved.
0950-0618/$ - see front matter Ó 2010 Elsevier Ltd. All rights reserved.
doi:10.1016/j.conbuildmat.2010.11.069
A.A. Ramezanianpour et al. / Construction and Building Materials 25 (2011) 2472–2479 2473
when pozzolanic materials are used. In addition, the flux in the For all mix designs, coarse aggregates were crushed calcareous stone with a
maximum size of 19 mm and fine aggregates were natural sand. The coarse aggre-
RCPT may not be in steady-state condition due to the high poten-
gates have a specific gravity and a water absorption of 2510 kg/m3 and 1.90%,
tial difference of 60 V [11]. Consequently the results obtained may respectively, and the fine aggregate has a water absorption of 2.75% and a specific
not represent true chloride diffusion in concrete. However, it is gravity of 2570 kg/m3. A superplasticizer was employed to achieve the desired
widely used because of its convenience and short-term duration. workability. Potable water was used for casting and curing all concrete specimens.
On the other hand, concrete resistivity is also a geometry indepen- The concrete production was carried out in a 60 l capacity mixer. All replacements
were made by mass. The mixture proportions for concrete specimens are summa-
dent material property that depends on the moisture content and
rized in Table 2.
the concrete composition [12].
Theoretical and experimental studies indicate a correlation be-
tween concrete resistivity and chloride ingress [13–15]. In general, 2.2. Testing procedure and specimen preparation
the chloride diffusion coefficient is inversely proportional to the
concrete resistivity. Within a particular structure, more permeable Concrete test specimens were vibrated over a vibrating table to remove en-
trapped air. After casting, the concrete specimens were covered with a wet towel
zones will have a comparatively lower resistivity and higher chlo-
for 24 h and cured under laboratory conditions. Then they were demolded and
ride penetration. cured in lime-saturated water at 23 ± 2 °C to prevent possible leaching of Ca(OH)2
It well understood that the resistivity of concrete and the corro- from these specimens.
sion rate of reinforcement after depassivation are related. Ion Concrete cubes of 100 100 100 mm dimension were cast for compressive
strength. They were tested after 7 and 28 days of water curing.
transport between anodes and cathodes on the steel surface is
The water penetration test, which is most commonly used to evaluate the per-
one of the factors controlling the rate of corrosion [12]. meability of concrete, is the one specified by BS EN-12390-8:2000. In this test,
One of the best methods to measure concrete resistivity is using water was applied on one face of the 150 mm concrete cubes specimen under a
four-point Wenner array probe resistivity meter. The non-destruc- pressure of 0.5 MPa. This pressure was maintained constant for a period of 72 h.
tive nature, speed, and ease of use, make the Wenner array probe After the completion of the test, the specimens were taken out and split open into
two halves. The water penetration profile on the concrete surface was then marked
resistivity technique a promising alternative test to characterise
and the maximum depth of water penetration in specimens was recorded and con-
the chloride penetration resistance concrete. The set up utilizes sidered as an indicator of the water penetration.
four equally spaced surface contacts, where a 25 V peak to peak The electrical resistivity meter was used to measure the surface resistivity (SR)
and 13 Hz alternating trapezoidal voltage is passed through a con- of the specimens. This non-destructive laboratory test method measures the electri-
crete sample between the outer pair of contacts [16]. cal resistivity of water-saturated concrete and provides an indication of its perme-
ability. The test result is a function of the electrical resistance of the specimen. A
Another main factor of concrete durability is permeability. Con- schematic figure of electrical resistivity meter is shown in Fig. 1. Saturated cylinders
crete with lower permeability shows better resistance against (100 200 mm) were used at each test age. The electrical resistivity test for con-
chemical attacks. When water penetrates into the concrete, some cretes was carried out by the four-point Wenner array probe technique. The probe
soluble salts including chloride ions go through concrete causing array spacing used was 40 mm. The resistivity measurements were taken at four
quaternary longitudinal locations of the specimen [21].
corrosion. Generally, it seems that lower permeability causes high-
The Rapid Chloride Penetration Test was conducted in accordance with ASTM
er durability in concretes. Various tests such as water penetration C1202 for each mixture. Two specimens of 100 mm in diameter and 50 mm in
test are used to evaluate the permeability of concretes and several thickness which had been conditioned according to the standard were subjected
studies have been carried out on this issue and validity of these to a 60 V potential for 6 h. The total charge passed through the concrete specimens
tests has been approved [17] and several researchers used these was determined and used to evaluate the chloride permeability of each concrete
mixture. The ages of specimens for the tests are shown in Table 3.
methods for evaluation of performance of concrete [18–20].
The aim of this study is to investigate the possibility of replac-
ing the Rapid Chloride Penetration Test and water penetration test
3. Results and discussions
by the simple non-destructive surface resistivity test.
Table 1
Chemical characteristics of supplementary materials and cement.
Chemical components Cement type I RHA Tuff Pumice Silica fume Metakaolin
A B C
SiO2 21.5 89.61 65.74 67.7 94.66 72.5 76.73 68.99
Al2O3 3.68 0.04 12.24 15.8 0.31 22.21 17.41 20.46
Fe2O3 2.76 0.22 2.05 3.39 0.60 0.81 0.59 0.99
CaO 61.5 0.91 2.87 3.9 0.36 2.22 3.58 2.75
SO3 2.5 0.15 0 0.33 0.23 – – –
MgO 4.8 0.42 0.96 0.99 0.78 0.13 0.19 0.50
Na2O 0.12 0.07 1.92 2.95 0.22 0.05 0.05 2.80
K2O 0.95 1.58 2.02 2 0.22 0.55 0.31 2.24
P2O5 0.23 0.41 0.03 0.12 – 0.05 0.04 0.05
TiO2 0.04 0.02 0.29 0.33 – 0.06 0.06 0.09
LOI 1.35 5.91 8.5 2.3 1.77 0.76 0.82 0.89
2474 A.A. Ramezanianpour et al. / Construction and Building Materials 25 (2011) 2472–2479
Table 2
Mixture proportions of concrete.
No. Mixtures Cement content w/c Supplementary material Aggregate (kg/m3, SSD) Compressive strength (MPa, 28 days)
Type (%) Coarse Fine
1 C35.50P0 350 0.5 Pumice 0 802 980 43.3
2 C35.50P10 350 0.5 Pumice 10 802 980 37.8
3 C35.50P15 350 0.5 Pumice 15 802 980 39.0
4 C35.50P20 350 0.5 Pumice 20 802 980 39.3
5 C35.50T15 350 0.5 Tuff 15 802 980 49.8
6 C35.50T20 350 0.5 Tuff 20 802 980 45.5
7 C35.50T25 350 0.5 Tuff 25 802 980 50.2
8 C42.45R0 420 0.45 RHA 0 760 929 40.3
9 C42.45R7 420 0.45 RHA 7 760 929 42.8
10 C42.45R10 420 0.45 RHA 10 760 929 44.8
11 C42.45R15 420 0.45 RHA 15 760 929 46.9
12 C40.45MS0 400 0.45 NS 0 778 951 52.3
13 C40.45NS4.5 400 0.45 NS 4.5 778 951 57.8
14 C40.45NS7.5 400 0.45 NS 7.5 778 951 62.0
15 C40.45MS4.5 400 0.45 SF 4.5 778 951 55.2
16 C40.45MS7.5 400 0.45 SF 7.5 778 951 61.0
17 C40.45M0 400 0.45 Metakaoline 0 778 951 46.3
18 C40.45Ma5 400 0.45 Metakaoline-A 5 778 951 49.7
19 C40.45Ma10 400 0.45 Metakaoline-A 10 778 951 52.0
20 C40.45Ma15 400 0.45 Metakaoline-A 15 778 951 51.8
21 C40.45Ma20 400 0.45 Metakaoline-A 20 778 951 47.3
22 C40.45Mb5 400 0.45 Metakaoline-B 5 778 951 52.2
23 C40.45Mb10 400 0.45 Metakaoline-B 10 778 951 50.0
24 C40.45Mb15 400 0.45 Metakaoline-B 15 778 951 46.7
25 C40.45Mb20 400 0.45 Metakaoline-B 20 778 951 43.7
26 C40.45Mc5 400 0.45 Metakaoline-C 5 778 951 50.0
27 C40.45Mc10 400 0.45 Metakaoline-C 10 778 951 48.3
28 C40.45Mc15 400 0.45 Metakaoline-C 15 778 951 42.0
29 C40.45Mc20 400 0.45 Metakaoline-C 20 778 951 39.0
30 C45.40MS0 450 0.4 SF 0 760 929 52.8
31 SCC45.40MS0 450 0.4 SF 0 740 949 56.7
32 SCC45.40MS7.5 450 0.4 SF 7.5 740 949 65.9
33 SCC45.40MS7.5 480 0.4 SF 7.5 715 918 69.5
34 SCC45.40P15 450 0.4 Pumice 15 740 949 46.5
35 SCC45.40P15 515 0.4 Pumice 15 686 883 58.2
36 SCC45.40R10 450 0.4 RHA 10 740 949 55.9
37 SCC45.40R10 495 0.4 RHA 10 703 903 61.3
38 C25.45 250 0.45 – – 910 1112 65.3
39 C25.55 250 0.55 – – 881 1077 52.5
40 C25.60 250 0.6 – – 867 1060 42.3
41 C30.45 300 0.45 – – 866 1059 61.9
42 C30.55 300 0.55 – – 832 1016 46.7
43 C30.60 300 0.6 – – 814 995 35.3
44 C35.45 350 0.45 – – 822 1005 54.0
45 C35.55 350 0.55 – – 782 956 42.6
46 C35.60 350 0.6 – – 762 931 33.8
47 C42.45 425 0.45 – – 756 924 46.5
48 C42.55 425 0.55 – – 707 864 36.8
49 C42.60 425 0.6 – – 683 835 28.3
50 C32.50MS0 325 0.5 SF 0 825 1009 28.4
51 C32.50MS7.5 325 0.5 SF 7.5 825 1009 34.7
52 C40.50MS0 400 0.5 SF 0 755 923 23.1
53 C40.50MS7.5 400 0.5 SF 7.5 755 923 32.6
54 C32.40MS0 325 0.4 SF 0 863 1054 48.3
55 C32.40MS7.5 325 0.4 SF 7.5 863 1054 43.1
56 C40.40MS0 400 0.4 SF 0 801 979 33.6
57 C40.40MS7.5 400 0.4 SF 7.5 801 979 41.0
Table 3 Table 4
Ages of tests. Comparison of ionic conductance [24].
Fig. 4. Relationship between water penetration and SR for mixtures containing metakaolin.
A.A. Ramezanianpour et al. / Construction and Building Materials 25 (2011) 2472–2479 2477
Fig. 7. Relationship between compressive strength and SR for mixtures containing metakaolin.
2478 A.A. Ramezanianpour et al. / Construction and Building Materials 25 (2011) 2472–2479
Table 5
Obtained models.
between the results of SR and water penetration is reduced. How- penetration resistance of the concrete, but not as a predictor of dif-
ever in samples made with the same cementitious materials and as fusion behavior for all kinds of concretes or as replacement of the
a result of the similar chemical compounds of pore solution, the re- long term diffusion tests. The long term diffusion tests should still
sults of both tests are more sensitive to microstructure of concretes be used when new concrete formulations are used in order to
and a good correlation between the results can be achieved. establish if the relationship between electrical properties and dif-
Compressive strength is one of the most important mechanical fusion properties still holds.
properties of concrete and a simple test is used to measure it. In Results show that although in concretes with similar cementi-
this paper several trial and error relationships between compres- tious materials different relationships can be found, but generally
sive strength and surface resistivity have also been studied. Gener- because of different mechanisms of compressive strength and elec-
ally, one of the main factors in compressive strength is the strength trical resistivity, there is no appropriate relationship between
of Interlayer Transition Zone (ITZ) that has no significant effect on them. Consequently it is not recommended to use electrical resis-
concrete resistivity. On the other hand, chemical compound of pore tivity as an indicator for evaluation of compressive strength.
solution has a great influence on concrete resistivity while not
affecting the compressive strength of concrete. Therefore, as seen
in Fig. 6, there is no sensible correlation between compressive References
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