Chemistry Chem_24.03.

2020_Full Test _Naresh sir

46. The weight of NaCl decomposed by 4.9g of
H2SO 4,if 6 g of sodium hydrogen sulphate and
1.825 g of HCl, were produced in the reaction is
:
(1) 6.921 g (2) 4.65 g
(3) 2.925 g (4) 1.4 g
47. Energy levels, A, B, C, of a certain atom (1) 8 and 5 atm (2) 9.6 anf 4 atm
correspond to increasing values of energy i.e., (3) 4.8 and 2 atm (4) 6.4 and 4 atm
53. Using the data provided, calculate the multiple
EA < E B <EC.If  1,2,3 are the wave lengths of –1) of a C
bond energy (kJ mol  C bond in
radiations corresponding to the transition from
C to B, B to A and C to A respectively, which of C H
2 2 .That energy is (take the bond energy of a
C – H bond as 350 kJ mol –1)
the following statements is correct ?

2C(s)H(g)HCCH(g);H225KJ
2
mol–1
1

2C(s)2C(g);H1410kJmol

H(g)2H(g);H330kJmol
2
1

(1) 1165 (2) 837

(3) 865 (4) 815
54. Under isothermal condition for one mole of ideal
 gas what is the ratio of work done under
(2) 3
12
(1) 
312 
revesible to irreversible process, initially held
12 at 20 atm undergoes expansion from 1 L to 2L,
(3) 
123
0 (4) 
222
312
at 298K, under external pressure of 10 atm ?
(1) 1.7 (2) 2.0
48. The ionization enthalpy of hydrogen atom is
1.312 × 10 6 J mol –1 . The energy required to (3) 1.4 (4) 1.0
55. The dissociation constant of a weak acid is
excite the electron in the atom from n = 1 to
1 × 10 –4. In order to prepare a buffer solution
n = 2 is
with a pH = 5 the [Salt]/[Acid] ratio should be
(1) 8.51 × 105 J mol–1 (2) 6.56 × 105J mol–1
(1) 1 : 10 (2) 4 : 5
(3) 7.56 × 105 J mol–1 (4) 9.84 × 105 J mol–1
49. Which one of the following arrangements (3) 10 : 1 (4) 5 : 4
56. The exothermic formation of ClF3 is represented
represents the correct order of lest negative to
by the equation :
most negative electron gain enthalpy for C, Ca,
Al,F and O ? 223 


Cl(g)3F(g)2ClF(g);H329kJ
(1) Ca < Al < C < O < F (2) Al < Ca < O < C < F Which of the following will increase the quantity
(3) Al < O < C < Ca < F (4) C < F < O < Al < Ca of CIF3 in an equilibrium mixture of Cl 2,F 2 and
50. Ortho – Nitrophenol is less soluble in water than CIF3 ?
p – and m – Nitrophenols because : (1) Adding F2
(1) o – Nitrophenol is more volatile steam than (2) Increasing the volume of the container
those of m – and p – isomers (3) Removing Cl 2
(2) o – Nitrophenol shows intramolecular (4) Increasing the temperature
H – bonding 57. For the reaction :
(3) o– Nitrophenol shows intermolecular
H – bonding 

2NO(g)2NO(g)O(g), 
22
(4) Melting point of o – Nitrophenol is lower than
those of m – and p – isomers  6
(K1.810at184C)
c

51. Which one of the following molecules is 

(R0.0831kJ/(mol.K))
paramagnetic When K p and K c are compared at 184°C, it is
(1) N2 (2) NO found that
(3) CO (4) O3 (1) Whether Kp is greater than, less than or equal
52. Two vessels containing gases A and B are to Kc depends upon the toal gas pressure
interconected as shown in the figure. The (2) KP = K c
stopper is opened, the gases are allowed to mix (3) K p is less than K c
homogeneously. The partial pressure of A and B (4) K p is greater than K c
in the mixutre will be, respectively

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 Chemistry Chem_24.03.2020_Full Test _Naresh sir
58. Which of the following reactions depict the cell potential at 25°C is :
oxidising behaviour of 2HSO4: (1) 1.47 V (2) 1.77 V

(1) 2PClHSO2POCl2HClSOCl (3) 1.87 V (4) 1.57 V
524322
68. Consider the following relations for emf of a

(2) 2NaOHHSONaSOHO
24242 electrochemical cell:

(3) NaClHSONaHSOHCl (i) emf of cell = (Oxidation potential of anode) –
244
(Reduction potential of cathode)

(4)2HIHSOISO2HO
24222 (ii) emf o cell = (Oxidation potential of anode) +
59. Identify x and y in following reaction. What is (Reduction potential of cathode)
the mixture ofx and y called ? (iii) emf of cell = (Reduction potential of anode) +
(Reduction potential of cathode)

CH(g)HO(g)xy 1270K
42 Ni (iv) emf of cell = (Oxidation potential of anode) –
(1) x = CO2,y = H2O, water gas (Oxidation potential of cathode)
(2) x = CO,y = H 2O, syn gas Which of the above relations are correct ?
(3) x = CO,y = H2, water gas (1) (ii) and (iv) (2) (iii) and (i)
(4) x = CO2,y = H2, syn gas (3) (i) and (ii) (4) (iii) and (iv)
60. Which of the following are arranged in increasing69. The reaction A(g) + 2B(g)  C(g) + D(g) is an
order of solubilities ? elementary process. In an experiment involving
(1) CaCO3 < KHCO 3< NaHCO3 this reaction, the initial partial pressure of A
(2) NaHCO3 < KHCO3 < CaCO3 and B are pA = 0.60 atm and p B = 0.80 atm
(3) KHCO3 < NaHCO3 < CaCO3 respectively. When pC = 0.20 atm, the rate of
(4) CaCO3 < NaHCO3 < KHCO 3 the reaction relative to the initial rate is
61. The catenation tendency of C, Si and Ge is in (1) 1/6 (2) 1/12
the order Ge < Si < C. The bond energies (in kJ (3) 1/36 (4) 1/18
mol–1) of C – C, Si – Si and Ge – Ge bonds are 70. Freundlich equation for adsorption of gases (in
respectively ; amount ofx g) on a solid (in amount of m g) at
(1) 348, 297,260 (2) 297, 348,260 constant temperature can be expressed as
(3) 348,260,297 (4) 260,297,348
62. Phosphate fertilizers when added to water leads x1

(1) loglogplogk
to mn
(1) increased growth of decomposers x1
(2) reduced algal growth 
(2) loglogklogp
(3) increased algal growth mn
(4) nutrient enrichment (eutrophication) x
63. The pyknometric density of sodium chloride (3)  pn
m
crystal is 2165 × 103 kg m –3 while its X – ray
density is 2.178 × 103 kg m –3. The fraction of x1
(4) logplogk
unoccupied sites in sodium chloride crystal is mn
(1) 5.96 × 10–3 (2) 5.96 × 104
71. Identity x, y, z for the following metallurgical
(3) 5.96 × 10–2 (4) 5.96 × 10–1
process.
64. AB; crystallizes in a body centred cubic lattice Metal sulphide  x medal oxide  y
with edge length ‘a’ equal to 387 pm. The
distance between two oppositely charged ions in Impure metal  z Pure metal.x, y, and z are
the lattice is : respectively
(1) 335 pm (2) 250 pm (1) roasting, smelting electrolysis
(3) 200 pm (4) 300 pm (2) roasting, calcination, smelting
65. Which of the following modes of expressing (3) calcination, auto – reduction,
concentration is independent of temperature ? bassemerisation
(1) Molarity (2) Molality (4) none of the above is correct
(3) Formality (4) Normality 72. Which one of the following statements regarding
66. How many grams of concentrated nitric acid helium is incorrect ?
solution should be used to prepare 250 mL of 2.0M (1) It is used to produce and sustain powerful
HNO3 ? The concentrated acid is 70% HNO 3 superconducting magnets
(1) 90.0 g conc. HNO 3 (2) 70.0 g conc.HNO
3 (2) It is used as cryogenic agent for carrying out
(3) 54.0 g conc. HNO 3 (4) 45.0 g conc. HNO
3 experiments at low temperatures
67. Consider the following cell reaction : (3) It is used to fill gas balloons instead of

 2

2Fe(s)O(g)4H(aq)2Fe(aq)2HO();E1.67V
22
hydrogen because it is lighter and non –
23
inflammable

At[Fe]10  M, p(O2) = 0.1 atm and pH = 3, the (4) It is used in gas – cooled nuclear reactors

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 Chemistry Chem_24.03.2020_Full Test _Naresh sir

73. Caro’s acid is 80. Choose the incorrect option regarding following
(1) H 2 SO 3 (2) H 3 S 2 O 5 reaction sequence is
H
(3) 2 5 SO (4) H 2 S 2 O 8
74. Which of the following are inner orbital complex
(i.e., involving d 2 sp 3 hybridisation) and is
paramagnetic in nature ?
333

(1) [Mn(CN)],[Fe(CN)],[Co(CO)]
66243
(1) (R) has common name acetophenone

333
(2) [Mn(Cl)],[FeF],[CoF]
666 (2) (P) is cyanohydrin
33 (3) Formation of (R) involves carbocation
(3 ) [Mn(CN)],[Fe(CN)]
66
intermediate
333
(4) [Mn(Cl)],[Fe(CN)],[Co(CO)]

66243
(4) Correct IUPAC name of (Q) is 2 – amino, 2 –
75. Of the following which one is classified as phenyl, 1 – ethanol
polyester polymer ? 81. The najor product obtained on pyrolysis of
(1) Nylon–6, 6 (2) Terylene following ester is
(3) Bakelite (4) Melamine
76. The most acidic Hydrogen in following compound
is
H
III S
H H
II I
S
(1) I (2) II
(3) III (4) Can’t compare
77. The following structures are resonance
contributors for a reactive intermediate formed
(1) (2)
during ozonolysis of alkenes. Energetically most
favourable and the least favourable contributors
are respectively.
(3) (4)

82. The final product ‘R’ is

(1) III and II (2) I and IV

(3) II and IV (4) I and II
78. Given compounds are related as

(I) (II)

(1) Identical (2) Diastereomer

(3) Enantiomer
(4)Constitutional isomer
79. Incorrect option regarding following reaction
sequence is : (1) (2)

(1) (Q) on reaction with Mg – Hg will give pinacolon

as product
(2) (R) can oxidise Zn – Hg /HCl
(3) (R) has highest value of index of hydrogen
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 Chemistry Chem_24.03.2020_Full Test _Naresh sir
deficiency among (P), (Q), (R)
(4) Both (Q) and (R) will give red orange ppt. with
2,4 – DNP

(3) (4)
(3) (4)

83. The major product obtained during the following Br

reaction is
Alc.KOH
86. +
(Y%) (X%)
X and Y respectively be
(1) 81, 19 (2) 50, 50
(3) 19,81 (4) 100, 0
87. The ring at which rate of bromination is fastest
by using Br 2 /Fe is :

(1) (2)

(3) (4) (1) a (2) b

(3) c (4) d
88. The following carbohydrate is
84. The compound which can never show S N 1 as
well as S N 2 mechanism is

(1) (2)

(1) A ketohexose (2) An aldohexose

(3) An  – furanose (4) An  – pyranose
89. Amongst the compounds given, the one that
would form a brilliant coloured dye on treatment
(3) (4) with NaNO 2 in dil. HCl followed by additional to
an alkaline solution of b–naphthol is
3
N(CH) 32 NHCH 3
85. In the given reaction,
(1) (2)

NHCH 3

the major product is (3)

HC
3

(1) (2)

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 Chemistry Chem_24.03.2020_Full Test _Naresh sir
46.Ans (3)
CHNH
22 
NaClHSONaHSOHCl
244
xg1.825g
4.9g 6g
(4) According to law of conservation
is neither created nor destroyed
90.Vanillin obtained as a product in the
chemical
following
change”
reaction structure of Vanilline is  Mass of the reactants = Mass o
x + 4.9 = 6 +1.825
orx = 2.925 g
47.Ans (2)
From the given data, we have

(EE)(EE)(EE)
CBBACA


hchchc
or 

123

  1
 12
12
or
3  
(1) (2)  
12  123
48.Ans (4)
(E), The energy required to excit
in an atom of hydrgoen fromE n =
(difference in 2energy
and1) E E
Values2ofand
E1 are,
E
62

1.31210(1)
2 
51 
(3) (4) E3.2810Jmol
2
(2)
E is given by the relation,
E 6 × mol
–1
seretgher 1 = – 1.312 J 10
ertgewr
561
____________________sdfsdrf 
EEE[3.2810][1.31210]Jmol
21


__________________–––––––––––––––– = (–3.28 5+
×10
1.3126) × –1
J 10
mol
––––––––––––––––– 5
= 9.84 ×J10 –1
mol
Thus the correct answer is (4)
49.Ans (1)
50.Ans (2)
51.Ans (2)
52.Ans (3)
pv 
81296
ofA 
MolesA,(n) AA
RTRTRT
pv 
8540
B 
BB
A,(n)
Moles of B,
RTRTRT
Total pressure × total
A +volume
n
B) ×RT = (
1

p(128)(9640)RT,P6.8
RT
Partial pressure of A = p × mole
 
969640
6.8


RTRT
= 4.8 atm
Partial pressure of B = 6.8 –4.8 =

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 Chemistry Chem_24.03.2020_Full Test _Naresh sir
For the reaction :–
53. 
(i) 2C(s)H(g)HCCH(g)
2 

2NO(g)2NO)(g)O(g) 
22
H225kJmol 1


Given K1.810
c
6
at 184°C

(ii) 2C(s)2C(g) H1410kJmol 1
R = 0.0831 kj/mol.k
66
p 
1410 1 K1.8100.08314576.83610

C(s)C(g)H750kJmol
2
 
[184C(273184)457k,n(21,1)1]

(iii) H(g)2H(g) H330kJmol 1
Hence it is clear that K
2 p >K c
From equation (i) : 
1604

2HIHSOISO2HO
24222


2252H1BE
 
C(s)C(g)HH
58. Oxidised
RA
Reduced
OA


[2BE1BE]

CHCC
59. Ans (3)

225[14101330][23501BE] CC
1270K
CH(g)HO(g)CO3H
422 Ni


225[1410330][700BE] CC
Mixture of CO and H 2 is called water gas.
60. Ans (4)

2251740700BE CC 61. Ans (1)

BE815kJmol 1 62. Ans (4)
CC
63. Ans (1)
54. Ans (1)

WP(VV)
irreversibleext21 64. Ans (1)
= 10 atm (2L – 1L) For bcc lattice body diagonal  a3
= 10 atm – L
The distance between the two oppositely charged
V2
V2 a
WPdv
irreversibleex 
V1
 2.303nRTlog
V1 ions 
2
3

2 
3871.732
= 12.3030.0821 atm – L/K/mol × log  335pm
 1 2
= 16.96 aatm – L 65. Ans (2)
66. Ans (4)
Wreversible 16.96
 1.691.7 
wt1000
W10.00
irreversible Molarity(M) 

mol.wt.vol(ml)
55. Ans (3)
[Salt] wt1000

pHpKlog 2 
a
[Acid] 63250

[Salt] 63

wt.gm

54log 
[pKlogK] 2
[Acid] aa

Given, K a = 1× 10 –4 100
wt. of 70% acid  31.545 gm
 pK a = – log (1 × 10 –4 ) = 4 70
Now from from Handerson equation 67. Ans (4)
[Salt] Here n = 4, and [H + ] = 10 –3 (as pH = 3)

pHpKlog a Applying Nernst equation
[Acid]
 22
Putting the values 0.059[Fe]

EElog  4
n [H](po) 2
[Salt]

54log
[Acid] 0.059
 7
1.67log101.670.1031.567V
4
[Salt]
log541  68. Ans (1)
[Acid] 69. Ans (1)
Taking antilog 
A(g)2B(g)C(g)D(g)
[Salt]/[Acid] =10 =10 :1 Rate =k[A][B] 2 = k(0.60)(0.80) 2 ...... (i)
56. Ans (1) when p c = 0.20 atm p A is reduced to 0.40 and
57. Ans (4)

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 Chemistry Chem_24.03.2020_Full Test _Naresh sir
p B = 0.40 (see stoichiometic representation)
Rate = k [0.40][0.40] 2 ...... (ii)

0.400.400.401
 (ii) divide by (i) 

0.600.800.806
70. Ans (2)
According to Freundlich equation.
xx
porkp
1/n1/n
mm
x

or loglogkp
1/n
or
m
x1

loglogklogp
mn
71. Ans (1)
72. Ans (3)
73. Ans (3)
74. Ans (3)

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