Question Number: 1

Question Type:
Question Difficulty Level: E

Question: Which is the most reactive ion?

Options
-
(a) Cl
-
(b) H
 C H  - C-
(c) 6 5

(d)        
-
Cl - C - C - C

Question Number: 2
Question Type:
Question Difficulty Level: E

Question: What is oxidation number of Carbon in methanol?

Options

(a) 4

(b) 2

(c) 2

(d) 4

Question Number: 3
Question Type:
Question Difficulty Level: M

2
Question: Previously used silica gel had 100 mMol M tracer adsorbed on it. It was then dipped
into tracer solution (effluent). Finally when the tracer concentration in effluent was measured
long time after dipping silica gel in it, concentration was 1 mMol L . What is the increase in
tracer concentration in silica gel? Adsorption isotherm guiding the process is y  K x , y is
concentration of adsorbate in solid phase, x is tracer concentration in effluent, K = 1 M
-1

Options
2
(a) 0.75 Mol M
2
(b) 0.85 Mol M
2
(c) 0.9 Mol M
2
(d) 0.95 Mol M
Question Number: 4
Question Type:
Question Difficulty Level: E

Question: How does EMF

 E  of a concentration cell vary with the concentration of product  C 
formed in cell due to redox reaction taking place in the concentration cell
Options
(a) E is directly proportional to C
C
(b) E is proportional to e
(c) E is proportional to log C
(d) None of the above

Question Number: 5
Question Type:
Question Difficulty Level: M

Question: In a polytropic process along the path AB as shown in the diagram.

V
 1.5,1

P
A  0.67, 1

Which statement regarding work done in the process AB by the system are correct. V
Represents total volume of system and P is pressure exerted by system
Options
0.5
(a) Work done is directly proportional to V
0.5
(b) Work done is directly proportional to P
1.5
(c) Work done is directly proportional to V
(d) None of the above
Answers
1.(b)

2.(c)

3.(c)

4.(c)

5.(a)
 Explanation

1. H- is rare case of two electrons in 2nd electron shell, so most reactive

2. 3*(-1)+1*(+1)= -2
3. Y (required concentration difference)=Y1-Y0. WhereY0=0.1mol/m2 (initial loading on
adsorbent, given in question). Y1(final adsorbent loading) =mx (where m=1 meter ; x=1
mol/m3)
Y1=1*1mol/m2. So, Y=1-0.1=0.9 mol/m2
4. Relation is clearly mentioned in Nernst equation E=Eo-0.05916/2*log(Activity of
product/Activity of Reactant)

5. Polytropic process can be PV  cons tan t .
i.e. logP= -  *logV
From the diagram Log P= -  * log V is represented by the straight line AB
So,  is slope of line AB = 1.5
W   PdV
Replacing P from equation for polytropic equation, relation between W and P or V can be
found out.