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LIPIDS
CHEMICALS THAT MAKE UP FATS AND ITS
FUNCTIONS
Carbon
Hydrogen
Oxygen
Functions
Energy – 1g of pure fat provides 37KJ (9kcal)
Processed Foods
Frying
Shortening
CHEMICAL STRUCTURE
Fat belongs to a group of substances called Esters.
Formed by the reaction between an alcohol and
organic acid – known as fatty acids
Glycerol is a complex alcohol because it has 3
hydroxyl groups therefore known as a Trihydric
Alcohol.
CHEMICAL STRUCTURE CONT.
Ester formed is a triglyceride.
If all 3 fatty acids are the same, then Simple
Triglyceride is formed.
If fatty acids are different then they are called Mixed
Triglyceride.
Fatty acid Formula = R- COOH (‘R’ represents any
acid).
CIS AND TRANS FATTY ACIDS
CIS
2 hydrogen atoms on the same side of a double
bond.
Trans
Hydrogen atoms on geometrically opposite sides of
the double bond.
SATURATED FATS
Occur when each carbon atom is attached to the
surrounding atoms by a single bond.
The carbon atoms are completely saturated with
hydrogen atoms.
Saturated fats have a melting point at about room
temperature and are therefore usually hard – Could
lead to heart disease and high cholesterol.
SATURATED FAT STRUCTURE
Hydrogen
Atom Carbon
Atom
UNSATURATED FATS
Occur when some of the carbon atoms are joined to
the surrounding hydrogen atoms by a double bond.
Monounsaturated fats have one double bond.
Double Bond
PROPERTIES OF FATS AND OILS
Solubility
Fats and oils are insoluble in water.
However, in the presence of a suitable substance
known as an emulsifying agent, it’s possible to form
a stable mixture of fat and water Emulsion.
The Emulsion may be a Fat – in – Water emulsion
e.g. Milk
Or a Water – in – Fat emulsion e.g. Butter
Fats and oils are soluble in organic solvents such as
petrol and carbon tetrachloride.
Solvents of this type can be used to remove grease
and stains from clothing.
PROPERTIES OF FATS AND OILS
Plasticity
Fats do not melt at fixed temperatures, but over a
range of temperatures.
This is because fats are mixtures of triglycerides
(contain 3 different fatty acids), all with different
melting points.
Some of the fatty acids forming the triglyceride will
stay solid for longer than others.
This feature gives fat its plasticity that makes some
fats spreadable.
E.g. Margarine – Has a wide range of plasticity and
will spread from the fridge whereas most animal fat
will have narrow plasticity and will not spread easily.
PROPERTIES OF FATS AND OILS
Effect of Heat
Oils and fats transfer heat well to foods being cooked but
will eventually breakdown.
Heating causes the triglycerides to decompose.
Melting Point
Fats melt when heated. Since fats are mixtures of
triglycerides they do not have a distinct melting point but
melt over a range of temperatures.
Temperature when melting occurs is known as the Slip
Point.
Most fats melt at temperatures of 30 /40 C
Melting point for oil is below normal air temperature – The
more double bonds, the lower the air temperature.
PROPERTIES OF FATS AND OILS
Smoke Point
When a fat or oil is heated to a certain temperature it starts
to decompose, producing a blue haze or smoke.
Most fats and oils start to smoke at 200 C
Smoke Point for lard = 185 C
Corn Oil = 232 C
In general, vegetable oils have a higher temperature than
animal fats.
Smoke is useful to measure when assessing the suitability
of a fat or oil for frying purposes.
Repeated heating of a fat or oil will reduce the smoke
point.
PROPERTIES OF FATS AND OILS
Saponification
Some triglycerides react with alkalis to form soap and a
glycerol.
Hydrogenation
Some oils are so unsaturated in the natural state that they
need to be treated to make them useful in food.
Hydrogenation is used to add hydrogen to the oil to break
the double bonds. This makes the resulting fat more
saturated and harder.
It is achieved by heating the oil in a large sealed vessel
under pressure.
Hydrogenated fat makes TRANS fats which increases
likelihood of cancer and free radicals in the body.
RANCIDITY
Used to describe the spoilage of fats and oils. Fat
which is rancid will have an unpleasant smell and
flavour.
Oxidative Rancidity
Equation
Fat + Water Glycerol + Fatty Acids