Beruflich Dokumente
Kultur Dokumente
China Coat
December 2014
Michelle Shen
Water resistance: what are we talking about?
The reduction in VOC, the lack of coalescent aids are contributing factors to
poor water resistance properties.
Water resistance of the film can be increase by the use of use specific
binders and a lower pigment volume concentration (PVC) but also by the use of an
efficient and hydrophobic dispersing agent.
3
Coatex – Arkema group
4
Our Brand
Mineral process
RHEOSPERSETM
Coat、Ink、adhesive Paper
RHEOTECHTM, COAPURTM TOPSPERSETM, RHEOCOATTM
VISCOATEXTM, ECODISTM RHEOCARBTM
COADISTM
Construction Detergent
ETHACRYLTM, RHEALISTM RHEOSOLVETM
5
Content
Dispersing theory
Dispersant introduction
Case studies
Wrap up
6
I. Pigment Dispersing Process
7
ZETA Theory : Stabilization
Definition:
Particles surface were coverd with charges. These charges help to increase the
thickness of the double layer charge and the surface ZETA potential. Then bigger
repulsion will occur and result to better dispersion between particles.
Repulsion between particles
+ + + + ++ ++ ++ ++
+ + + +
+ + + +
+ + + + + +
+ + + + + +
+ + + + + +
+ + ++ ++
+ + + + + ++ + + ++ +
8
Steric and Ionic Dispersants
Steric Dispersants
Ionic Dispersants
(comb polymers)
E
+
+ +
E ?
+ dc
dc d +
d
+
9
Coadis™ and Ecodis™
Pigment
Matt Eggshell Satin Semi gloss Gloss Paste
Coadis™ 123 K
+
Water Resistance
Potassium salt
Ecodis™ P 30
Sodium salt
-
Coarse Fine
Oxide Organic
Fillers CaCO3 CLAY TiO2 ZnO Fe2O3
pigments pigment
10
Case Studies
Exterior primer
● Alkali burnout and Salting out resistance
11
Amount/g
Test results
Tinting strength of
Reference Coadis 123K formulas with 123K is
better than that of
general salt dispersant.
13
Tinting Strength
Tinting Strength
107%
106%
105%
104% Reference
103% 123 K
102% Reference
101% 123 K
100% Reference
99%
123 K
98%
97%
96%
Reference 123 K Reference 123 K Reference 123 K
Tinting strength of reference paint is 100% and as the std., higher than 100% is better and
lower than 100% is worse.
14
Stain Resistance
Basic processes:
Drops 5 liquid stains and brush 1 solid stain on the panels, after 2 hours, moves away
stains by water and tissue.
Uses GB scrub machine and 2% washing powder solution as media, brushes 200
times and dries.
900
800
700
600
500
400
300
200 123 K reference
100
0
reference 123 K
Scrub resistance of 123K is much better than that of general salt dispersant.
16
Amount/g
Ingredient Function Reference Coadis 123K
Grinding Water Water 19.00 19.00
Anti Freeze-thaw
PG 1.60 1.60
agent
18
Performance additives: Coadis™ dispersants
20
Tinting strength
Tinting Strength
130%
120%
Reference
123 K
110%
Reference
123 K
100%
Reference
123 K
90%
80%
Reference 123 K Reference 123 K Reference 123 K
21
Exterior Primer PVC=40%
Amount/g
Ingredient Function Reference Coadis 123K
Grinding Water Water 20.00 20.00
LXE Biocide 0.10 0.10
Dispersant Dispersant 1 0.50 0.00
Coadis 123K Dispersant 2 0.00 0.80
AMP 95 pH adjuster 0.10 0.10
Anti Freeze-thaw
PG 1.99 1.99
agent
Texanol Coalescent 2.30 2.30
CF 246 Defoamer 0.10 0.10
LF-45 Wetting 0.15 0.15
R996 Pigment 4.50 4.50
MS 800 Filler 26.00 26.00
250HBR Thickener 0.60 0.45
Let down Water Water 10.46 10.31
Encor 2470 Binder 33.00 33.00
CF 246 Defoamer 0.20 0.20
Total 100.00 100.00
22
Alkali burnout and Salting out resistance
23
Trim paint
Amount/g
24
gloss
25
Coadis 123 other application
Wood coating
Muti-color paint
Industrial paint
….
26
Conclusion
The different concerns linked to water resistance
Scrub resistance
Snail traces
Extending painting season
27
Conclusion
How to improve water resistance?
Improve hydrophobicity
Optimize pigment dispersion
by using an efficient
and hydrophobic
dispersing agent
Coadis™ 123 K
28
29
Thank you for your attention!
Chinacoat
December 2014