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1. Suppose that 1.0 mol H2 at 2.0 atm and 25oC and 2.0 mol N2 at 3.0 atm and 25 oC are mixed at
constant volume.
a. Calculate ΔGtot.
b. What would be the value of ΔGmix when the pressures been identical initially?
2. Draw Temperature-composition phase diagrams (T vs wt%) for binary systems with
a. complete liquid and solid solubility,
b. complete liquid but zero solid solubility, and
c. complete liquid and limited solid solubility.
(In your sketches label phase fields and give characteristic temperatures.)
4. For the binary system Cu-Ni the following data are available from cooling experiments:
1. Suppose that 1.0 mol H2 at 2.0 atm and 25oC and 2.0 mol N2 at 3.0 atm and 25 oC are mixed at
constant volume. Calculate ΔGmix. What would be the value of ΔGmix when the pressures been
identical initially?
= C Joule
=A+B+C
When the pressure identical initially:
a.
b.
5. Pada 90 °C, tekanan uap metilbenzena dan 1,3-dimetilbenzena masing-masing sebesar 53,3
dan 18,0 kPa.
a. Berapakah komposisi cairan bila mendidih pada 90 °C dan tekanan 0,40 atm?
C6H6 (% 60, 65, 75, 82,5 87, 91, 45, 36, 20, 10,9 5,9 2,8
berat) 8 9 7 6 2 1 5 9
H2O (% 7,1 5,6 3,4 2,0 1,2 0,7 12, 16, 26, 37,2 46, 55,6
berat) 6 7 6 2
Etanol (% 32, 28, 21, 15,5 11, 8,1 42, 46, 52, 51,9 47, 41,6
berat) 1 5 1 2 3 8 2 9
Jawab
100
90
80
70
60
50
40
30
20
10
7. Tekanan uap larutan 0,5 M KNO3 (aq) pada temperatur 100 oC adalah 749,7 Torr. Hitunglah
aktivitas air pada temperatur tersebut.
Jawab:
Karena tekanan uap air murni pada temperatur 100 oC adalah 760,0 torr, maka kita memperoleh:
a(H2O) = 749,7 torr / 760,0 torr = 0,9864