BLUE Msds PDF

DYEGUARD BLUE 98
(Version 7) Issue date: January 2009 M500

Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: DYEGUARD BLUE 98
Application: Liquid dye for petroleum products.
Manufacturer/Supplier: John Hogg Technical Solutions
Address: Mellors Road

Trafford Park
Manchester
M17 1PB
UK
Contact: Mr. A. Maconachie
Phone Number: + 44 161 872 5611

Fax Number: + 44 161 848 8206
Emergency Phone Number: + 44 7713 788 771
E-mail: info@johnhogg.co.uk
2. HAZARD IDENTIFICATION
HEALTH HAZARDS
Limited evidence of a carcinogenic effect.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
PHYSICAL AND CHEMICAL HAZARDS

Static discharge. Product can accumulate static charges, which can cause an
incendiary electrical discharge.
FIRE AND EXPLOSION HAZARDS

Low hazard. Material can form flammable mixtures or can burn on heating to
temperatures at or above the flash point.
ENVIRONMENTAL HAZARDS
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
John Hogg Technical Solutions Limited p1 of 9

Mellors Road, Newbridge, Trafford Park, Manchester M17 1PB United Kingdom
Tel: +44 (0)161 872 5611 Fax: +44 (0)161 848 8206
Certificate No.FM09757 E-mail: info@johnhogg.co.uk Web: www.johnhogg.co.uk
DYEGUARD BLUE 98
3. COMPOSITION/INFORMATION ON INGREDIENTS
NAME
CAS No. EINECS No CLASSIFICATION CONTENT
SOLVENT NAPHTHA (PETROLEUM) HEAVY AROMATIC

64742-94-5 265-198-5 Xn, N R51/53,65,66,67 50 - 55%
C.I. SOLVENT BLUE 98 DYES

2475-44-7 219-602-1} -------- 45 - 50%
2646-15-3 220-161-2}
75476-94-7 278-219-8}
29887-08-9 249-931-6}
91696-32-1 294-187-8}
91696-30-9 294-185-7}
---------------------------------------------------------------------------------------------------------------------------------------
Note that the Solvent Naphtha is a complex mixture in which the following reportable
component is identified.
NAPHTHALENE
91-20-3 202-049-5 Xn, N R22,40,50/53 2–4%
The full text for all R-Phrases is displayed in Section 16.
4. FIRST AID MEASURES
EYES: Immediately wash with fresh water for at least 15 minutes

and seek MEDICAL ATTENTION IMMEDIATELY.
SKIN: Remove contaminated clothing as soon as possible; this

will be a fire hazard. Wash exposed skin thoroughly with
soap and water. If irritation persists, consult a physician.
Launder contaminated clothing before re-use. Badly
contaminated leather shoes or clothing should be
discarded.
INHALATION: In event of over-exposure remove individual to fresh air,

taking steps necessary to protect the rescuer. If
unconscious but breathing, place in recovery position. If
breathing stops, administer artificial respiration. SEEK
MEDICAL ASSISTANCE.

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DYEGUARD BLUE 98
INGESTION: If this material is swallowed DO NOT INDUCE VOMITING.

If vomiting begins, lower victim's head in an effort to
prevent vomit from entering lungs. IMMEDIATELY SEEK
MEDICAL ASSISTANCE. If victim is unconscious do not
attempt to administer fluids, place in recovery position and
protect airway.
5. FIRE FIGHTING MEASURES
EXTINGUISHING Use water spray, dry chemical, foam or carbon dioxide.

MEDIA: NEVER USE WATER IN A JET.
SPECIAL FIRE Wear impervious clothing and self contained breathing

FIGHTING apparatus. Use water to keep fire-exposed containers
PROCEDURE: cool. If a leak or spill has not ignited use water spray to
disperse the vapours and to provide protection for
personnel attempting to stop a leak. Take care not to
spread the fire with water. Contain fire-fighting water to
prevent ingress to watercourses as it will cause oil
pollution.
FIRE AND Products of combustion may contain carbon monoxide,

EXPLOSION carbon dioxide and other toxic materials. Do not enter
HAZARDS: enclosed or confined space without proper protective
equipment including respiratory protection. Solvent
vapours are an explosion hazard. Keep material away
from sources of ignition. Closed containers may explode
from vapour pressure increases when exposed to extreme
heat. Vapours may travel great distances and ignite and
flashback to source.
6. ACCIDENTAL RELEASE MEASURES
Remove all sources of ignition. Ensure adequate ventilation. Shut off source and
contain with sand or earth to prevent entry to watercourses and sewers. Contain spill
immediately in smallest area possible. Recover as much of the product itself as
possible by such methods as vacuuming, using an approved vacuum pump powered
by a flame proof motor, followed by soaking up of residual fluids by use of
absorbent materials. Remove contaminated items including contaminated soil and
place in proper containers for disposal. Avoid washing, draining or directing material
to sewers/watercourses.

Tel: +44 (0)161 872 5611 Fax: +44 (0)161 848 8206
DYEGUARD BLUE 98
7. HANDLING & STORAGE
Handle in a well-ventilated area or provide efficient exhaust ventilation. Wear long

sleeved, chemical resistant gloves, and also safety glasses if there is a risk of
splashing. Avoid prolonged contact with the skin.
Store in properly designed tanks or approved tightly closed containers in cool, well
ventilated situations away from sources of ignition. Protect from static discharges.
All hazard precautions given here must be applied to handling of empty containers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
INGREDIENT NAME: CAS No.: STD LT EXP (8 HRS)
Heavy Solvent Naphtha 64742-94-5 WEL 5 mg/m3 (Oil mist)
RESPIRATORY Unprotected inhalation of vapour should be avoided.

PROTECTION: Self contained breathing apparatus or other suitable
protection must be worn if TLV levels are exceeded.
Provide adequate ventilation.
EYE Goggles to BSEN 166 are required when exposed to

PROTECTION: vapour or when splashing is possible. Eyewash should
be provided.
SKIN PROTECTION: Unprotected exposure by skin contact to liquid or vapour

should be avoided. Protective clothing consisting of
impervious gloves (nitrile rubber or PVC) and coveralls
should be used when necessary to avoid skin contact.
9. PHYSICAL & CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid

COLOUR: Blue
ODOUR: Distinctive (Aromatic Hydrocarbon)
BOILING POINT/RANGE: 185 - 215°C
FREEZING POINT: < -20°C
FLASH POINT: ≥ 61°C (Closed cup, IP34)
EXPLOSIVE LIMITS: 0.7 – 6.0 % Vol. (Heavy Solvent Naphtha)
AUTO IGNITION TEMP.: 425°C (Heavy Solvent Naphtha)
DENSITY: (15°C) approx. 0.98 kg/dm3

VISCOSITY: (20°C) approx. 25 cPs
(40°C) approx. 10 cPs
SOLUBILITY IN WATER: Essentially insoluble

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DYEGUARD BLUE 98
10. STABILITY & REACTIVITY
STABILITY: Stable under normal storage conditions.
CONDITIONS TO AVOID: Do not heat above flash point. Avoid naked flames
and sparks.
MATERIALS TO AVOID: Strong Oxidising Agents, Strong Reducing Agents,

Acids.
HAZARDOUS DECOMPOSITION
PRODUCTS: Does not decompose under normal conditions.
HAZARDOUS COMBUSTION
PRODUCTS: Carbon Monoxide, Polycyclic Aromatic
Hydrocarbons, Unburnt Hydrocarbon, Oxides of
Nitrogen
HAZARDOUS
POLYMERISATION: Does not polymerise.
ELECTROSTATIC
ACCUMULATION HAZARD: Yes.
11. TOXICOLOGICAL INFORMATION
PRIMARY ROUTE OF
EXPOSURE/ENTRY: Eye, skin, inhalation
SKIN/EYE: Vapour may irritate the eyes. Liquid is irritating and

potentially damaging to eyes. Liquid may irritate
and dry the skin. Prolonged contact may lead to
burns and blisters and may aggravate dermatitis.
INGESTION: May lead to headache, dizziness, nausea and

abdominal pain.
INHALATION: Vapours may irritate the respiratory tract and may

lead to headache, dizziness, nausea, vomiting and
unconsciousness.
High vapour concentrations are anaesthetic and
may have other central nervous system effects
including death.

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DYEGUARD BLUE 98
Known toxicological information for the components of the product.
COMPONENT: SOLVENT NAPHTHA (PETROLEUM), HEAVY

AROMATIC
Toxicological data: Acute toxicity. LD50. (Oral) > 2000 mg/kg

Acute toxicity. LD50. (Skin) > 2000 mg/kg
Acute toxicity. LC50. 4 hours. Inhalation. > 5 mg/l
Sensitisation. Skin. Guinea Pig. Negative
COMPONENT: C.I. SOLVENT BLUE 98
Toxicological data: Acute toxicity. LD50. (Oral rat) > 5000 mg/kg
COMPONENT: NAPHTHALENE
This product contains naphthalene. The International Agency for Research on Cancer
evaluated naphthalene and concluded that there was sufficient evidence for
carcinogenicity in experimental animals, but inadequate evidence for cancer in
exposed humans.
12. ECOLOGICAL INFORMATION
If released to water, the majority of this product will evaporate at a slow rate. Aerobic
degradation will occur in water and in sediments.
COMPONENT: SOLVENT NAPHTHA (PETROLEUM), HEAVY

AROMATIC
Toxicological data: Acute toxicity. Fish 1<LC/EC/IC50<= 10 mg/l

Acute toxicity. Daphnia 1<LC/EC/IC50<= 10 mg/l
Acute toxicity. Algae 1<LC/EC/IC50<= 10 mg/l
13. DISPOSAL
When material cannot be re-cycled or incinerated in a safe manner, it should be

disposed of in accordance with local regulations.

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DYEGUARD BLUE 98
14. TRANSPORT INFORMATION
SYMBOLS FOR TRANSPORT
LAND TRANSPORT (Rail/Road)
ADR/RID CLASS: 9.11(c) UN Number: 3082

PACKING GROUP: III HAZARD No. 90
TRANSPORT NAME: Environmentally Hazardous Substance, Liquid, n.o.s.
(alkyl C3 – C15 benzenes)
SEA TRANSPORT (IMDG)
IMDG CLASS: 9 UN Number: 3082

PACKING GROUP: III MARINE POLLUTANT: NO
SHIPPING NAME: Environmentally Hazardous Substance, Liquid, n.o.s.
(alkyl C3 – C15 benzenes)
AIR TRANSPORT (IATA/ICAO)
IATA/ICAO CLASS: 9 UN Number: 3082

PACKING GROUP: III PACKING INSTRUCTION: 914
TRANSPORT NAME: Environmentally Hazardous Substance, Liquid, n.o.s.
(containing alkyl C3 – C15 benzenes)
15. REGULATORY INFORMATION
HAZARD CLASS: Xn – Harmful

N - Dangerous for the environment.
SYMBOL: St. Andrews Cross
Dead fish and tree.

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DYEGUARD BLUE 98
RISK PHRASES: R40: Limited evidence of a carcinogenic effect.

R51/53: Toxic to aquatic organisms, may cause long term
adverse effects in the aquatic environment
R66: Repeated exposure may cause skin dryness or
cracking.
R67: Vapours may cause drowsiness and dizziness.
SAFETY PHRASES: S23: Do not breathe gas/fumes/vapour/spray.

S24/25: Avoid contact with skin and eyes.
S36/37: Wear suitable protective clothing and gloves.
S57: Use appropriate containment to avoid environmental
contamination.
S60: This material and its container must be disposed of
as hazardous waste.
S61: Avoid release to the environment. Refer to special
instructions/safety data sheet.
UK REGULATORY REFERENCE:
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002
(CHIP 3)
EU DIRECTIVES: Directive 67/548/EEC

Directive 1999/45/EC
APPROVED CODE OF PRACTICE: The compilation of safety data sheets L130

Approved classification and labelling guide
L131
Approved supply list L129
GUIDANCE NOTES: Occupational Exposure Limits EH40

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DYEGUARD BLUE 98
16. OTHER INFORMATION
REVISION COMMENTS: Sections 8 & 16 have revised information.
DISCLAIMER:
This product should be stored, handled and used in accordance with good industrial
hygiene practices and in conformity with any legal regulations. This information is
based on our present state of knowledge and is intended to describe the product from
the point of view of safety requirements. It should not be construed as guaranteeing
specific properties.
R PHRASES (full text) R22: Harmful if swallowed.

R40: Limited evidence of a carcinogenic effect.
R50/53: Very toxic to aquatic organisms, may cause long
term adverse effects in the aquatic environment.
R51/53: Toxic to aquatic organisms, may cause long term
adverse effects in the aquatic environment.
R65: Harmful, may cause damage to lungs if swallowed.
R66: Repeated exposure may cause skin dryness or
cracking.
R67: Vapours may cause drowsiness and dizziness.

Tel: +44 (0)161 872 5611 Fax: +44 (0)161 848 8206

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DYEGUARD BLUE 98

(Version 7) Issue date: January 2009 M500

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: DYEGUARD BLUE 98

Application: Liquid dye for petroleum products.

Manufacturer/Supplier: John Hogg Technical Solutions

Address: Mellors Road

Phone Number: + 44 161 872 5611

PHYSICAL AND CHEMICAL HAZARDS

FIRE AND EXPLOSION HAZARDS

John Hogg Technical Solutions Limited p1 of 9

SOLVENT NAPHTHA (PETROLEUM) HEAVY AROMATIC

C.I. SOLVENT BLUE 98 DYES

The full text for all R-Phrases is displayed in Section 16.

4. FIRST AID MEASURES

EYES: Immediately wash with fresh water for at least 15 minutes

SKIN: Remove contaminated clothing as soon as possible; this

INHALATION: In event of over-exposure remove individual to fresh air,

John Hogg Technical Solutions Limited p2 of 9

INGESTION: If this material is swallowed DO NOT INDUCE VOMITING.

5. FIRE FIGHTING MEASURES

EXTINGUISHING Use water spray, dry chemical, foam or carbon dioxide.

SPECIAL FIRE Wear impervious clothing and self contained breathing

FIRE AND Products of combustion may contain carbon monoxide,

6. ACCIDENTAL RELEASE MEASURES

John Hogg Technical Solutions Limited p3 of 9

7. HANDLING & STORAGE

Handle in a well-ventilated area or provide efficient exhaust ventilation. Wear long

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

INGREDIENT NAME: CAS No.: STD LT EXP (8 HRS)

Heavy Solvent Naphtha 64742-94-5 WEL 5 mg/m3 (Oil mist)

RESPIRATORY Unprotected inhalation of vapour should be avoided.

EYE Goggles to BSEN 166 are required when exposed to

SKIN PROTECTION: Unprotected exposure by skin contact to liquid or vapour

9. PHYSICAL & CHEMICAL PROPERTIES

PHYSICAL STATE: Liquid

DENSITY: (15°C) approx. 0.98 kg/dm3

SOLUBILITY IN WATER: Essentially insoluble

10. STABILITY & REACTIVITY

STABILITY: Stable under normal storage conditions.

MATERIALS TO AVOID: Strong Oxidising Agents, Strong Reducing Agents,

11. TOXICOLOGICAL INFORMATION

SKIN/EYE: Vapour may irritate the eyes. Liquid is irritating and

INGESTION: May lead to headache, dizziness, nausea and

INHALATION: Vapours may irritate the respiratory tract and may

John Hogg Technical Solutions Limited p5 of 9

Known toxicological information for the components of the product.

COMPONENT: SOLVENT NAPHTHA (PETROLEUM), HEAVY

Toxicological data: Acute toxicity. LD50. (Oral) > 2000 mg/kg

COMPONENT: C.I. SOLVENT BLUE 98

12. ECOLOGICAL INFORMATION

COMPONENT: SOLVENT NAPHTHA (PETROLEUM), HEAVY

Toxicological data: Acute toxicity. Fish 1<LC/EC/IC50<= 10 mg/l

When material cannot be re-cycled or incinerated in a safe manner, it should be

John Hogg Technical Solutions Limited p6 of 9

14. TRANSPORT INFORMATION

SYMBOLS FOR TRANSPORT

LAND TRANSPORT (Rail/Road)

ADR/RID CLASS: 9.11(c) UN Number: 3082

SEA TRANSPORT (IMDG)

IMDG CLASS: 9 UN Number: 3082

AIR TRANSPORT (IATA/ICAO)

IATA/ICAO CLASS: 9 UN Number: 3082