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Reactivity
3. For each of the following, state whether or not you expect any reaction to occur to any
significant extent. Fully describe and write equations for any reactions which would be
expected to occur.
(a) Sodium metal is added to warm hexane.
No reaction
(b) Chlorine and hexane vapour are heated in the dark.
No reaction
Complete Combustion:
7
C2H6 (g) + O (g) 2CO2 (g) + 3H2O (l)
2 2
(e) Nonane was reacted with a limited supply of oxygen.
Incompletion Combustion:
C9H20 (l) + 19 O2 9CO (g) + 10H2O (l)
2
Combustion
4 For complete combustion, 1 mole of alkane was found to require 5 moles of oxygen.
Give the possible formula of this hydrocarbon.
y y
CxHy (g) + (x + ) O2 (g) xCO2 (g) + H O (l)
4 2 2
10cm3 100 cm3
x 40 10cm3 65cm3
= x y
1 10 4 65
x = 4 =
1 10
4x y
= 6.5
4
4x+y = 26
y = 10
Alkanes Tutorial 2
2011 DHS Year 5 H2 Chemistry
(c) Briefly describe what happens and write any equations for reactions that occur in this
reaction.
Step 1: Initiation
Chlorine is supplied with energy (ultraviolet light) to split into free
radicals via homolytic fission of Cl – Cl bond.
UV light
Cl – Cl Cl + Cl (slow step)
Step 2: Propagation
Highly reactive chlorine radicals collide with propane molecules and
abstract one of its hydrogen atoms leaving another free radical.
The free chlorine radical reacts with another molecule and the
chain reaction continues
Step 3: Termination
The chain reaction ends when two free radicals collide and
combine to form a stable product, i.e. no reactive free radicals
present.
Cl + Cl Cl2
CH3CH2CH2 + Cl CH3CH2CH2Cl
CH3CH2CH2 + CH3CH2CH2 CH3(CH2)4CH3
(d) State the type of isomerism exhibited by the two different mono–chloropropanes.
Positional isomerism
(e) Draw the structural formula of each of the two isomeric products. Suggest (with a reason)
in what ratio they might be formed.
Isomers: 1–chloropropane and 2–chloropropane
H H H H H H
H C C C H H C C C H
Cl H H H Cl H
*(f) In a separate experiment, a sample of propane was reacted with bromine under sunlight
to yield disubstituted halogenoalkanes as products.
(i) Draw the displayed formula of all possible products and name them.
Isomers:
1,1–dibromopropane 2,2–dibromopropane
Br H H H Br H
H C C C H H C C C H
Br H H H Br H
1,2–dibromopropane 1,3–dibromopropane
H H H H H H
H C C C H H C C C H
Br Br H Br H Br
Step 2: Propagation
Highly reactive bromine radicals collide with propane molecules and
abstract one of its hydrogen atoms leaving another free radical.
Alkanes Tutorial 4
2011 DHS Year 5 H2 Chemistry
The free bromine radical reacts with another molecule and the
chain reaction continues
Step 3: Termination
The chain reaction ends when two free radicals collide and
combine to form a stable product, i.e. no reactive free radicals
present.
Br + Br Br2
CH3CH2CH2 + Br CH3CH2CH2Br
CH3CH2CH2 + CH3CH2CH2 CH3(CH2)4CH3
CH3CH2CHBr + Br CH3CH2CHBr2
7. If a few drops of bromine are added to pentane a deep red solution is formed. No
reaction occurs if the mixture is kept in the dark, but in sunlight the red colour slowly
disappears and a misty gas is given off.
* the misty colourless gas formed in the reaction.
Energy from ultraviolet light (in sunlight) causes homolytic fission of Br–
Br bond to occur and this leads to the formation of chlorine free
radicals, Br .
Alkanes Tutorial 5
2011 DHS Year 5 H2 Chemistry
Nomenclature (Self–Attempt)
1. Name the following alkanes:
n–hexane ethylcylopentane
CH3 CH2CH3
CH3CHCH2CHCH2CH3
(b) (d)
4–ethyl–2–methylhexane methylcyclopropane
2 Write the full structural formula of the following alkanes:
(a) ethylcyclohexane (d) 3,4–diethyl–2,2–dimethylheptane
H H H
H H H
C C
H C C C H
H H
C C H
C H
H H
H H
H H H
H H
C C
H C C H
H
C C H
H C
H H H
H
Alkanes Tutorial 6