Para el Zn sólido

𝐺_𝑇1^𝑠=𝐻_𝑇1^𝑠−𝑇𝑆_𝑇1 ecuacion………1
^𝑆
Entalpia:
𝐻_𝑇1^𝑠=∫24_298^𝑇
▒𝐶𝑝(𝑠)𝑑𝑇

Entropia:
𝑆_𝑇1^𝑆=∫_298^𝑇▒
〖𝐶𝑝 (𝑠)/𝑇 𝑑𝑇 〗

Para el Zn liquido

𝐺_𝑇1^𝐿=𝐻_𝑇1^𝐿−𝑇𝑆_𝑇1
^𝐿 ecuacion….2

Entalpia
𝐻_𝑇1^𝐿−𝐻_692^𝐿=∫_692^𝑇
▒𝐶𝑝(𝑙)𝑑𝑇

DESPUES LA ENTALPIA RESULTA

𝐻_𝑇1^𝐿=4360.081+∫_692^𝑇▒𝐶𝑝(𝑙
)𝑑𝑇

ENTROPIA:
𝑆_𝑇1^𝐿−𝑆_692^𝐿=∫_692^𝑇▒ 〖𝐶𝑝 𝑆_692^𝐿−𝑆_692^𝑆=∆𝑆𝑓
(𝑙)𝑑𝑇/𝑇 〗

DESPUES LA ENTROPIA RESULTA

𝑆_𝑇1^𝐿=8.0375+∫_692^𝑇▒ 〖𝐶𝑝 (𝑙 𝑆_𝑇1^𝐿=8.0375+∫_692^𝑇▒ 〖 (7.5
)𝑑𝑇/𝑇 〗
〗

Gsolido T (°K)
-82.6830662887721 392
-186.790781361297 442
-327.406724699632 492
-501.495607096513 542
-706.584821219488 592
-940.621077587014 642
-1201.87197675899 692
-1488.85617675853 742
-1800.29246716438 792
-2135.0617529582 842
-2492.17809887218 892
-2870.7662854174 942
-3270.04414273962 992
-3689.30845466497 1042

G liquido T (°K)
598.531873308231 392
396.660733803383 442
150.392698577107 492
-135.88407140239 542
-458.594892391604 592
-814.771294454367 642
-1201.90872297157 692
-1617.86558068519 742
-2060.78960338622 792
-2529.06289941957 842
-3021.26008808379 892
-3536.11585206058 942
-4072.49939721784 992
-4629.39407388707 1042
 𝐻_𝑇1^𝑠=∫_298^𝑇▒(5.25+0,002
7𝑇)𝑑𝑇

𝑆_𝑇1^𝑆=∫_298^𝑇▒ 〖 ((5.25+0
.0027𝑇))/𝑇 𝑑𝑇 〗

Reemplazando HT1 solido y ST1 solido en ecuac. 1

𝐻_692^𝐿−𝐻_692^𝑆= 〖∆
𝐻〗 _(𝑆−𝐿) 𝐻_692^𝐿=1765+5.25T+0.00135𝑇^2−1684
𝐻_692^𝐿=1765+𝐻_692^𝑆

𝐻_𝑇1^𝐿=4360.081+∫_692^𝑇▒ 〖 (7.59+0.000
55𝑇)𝑑𝑇 〗 𝐻_𝑇1^𝐿=4360.081+7.59(𝑇−692)+0.0002
〗 ^2)

𝑆_692^𝐿−𝑆_692^𝑆=∆𝑆𝑓
𝑆_692^𝐿=2.5506+𝑆_692^𝑆
𝑆_𝑇1^𝐿=8.0375+∫_692^𝑇▒ 〖 (7.59+0.00055𝑇)𝑑𝑇/𝑇
𝑆_𝑇1^𝐿=8.0375+7.59(𝑙𝑛𝑇−𝑙𝑛692)+0.00055(𝑇−
〗

Reemplazando HT1 LIQUIDO y ST1 LIQUIDO en ecuac. 2

1000 ENERGIA LIBRE vs TEMPERATURA PARA E

0
300 400 500 600 700 800

-1000
ENERGIA LIBRE(G)

-2000

-3000

-4000
G liquido Gsolido

-5000
TEMPERATURA (°K)
 𝐻_𝑇1^𝑠=5.25(𝑇−298)+0.0027 ((𝑇^2− 〖 298 〗
^2))/2

⁡ 𝑇−𝑙𝑛 298) 〗
𝑆_𝑇1^𝑆=5.25 〖 (ln 〗〖
+0.0027(𝑇−298)

𝐺_𝑇1^𝑠=35.9643𝑇−0.00135𝑇^2−1684.3854−5.25Tln(T)

POR TABLAS: 〖∆𝐻〗 _𝑓=1765𝑐𝑎𝑙/𝑚𝑜𝑙

𝐻_692^𝐿=1765+5.25(692)+0.0013
𝐻_692^𝐿=1765+5.25T+0.00135𝑇^2−1684.3854

𝐻_𝑇1^𝐿=4360.081+7.59(𝑇−692)+0.000275(𝑇^2− 〖 692
〗 ^2)
∆𝑆𝑓=∆𝐻𝑓/𝑇𝑓=1765/692=2.5506

𝑆_692^𝐿=2.5506+5,25 ln⁡(𝑇)+0.0027𝑇−30.7143
055𝑇)𝑑𝑇/𝑇
𝑆_𝑇1^𝐿=8.0375+7.59(𝑙𝑛𝑇−𝑙𝑛692)+0.00055(𝑇−692)

𝐺_𝑇1^𝐿=49.5685𝑇−0.000275𝑇^2−7.59𝑇𝑙𝑛𝑇−1023.8866

ENERGIA LIBRE vs TEMPERATURA PARA EL Zn

500 600 700 800 900 1000 1100

Gsolido

TEMPERATURA (°K)
 𝐻_𝑇1^𝑠=5.25𝑇+0.00135𝑇^2−1684.3854

𝑆_𝑇1^𝑆=5.25 ln⁡(𝑇)+0.0027𝑇−30.7143

84.3854−5.25Tln(T)

A la T=692 °K
𝐻_692^𝐿=1765+5.25(692)+0.00135(692)^2−1684.3854
𝐻_692^𝐿=4360.081

𝐻_𝑇1^𝐿=7.59𝑇+0.000275𝑇^2−1023.8866

− 〖 692

A la T=692 °K
𝑆_692^𝐿=2.5506+5.25 ln⁡(692)+0.0027(692)−30.7143
𝑆_692^𝐿=8.0375
5.63 ln⁡(T)+0.00233T
 𝑆_𝑇1^𝐿=7.59𝑙𝑛𝑇+0.00055𝑇−41.9785

𝑛𝑇−1023.8866

900 1000 1100