Beruflich Dokumente
Kultur Dokumente
Question1:
a. One mark each
a. sp3d, T shaped c. 8,6
b. Glucose and fructose d. methyl iodide, ethanol
OR
a. (i) potassium trioxalatoaluminate (III) ½ mark each
(ii) bromo bis(ethylenediammine)nitrito-Ncobalt(III)ion
b. (i) [Fe(H2O)6]SO4 (ii) Na3[Co(NO2)6] ½ mark each
Question 3:
a. HCHO + CH3CHO dil. NaOH HO- CH2- CH2 – CHO 1 mark
b. C6H3CHO + (CH3CO)2O C6H5CH = CH – COOH + CH3COOH 1mark
Question 4
W = At wt. x I x t / valency x 96500
1.45= 108 x 1.5 x t / 1 x 96500 t= 863.74s 1mark
Wcu/Wag = Ecu/Eag
Wcu/1.45 = (63.5/2)/ (108/1) WCu = 0.426g ½ mark
WZn/Wag = EZn/Eag
WZn/1.45 = (65.3/2)/ (108/1) WCu = 0.438g ½ mark
Question 5
a. PbS + 4O3 PbSO4 + 4O2 ½ mark reaction + ½ mark balancing
b. MnO2 + 2NaCl + 3H2SO4 MnSO4 + 2NaHSO4 + H2O + Cl2
CHO CHO
| 5(CH3CO)2O |
(CHOH)4 (CHOCOCH3)4 + 5CH3COOH
| |
CH2OH CH2OCOCH3
Question 7
a. p=1, q=1, r=2
Rate law is R = k [A]1[B]1[C]2 1 mark
k = 2.08 x 10-4 / ([0.02][0.02][0.02]2) = 1300 mol-3L2s-1 1 mark
OR
a. k = 0.693/t1/2 = 5.77 x 10-3 per min 1 mark
For 90%
t = 2.303 / k log (100/10) = 399 min 1mark
Question 8
a.
1 mark
b.
1 mark
Question 9
Po –P = weight of solute x molecular weight of solvent
Po molecular weight of solute x weight of solvent
4.579 – 4.559 = 8.45 x 18 = 348.25g 1 marks
4.579 m2 x 100
∆Tb = Kb
∆Tf Kf
OR
74.5 X 700
W2 = 172.193 g 1 mark
c. π = i x C x R x T
4.6 = i x 0.1 x 0.0821 x 30 thus i = 1.86
α = i-1/ n-1
α = 1.86-1/2-1 = 0.867 or 86.7% 1 mark
Question 10
a. CHCl3 + 3KOH -3KCl CH(OH)3 HCOOK + H2O 1 mark
b. CH3CH2Br + KNO2 CH3ONO + KBr 1mark
c. CH3CH2Cl + CH3COOAg CHCOOCH2CH3 + AgCl 1 mark
Question 11
a. dsp2, square planar, diamagnetic ½ mark each
b. Ionisation isomerism ½ mark
Add AgNO3 ½ mark
[PtCl2(NH3)4]Br2 : gives a pale yellow ppt ½ mark
[PtBr2(NH3)4Cl2 : gives a white ppt
Question 12
a. 3.5 = 2 x 98/6.023 x 1023 x a3
a3 = 2x98/3.5x6.023x1023 = 453pm 1mark
r = √3/4a = 0.433x 453= 196.14 pm 1marks
b. F-center defect. Anions are missing from the lattice points and their position is taken by
electrons. These electrons give colour to the compound due to excitation
1 mark
Question 13
a. CH3COCH3 + CH3MgCl H+/H2O (CH3)3COH + MgClOH ½ mark
tert-butyl alcohol ½ mark
b. C6H5OH PCl5 C6H5Cl CH3Cl/AnhyAlCl3 C6H5CH3 CrO2Cl2 C6H5COOH
2 marks
OR
Question 14
a. K1 = 0.693/t1/2 = 1.925 x 10-3 min-1 1 mark
Log(k2/k1) = Ea/2.303R (1/T1 – 1/T2) thus k2 = 0.0681 min-1 1 mark
At 4500C
t = 2.303/k2 log (100/25) = 20.36 min 1mark
Question 15
a. Ammoniacal silver nitrate: Glucose gives silver mirror, sucrose does not. 1mark
b. Vit D and Vit K ½ mark each
c. CHO – (CHOH)4 – CH2OH + NH2OH HON = C – (CHOH)4 – CH2OH
1 mark.
Question 16
a. (i) 52/6 g of Cr = 96500C
For 24000C; x = 52 x 24000/6 x 96500 = 2.155g 1 mark
(ii) 1.5 = 52 x 12.5 x t/ 6x96500 t= 1336.15s 1 mark
b. Cathode 3Ni2+ + 6e- 3Ni
Anode 2Al 2Al3+ + 6 e- ½ mark each
Ecell = Eocell – 0.059/n log[Al3+]2/ [Ni2+]3
= (-0.25 – (-1.66)) – 0.059/6 log (0.001)2/ (0.50)3
Ecell = 1.46V 1 mark
c. Nature of metal, conc of ions, temperature. Any 2; 1 mark
OR
a. ∧ ∞
∧ ∧
(NH4OH) = (NH4Cl) + (NaOH) - (NaCl) ∧
= 129.8 + 217.4 – 108.9 = 238.3 Scm2mol-1 1 mark
ά = 9.33/238.3 = 0.039 1 mark
b. Ecell = EoCell – 0.059/n log[Zn2+]/[Ag+]2
1.48 = (0.8+0.763) – 0.059/2 log (0.10)/[Ag=]2
[Ag+]2 = 1.536 x 10-4
[Ag+] = 1.247 x 10-2 M 2 marks
c. Connect two half cells, maintain electrical neutrality, minimize junction potential.
Any 2; 1 mark
Question 17
a. (i) sp3d3, pentagonal bi pyramidal 1 ½ mark
OR
a. (i) sp3d2, square pyramidal 1 ½ mark
Question 18
a. Fehling solution test: Formaldehyde gives brick red ppt, benzaldehyde does not
Add alk. KMnO4 Benzaldehyde gives white ppt, formaldehyde does not
Any one 1 mark
b. A: Benzaldehyde , B: Benzyl alcohol , C: Benzoic acid , D: Benzylidine dichloride , E: Benzoyl
chloride Name: Cannizaro’s reaction ½ mark each
c. CH3COOH Ca(OH)2 (CH3CO)2Ca dry distillation/heat CH3COCH3 1 mark
OR
a. Fehling solution test or Tollens reagent test: Formic acid gives brick red ppt and silver mirror. Acetic
acid does not. Any one, 1 mark
b. A: Propanamide B :ethanamide C: ethanol D: ethanol E: Cyanohydrin F: Lactic acid
½ mark each
c. C6H5COOH NaOH C6H5COONa NaOH, CaO/heat C6H6 CH3Cl C6H5CH3
Anhy AlCl3
(O)/KMnO4 C6H5CHO 1 mark