SR+LT BIPC PHASE-3 ALL BATCHES DAILY PRACTICE ASSIGNMENTS

DAY – 8 (DT 25-05-2020)

SUBJECT: CHEMISTRY
Chapter: Organic chemistry: Electron migration effects & reagents in organic
chemistry
==================================================================
1. Most stable carbonium ion is
   
(1) C 2 H 5 (2)  CH 3 3 C (3)  C6 H 5 3 C (4) C6 H 5 C H 2
Key: (3)

Hint :  C6 H 5 3 C
2. Which of the following species is paramagnetic in nature?
(1) Carbonium ion (2) Free radical (3) methane (4) Carbanions
Key: (2)
Hint : Conceptual
3. Which of the following has minimum–I–effect?

(1)  NO2 (2)  COOH (3)  F (4)  N R 3
Key: (3)
Hint : Conceptual
4. Which one of the following have least pKa value?
(1) CCl3COOH (2) CH2ClCOOH (3) CF3COOH (4) CH3COOH
Key: (3)
Hint : Conceptual
5. The displacement of electrons in a multiple bond in the presence of attacking reagent is called
1) inductive effect 2) electromeric effect 3) resonance 4) Hyper-conjugation
Key: (2)
Hint : Conceptual
6. Hyper conjugation effect is not possible in which of the following species

1) CH 3  C H 2 2) C6 H 5  CH3 3) CH2  CH2 4) CH3

CH3 – CH = CH – C – CH3

CH3
Key: (3)
Hint : Conceptual
7. The arrangement of
 CH 3 3 C ,  CH3 2 CH , CH 3  CH 2  when attached to Benzene or unsaturated group increasing order
of hyper conjugation?
1)  CH 3 3 C    CH 3 2 CH   CH 3  CH 2  2) CH 3  CH 2    CH 3  2 CH    CH 3 3 C 
3)  CH 3 2 CH    CH 3 3 C   CH 3  CH 2  4)  CH3 3 C  CH3  CH2    CH3 2 CH 
Key: (1)
Hint : Conceptual
8. Which among the following statements are true with respect to electronic displacement in a covalent
bond?
I. Inductive effect operates through  -bonds. II. Resonance effect operates through  -bond also.
III. Inductive effect operates through  -bonds. IV. Resonance effect operates through  -bonds.
(1) II, III & IV (2) I & II (3) II & IV (4) I & III
Key: (1)
Hint : Conceptual
9. Which among the following compounds behave both as an electrophile as well as a nucleophile
c) O d) O

a) CH 2  CH 2 b) CH 2  CH  C H 2
CH3 – C – CH3 CH3 – C – Cl
1) Only a 2) a and b 3) c and d 4) b,c and d
Key: (3)
Hint : Conceptual
10 Which of the following statements are correct for nucleophile
1) All negatively charged species are nucleophiles
2) Nucleophiles are Lewis bases
3) Alkenes, alkynes, benzene and pyrrole are nucleophiles
4) All are correct
Key: (4)
Hint : Conceptual
11. Consider the following statements :-
   
(a) CH 3 O C H 2 is more stable than CH 3 C H 2 (b) Me 2 C H is more stable than CH 3 CH 2 C H 2
 
(c) CH2 CH— C H 2 is more stable than CH 3 CH 2 C H 2
 
(d) CH2 C H is more stable than CH 3 C H 2
of these statements :-
(1) a and b are correct (2)c and d are correct
(3) a, b&c are correct (4) b, c and d are correct
Key: (3)
Hint : Conceptual
12. The formation of cyanohydrin from acetone is which type of reaction?
(1) Electrophilic substitution reaction (2) Electrophilic addition reaction
(3) Nucleophilic addition reaction (4) Nucleophilic substitution reaction
Key: (3)
Hint : Conceptual
13. The reaction,
CH2 = CH – CH3 + HBr  CH3CHBr – CH3 is
(1) Nucleophilic addition (2) Electrophilic substitution
(3) Electrophilic addition (4) Free radical addition
Key: (3)
Hint : Conceptual
14. Decreasing order of stability for the following radicals is :

CH3 CH2


 
CH2 = CH CH2CH = CH2
(I) (II) (III) (IV)
 1) II > III > I > IV 2) III > II > I > IV 3) I > II > III > IV 4) III > III > IV< I
Key: (4)
Hint : Basing on resonance and hyper conjugation
15. Decreasing order of the followin stability is:
(II)
CH3
CH3CH = CH2 CH3CH2CH = CH2 CHCH = CH2 (CH3)3 CCH = CH2
(I) (II) CH3 (IV)
(III)

1) I > II > III > IV 2) I > III > II > IV 3) I > IV > III > II 4) IV > III > II > I
Key: (1)
Hint : Refer hyper conjugation
16. Which will be the least stable resonating structure ?

1)
CH 2  CH  CH  CH  NH 2
.. 2) ..
CH 2  CH  CH  CH  NH 2

3) CH 2  CH  CH  CH  NH 2 4) CH 2  CH  CH  CH  NH 2
Key: (1)
Hint : In Structure one the opposite charges are present on adjacent atoms and both are in conjugation
17. The most stable resonating structure of CH 3  O  CH  CH is

..
3 ..
1) CH  O  CH  CH
2
2) CH 3  O  CH  CH 2

..
3 ..
3) CH  O  CH  CH
2
4) CH 3  O  CH  CH 2

Key: (2)
Hint : Structure 2 is only possible resonating structure
18. The correct order of increasing basicity of the given conjugate bases ( R  CH 3 ) is
1) RCOO  HC  C  N H 2  R 2) RCOO  HC  C  R  NH 2
3) R  HC  C  RCOO  N H 2 4) RCOO  N H 2  HC  C  R
Key: (1)
Hint : Acidity strength R - COOH > HC  CH  NH 3  R  H
19. Reactivity of H-atoms attached to different atoms in alkanes has the order
1) 3 0  10  2 0 2)10  2 0  3 0 3) 30  20  10 4) None
Key: (3)
Hint : 30  20  10
20. The correct order of stability of given carbocations is
I) II) III) IV) + 
  O O
O
 + O



+
+
1) I > IV > III > II 2) I > IV > II > III 3) IV > I > III > II 4) IV > I > II >III
Key: (4)
Hint : Conceptual
21. The decreasing order of nucleophilicity among the nucleophiles is
–
I) CH3 – C – O IV) O

II) CH 3O III) CN 
–
O H3C S–O

O
1) I > II > III > IV 2) IV > III > II > I 3) II > III > I > IV 4) III > II > I > IV
Key: (3)
Hint : Conceptual
22. Correct order of stability
P)  Q) 
CH2 CH2 R)  CH S)  CH
2 2

OH NO2 CH3 Cl
1) P > Q > R > S 2) Q > S > R > P 3) Q > P > S > R 4) P > R > S > Q
Key: (4)
Hint : Conceptual
23. For the following reactions
a) CH 3  CH 2  CH 2  Br  KOH  CH 3  CH  CH 2  KBr  H 2O
b) CH3 CH3 CH3 CH3 c) Br
+ KOH + Br2
Br OH
Br
Which of the following statements is correct ( NEET -2016)
1) a is substitution b and c are addition reactions 2) a and b are elimination reactions and c is addition reaction
3) a is elimination b substitution and ‘C’ is addition reaction 4) a is elimination b, c are substitution reactions
Key: (3)
Hint: Conceptual
24. Presence of a nitro group in a benzene ring [CBSE AIPMT 2009]
1) deactivates the ring towards electrophilic substitution 2) activates the ring towards electrophilic substitution
3) renders the ring basic 4)deactivates the ring towards nucleophilic substitution
Key: (1)
Hint: Conceptual
25. The order of decreasing reactivity towards an electrophilic reagent, for the following:
[CBSE AIPMT 2007]
(i) Benzene (ii) Toluene (iii) Chlorobenzene (iv) Phenol would be
(1) (i) > (ii) > (iii) > (iv) (2) (ii) > (iv) > (i) > (iii) (3) (iv) > (iii) > (ii) > (i) (4) (iv) > (ii) > (i) > (iii)
Key: (4)
Hint: Conceptual
26. Consider the following compounds

I) CH3

CH3 – C – CH

CH3
II) Ph 
III)
Ph – C – Ph

CH3
 Hyper conjugation occurs in ( AIPMT 2015)
1) III only 2) I, III only 3) I only 4) II only
Key: (1)
Hint : Conceptual
27. Base strength of [CBSE AIPMT 2008]
 
(i) H 2 C C H 2 , (ii) H 2 C  C H and (iii) H  C  C  is in the order of
(1) (ii) > (i) > (iii) (2) (iii) > (ii) > (i) (3) (i) > (iii) > (ii) (4) (i) > (ii) > (iii)
Key: (4)
Hint : Acidic strength
HC  CH  CH 2  CH 2  CH 3  CH 3
Electronegativity SP  SP 2  SP 3
28. Which of the following reactions is an example of nucleophilic substitution reaction?
[CBSE AIPMT 2009]
(1) RX  KOH  ROH  KX (2) 2RX  2 Na  R  R  2 NaX
(3) RX  H 2  RH  HX (4) RX  Mg  RMgX
Key: (1)
Hint : Conceptual
29. Which one of the following compounds has the most acidic nature? [CBSE AIPMT 2010]
3) OH 4) OH
1) CH2OH 2) OH
CH

Key: (2)
Hint : Phenols are more acidic than alcohols
30. Which of the following is the most correct electron displacement for a nucleophilic reaction to take
place? [AIPMT-2015]
1) H H2
2) H H2
H3C – C = C – C – Cl H C – C = C – C – Cl
H 3
H

3) H H2 4)
H3C – C = C – C – Cl H H2
H H3C – C = C – C – Cl
H
Key: (3)
Hint : Conceptual
31. Which of the following statements is not correct for a nucleophile? [AIPMT-2015]
(1) Nucleophiles attack low e density sites (2) Nucleophiles are electron donating
(3) Nucleophiles is a Lewis acid (4) Ammonia is a nucleophile
Key: (3)


Hint : ‘N’ is SP2 hybridised N L.P is inovlved in delocalization
N



H



NH2



N 20 amine, N is SP3 hybridised L.P of N involved in resonance

H
32. The strongest base among the following is
[AIPMT-2003]
1) 2) NH2
3) 4)

N N
N
H H
Key: (3) NH
Hint : Conceptual
33. Nucleophilic addition reaction will be most favoured in : [AIPMT-2006]
1) O 2) O 3) O 4) O

CH3CH2CH2 – C – CH3 CH3 – C – CH3 CH3 – CH2 – CH2 – C – H CH3 – C – H

Key: (4)
Hint : Conceptual
34. Which of the following presents the correct order of the acidity in the given compounds :[AIPMT-2007]
(1) FCH2COOH > CH3COOH > BrCH2COOH > ClCH2COOH
(2) BrCH2COOH > ClCH2COOH > FCH2COOH > CH3COOH
(3) FCH2COOH > ClCH2COOH > BrCH2COOH > CH3COOH
(4) CH3COOH > BrCH2COOH > ClCH2COOH > FCH2COOH
Key: (3)
Hint : With drawing effect ( -I). F > Cl > Br > I
35. For the following : [AIPMT-2007]
(a) I– (b) Cl– (c) Br–
the increasing order of nucleophilicity would be:
(1) Cl– < Br– < I– (2) I– < Cl– < Br– (3) Br– < Cl– < I– (4) I– < Br– < Cl–
Key: (1)
Hint : Conceptual
36. Which one of the following is most reactive towards electrophilic attack :- [AIPMT-2008]
1) OH 2) Cl
3) CH2OH 4) NO2

Key: (1)
Hint : Conceptual
37. Among the following four compounds :- [AIPMT (Main)-2010]
(a) phenol (b) methyl pheno (c) metanitrophenol (d) paranitrophenol,
The acidity order is :
(1) c > d > a > b (2) c > d > c > b (3) b > a > c > d (4) d > c > a > b
Key: (4)
Hint : Conceptual
38. The correct increasing order of reactivity for following molecules towards electrophilic aromatic
substitution. [AIIMS-2011]
OH OH OH OH

OMe Cl
NO2
(I) (II) (III) (IV)
(1) I < IV < II < III (2) I < IV < III < II (3) I < III < II < IV (4) I < III < IV < II
Key: (2)
Hint : - M and - I gp on ring decreases the reactivity
NH2 NH2 CH2 – NH2 NH2

39.
OCH3 CH3 Cl
(I) (II) (III) (IV)
The correct decreasing order of pKb is:– [AIIMS-2011]
(1) I > II > III > IV (2) III > IV > II > I (3) II > III > IV > I (4) IV > II > I > III
Key: (4)
Hint : + M and + I group on ring of Anilina increase the basicity
40. Whcih of the following carbocations is expected to be most stable?(NEET-2018)
NO2 NO2 NO2
NO2
H

Y
1) 2) 3) 4)
H
Y Y H Y H
Key: (1)
Hint: Conceptual
41. Whcih of the following is correct with respec to -I effect of the substituents? (R = alkyl)
(NEET-2018)
1)  NH 2  OR   F 2)  NR2  OR   F 3)  NH 2  OR   F 4)  NR2  OR   F
Key: (1)
Hint : Conceptual