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TARA PAA®

PERACETIC ACID
INFORMATION BROCHURE

REDOX PHARMACHEM PVT.LTD.


PLOT #15, SECTOR 6A, IIE SIDCUL, HARIDWAR
UTTARAKHAND 249403, INDIA

Phone No. 01334-239196


FAX: 011-41551269
Email: redoxdelhi@yahoo.co.in
www.tara-paa.com
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TARA PAA® 5 - PERACETIC ACID SOLUTION

Peracetic acid (PAA) is a liquid chemical sanitizer used for


sterilizing or disinfecting.

Now PAA is available to end users at a competitive price and a


wide variety of uses were introduced. In medical applications
PAA has been used to sterilize rooms, equipments,
hemodialyzers, and medical, surgical and dental instruments.
PAA destroy cell membranes by disrupting sulfur and sulthydryl
bonds. PAA inactivates a catalase that breaks down Hydrogen
Peroxide and oxidizes enzymes that support biochemical
transportation across cell membranes, thus causing the cell
wall to rupture. PAA is known to be a protein denaturant and
destroys pyrogens.

PAA is most active against bacterial spores. In one test of 23


agents, the anti microbial activity of PAA was efficacious against
Bacillus thermoacidurant spores, including chlorine containing
compounds. PAA is efficacious against a wide range of
Bacteria, Mycobacteria, Spores, Viruses, Algae, and Fungi.

PAA is more efficacious than Hydrogen Peroxide,


Formaldehyde and Glutaraldehyde. Additional advantages are
its rapid action, ability to remain effective at low temperatures
and efficacy in presence of organic material. The
decomposition products of PAA are Acetic Acid, Water and
Oxygen.

Oxidation Capacity of Various Oxidisers

Oxidizer eV*
Ozone 2.07
Peracetic Acid 1.81
Chlorine Dioxide s 1.57
Sodium Hypochlorite 1.36
Hydrogen Peroxide 1.33(pH7)
*electron volts

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Comparison Chart for various Sanitizer/Disinfectant/Biocide

Optimum Use Effect of Effect of Germicidal Activity Activity Activity


pH Range Dilution Hard Organics Activity against against against
for Concentr Water in Water Gram Gram Spores
Sanitizati ation on Positive Negative
on in ppm Sanitizati Bacteria Bacterial
on

Moderate
HYPOCHLORITE 5-7 200 Inactivated High   
tolerance

Reduced
Activity
activity; Moderate,
reduced
more less effective
IODOPHORS 1-5 25 More   
stable than than
sanitizer
hypochlorit hypochlorites
required
es

Activity Moderately
QUATS 8 - 11 200 Varied   
reduced Stable

Activity
reduced
ACID Low
1-3 200 more Very Good   
SANITIZERS reactivity
sanitizer
required

2% for
Activity
ALDEHYDES 6-8 Sterilizatio No effect High   
reduced
n

Loss of
ALCOHOLS 5-8 70% No effect Moderate 
  
activity

Moderate Moderately
PHENOLICS 10.5 - 11.5 200 - 400 Very good   
tolerance stable

Reacts High, better


limited and than
PAA 2 - 8.5 150 - 200   
effect looses hypochlorit
activity e

High, better
CHLORINE Little
2-5 5 - 15 No effect than   
DIOXIDE influence
hypochlorite

Highly Effective, Moderately Effective,Slightly effective, Ineffective

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TARA PAA ® Solution for Various Uses


S.no. Application Concentration Required Temperature Exposure Note
in ppm TARA PAA Time
®
for 100
Ltrs
solution
1 Foot Dip 500 895 ml Normal Clean the Boots
with Soft Bruch
2 Washing Fruits 25 45 ml Normal 60 Second Dry the
& Veg. vegetable &
Fruit before
use. No
washing with
fresh water
required.
3 Washing Meat 80-200 143 ml to Normal 60 Second Allow it to drip
357 ml 230 ppm –FMC
4 Hatching Egg 80 - 200 143 ml to 43°C 60 second Allow it to Dry.
+ Shell Egg for 357 ml Active against
food as per gillus
fumigates 280
ppm
5 Fogging 150 - 750 268 ml to Normal Allow it for 2
1340 ml hrs. 3 Ltr solu
for every 100
cu.mtr.
6 Utensils & 75 135 ml Normal 60 second Apply Physical
Tableware cleaning &
used in eating washing prior
Drinking & to use.
Food
Preparation
7 Non Food 135 – 1775 240 ml to
Contact- Hard 3000 ml
Surface –
Disinfectant
8 Disinfectant 80 - 320 143 – 570 10 minutes
for Animal & ml
Poultry
Premises,
Trucks &
Crates.
9 Antimicrobial 1120 - 1700 2000 to 40 - 60°C 15 second
rinse of Pre- 3000 ml
cleaned
Container
(Returnable &
Non
Returnable)
10 Algae control 3-6 6-10 ml Normal
and Bio Film
removal in
Cooling Tower

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TARA PAA® - 5

Applications
Thermal Fogging
Peracetic Acid has been independently approved in accordance with
the French AFSSA for use in thermal fogging, under the requirements
of the AFNOR test method NFT 72-281(1986) for
‘Thermonebulisation’

The approval demonstrates the efficacy of Peracetic Acid (TARA


PAA® with an in-use concentration of 1.7ml/m3 using three different
type of fogging machines.

The following Table indicates the volume of TARA PAA® 5


concentrate and water required to achieve effective thermal fogging
with in a given size of Building:

Total Airspace Volume of TARA PAA® Volume of Water to be


Volume (m3) 5 concentrate to achieve added to concentrate
a 1:10 dilution (Liters) (Liters)
100 m3 0.17 1.7
200 m3 0.34 3.4
500 m3 0.85 8.5
1000 m3 1.70 17.0
2500 m3 4.25 42.5
3000 m3 5.10 51.0
3500 m3 5.95 59.5
4000 m3 6.80 68.0

How to calculate your building total airspace volume for thermal fogging:

The total airspace volume of a given building is the floor area multiplied by the average
height.

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Surface Disinfection

The level of disease causing organism present after basic cleaning


remains high enough to offer a serious disease challenge.

Using a disinfectant proven to be effective against viruses, bacteria,


Yeast’s and moulds such as TARA PAA 5, is essential.

Surface Disinfection Dilution Rate Application


Routine disinfection 1:100 Using a pressure
for all surfaces (10 ml of TARA washer or other
including, earth, wood PAA® 5 concentrate mechanical sprayer,
and concrete to 1 Litre of water) apply TARA PAA® 5
solution at an
application rate of
300ml/m2
Example:
Routine disinfection of a 100 m2 building, with a total surface area of 320 m2
(Approx.) including walls and ceiling, at a dilution rate of 1:100 and an application
®
rate of 300mls/m2, will require a solution consisting of 0.96 litres of TARA PAA 5
concentrate added to 96 liters of water.

Equipment Disinfection

Equipment Dilution Rate Application


Disinfection
Routine cleaning and 1:100 Using a pressure
disinfection of (10ml of TARA PAA® washer or other
movable equipment 5 concentrate to 1 mechanical sprayer,
liter of water) apply TARA PAA® 5
solution at an
application rate of
300ml/m2

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Water System Disinfection

All water system contain some bacterial contamination, especially


header tanks dust and debris can accumulate. Sanitizing will clean
the system and eliminate existing bacterial or fungal growth.

Water System Dilution Rate Application


Disinfection
Terminal disinfection 1:100 Wash all equipment
of water system (10ml of TARA PAA® with TARA PAA® 5
5 concentrate to 10 Solution.
liters of water) Leave for a
minimum of 10
minutes and then
rinse thoroughly
with clean water.

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Efficacy Summary Data


The United Kingdom’s Department for Environment, Food and Rural Affairs
(DEFRA) testing protocols include not only high organic challenge (2.5% yeast)
but also low temperatures (4ºC) that are frequently experienced on farms in
Europe and they particularly demonstrate the benefit of using Peracetic Acid over
alternative formulations. Results show that Peracetic Acid is effective in the face
of organic challenges and at low temperature providing a broad spectrum activity
with efficacy against bacterial, fungal and viral disease causing organisms.

United Kingdom DEFRA Approvals

DEFRA Foot & Swine Disease of Poultry General


Approvals Mouth Vesicular General Orders Orders
Disease Disease (Newcastle Disease &
Avian Influenza)
Peracetic Acid
5% 1:150 1:50 1:375 1:179
dilution rates

*United Kingdom DEFRA Approvals – testing is perfomed at 4°C in hard water


and against Organic challenges.

Germany using DVG test methods

DVG test Bacteria Bacteria Fungus Virus Virus


Methods Porous Suspension Suspension Porous Suspensi
Surface Test Test Surface on Test
Test Test

Peracetic Acid 1:67 1:200 1:200 1:100 1:200


5% (1.5%) (0.5%) (0.5%) (1.0%) (0.5%)
Dilution rates 60 min 30 min 60 min 30 min 30 min
* Germany using DVG test methods – testing is performed at 20°C in hard water
and against an organic challenge

France AFNOR Homologation (Approval)

AFNOR Approval Bacteria Virus


Peracetic Acid 5% 1:200 1:200
dilution rates (0.5%) (0.5%)
* France AFNOR Homologation (Approval) – testing is performed at 20°C with
varying degrees challenge

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Bactericidal Efficacy Data


Organism Strain Dilution
Campylobacter Jejuni Wild strain ex Preston PHLS 1:200
Entercoccus Faecium Kulmbach Str.2 1:200
Entercoccus Faecium DSM 2918 1:400
Entercoccus hirae CIP 58.55 1:1000
Enterococcus hirae CIP 58.55 1:100
Enterococcus hirae CIP 58.55 1:200
Escherichia coli CIP 54.127 1:10000
Escherichia coli CIP 54.127 1:200
Escherichia coli O157 1:200
Escherichia coli CIP 54.127 1:200
Proteus mirabilis ATCC 14153 1:200
Proteus mirabilis ATCC 14153 1:400
Pseudomonas aeruginosa ATCC 15442 1:200
Pseudomonas aeruginosa ATCC 15442 1:200
Pseudomonas aeruginosa CIP A22 1:1000
Pseudomonas aeruginosa CIP A22 1:100
Pseudomonas aeruginosa ATCC 15442 1:200
Pseudomonas aeruginosa CIP A22 1:200
Pseudomonas aeruginosa ATCC 15442 1:256
Salmonella choleraesuis ATCC 10708 1:179
Salmonella choleraesuis DT104 1:256
Salmonella typhimurium ATCC13311 1:200
Salmonella typhimurium ATCC6538 1:200
Staphylococcus aureus ATCC6538 1:200
Staphylococcus aureus CIP 53.154 1:400
Staphylococcus aureus 53.154 1:1000
Staphylococcus aureus ATCC 6538 1:100
Staphylococcus aureus CIP 53.154 1:200
Staphylococcus aureus CIP 53.154 1:200
Staphylococcus aureus ATCC 6538 1:256
Streptococcus faecalis NCTC 8213 1:200

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Fungicidal Efficacy Data


Organism Strain Dilution
Absidia corymbifera IP 1129.75 1:200
Absidia corymbifera IP 1129.75 1:100
Aspergillus versicolor IP 1187.79 1:166
Aspergillus versicolor IP 1187.79 1:100
Candida albicans ATCC 10231 1:200
Candida albicans ATCC 10231 1:200
Cladosporium cladosporoides IP 1232.80 1:100
Trichophyton mentagrophytes ATCC 9533 1:256

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Virucidal Efficacy Data


Group Genera Dilution Disease
Adenoviridae 1:200 ICH
Birnaviridae Birnavirus 1:150 IBD
IBD virus 1:25 IBD
Flaviviridae Pestivirus 1:100 Classical swine
fever
Herpesviridae Suids herpes virus 1:50 Aujesky’s disease
Orthomyxoviridae ISA virus 1:100 ISAV
Orthomyxoviridae Influenza virus 1:200 AI
Paramyxoviridae Avian 1:200 Newcastle disease
Paramyxovirus
Paramyxoviridae Avian 1:200 Newcastle disease
Paramyxovirus
Paramyxoviridae Avian 1:375 Newcastle disease
Paramyxovirus
Picornaviridae Enterovirus 1:200 Teschen Talfan
disease
Picornaviridae Enterovirus 1:50 Swine vesiculer
disease
Picornaviridae Enterovirus 1:128 Poliomyelitis
Picornaviridae Apthovirus 1:150 Foot & mouth
disease
Picornaviridae Enterovirus 1:200 Enteric respiratory &
reproductory
diseases
Picornaviridae Enterovirus 1:200 Enteric respiratory &
reproductory
diseases
Poxviridae Orthopoxvirus 1:200 Cowpox
Poxviridae Orthopoxvirus 1:200 Cowpox
Poxviridae Leporipoxvirus 1:200 Myxomytosis
Reoviridae Avian paramyxovirus 1:200 Tenosynovitis
Reoviridae Avian paramyxovirus 1:200 Tenosynovitis

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Efficacy at Low Temperatures


Stringent analyses recently carried out in France at 4°C to represent the colder
conditions found on farms during winter months prove that TARA PAA® 5, has
greater efficacy at much lower concentrations than other disinfectants. The tests
show that TARA PAA® 5 requires up to 500% less disinfectant for efficacy at a 5
minute contact time compared with other tested disinfectants, see table 1.

TARA PAA® 5 is a powerful broad spectrum, multipurpose disinfectant for all areas of
routine disinfection on pig and poultry units including surface, equipment and water
system disinfection, foot & wheel dips and thermal fogging. Its unique, stabilized
Peracetic Acid readily breaks down after use into Oxygen, Water and a naturally
occurring, biodegradable organic acid (Acetic Acid). As a result, TARA PAA® 5 is
considered to be “readily degradable ” in accordance with OECD & EU standards
making it a highly effective yet of low environmental impact.

The independent test, carried out by the Laboratory de Microbiologieque ADREMI in


Tours, France using the AFNOR NFT72 – 180 method, were performed against two
highly infectious viruses of vertebrates: Talfan Disease Virus and contagious Canine
Hepatitis Virus . Both viruses can survive outside the body and are transmitted by
direct contact with urine, faeces and other bodily secretions and are therefore
particularly relevant to testing disinfectants used in pig and poultry farming. The tests
were carried out at 4°C in presence of an albumin and yeast mixture organic
challenge to represent the colder, realistic conditions found on farms during the
winter months.

TARA PAA® 5 exceeded the pass rate required, by a 3 log reduction in virus titre, at a
substantially less concentrated dilution of 1:200 compared with its competitors. The
three, glutaraldehyde – QAC based disinfectants tested against TARA PAA® 5
required >3.0% concentrations of disinfectant to pass the test. The tests prove that,
at low temperatures, the biocidal performance of TARA PAA® 5 is superior to that of
the three other disinfectants.

See Table 1 for the concentration at which each of the four disinfectants tested
passes the 3 log reduction test – noting that at lower percentage, less product is
required and therefore it is more economical use the product.

Table 1:

Product Product concentration required to pass


AFNOR test at 5 minutes contact
TARA PAA 5 (DAHS) 0.5%
TH4+ (Sogeval) 4.0%
Virocid (CID Lines) 3.0%
Tegodor (GoldshmidtAG) >5.0%

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In conclusion, the independent AFNOR test results make it fully apparent that the
Virucidal activity of TARA PAA® 5 would not be adversely affected when lower
temperatures, above freezing, are experienced on farm during the winter period. This
is very important to pig and poultry producers. TARA PAA® 5 passed the test at a
0.5% dilution (of 1:200) with the other disinfectants tested requiring much more
concentration in the solution to be effective against both test organisms. This shows
that, in terms of the amount of product necessary to be effective, TARA PAA® 5 is
clearly more efficient.

The specified uses and registered claims for TARA PAA® 5 may vary from country.

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TARA PAA® 5

TECHNICAL DATA SHEET

Peroxyacetic acid

Synonyms Peracetic acid, Ethaneperoxoic acid,


Acetyl hydroperoxide

Formula CH3COOOH

Description Colorless liquid with a strong, pungent,


acrid odor.

Uses Bactericide & fungicide, especially in


Food processing, reagent in making
caprolactam, synthetic glycerol.

Registry Numbers and Inventories.


CAS 79-21-0
EC (EINECS/ELINCS) 201-186-8
EC Index Number 607-094-00-8

EC Class Flammable; Oxidising; Harmful;


Corrosive; Dangerous for the
Environment

RTECS SD8750000

RTECS class Agricultural Chemical and Pesticide;


Tumorigen; Primary Irritant
UN (DOT) 2131
Merck 127293
Beilstein/gmelin 1098464

Beilstein Reference 4-02-00-00390

EGA OPP 63201

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Swiss Giftlistef G-2709

Canada DSL/NDSL DSL

US TSCA Listed

Australia AICS Listed

Japan ENCS (MITI) Listed

Properties :

Formula C2H403

Formula mass 76.05

Melting point, °C 0.1

Boiling point, °C 105

Vapor pressure, mmHg 7.9(25°C)

Density 1.1037 g/cm3 (20°C)

Solubility in water Very soluble

Viscosity 3.280 cp @ 78°F

Refractive index 1.3994 (15°C)

pKa/pKb 8.20 (pKa)

Heat of vaporization 44,25k

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Hazards and Protection

Storage Store in a cool, dry, well-ventilated location. Separate from acids,


alkalies, organic materials, heavy metals. Normally kept refrigerated outside or
detached storage is preferred.

Handling All chemicals should be considered hazardous. Avoid direct Physical


contact. Use appropriate, approved safety equipment. Untrained individuals
should not handle this chemical or its Container. Handling should occur in a
chemical fume hood.

Protection Full protective clothing (goggles, rubber gloves, etc)

Respirators Self-contained breathing apparatus.

Caution Peracetic acid is a strong oxidizer. Fire or other violent


reaction may occurs upon contact with combustible organic material. Avoid
breathing vapors. Do not touch the spilled material; shut off all ignition sources
and stop the leak if this can be done without risk. The spilled material should be
absorbed with a noncombustible absorbent such as vermiculite.

Small spills Sweep up and place in a metal container for immediate disposal.
Do not use spark-generating metals or organic materials for sweeping up or
handling spilled material. Dispose of the absorbed Peroxyacetic acid solution, in
small quantities at a time, by placing it on the ground in a remote outdoor area
and igniting with a long torch. Empty containers should be washed with a 10%
Sodium Hydroxide solution.

Stability Thermally unstable. After 30 days the specific Peracetic acid in 20gl
(with wetting agent), and Peracetic acid Spirit show a loss of Peracetic acid of
25,35,22% respectively with storage at 2-5 degrees.

Decomposition Decomposes violently @ 110° C peracetic acid diluted with 60%


acetic acid when heated to decomposition it emits acrid smoke and irritating
fumes.

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Fire

Flash Point, °C 40.5

Autoignition, °C 200

Fire fighting: If fire occurs in the vicinity of this compound, water should be
used to keep containers cool. Cleanup salvage operations should not be attempted
until all of the Peroxyacetic acid solution has cooled completely. Keep
unnecessary people away; wear self-contained breathing apparatus and full
protective clothing. Fight fires from an explosion-resistant location. In advanced or
massive fires, area should be evacuated. For small fires: use Dry Chemical,
Carbondioxide, Water Spray, or Foam. For large fires: flood area with water.

Fire potential: Flammable liquid. Dangerous fire hazard by chemical reaction with
reducing agents or exposure to heat.

Hazards Decomposes violently at 230ºF, When heated to decomposition, this


compound emits acrid smoke and fumes, runoff to sewer may create a fire or
explosion hazard. Powerful oxidizer. Isolate from other stored material,
particularly accelerators, oxidizers, and organic or flammable materials. Avoid
shock and heat.

Combustion: Fire may produce irritating, corrosive and / or toxic gases, Products

Health 3
Flammability 2
Reactivity 4
Special 0

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Health

Poison-Class 2

Exposure effects An increase in blood pressure, respiratory rate and pulse


has been noted in animal experiments. No data were
available to assess the teratogenic potential of this agent.
No data were available to assess the potential effects of
exposure to this agent during pregnancy or Lactation.

Ingestion Ingestion of Peracetic acid may cause gastrointestinal


tract Irritation and possible oral and esophageal burns.

Inhalation Mice exposed by inhalation developed signs of respiratory


tract irritation.

Skin Peracetic acid is highly irritating and possibly corrosive to the


skin.

Eyes Peracetic acid can cause servere eye irritation. A 10


percent solution of Peracetic acid applied to rabbit eyes
caused corneal ulceration, perforation, and symblepharon
formation.

Irritation of nasal and throat mucosa is common with exposure to vapors.

First aid:

Ingestion Seek medical assistance.

Inhalation Move victim to fresh air. Apply artificial respiration if victim is


not breathing. Administer oxygen if breathing is difficult.

Skin Remove contaminated clothing and wash exposed


area thoroughly with soap and water. A physician should
examine the area if irritation or pain persists.

Eyes Irrigate exposed eyes with copious amounts of tepid water for
at least 15 minutes. If Irritation, pain, swelling, facrimation, or
photophobia persist the patient should seen In a health care
facility.

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Transport.
UN number 2131

Response guide 147

Hazard class 5.2

USCG CHRIS PAA

19.12.09

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