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NUMBER 108 208 307 400 401 402 403 404 405 406 407 408 409 410

307 400 401 402 403 404 405 406 407 408 409 410 411 412 413
STREAM Saturator Circ. Water Loop Start-up HP Steam Synthesis Gas Converter Effluent Loop Gas to Sat'r Water Loop Gas from Warm Loop Gas to Crude Loop Gas to Trim Loop Gas to Crude Gas exit Separator Crude Methanol exit Circulation Gas exit Circulation gas Exit Loop Converter Quench Feed Converter Inlet Feed Flash Gas from Let Down
NAME Recycle Gas
Heater Interchager Metanol Condenser Condenser Metanol Separator Separator Circulator Interchanger Vessel
ID COMPONENTS M.W. Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h
1 CARBON MONOXIDE 28.011 16.29 2,148.3 1.75 995.1 1.75 874.5 1.75 120.6 1.75 995.1 1.75 995.1 1.75 995.1 1.85 994.6 0.05 1.6 1.85 937.9 1.85 937.9 1.85 937.9 4.86 2,424.4 4.86 676.0 2.90 1.4
2 HYDROGEN 2.016 72.21 9,524.8 76.15 43,262.1 76.15 38,020.8 76.15 5,241.3 76.15 43,262.1 76.15 43,262.1 76.15 43,262.1 80.48 43,234.1 0.41 12.6 80.48 40,769.5 80.48 40,769.5 80.48 40,769.5 78.76 39,320.9 78.76 10,963.0 26.71 12.5
3 CARBON DIOXIDE 44.010 13.65 5.1 8.13 1,073.0 2.79 1,585.2 2.79 1,393.1 2.79 192.0 2.79 1,585.2 2.79 1,585.2 2.79 1,585.2 2.90 1,559.1 0.94 28.9 2.90 1,470.2 2.90 1,470.2 2.90 1,470.2 3.97 1,979.5 3.97 551.9 21.52 10.1
4 METHANE 16.043 13.65 5.1 3.37 445.1 13.28 7,544.0 13.28 6,630.0 13.28 914.0 13.28 7,544.0 13.28 7,544.0 13.28 7,544.0 13.99 7,515.7 0.83 25.7 13.99 7,087.3 13.99 7,087.3 13.99 7,087.3 11.81 5,893.6 11.81 1,643.2 41.35 19.4
5 ETHANE 30.068
6 PROPANE 44.094
7 BUTANE 58.120
8 METHANOL 32.042 72.69 26.9 6.04 3,430.7 6.04 3,015.0 6.04 415.6 6.04 3,430.7 6.04 3,430.7 6.04 3,430.7 0.76 408.6 97.71 3,017.9 0.76 385.3 0.76 385.3 0.76 385.3 0.60 299.9 0.60 83.6 7.37 3.5
9 BUTANOL 74.120 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.03 0.8 0.00 0.00 0.00 0.00 0.00 0.00
10 DME 46.068 0.01 5.8 0.01 5.1 0.01 0.7 0.01 5.8 0.01 5.8 0.01 5.8 0.01 5.38 0.04 1.2 0.01 5.1 0.01 5.1 0.01 5.1 0.01 5.0 0.01 1.4 0.13 0.1
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DRY FLOW (kmol/h) 100.00% 37.0 100.00% 13,191.1 100.00% 56,811.1 100.02% 49,928.3 100.02% 6,882.8 100.02% 56,811.1 100.02% 56,811.1 100.02% 56,811 100.00% 53,717.4 100.00% 3,088.7 100.00% 50,655.1 100.00% 50,655.1 100.00% 50,655.1 100.00% 49,923.5 100.00% 13,919.0 100.00% 47
WATER (% on tot) (kmol/h) 99.86 % 26,423.6 0.30 % 39.2 1.78% 1,029.6 1.78% 904.8 1.78% 124.7 1.78 % 1,029.6 1.78% 1,029.6 1.78% 1,030 0.08 % 43 24.16% 984.0 0.08 % 40.6 0.08 % 40.6 0.08 % 40.6 0.13% 65.0 0.13% 18.1 0.80 % 0
TOTAL FLOW (kmol/h) 26,460.6 Norm. Zero 13,230.4 57,840.7 50,833.1 7,007.5 57,840.7 57,840.7 57,840.7 53,760.4 4,072.7 50,695.7 50,695.7 50,695.7 49,988.5 13,937.1 47.2
TOTAL FLOW (kg/h ) 477,213 134,444 434,609 381,955 52,654 434,609 434,609 434,609 318,311 116,298 300,165 300,165 300,165 339,855 94,754 938
PHASE / MOLECULAR WEIGHT LIQUID 18.035 VAPOUR VAPOUR 10.162 VAPOUR 7.514 VAPOUR 7.514 MIXED 7.514 MIXED 7.514 MIXED 7.514 MIXED 7.514 VAPOUR 5.921 LIQUID 28.555 VAPOUR 5.921 VAPOUR 5.921 VAPOUR 5.921 VAPOUR 6.799 VAPOUR 6.799 VAPOUR 19.868

PRESSURE (kg/cm2 abs) 29.00 115.00 85.00 81.60 81.20 80.60 79.50 78.50 78.10 77.80 77.80 77.80 85.60 85.00 85.00 84.30 6.10
TEMPERATURE (deg C) 140 320 140 264 264 116 121 83 50 50 50 50 60 105 115 198 49

NUMBER 414 415 416 417 418 419 420 421 422 423 424 425 426 427 507 611
STREAM Crude Methanol to Saturator Circulation Recycle Purge Gas to Purge and Flash Gas to Purge Gas to Methanol Crude Methanol from Refining Column Btms to Demi Water to Let Down Light Ends Refining Column Bottoms
NAME Converter Quench Bed #2 Converter Quench Bed #3 Converter Quench Bed #4 Converter Quench Bed #5 Converter Quench Bed #6 Purge Gas
Topping Section Water Hydrogenator Fuel Scrubber Scrubber Scrubber Vessel to V-4202
ID COMPONENTS M.W. Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h Dry Mol% kmol/h
1 CARBON MONOXIDE 28.011 0.01 0.2 4.86 412.2 4.86 642.2 4.86 608.7 4.86 761.3 1.85 56.7 1.85 1.9 1.87 56.3 1.85 56.3 0.00 0.0 0.52 0.2
2 HYDROGEN 2.016 0.01 0.5 78.76 6,685.6 78.76 10,415.8 78.76 9,872.3 78.76 12,347.3 80.48 2,464.7 80.48 83.6 79.47 2,394.0 78.74 2,394.0 0.10 0.0 1.29 0.5
3 CARBON DIOXIDE 44.010 0.60 18.5 3.97 336.6 3.97 524.4 3.97 497.0 3.97 621.6 BED 14.29 5.3 2.90 88.9 2.90 3.0 3.80 114.5 3.77 114.5 0.10 0.0 53.03 18.5
4 METHANE 16.043 0.21 6.3 11.81 1,002.1 11.81 1,561.2 11.81 1,479.7 11.81 1,850.7 SIX 14.29 5.3 13.99 428.4 13.99 14.5 14.59 439.6 14.46 439.6 0.00 0.0 18.11 6.3
5 ETHANE 30.068 HAS
6 PROPANE 44.094 BEEN
7 BUTANE 58.120 REMOVED
8 METHANOL 32.042 99.12 3,042.6 0.60 51.0 0.60 79.4 0.60 75.3 0.60 94.2 71.43 26.5 0.76 23.3 0.76 0.8 0.23 6.9 1.14 34.6 99.69 27.7 24.60 8.6
9 BUTANOL 74.120 0.03 0.86 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.0 0.00 0.0 0.00 0.0
10 DME 46.068 0.03 0.86 0.01 0.8 0.01 1.3 0.01 1.3 0.01 1.6 0.01 0.3 0.01 0.04 1.2 0.04 1.2 0.10 0.0 2.46 0.9
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DRY FLOW (kmol/h) 100.00% 3,069.7 100.00% 8,488.3 100.00% 13,224.3 100.00% 12,534.2 100.00% 15,676.6 100.00% 37.0 100.00% 3,062 100.00% 103.9 100.00% 3,012.5 100.00% 3,040.2 100.00% 27.7 100.00% 35.0
WATER (% on tot) (kmol/h) 29.44 % 1,281 0.13% 11.0 0.13% 17.2 0.13% 16.3 0.13% 20.4 99.86 % 26,423.6 0.08 % 2 0.08 % 0 1.50% 45.9 0.09 % 2.7 90.36 % 260.0 100.00% 303.1 100.00% 0.0 100.00% 340.1
TOTAL FLOW (kmol/h) 4,350.3 8,499.3 13,241.6 12,550.5 15,697.0 26,460.6 3,064.7 104.0 3,058.3 3,043.0 287.7 303.1 0.0 35.0 340.1
TOTAL FLOW (kg/h ) 121,589 57,784 90,025 85,327 106,719 477,213 18,146 616 19,596 19,708 5,573 5,461 0 1,239 6,128
PHASE / MOLECULAR WEIGHT MIXED 27.949 VAPOUR 6.799 VAPOUR 6.799 VAPOUR 6.799 VAPOUR 6.799 VAPOUR LIQUID 18.035 VAPOUR 5.921 VAPOUR 5.921 VAPOUR 6.407 VAPOUR 6.477 MIXED 19.368 LIQUID 18.016 LIQUID 18.016 VAPOUR 35.427 LIQUID 18.016

PRESSURE (kg/cm2 abs) 5.60 85.00 85.00 85.00 85.00 27.10 77.80 40.00 5.80 6.00 6.00 8.00 8.70 1.30 6.10
TEMPERATURE (deg C) 49 115 115 115 115 222 50 50 43 50 39 50 32 40 50
Note: The data of the synthesis loop has been taken from DPT heat and material balance at BOL conditions and with ICI 51-7 catalyst.