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Journal of Cleaner Production 113 (2016) 400e410

Contents lists available at ScienceDirect

Journal of Cleaner Production


journal homepage: www.elsevier.com/locate/jclepro

Sustainability analysis of pelletized bio-fuel derived from recycled


wood product wastes in Hong Kong
Md. Uzzal Hossain, Shao-Yuan Leu, Chi Sun Poon*
Department of Civil and Environmental Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong

a r t i c l e i n f o a b s t r a c t

Article history: The possibility of recovering energy from biomass residues has attracted a lot of research interest due to
Received 24 May 2015 the environmental problems associated with burning coal. Wood wastes generated from construction
Received in revised form and demolition activities and other wood product wastes can be a good potential source of renewable
24 October 2015
energy. The present study was conducted by using Hong Kong as an example to assess the environmental
Accepted 23 November 2015
sustainability of converting recycled wood wastes (from construction and demolition activities and other
Available online 14 December 2015
wood product wastes) to produce wood pellets for direct energy generation. The chemical and physical
characteristics of different types of wood product wastes were tested. An attributional lifecycle assess-
Keywords:
Wood wastes
ment approach was used to assess and compare the environmental impacts and sustainability for heat
Bio-fuel generation from the pelletized bio-fuel and coal. The test results showed that the energy content,
Lifecycle assessment chemical compositions and the trace metal concentrations all met the relevant standards. The results
Energy recovery also showed that significant impacts on health, ecosystem, climate change and resources damage can be
Sustainability potentially avoided by using wood pellets instead of coal for energy generation. The overall findings
demonstrated that the proposed “energy recovery” approach for using wood pellets as a bio-fuel in Hong
Kong is environmentally sustainable, which can provide an alternative route for managing wood product
wastes with the added benefits of energy recovery, and may be more applicable in mega cities especially
when city-based incineration is a concern.
© 2015 Elsevier Ltd. All rights reserved.

1. Introduction material. The non-inert materials, such as bamboo, plastics, wood


waste, paper, vegetation and other materials are disposed of at
In recent years, alternative energy production due to the emis- landfills (Poon et al., 2004). According to the Environment Protec-
sion of greenhouse gases (GHGs) and other pollutants from fossil tion Department of Hong Kong (HKEPD), about 394 tpd (tonnes per
fuel combustion has been of particular interest. Biomass is a day) of wood wastes were disposed of at landfills in 2013 as
renewable and cost-effective energy source (Luque et al., 2008). A municipal solid waste. In addition, about 10% of the 3591 tpd of
significant amount of wood wastes is generated from construction C&D wastes landfilled in 2013 was wood waste. Therefore, the total
and demolition activities and the recycling rates of the wastes are amount of wood waste disposed of at landfills in 2013 was about
low in comparison to other inorganic compounds (Daian and 700 tpd (HKEPD, 2015). Due to the lack of a viable recycling market,
Ozarska, 2009). Wood wastes are a low-cost biomass and can also wood product wastes are normally disposed of at landfills. This has
be considered a renewable fuel, which is an attractive source of created tremendous environmental problems as Hong Kong will
energy for large-scale biomass combustion plants (Gori et al., 2013). soon be running out of landfill space to manage the city's waste.
In Hong Kong, a huge quantity of wood product wastes is generated. According to the Hong Kong Environment Bureau (HKEB), the three
In Hong Kong, construction and demolition (C&D) wastes are currently operated strategic landfills will be full by 2018 ((HKEB,
categorized into inert and non-inert wastes. The inert C&D wastes 2011).
consist mainly of sand, bricks and concrete, and they are normally The three major wood wastes management options are land-
deposited at public filling areas for use as a land reclamation filling, recycling and energy from wastes (Ruisheng et al., 2014).
Among them, landfilling is mostly applied but is not a sustainable
option in Hong Kong due to the land scarcity for disposal and the
* Corresponding author. Tel.: þ852 27666024; fax: þ852 23346389. environmental consequences of landfilling (HKEB, 2011).
E-mail address: cecspoon@polyu.edu.hk (C.S. Poon).

http://dx.doi.org/10.1016/j.jclepro.2015.11.069
0959-6526/© 2015 Elsevier Ltd. All rights reserved.
Md.U. Hossain et al. / Journal of Cleaner Production 113 (2016) 400e410 401

Composting and particle board production are commonly used the information and methods conducted in this study aimed to
approaches in some countries (SQ Consult, 2013) but are also not create new references for future development of the energy
applicable in Hong Kong due to the lack of industry and down- industry.
stream consumers. Incineration is currently not available in Hong Hong Kong has started commercial wood pellets production by
Kong due to public opposition and health concerns. using recycled wood wastes, but the pellets are not used locally at
Wood pellets combustion is a burgeoning technology due to fuel present due to the lack of understanding of their potential benefits,
scarcity and environmental concerns over burning fossil fuels lack of environmental awareness and also the difficulty of obtaining
(Zhang et al., 2010). Wood pellets are considered one of the largest permission for wood pellets to be utilized as a fuel source from the
type of internationally traded solid biomass that is normally used authority. Therefore, a comprehensive study is necessary to assess
for energy production purposes (Sikkema, 2011). It is also an the suitability of using the wood wastes for bio-fuel production and
established fuel in the EU and USA because of rising conventional its sustainability for use as an alternative fuel to substitute coal in
fuel prices and increasing demand for greener fuels (Reed et al., an industrial setting.
2012). Wood residue produces a more suitable fuel pellet that can The main objective of this study was to assess the suitability
be burned directly as a heating fuel, and used as co-fuel with coal and sustainability of bio-fuel production from recycled wood
and other fuels (Magelli et al., 2009). It also emits less air pollutants wastes and its potential application in Hong Kong. The first part of
than conventional fossil fuels (Cambero and Sowlati, 2014). the methods was materials characterization; (i) chemical analysis
Biomass firing is more stable, because it does not require the spe- of different types of wood wastes was conducted to assess their
cific types of environmental conditions like other renewable energy chemical compositions (proximate analysis), and (ii) the energy,
sources such as wind, solar and hydropower. In addition, biomass is moisture and trace metal contents were assessed and compared
almost applicable to all types of utility boilers (Zhang et al., 2010). with that of a reference material (e.g. coal). In the second part, the
Wood pellets have good potential to provide thermal energy in the environmental impact of using recycled wood wastes for wood
cement industry, electricity generation and other relevant pellets production and using the latter as a fuel for energy re-
industries. covery in Hong Kong was assessed by conducting an attributional
Despite the advantages of using wood wastes for biomass LCA. A detailed LCA for wood pellets production and the eco-
combustion, there are some technical and economic challenges efficiency for using the pellets as a fuel are presented along with
such as difficulties in wastes collection, handling, and processing the explanations of the key steps and pertinent aspects of the
which hinder a more extensive use of the products. Contamination assessment. Therefore, the present study will help to maximize
in wood wastes is also another limiting factor as during combus- the recycling of wood wastes, and bio-fuel production for energy
tion, it may pose potential air pollution and ash disposal problems recovery.
(Chandrasekaran et al., 2012; Tissari et al., 2008).
To lessen the dependence on non-renewable energy resources, 2. Materials and methods
there is increasing interest in sustainable and long-term alternative
energy supplies. Hong Kong has also set a target to reduce carbon The first part of the ‘Materials and methods’ section is focused
intensity by 50e60% by 2020 with 2005 as the baseline (HKEB, on the characterization of the studied samples, and the second part
2010). To achieve the reduction target will be challenging without describes the procedure used for the lifecycle assessment.
reducing the use of coal and increasing the use of renewable energy
sources. Hence, significant reduction of carbon emissions is
possible by the increasing use of renewable resources as fuel, such 2.1. Physical and chemical analysis
as wood pellets in the local industry.
Lifecycle assessment (LCA) techniques quantitatively assess The wood waste samples were collected from typical sources
environmental performance and associated impacts which can such as formwork used for concrete casting and bamboo used for
help decision makers to understand the impact mitigation and scaffolding in the construction industry, wooden pallet used for
increase the scope of use of renewable energy sources, such as shipping and packaging goods, cut tree branches, and ‘mixed’ (a
wood wastes (Cambero and Sowlati, 2014). A few LCA studies have mixture of the above). Furniture plywood (old or new) was not used
been conducted on wood pellets production to assess their ap- for wood pellet production in Hong Kong (based on the field sur-
plications for energy generation in North America (Pa et al., 2011; vey), as it contains hazardous chemicals such as phthalates, volatile
Katers et al., 2012; Zhang et al., 2010) and in Europe (Chen, 2009; organic compounds, polybrominated diphenyl ethers, per-
Giuntoli et al., 2015). But the previous studies did not assess the fluorinated compounds, perchloroethylene, formaldehyde, heavy
physical and chemical compositions of the wood wastes. This metals and others (FBPR, 2008). However, a furniture sample was
aspect is very important, because the composition helps to un- also collected for the analysis to compare the physical and chemical
derstand the suitability of the wood wastes for fuel combustion. composition with other wood wastes and coal. In addition, chem-
Proximate and elemental analysis is particularly important for the ically treated wood wastes were not used to produce wood pellets
evaluation of the fuels in terms of heating value and potential in Hong Kong.
technical problems (e.g. slagging) and pollution problems (e.g. ash
content, trace metals and emissions) (Gehrmann et al., 2004). 2.1.1. Heat value and moisture content
Moreover, the previous studies did not assess the avoided impacts The physical and chemical characterizations of the wood wastes
due to wood wastes landfilling. This is also important because the were tested by using the American Society for Testing and Materials
assessment of the avoided impacts helps one to understand the (ASTM) standards described by NYSERDA (2013). The collected
benefits of recycling and reuse of the waste materials. Physical and wood samples were ground using a SPEX c 6770 Freezer/Mill® to
chemical analysis was conducted to characterize the most repre- produce a fine powder and screened to pass through a No. 40 (425-
sentative wood product wastes that are generated in Hong Kong, mm) sieve. The grounded materials were then pelletized for analysis
which included sources from the logistic and packaging industry in a Bomb Calorimeter as per the ASTM method (ASTM E711-87) for
(i.e. wooden pallet), and construction and demolition activities the determination of energy content (gross calorific value). The
(i.e. formwork, bamboo, etc.). These two types of wood wastes moisture content was assessed by using the standard procedure of
have not been considered in the previous LCA studies. Therefore, ASTM E871-82.
402 Md.U. Hossain et al. / Journal of Cleaner Production 113 (2016) 400e410

2.1.2. Proximate and trace metal analysis distinct questions. Attributional LCA provides information about the
The analysis procedure of the fuel wood is described in ASTM impacts of the processes used to produce a product, but does not
E870-82. The elemental characterization was assessed by using the consider indirect effects arising from changes in the output of a
standard procedure of ASTM E870-82 (proximate analysis) using product. It generally provides information on the average unit of
an Elmentar vario EL III analyser (CHN-OS, German). The wood products and is useful for consumption-based impact accounting.
samples were ground using a Freezer Mill (described above) to Mass allocation is frequently used in attributional LCA system
produce a fine powder. At least 2 g of the ground sample was ashed boundaries, whereas avoiding allocation by system expansion is
in a porcelain crucible for 2 h at 580  C using a muffle furnace normally used in the consequential LCA system boundaries, as it
according to ASTM D1102-84. The trace metals were quantified reflects the consequences of a change in production. In addition, the
after an acid digestion e sample analysis approach as summarized environmental load of the avoided burden is subtracted in conse-
as follows. The samples were placed in a desiccator one night quential LCA, when system expansion is performed (Thomassen
before the analysis. A small dose of samples with a specific weight et al., 2008). However, attributional LCA has low uncertainty
of 0.25 g (±0.001 g) was placed into pre-washed Pyrex test tubes because the relationships between inputs and outputs are generally
for acid digestion. A fixed amount (i.e. 4.0 ml HNO3, 70%, AR) and stoichiometric (Brander et al., 2009; Thomassen et al., 2008). This
1.0 ml HClO4 (60%, AR) was mixed into the sampling tubes, shaken study was conducted to assess the sustainability of pelletized bio-fuel
gently using a vortex (scale < 4), and then placed in an aluminium production from wood wastes and then energy recovery through
heating block. The heating block was programmed as follows: heat generation by following the attributional LCA approach.
50  C 3 h, 75  C ½ h, 100  C ½ h, 125  C ½ h, 150  C 3 h, 175  C 2 h and Nevertheless the indirect impact savings due to wood wastes
190  C until dry. The conditions of the samples were checked every landfilling was also assessed. However, the recycling credits due to
15e20 min once the temperature reached 150  C. The dry samples the wood wastes landfilling were not given to wood pellet pro-
were allowed to cool to room temperature, and then 10 ml of 5% duction and also not included in the final assessment as the study
HNO3 was mixed into the test tubes. The samples were placed in a followed the attributional approach.
vortex and heated to 60  C for 1 h, and then centrifuged at
3500 rpm for 10 min. The solutions were analysed by using an 2.2.2. Lifecycle inventory analysis
inductively coupled plasma-mass spectrometer (ICP-MS) to According to the ISO 14040-44 (2006a,b) series, the aims of
quantify the mass contents of six trace metals, i.e. Cd, Cr, Cu, Fe, Pd lifecycle inventory (LCI) analysis are to quantify the environmental
and Zn. significant inputs and outputs of the systems by means of mass and
energy balances. The required data to conduct this LCA were
2.2. Environmental impacts assessment by LCA collected from the respective recycler and wood pellet manufac-
turers in Hong Kong as the first-hand data. The functional unit data
LCA is considered an internationally accepted way to quantify were calculated based on the company's six-month total produc-
the associated environmental consequences and outputs of a tion of wood pellets and total energy (e.g. electricity) and fuel (e.g.
product (Hunt et al., 1992). This LCA was conducted by following diesel) consumption. Therefore, the LCI data were not collected for
the methods of the International Organization for Standardization separate unit processes (e.g. for specific motors, conveyers,
(ISO), such as ISO 14040 (2006a) and ISO 14044 (2006b) which hammer mills and dryers). However, this would not affect the final
included (i) defining goal and scope, (ii) creating lifecycle inventory, results of the study. The China Light and Power (CLP) and the
(iii) assessing the impacts, and (iv) interpreting and analysing the Chinese Life Cycle Database (CLCD) were used as the upstream data
results. sources (e.g. electricity generation, fuel consumption and trans-
portation) for this LCA. The CLCD is a national LCI database for key
2.2.1. Goal and scope definition materials and chemicals, energy and energy carriers, transport, and
The goal and scope definition phase defines the objective, sys- waste management in the Chinese market. Because Hong Kong is a
tem boundaries, sources of data and the functional unit of the study Special Administrative Region (SAR) of China, the use of CLCD
(ISO 14044, 2006b). The aim of the study was to assess the suit- database was more appropriate rather than other databases. In
ability of bio-fuel production from recycled wood wastes, and addition, CLCD is also a professional database (applicable for China
sustainability of heat generation and its potential application in and its territories), and can be accessed via http://www.ike-global.
Hong Kong. The system boundary for the assessment was ‘cradle- com/. As some of the materials and processes were not available in
to-grave’ which included wood wastes collection, transport to the the CLCD database, the Ecoinvent 3.0 database and literature were
recycling plant, processing, pelletizing, transport to user sites and used to fill this gap. For example, the environmental impacts for
then combustion. Fig. 1 illustrates the overall flow chart of the heat landfilling of wood wastes were assessed based on the Ecoinvent
generation from both wood pellets and coal. Wood pellets are one database 3.0 (Table 1).
type of bio-fuel and are normally used to produce energy, either as
heat or electricity. Therefore, the functional unit in the LCA is 1 kWh 2.2.3. Lifecycle impact assessment and results interpretation
of heat generated from the wood pellets. Although kWh is normally All the steps related to the collection and transportation of wood
used as a unit for electricity, many studies also used it as a func- wastes and pellets production were modelled and assessed by us-
tional unit for heat (e.g. Greening and Azapagic, 2014). According to ing SimaPro 8.0.1 software (PRe  Consultants, 2014), and the asso-
the IMPACT 2002 þ method, one impact indicator is ‘non-renew- ciated impacts were assessed by using the IMPACT 2002 þ Impact
able energy consumption’ (as primary energy resource) which is Method. There are essentially two methods employed for lifecycle
expressed as MJ primary. It would be confusing if the study had impact assessment, such as problem-oriented mid-points method
used the same unit (e.g. MJ) to express heat. Therefore, to differ- and damage-oriented end-points method. The mid-points
entiate the primary energy resources from heat, the study used approach translates the environmental impacts into the real phe-
kWh as the functional unit of heat generated. nomena, such as global warming, acidification, ozone depletion,
After defining goal and scope, it is important to distinguish and eutrophication, and human toxicity which can be evaluated using
define the LCA approach used in the study because different ap- the CML, EDIP, ReCiPe, and IMPACT 2002 þ Impact Method. The end
proaches, such as attributional LCA and consequential LCA, use points approach translates the mid-point impacts by modelling the
different methods and system boundaries in order to answer the damage to human beings, environment, climate change, resources
Md.U. Hossain et al. / Journal of Cleaner Production 113 (2016) 400e410 403

T
Landfill System boundary: Cradle-to-grave
Formwork

Collection & transport


Bamboo
E E E E E
On-site Milling Sorting Screening Pelleting
Trees &
handling
branches T
E
Wooden
Pallet Transport to T T Storage &
Transport to Transport to
T ship loading Hong Kong combustion plant baggage
Furniture &
Plywood T E
Coal
Combustion for 1 kWh
production
heat generation heat
Physical & chemical
analysis
T, Transport; E, Energy (electricity, diesel) Emissions

[Note: Raw materials; Characterization; Transport and processing;


Combustion; Emissions; Landfill; Output]

Fig. 1. System boundary and processes of the study.

(e.g. Ecoindicator 99, ReCiPe and IMPACT 2002 þ methods) (Ortiz locations, such as designated storage areas, landfill sites, con-
et al., 2009). In addition, the IMPACT 2002 þ Impact Method struction sites and other locations. After transporting to the pellet
combines the advantages of another three methods including Eco- manufacturing plant, the collected wastes are then stored in an
indicator 99, IPCC and CML. Hence, the study selected the Impact open place and allowed to dry (although most of the wood wastes
2002 þ Impact method for comprehensive assessment. The IMPACT are already dry). Based on the geographic location of the plant in
2002 þ Impact Method contains 15 mid-point indicators for Hong Kong, 10 locations were identified as the sources of wood
assessing the environmental impacts, and 4 end-points (such as wastes and the average transport distance to the plant by 30 t
human health, ecosystem quality, climate change, and resources) trucks was calculated. The study assumed that the measured
for assessing the damage (Jolliet et al., 2003). The method and in- average distance would not change too much, as Hong Kong is a
dicators were selected based on the particular concern of energy small city.
consumption, GHGs, particulates, SO2, and other emissions in Hong The collected wood wastes are then transferred to the hammer
Kong. mill by mechanical feeding controls and the waste is broken down
into small and uniform particles (wood chips, ~2 mm). The wood
3. Description of the processes chips are then transferred to the pelleting mill by a screw feeder.
Pelletizers use large electric motors to extrude the pellets through
This section describes the production of (i) wood pellets from steel dies. High pressure and temperatures soften lignin and binds
wood wastes systemically, (ii) coal in Indonesia and importation to the wood particles together to make uniform sized pellets (>10 mm
Hong Kong, and (iii) heat based on the defined functional unit. in length and ~ 6 mm in diameter). Sometimes small amounts of
additive and water are added to improve the processing. After-
3.1. Impacts assessment of wood pellets wards, the hot finished pellets enter a counter-flow cooler to
expedite cooling and evaporation. Cooling is necessary since it
The first step of the pellet manufacturing process is wood enhances pellet durability and storage stability. Designated tem-
wastes collection. Wood wastes are collected from various porary storage areas are available in the plant to keep the pellets

Table 1
Key inputs for this study.

Materials/Processes Unit Sources of upstream data

Energy
Electricity (for pellet production) 140 kWh/tonne of wood pellets,a CLP (2014) and CLCD (2010a)
Diesel (for pellet production) 3.0 L/tonne of wood pellets,a CLCD (2010b)
Transports
Wood waste transport (to pellet manufacturing plant) 43 km by 30 t trucks,b CLCD (2010c)
Wood pellet transport (to cement manufacturing plant) <1 km by 30 t trucks,a CLCD (2010c)
Wood waste transport (to landfill sites) 53 km by 18 t trucks,a CLCD (2010c)
Coal transport to ship loading 80 km by inland barge,b CLCD (2010d)
Coal transport to Hong Kong Port 4072 km by ocean ship,b Ecoinvent 3.0 (2013b)
Coal transport to cement manufacturing plant <2 km by 30 t truck,b CLCD (2010c)
Processes
c
Wood wastes landfill disposal Ecoinvent 3.0 (2013c)
Pellet combustion 1 kWh heat generation Chen (2009)
Coal production (Indonesia) 1 tonne Ecoinvent 3.0 (2013a)
Coal combustion 1 kWh heat generation Babbitt and Lindner (2005)
a
First-hand data.
b
Measured.
c
Equivalent amount of wood pellets production.
404 Md.U. Hossain et al. / Journal of Cleaner Production 113 (2016) 400e410

dry. However, no long-term storage is required as the company is 3.3. Comparative impacts assessment of heat generation from wood
producing on a limited scale currently. The finished pellets are then pellets and coal
packaged and ready for shipment to users. The plant operates 5
days per week, 9 h per day. To compare the impacts of using wood pellets and coal as a fuel
In LCA studies, some logical assumptions are coherently needed source for the combustion process in a real industrial setting
as it is almost impossible to model a product by strictly following (cement kiln), the system boundary of the LCA was extended from
the real process step by step (Blengini et al., 2012). However, it is ‘cradle-to-gate’ to ‘cradle-to-grave’ (for combustion). The LCI data
important to define the most important steps in the manufacturing for wood pellets combustion for energy generation were collected
process of a product. The main steps of producing wood pellets from Chen (2009), and that for coal combustion from Babbitt and
involve the following steps: Lindner (2005). The LCI data were adjusted and updated based on
Step 1: Wood wastes are collected and transported from various the energy content and efficiency of the fuels, as well as the mea-
locations to the pellet manufacturing plant (average 43 km by 30 t surement results (e.g. chemical analysis) in this study. Although
trucks was measured in this study) material characterization and LCA were two separate parts of the
Step 2: The collected wood wastes are stored in a dry facility on study, there is a clear linkage between them. For example, (1) based
site (no material and energy consumption is required) on the energy content (characterization), lifecycle inventory (LCI)
Step 3: Most of the wood wastes used to produce wood pellets in was adjusted and the values were used for LCA of the combustion,
this plant are already dry (e.g. formwork, bamboo and wooden (2) similarly, the energy content, trace metal and ash contents were
pallet). Additional drying is not performed in this plant currently. determined (characterization) which were used to update the LCI
Step 4: On-site handling (by forklift trucks) for this particular study to assess the impacts more accurately. A
Step 5: Transfer to the hammer mill (by conveyor) schematic of the system boundary and processes is given in Fig. 1.
Step 6: Broken down into small and uniform particles (using the The environmental impacts were assessed using the IMPACT
hammer mill) 2002 þ Impact Method with the functional unit of 1 kWh of heat
Step 7: Sorting and screening. generation.
Step 8: Pelletization by applying high pressure and temperature.
Step 9: Cooling and evaporation for hot finished pellets. 4. Results and discussion
Step 10: Screening for recycling the fine fractions back to the
pelleting process. The first part of the results will focus on the physical and
Step 11: Bagging and storage (from steps 4e11, average 140 kWh chemical characterization of the studied samples, and the second
electricity and 3 L diesel is needed to produce 1 tonne of pellets) part will be related to the sustainability assessment using LCA
Step 12: Transport to cement manufacturing plant (<1 km by techniques.
30 t trucks).
The necessary processing data were collected from the wood 4.1. Materials characterization
pellets producer. Currently, the annual production rate of the
company is about 15,000 t. The plant processes over 16,500 t of The quality of wood pellets was determined by several key pa-
locally generated wood wastes (wood wastes to pellets ratio, 1: 0.9). rameters including moisture content, calorific value, ash content,
According to the pelleting ratio, there is 1.11 tonnes of wood wastes elemental composition and other chemical contents (Tarasov et al.,
that would need to be disposed of at landfills per tonne of wood 2013). According to the proximate and ultimate analysis, the results
pellets produced. The average distance from the 10 selected waste of the physical and chemical characteristics of different wood waste
wood generation locations to the landfills is about 53 km using 18 t samples and the reference coal are summarized in Table 2.
trucks. All the steps related to the collection and transportation of
wood wastes and pellets production are modelled into the soft- 4.1.1. Energy and moisture content
ware. To unify the functional unit, the amount of wood pellets The energy values of the tested samples ranged between 18.70
required to generate 1 kWh of heat was taken as a functional unit in and 25.00 MJ/kg and were all very close to the value measured from
this part of the study. the coal sample (sub-bituminous coal, i.e., 22.00 MJ/kg). Among the
five wood waste samples, furniture had the highest energy value
3.2. Impacts assessment of reference coal due to its high polymer content contributed by the paints and resin
binders. On the contrary, bamboo had the lowest energy value
According to the Hong Kong Energy Statistics annual report mostly due to its lower lignin content in its structure. However, the
(HKES), about 95% of coal used in Hong Kong was imported from energy content of bamboo could still meet the requirement of the
Indonesia in 2013 (HKES, 2013). Hence, the environmental impacts standards. The energy content of the mixed wastes was about
of coal production in Indonesia and transport to Hong Kong were 19.87 MJ/kg, which is very close to the energy content of the
modelled in this study. The system boundary was ‘cradle-to-site’ reference coal (21.76 MJ/kg).
which includes the coal mining in Indonesia and the transport of Furthermore, the moisture content of the mixed wood waste
coal to Hong Kong. There are three main coal mine areas in sample was 8.86% which is acceptable for use in pellet production
Indonesia: South Sumatra Island, South Kalimantan and East Kali- (acceptable values are about 9e11% on an oven dry basis according
mantan. The study assumed that the coal was imported from to Reed et al. (2012)). Therefore, no additional drying is necessary at
Banjarmasin Terminal in the Port of Banjarmasin, Kalimantan to the plant. However, a significantly higher moisture content was
Hong Kong. The transport distance by bulk oceanic carrier was then observed in the coal sample (about 13.34%).
calculated. The Ecoinvent 3.0 database was used as a source of LCI
data for hard coal production in Indonesia, and the transport of coal 4.1.2. Ash content
to Hong Kong (by ocean carrier, Global average). Finally, all the The ash content was low in the analysed wood samples
steps were incorporated into the model using software and the (0.4e3.7%) except for the furniture plywood indicating that they
associated impacts were assessed. To unify the functional unit, the can be used as clean sources of fuel. High ash content indicates high
amount of coal required to generate 1 kWh of heat was taken as the content of contaminants or additives used during the
functional unit for this part of the study. manufacturing processes (such as coating, adhesives, dirt and other
Md.U. Hossain et al. / Journal of Cleaner Production 113 (2016) 400e410 405

Table 2
Physical and chemical compositions of the wood wastes samples.

Parameters Unit Sample

Coal Furniture plywood Formwork Bamboo Wooden Pallet Mixed

Energy Value MJ/kg 21.76 24.98 21.13 18.79 18.95 19.87


Moisture content % 13.34 8.07 10.78 9.62 10.20 8.86
Cd mg/kg 0.009 0.014 <0.005 0.007 <0.005 0.006
Cr 0.318 0.896 0.375 0.261 0.112 0.348
Cu 0.309 0.709 0.624 0.342 0.464 0.411
Fe 3.511 415.150 16.114 3.107 2.075 15.737
Pb 3.692 1.252 0.129 0.025 0.067 0.199
Zn 0.890 3.539 1.389 0.965 0.890 1.193
N % 0.72a 1.90 0.10 0.10 0.20 0.80
C 73.32a 29.10 44.60 42.90 46.40 45.40
H 4.56a 4.00 6.20 6.00 6.50 6.10
O 20.12a 29.30 46.80 47.30 46.50 45.80
S 0.11a 0.00 0.00 0.00 0.00 0.00
Ash 1.17a 35.80 2.30 3.70 0.40 1.90
a
Indonesian sub-bituminous coal [(Silaen and Wang, 2010)].

waste materials), and it induces a high risk of fouling and slagging, collected wood pellets were produced from hardwood, straw,
and also induces corrosion due to the presence of Cl, S, K and Na in softwood, logging residues, wood chips, compressed wood, un-
the boiler which can create operational and maintenance problems, treated wood, sawdust and bark. However, the study did not
and as well as reduce the operating life of the heating equipment include the characterization of the raw materials used for pellet
(Ferreira et al., 2014; Biedermann and Obernberger, 2005; production.
Gehrmann et al., 2004). The ash content in the mixed wastes was The caloric value of wood pellets is higher, while the ash content
1.9%, which is slightly higher than in the sub-bituminous coal of and trace elements are lower than the standards, which indicates
Indonesia (1.17%) as reported by Silaen and Wang (2010), and also the suitability of wood pellets as an alternative fuel source. The
higher than wood pellets (1.2%) reported by Ferreira et al. (2014) results from this study are shown in Fig. 2 which provides similar
(wood pellets produced from sawdust). However, the ash content conclusions that the wood pellets produced from Hong Kong can
of the mixed wastes met the standard of PFI for standard pellets meet all the requirements of the German standard. The concen-
(<2%) (PFI, 2010). trations of all the measured metals were approximately ten times
lower than the German standard. It can be seen from Fig. 2 that
4.1.3. Elemental analysis slightly higher contents of some trace metals were associated with
The variation of elemental composition in the different wood the mixed wastes than that in the coal (e.g. Cr, Cu and Zn). The Pb
residues was very small. For example, carbon content was content of the coal used was found to be 3.69 mg/kg in this study
42.9e46.4%, hydrogen content was 6.0e6.5% and oxygen content which was also consistent with other studies (average 3.00 mg/kg
was 45.8e47.3%. No sulphur was detected in all the wood samples. of the analysed eight Indonesian hard coal samples) reported by
The sulphur content in the sub-bituminous Indonesian coal is Belkin and Tewalt (2007). Besides, the Pb content for the mixed
approximately 0.07e0.90% as reported by Ewart and Vaughn wastes was 0.199 mg/kg which is also consistent and even lower
(2009) and 0.11% by Silaen and Wang (2010). than the other studies (such as 0.38 mg/kg was reported by
Chandrasekaran et al., 2012).
4.1.4. Trace metal analysis In addition, the ash content (1.9%) and energy content (19.87 MJ/
The results of the trace metals of different wood waste samples kg) of the mixed wood wastes sample (typically used to produce
and the reference coal are summarized in Table 2. The concentra- wood pellets) are almost similar to the wood pellets reported by
tions of many metals, such as Cd, Cr, Cu, Fe and Zn were higher in Ferreira et al. (2014) and Obernberger and Thek (2004). The
the wood samples but Pb was higher in the coal samples than in the elemental compositions are also consistent with the previously
wood products wastes. reported cases. There was no sulphur content detected in this
A comparison of the physical and chemical characteristics of sample, whereas about <0.01% sulphur content was found in the
wood waste samples with the reference standards of a few pellets (Ferreira et al., 2014). Since no sulphur was detected in any
different countries are given in Table 3. The standards in some of the collected wastes, the risk of sulphate production using these
European countries are discussed because currently there is no wastes is negligible.
related standard for wood pellets in Hong Kong. Among all the Besides the tests conducted in this study, some additional tests
standards, Germany provides the most detailed guidelines and may be useful for volatile compounds such as sulphate, chloride,
standards for using wood pellets as a fuel. In Table 3, two reported and mercury because chloride and sulphate are harmful to the
cases (e.g. Ferreira et al., 2014; Obernberger and Thek, 2004) on combustion appliances (can cause fouling, slagging and corrosion)
the chemical compositions of wood pellets characteristics showed (Sippula et al., 2007). NYSERDA's test on wood pellets (2013) found
that wood pellets can meet the requirements of all countries. wide variations (21e525 ppm) of sulphate content, whereas the
Ferreira et al. (2014) conducted a comparative study on the wood chloride content was 16e95 ppm and the mercury content was
pellets produced from a mix of sawdust and six different residues, 0.0012e0.0022 mg/kg. The standard for sulphate in wood pellets is
including plastics, polymeric mould wastes, tyre fluff, polishing not included in the German, Austrian, UK, Swedish, Italian and PFI
dust, textile, and shoemaking residues (5e10% by weight). The standards. However, the chlorine and mercury contents found in
study showed that the pure sawdust pellets had better quality the wood pellets by NYSERDA (2013) were much lower than the
compared to the others. In addition, Obernberger and Thek (2004) German (for chlorine <300 ppm and for mercury <0.05 mg/kg) and
studied the physical and chemical compositions of various types PFI (for chlorine <300 ppm) standards. In contrast, the average
of wood pellets from Austria, Spain, Italy, and Sweden. The chlorine content of hard coal is about 340 ± 40 ppm (Yudovich and
406 Md.U. Hossain et al. / Journal of Cleaner Production 113 (2016) 400e410

Table 3
Characteristics and standards for wood pellets.

Parameters Wood pelleta Wood pelletb Austriac Swedenc Germanyc Italyc UKc PFI (USA)d

Moisture content (%) 5.10 7.70 12 10e12 12 10e15 10 <8
Bulk density (kg/m3) 624 591 500e600 550e720 500
Ash content (%) 1.20 0.51 0.50 0.7e1.5 1.5 0.7e1.5 1e6 1
Calorific value (kJ/kg) 17.10 19e20.3 18 16.9 17.5e19.5 16.2e16.9 15.12e16.9 18.61
C (%) 50 50.30
N (%) 0.10 0.22 0.30 <0.30 0.30
H (%) 6.20 5.70
S (%) <0.01 0.04 0.08 <0.08 0.05
Cl (ppm) <200 300 <300 300 800 <300
As (mg/kg) <0.80
Cd (mg/kg) 0.14 <0.50
Cr (mg/kg) 0.6 <8
Cu (mg/kg) 1.10 <5
Hg (mg/kg) <0.05
Pb (mg/kg) 0.43 <10
Zn (mg/kg) 13.20 <100
K (mg/kg) 493
a
Ferreira et al., 2014.
b
Obernberger and Thek, 2004.
c
Hahn, 2004.
d
PFI (Pellet Fuel Institute), 2010.

Ketris, 2006), and the average mercury content in coal is about the burning of wood pellets emits less volatile compounds than
0.2 mg/kg (Toole-O’Neil et al., 1999), which is much higher than in burning coal.
any types of wood pellets. In addition, no sulphur was detected in Based on the specification given by ISO 17225-1 (ISO, 2014),
all the wood samples tested in this study, whereas 0.07e0.90% post-consumer used wood can be burned in boilers equipped with
sulphur content was found in the sub-bituminous Indonesian coal good combustion technologies. However, the standard also rec-
(Ewart and Vaughn, 2009), and 0.10 sulphate (wt%) was reported in ommends analysis to detect heavy metals, and burning is only
the Indonesian coal by Ishak et al. (2003). Therefore, comparatively, allowed if the used wood does not contain heavy metals or

0.6 Cd (mg/kg) 9 Cr (mg/kg) 8


0.5 8
0.5
7
0.4 6
5
0.3
4
0.2 3
2 0.896
0.1 0.014 0.318 0.375 0.261 0.348
0.009 0.005 0.007 0.005 0.006 1 0.112
0 0

6 Cu (mg/kg) 12 Pb (mg/kg)
5 10
5 10
4 8
3 6
3.692
2 4
1 0.709 0.624 0.464 0.411 2 1.252
0.309 0.342 0.129 0.067 0.199
0.025
0 0

120 Zn (mg/kg) 100


100
80
60
40
20 3.539
0.89 1.389 0.965 0.89 1.193
0

Fig. 2. Comparisons of trace metal contents with German standards.


Md.U. Hossain et al. / Journal of Cleaner Production 113 (2016) 400e410 407

halogenated organic compounds at levels more than that of virgin for wood pellets it is about 80%~90% (Qian and McDow, 2013). As
wood. Therefore, the wood pellets in Hong Kong are suitable for use the studied bio-fuel is not used in Hong Kong currently, the study
as a fuel, based on the mentioned ISO specifications and standards used the efficiency of thermal conversion from Qian and McDow
set up by different countries. (2013), and assumed that a similar combustion technology will be
used when the considered fuel is used for energy generation. With
4.2. Lifecycle impacts assessment the mentioned efficiency, about 183.86 g of coal is required to
produce 1 kWh of heat. By assuming 80% efficiency, about 226.42 g
This part reports the results of the sustainability assessment of of wood pellets is required to produce 1 kWh of heat.
fuel production and energy generation by wood wastes using a Based on the energy content and fuel efficiency, the study
comparative LCA. assessed the lifecycle environmental impacts of generating 1 kWh
of heat from burning coal or wood pellets and the results are given
4.2.1. Comparative impacts assessment of wood pellets and coal in Table 5 and Fig. 3 (assessed 15 mid-point impacts indicators
production based on the IMPACT 2002 þ Impact method). According to the LCA
Within the LCA system boundary and methods used in the results given in Table 5, it is estimated that about 4.53 MJ of total
study, it is estimated that about 0.45 MJ of non-renewable energy is energy is required to generate 1 kWh of heat from coal, whereas
needed to produce 0.226 kg of wood pellets from the locally only 1.17 MJ energy is required from wood pellets. In addition, for
generated wood wastes in Hong Kong (the amount of fuel needed the same heat output, about 0.33 kg of CO2 eq GHGs are emitted as
to generate 1 kWh of heat, the functional unit of this study). Also, global warming potential from coal, while only 0.06 kg of CO2 eq
about 0.02 kg of CO2 eq GHGs are emitted. The pelletizing process GHGs are emitted from wood pellets. The values show that about
requires the highest energy input (about 84%), followed by 8.23% 74.17% lower energy is required with a saving of 80.91% of GHGs
for transport of the waste wood to the plant site and pellet trans- emission for heat generation from wood pellets instead of the
port to the cement production plant, and 7.77% for on-site transport reference coal. Furthermore, the LCA results show that a 44.94%
and handling. Similarly, about 81.4%, 9.36%, and 9.22% of GHGs reduction in SO2 emission is possible for heat generation from
emissions are generated by the production process (only emissions wood pellets instead of coal, because about 4.24 g of SO2 is emitted
associated with electricity and fuel used have been considered), to the air to generate 1 kWh of heat from wood pellets, whereas
wood waste transport to the plant site and pellet transport to 7.70 g of SO2 is emitted from coal (based on both acidification po-
cement production plant, and on-site transport and handling, tentials mentioned in Table 5).
respectively. According to the Impact 2002 þ Method, respiratory inorganics
According to the LCA results of using coal from Indonesia as a including particulate matter (e.g. sulphate and nitrate aerosols,
fuel source, it is estimated that about 4.16 MJ of non-renewable dust particles, etc.) are expressed as PM 2.5 equivalent. All sources
energy is required to extract/process and transport 0.184 kg of of dust emissions were considered in this assessment. However, the
coal to Hong Kong, and this emits 0.02 kg of CO2 eq GHGs (the direct emission of dust particles and other emissions during pellet
amount of fuel needed to generate 1 kWh of heat). For this amount manufacturing were not accounted for in this study (although in-
of energy used, about 96.7% is required for mining and processing, direct emissions from upstream processes due to electricity and
and the rest of the energy is needed for handling and transporting fuel consumption were included), because the contribution of
to Hong Kong. Similarly, mining and processing is responsible for emissions by the pelletization process is insignificant when
the higher GHGs emission (62.4%), and then transporting to Hong compared to the upstream processes (corresponding to materials
Kong (35.3%), and others (2.3%). A summary of the LCA results on transport, electricity and fuel combustion) and the downstream
GHGs emissions and energy consumption for producing the processes (e.g. burning fuel for energy generation) (Reed et al.,
amount of wood pellets and coal required to generate 1 kWh of 2012).
heat is given in Table 4. A comparison of characterized mid-point impact indicators for
heat generation is shown in Fig. 3. The figure shows that heat
4.2.2. Comparative environmental impacts assessment of heat generation from wood pellets induces much lower impacts for 14 of
generation the 15 indicators, with the impact of only one indicator (IR) higher
A ‘cradle-to-grave’ system boundary was considered in this part than that of coal. It has already been mentioned that significantly
of the LCA, which included wood wastes collection and transport to lower impact on global warming, non-renewable energy, terrestrial
the pellet manufacturing plant, on-site transport and handling, and aquatic acidification are associated with heat generation from
pellet manufacturing, storage, bagging, and then transport to the wood pellets compared to coal. In addition, the values of other
sites of use of the pellets, and finally combustion. indicators are much lower for heat generation from pellets than the
According to the analysis of the study, the average heating value coal, such as carcinogens (98%), non-carcinogens (99%), mineral
of the coal is about 21.76 MJ/kg, and 19.87 MJ/kg for wood pellets. extraction (87%), respiratory organics (88%), aquatic ecotoxicity
The efficiency of thermal conversion for coal is about 90%, whereas (87%), land occupation (99%), aquatic eutrophication (99%), ozone

Table 4
Summary of environmental impacts of producing wood pellets and coal as fuel sources.

Fuel Processes GHGs emission, kg CO2 eq Energy consumption, MJ

Wood pellet Wood waste collection and transport to processing plant 0.00225 0.03654
On-site transport and handling 0.00227 0.03527
Wood waste processing and pelletizing 0.02001 0.38094
Pellets transport to cement plant 5.23E-05 0.00085
Total 0.02458 0.45360
Coal Coal extraction and processing 0.01509 4.02354
Transport to Hong Kong, and then to cement plant 0.00905 0.14007
Total 0.02414 4.16361

[Note: Functional unit: fuel needed to generate 1 kWh heat].


408 Md.U. Hossain et al. / Journal of Cleaner Production 113 (2016) 400e410

Table 5
Summarized LCA results for 1 kWh heat generation.

Impact category Unit Heat generation from coal Heat generation from wood pellets

Carcinogens (CG) kg C2H3Cl eq 0.00247 3.55E-05


Non-carcinogens (N-CG) kg C2H3Cl eq 0.02344 0.000241
Respiratory inorganics (RIn) kg PM2.5 eq 0.00059 0.00017
Ionizing radiation (IR) Bq C-14 eq 0.15034 0.62147
Ozone layer depletion (OL) kg CFC-11 eq 8.66E-10 4.13E-10
Respiratory organics (ROg) kg C2H4 eq 6.61E-05 7.87E-06
Aquatic ecotoxicity (AEco) kg TEG water 41.73321 5.47975
Terrestrial ecotoxicity (TEco) kg TEG soil 14.07308 2.00774
Terrestrial acid/nutria (TAci) kg SO2 eq 0.00514 0.00354
Land occupation (LOc) m2org.arable 0.00378 2.45E-05
Aquatic acidification (AAci) kg SO2 eq 0.00256 0.00070
Aquatic eutrophication (AEu) kg PO4 P-lim 7.57E-05 4.20E-07
Global warming (GW) kg CO2 eq 0.33053 0.06308
Non-renewable energy (NeRe) MJ primary 4.53134 1.17455
Mineral extraction (MEx) MJ surplus 0.00054 7.06E-05

[TEG, Tri-ethylene glycol].

100
layer depletion (52%), Terrestrial ecotoxicity (86%) and respiratory 95
in-organics (71%). 90
85
In addition, the major concern associated with burning wood 80
75
residues is the emission of several pollutants at higher concentra- 70
65
tions than conventional fuels (e.g. natural gas), especially for par- 60
ticulate matter and photochemical ozone forming chemicals 55
% 50
(Giuntoli et al., 2015). Giuntoli et al. (2015) compared these emis- 45
40
sions from burning wood pellets, wood residues and natural gas, 35
and concluded that the mentioned emissions were higher from 30
25
wood pellets and wood residues than from natural gas. Nonethe- 20
15
less, the findings from this study show that the mentioned pol- 10
5
lutants' emissions from burning wood pellets is much lower than 0
from burning coal. Human health Ecosystem quality Climate change Resources
According to the IMPACT 2002 þ method, there are four end- Heat generation from coal Heat generation from wood pellet
point indicators for damage assessment including human health,
Fig. 4. Comparative damage assessment for heat generation by wood pellets and coal.
ecosystem quality, climate change and resources. The respective
damage units are DALY (Disability-adjusted Life Year) for human
health, PDF.m2.yr (Potentially Disappear Fraction of Species) for landfilling of the equivalent amount of wood wastes to produce the
ecosystem quality, kg eq CO2 into air for climate change and MJ wood pellets (to generate 1 kWh of heat) by the IMPACT
primary non-renewable for resources. A comparative damage 2002 þ Impact Method. The adopted approach in this study in-
assessment for heat generation from wood pellets and coal is given cludes the avoided impacts as indirect benefits if the wood wastes
in Fig. 4. The figure indicates that compared with coal, the use of are not recycled but disposed of at landfills. The avoided impacts of
wood pellets for heat generation induces minor ecosystem damage not needing to dispose of 0.251 kg of wood wastes (for producing
(~15%), 76% lower damage to human health, 81% lower damage to 0.226 kg of wood pellets) at landfills saves a total 0.15 MJ of non-
climate change and 74% lower resources damage. This is due to the renewable energy and 10.88 g of CO2 eq GHGs, 0.43 g of SO2 eq
generation of energy from biomass emitting a much lower amount acidification, 0.011 g of PM2.5 eq respiratory inorganics emissions,
of pollutants, saving ecosystem degradation and consuming much and other potential impacts, whereas about 0.45 MJ of energy
lower resources than coal. consumption, 24.52 g of CO2eq GHGs, 0.83 g of SO2 eq acidification,
0.045 g of PM2.5 eq respiratory inorganics emissions was induced
4.2.3. Wood wastes landfill to produce 0.226 kg of wood pellets (Table 6). It is already
Based on the assumptions and input data for wood wastes mentioned that this LCA was conducted based on the attributional
landfilling, the study also assessed the associated impacts for LCA. Hence, the impacts due to the wood wastes landfilling were
not included in the pellet production and heat generation as
100 recycling credits. However, the results of landfilling of wood
95
90
85
wastes indicates that a significant environmental impact including
80 GHGs emission, energy consumption, particulates emission and
75
70
65
60
55 Table 6
% 50
45 Comparison of LCA results for wood wastes management options (landfill vs.
40
35 wood pellets).
30
25
20 Impact category Unit Wood pellet Wood wastes
15 production landfill
10
5
0 Respiratory inorganics g PM2.5 eq 0.045 0.011
CG N-CG RIn IR OL ROg AEco TEco TAci LOc AAci AEu GW N-Re MEx
Acidification potential g SO2 eq 0.830 0.430
Heat generation from coal Heat generation from wood pellet
Global warming g CO2 eq 24.520 10.880
Non-renewable energy MJ primary 0.450 0.150
Fig. 3. Comparison of characterized mid-point impacts for heat generation.
Md.U. Hossain et al. / Journal of Cleaner Production 113 (2016) 400e410 409

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