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29 W. 39 S t . . N. Y. C.
0 Filtration Problems
With
High Detergency Lubricants
By
H. M c QADEBUSCH
Detroit Diesel Engine Division,
General Motors Corp.
R. T. KABR
Purolator Products, Incorporated
And
W0 B. BASSETT
Lubrizol Corporation
-I'^l
r SOCIETY of AUTOMOTIVE ENGINEERS, Inc., 29 West 39th Street, New York 18, N. Y.
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Foreword
On one side, many well-conducted tests have proved time after time that
presence of even minute amounts of abrasive materials in the crankcase oil
will accelerate the wear of all moving parts at a tremendous rate and that
considerable relief can be gained! from intelligently applied oil filters„
On the other hand, engine builders remained for a long time unconvinced of the
necessity for oil filtration and considered filters as additional gadgets
complicating the design and taking up some valuable apace, lubricating oil
marketers grew apprehensive of the ejxfaprblt ant claims made by some filter
manufacturers with regards to lengthened oil life and feared service reper
cussions, Itogine users, finally,; objected to the continuous expense for
filter element replacements which! did not always appear to be compensated by
the promised longevity and more economical operation of their equipment,
By 1935* these pros and cons had fairly well reached a balanee0 Pleasure car
manufacturers still alternated between making oil filters available as an
option or using them as standard equipment,. But in the commercial field
where uninterrupted service and long power plant life are of foremost
importance, oil filters had become standard equipment on all makes of engines0
However, with the advent of determent lubricating oils one of the most con
vincing promotional oil filter arguments seemed lost, Begardless of whether
or not filters were employed, the; crankcase oil always turned black and the
dipstick ceased to "tell the tale!', Operators accustomed to change fiiter
elements on an oil color basis, began to question not only the quality of the
new oils but also that of the filters since the slndge-^eposits normally coat
ing used filter elements were no longer e2qjerien$ad after comparable periods
of use,
During the last three years this condition has grown considerably more dif
ficult, Mot only have detergent lubricants become so widely accepted that.
even some passenger car manufacturers recommend their use for ordinary
driving conditions but the general level of detergeney in crankcase oils
intended for bona fide "heavy-duty" service has increased at a rapid rate,
It may therefore be well to dispense some of the fog surrounding the action
of highly detergent lubricants by a review of their effect on crankcase oil
condition, oil filter efficiency and engine cleanliness,
- 2
All these external oil contaminants pass into the crankcase from the combus
tion chambers, they have no relation whatsoever to the quality of the lubri
cating oil arid may form, at low coolant and lubricating oil temperatures such
as commonly encountered in stop-and-go service, obnoxious "cold sludges",
In addition, the lubricant may also develop some deterioration products of its
own. As a result of oxidation under the influence of the elevated oil tempera
tures synonymous with high engine output colloidal carbon, granular carbon,
oil-soluble varnishes and organic acids are being formed,
The magnitude of this internal phase of the oil contamination depends on the
oil temperature, the crankcase content, the oil consumption, the change periods
and, last but not least, the characteristics of the lubricant itself,
TABLE I
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What Types of Filters?
The simplest type of strainer consists of fine wire mesh such as still general
ly used at the oil pump intake (Fig;* 3 ) . Since only particles of fairly large
size such as granular carbon and metal chips can be removed in this manner and
since the suction side of the oil pump does not tolerate any appreciable re
striction, strainers of the cloth bag type were next developed for use on the
pressure side of the lubrication system (Fig. k)« The demand for cleanable
rather than replaceable elements then led to the metal edge-type strainer de
signs still frequently employed as a coarse stage of full-flow filtration
(Fig» 5). While these early types of oil strainers can retain some sludge and
relatively large particles of foreign matter they are ineffectual as far as
oil discoloration is concerned,,
In line with the demand for color-clean filtration and following the basic rule
that filter efficiency increases with the density of the filtering medium and
also with a lowering of the oil flow rate, depth-type by-pass filters came now
into existence. This principle employs a relatively thick layer of fibrous or
granular materials such as felt, cotton, cellulose, paper, mineral wool or
sawdust (Fjjg., 6 ) .
With use of straight mineral oils such filters can do an excellent job of main
taining visible oil cleanliness and they have therefore dominated the filter
market for many years by virtue of their ease of application to existing engines
and the simplicity of element changes. Their natural shortcoming is that only a
relatively small percentage of the circulated oil (5 to 2D%) is filtered at any
one time. Consequently, no assurance is obtained that some of the solid
particles may not have done their damage before they can be finally eliminated
by the filter. The filtered oil is in most instances directly returned to the
crankcase where it is again mixed with the bulk of the contaminated lubricant.
Some engine manufacturers, however, have found it expedient to utilize this
cleaned oil for the lubrication of such critical parts as the valve gear,
speed governors, superchargers, etc., before returning it to the crankcase.
Realization of the principle that the beneficial effect of an oil flow reduc
tion on filtration quality may be also obtained by a corresponding increase of
the filtering area, led during the last decade to the development of multifold
paper filters (Fig^ "?)* As compared to a depth-type design of equal size this
unique arrangement of paper folds provides an increase of 700$ to 800$ in
filtering area and, at the same time, a tremendous increase in dirt storage
capacity.
Even though filters of this type may not immediately achieve color-clean
filtration of straight mineral oils, they are producing excellent results
once a small layer of sludge has been established. Due to their increased
operational life multifold paper filters have not not made substantial in
roads on the use of depth-type by-pass filters but have also found wide
spread application in full-flow filtration systems where their increased flow
capacity permits a reduction of the exterior dimensions.
-4 -
filters depends on a purely mechanical process and achieves, therefore, mainly
the elimination of solid matter, the filtering media used in oil conditioners
have the additional ability to adsorb the oxidized varnish-forming petroleum
fractions and to neutralize the oil oxidation acids0
This type of filter is, therefore, capable of restoring contaminated oil al
most to its original condition. However, they are unable to cope completely
with fuel dilution, have a high susceptibility to "caking" in the presence of
even small amounts of water and possess for a given filter volume a very low
capacity. While widely used for "batch-type" oil reclaiming, these drawbacks
together with the tendency to remove the chemical additives from heavy-duty
oils, have prevented chemically active oil conditioners from reaching major
importance in the high-speed engine field.
To prevent accelerated abrasive wear, oil filters should remove all solid
foreign matter exceeding the thickness of the oil film separating the moving
parts. Depending on load, speed, running clearances and oil viscosity, film
thicknesses from two ten-thousandths to three thousandths of an inch may be
encountered in high-speed engines. The size of small particles is usually
quoted in "MICRONS", one micron being one thousandth of a millimeter or
roughly four hundred-thousandths of an inch.
Pifl. & shows a comparison of these two scales. Normal automotive engine
clearances extend over the range from one^half thousandth to four thousandths
of an inch equivalent to twelve and one-half to one hundred microns. To
minimize wear, elimination of all abrasive particles exceeding five to ten
microns in size appears therefore desirable. In new condition, metal strain
ers will filter out particles as small as 75 microns, cloth bag strainers
down to 35 or 40 microns. They will effectively trap larger particles of
dirt or metal chips but cannot be relied upon to eliminate most of the wear-
producing fine solids or to maintain oil color. Well-designed depth-type
filters at low flow rates will possess a filtration quality as low as two
microns. ..
-5 -
necessity for removing frem the oil by suitable filtration the considerable
amounts of fine air-born, abrasive contaminants.
Typical samples of the same two types of standardized road dust are shown in
3500 times magnification by the electron micrographs of FJftT 9* The fine
grade appears at the left, the coarse grade in the center and the picture at
the right shows small styrene balls of 0,25 micron diameter for size comparison,
The presence of numerous potentially destructive particles in the range from
five to approximately twenty microns is self^eviderit.
As pointed out before, that portion of the abrasive material introduced with
the intake air stream which is not eliminated by the air cleaners as well as
all by-products of fuel combustion must first pass the pistons before reaching
the crankcase. This passageway is normally coated with a film of highly
oxidized oil forming a perfect bond for the solid contaminants. Much of the
piston ring and cylinder wall wear and most of the deposit formation on piston
skirts and in the ring groove's will therefore have been accomplished before
the oil filter ever gets its chance to render these materials harmless.
Realization of this fact confronted the oil industry with the challenge to
develop motor oils which could effectively prevent the formation of deposits
on these most vital engine parts. Two means were employed to achieve this
goal. First, fortification of the oil with chemical compounds increasing its
resistance to oxidation and second, addition of cleansing or «detergent"
materials. The results achieved in this" manner during the past decade have
exceeded a U expectations. Use of oxidation inhibitors accomplishes much
lower oxidation levels not only in the oil sump but also on the cylinder walls
than obtainable with even the best straight mineral oils. The formation of
varnish-like oxy-hydrocarbon compounds and corrosive organic acids is thus
effectively reduced. The detergents, in turn, counteract the coagulating
tendency of the already lowered amount of oxidation products thus keeping the
varnish-forming materials as well as the colloidal earbon particles dispersed
in the oil.
During the early period of engine operation without oil filters, the dis
carded dirty oil left its sludge deposits behind in the crankcase. In the
following stage with filtration clean oil could be drained from comparatively
clean crankcases but pistons and rings still remained unaffected. With use
of detergent lubricating oils engine maintenance has now progressed to the
point where the entire engine interior can be kept in cleaner condition than
obtainable from straight mineral oils with the most perfect type of oil
conditioning. '
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How Much Detergency?
TABLE II
It must be pointed out at this time that the effect of these adverse condi
tions is basic for all types of engines regardless of the fuel being used.
Both gasoline as well as Diesel engines will therefore be found equally
responsive to the effects of cracked fuels, high fuel sulfur content, low
combustion temperatures and overrich mixtures. However, the method by which
the fuel and air are being mixed, has a noticeable bearing on the formation of
unburned carbon during the combustion processc Fuel injection into the com
pressed air, such as employed in Diesel engines, generally provides less uni
form mixture ratios than found in carbureted engines. Overrich mixture strata
thus formed account for the considerable higher quantities of carbon "soot"
contaminating the crankcase oil of Diesel engines even under normal operating
conditions„
To take care of the detergency requirements of both types of engines under all
possible operating conditions and with fuels of widely varying combustion
characteristics and sulfur contents, the petroleum industry has made available
lubricating oils of five different detergency levels as approximately shown in
Table III,
"Premium" 1
"Heavy-Duty" (2-1D4B) 3
"Heavy-Duty (MIL-0-2LQ4) 4o5
"Heavy-Duty" (2-104B S-l) 8
"Super-Duty" (2-104B S-2) 16
TABLE III
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For proper choice of one of these five types of detergent oils all fuel fac
tors contained in Table II must be taken into consideration.
Whiijia the light load level of gasoline engines in passenger car use generally
permits their satisfactory operation on "PREMIUM11 or "2-1D4B" oils, the same
engines in commercial use may already require the higher detergency of
"MIL-O-2104" oils, particularly if highly cracked gasoline is used.
Under the operatisag conditions for which Diesel engines have become famous as
low cost power producers, i.e. high load factors, high oil temperatures and
inexpensive grades of fuel oil, use of one of the three highest detergency
level lubricants is required for longest life, As a rule, M£L-0-2H)4 lubri
cants will satisfactorily handle fuel oils with a sulfur content below 0.5&
S-l oils will tolerate sulfur percentages approaching 1.0$ and beyond that
point, or under particularly severe operating conditions, super-duty lubri
cants of the S-2 type may even be recommended.
The physical size of the carbon particles originating from incomplete fuel
combustion or as the result of lubricating, oil oxidation is submicronic.
Their coloring value is very high, as little as 0.2/6 of this type of carbon
visually blackening.the lubricant. Color-clean filtration of crankcase oils
would therefore be impossible even with the best-constructed depth-type
filters and low oil flow if it were not for the help of the coagulating action
exerted by even small amounts of the resinous oxidation products upon these
colloidal particles. With straight mineral oils, this coagulation of the
carbon to larger globules establishes on all types of filters a "sludge bed"
which increases the filtration efficiency and can, therefore, normally be con
sidered as a sign of satisfactory filtration,
A typical example of this condition is given in Fip. 1Q. The metal edge-type
strainer shown has free openings of 125 microns in one dimension and should,
by all rights, retain only solid particles exceeding approximately five
thousandths of an inch. let it has accumulated with use of straight mineral
oil, a heavy layer of carbonaceous sludge known to consist mainly of colloidal
materials. Chemical analysis data of this sludge are shown in Table IV.
TABLE 17
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With use of detergent lubricants, oil color has therefore completely lost its mean
ing as a grademeter for oil cleanliness and the necessity of filter element changes.
The rapid blackening of heavy-duty oils and absence of the tell-tale sludge de
posits on used filter elements, have instilled in some engine operators the feel
ing that since the effects of lubricating oil filtration are no longer visible,
filters could be completely dispensed with or at least the filter elements need
not be changed any more0
Nothing, of course, could be farther from the truth. The cleansing and dispersing
action of heavy-duty lubricants is most effective on deposition of organic col
loidal contaminants and has lesser influence on minute metallic, abrasive or hard
carbon particles. To profit from the wear-reducing effect of oil filtration the
inorganic solids must be removed from detergent oils just as completely as from
ordinary lubricants,
The overall efficiency of most oil filter designs developed for use with straight
mineral oils depends to a large extent on speedy establishment of a density-
promoting sludge bed. Since with detergent oils this sludge bed can be no longer
relied upon, the density of the filtering media must be increased to assure satis
factory filtration quality,
To filter such formidable amounts of lubricant with the same degree ©f efficiency
as obtainable from a by-pass filter handling only 5% to 1D% of the total a full-
flow filter would obviously have to be materially larger in filtering area. True
full-flow filtration of straight mineral oils becomes therefore largely a problem
of space which is usually solved by a compromise between filtration quality and
filter size,
- 9 -
When to Change Detergent Oils
However, two factors limiting the life of heavy-duty lubricating oils must be
understood, first, the fact that while detergent additives prevent the
organic contamination from depositing on engine parts, they do not remove it
from the crankcase. Consequently, the oil viscosity will show a gradual in
crease due to the dissolved and suspended organic contaminants until finally
a point may be reached where satisfactory oil supply to splash-lubricated
parts is no longer assured,
Considerable attention has been directed during the past few years to the
possible use of oil drain analyses as an indication of oxidation resistance
and detergency effectiveness. Since most of the current heavy-duty oils
derive their detergency from compounds containing either calcium or barium,
much can be learned about the condition of used oil samples by sulfate ash
determinations. These metals may thus be readily analyzed in new oils and
have very definite values for each particular lubricant,
In used oil samples, however, the same metals may show up in identical amounts
without necessarily indicating their presence in an effective form. The sul
fate ash analysis of used oil may also be increased by presence of undis-
solved or dissolved organic salts contributed by iron, lead and dirt con
tamination products. Or reduced sulfate ash values may be found in the used
oil which could then probably be attributed to removal of some organic com
pounds by effective filtration. While it is generally felt that analysis
for the calcium or barium present as the detergent compound is possible
after filtration of the used oil through paper, these methods are far too
complicated to be recommended for field use,
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lubricants. With this method the presence of a strong as well as a weak base
can be shown and it is probably the latter which Indicates the reserve alka
linity. Even at such time as the weak base becomes completely neutralized
there undoubtedly will still be present a considerable amount of detergency
which may be then attributed to the neutral type materials .
Occasionally, the observation may be made that in continued use the color of
detergent oils gradually becomes clean. This may be caused by selective dis
placement of the detergent from the heavier carbon particles to the trans
parent oxidation varnishes* The polarizing action of the detergent may thus
be completely exhausted by light-colored colloidal compounds with the result
that the discoloring carbonaceous solids will be coagulated and can then be
removed by the oil filter. Consequently, with use of detergent lubricants
clean oil color as well as sludge deposits on the filter elements should be a
warning that the internal cleansing action of the oil can no longer be relied
upon and that the oil change periods should be reduced.
To avoid initial contamination of the highly detergent new oil with the con
taminants stored in the oil filters during the previous period of use, filter
element changes should be made simultaneously with changes of the crankcase
lubricant.
Summation
Use of these superior crankcase oils has created a number of new problems.
The detergent additives not only effectively counteract the formation of
engine deposits by polar suspension of the colloidal contaminants in the oil,
but also render the bulk of the organic contaminating matter unfilterable.
Establishment of an efficiency-promoting sludge bed on the oil filter elements
is thus prevented and color-clean oil filtration made impossible.
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FACTORS GOVERNING
FILTRATION REQUIREMENTS
INCHES MICRONS
.0040 100
T
ENGINE
PARTICLE SIZE CLEARANCES
DISTRIBUTION
OF TYPICAL
ROAD DUST
SAMPLE OIL FILM
THICKNESSES
///////////////////////// 'z/
DESIRABLE
25 50 75 100% FILTRATION
FtG. 8
(&*-)
FtG. 9
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"'/
FIG. 6
FIG. 5
frs"0
FIG. 7
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LUBRICATING
OIL
CONTAMINATION LUBRICATING OIL CONTAMINATION
D
I
R
T
COLLOIDAL
CARBON
M W DIRT 1
E A
T T VARNISH
A E
L R METAL 1 I
ORGANIC
•3
ACIDS
FUEL 1
GRANULAR
CARBON
I
WATER 1
II
11
.--"fcSS* 8 *
^
w
*w •«*»
«*«y FIG. 10
EFFECTIVENESS OF DETFRrFM-re
IN
N DISPERSING C O l I S S K ^
CASE *A
(EXCESS)
CASE B
CASE V
(BALANCE)
(LACK)
FIG. u