3TiO2+4Al=3Ti+2Al2O3

T deltaH deltaS deltaG K Log(K)

K kJ J/K kJ 300 3000 1

300.000 -517.202 -70.119 -496.166 2.497E+086 86.397
400.000 -520.192 -78.771 -488.684 6.621E+063 63.821
500.000 -522.212 -83.325 -480.550 1.610E+050 50.207
600.000 -523.257 -85.251 -472.107 1.271E+041 41.104
700.000 -523.875 -86.204 -463.532 3.909E+034 34.592
800.000 -524.852 -87.497 -454.854 5.028E+029 29.701
900.000 -526.156 -89.028 -446.031 7.748E+025 25.889
1000.000 -569.982 -135.983 -433.998 4.695E+022 22.672
1100.000 -569.395 -135.440 -420.411 9.233E+019 19.965
1200.000 -556.064 -123.862 -407.430 5.451E+017 17.736
1300.000 -557.071 -124.671 -394.999 7.458E+015 15.873
1400.000 -557.531 -125.014 -382.511 1.874E+014 14.273
1500.000 -557.435 -124.950 -370.010 7.691E+012 12.886
1600.000 -556.767 -124.521 -357.534 4.713E+011 11.673
1700.000 -555.515 -123.764 -345.117 4.028E+010 10.605
1800.000 -553.663 -122.707 -332.791 4.551E+009 9.658
1900.000 -551.194 -121.374 -320.585 6.520E+008 8.814
2000.000 -504.610 -97.390 -309.831 1.238E+008 8.093
2100.000 -499.534 -94.913 -300.216 2.938E+007 7.468
2200.000 -698.841 -188.478 -284.190 5.599E+006 6.748
2300.000 -699.949 -188.970 -265.317 1.062E+006 6.026
2400.000 -470.970 -90.616 -253.490 3.293E+005 5.518
2500.000 -461.261 -86.653 -244.628 1.293E+005 5.112
2600.000 -451.552 -82.845 -236.154 5.556E+004 4.745
2700.000 -441.843 -79.181 -228.054 2.584E+004 4.412
2800.000 -432.135 -75.650 -220.314 1.289E+004 4.110
2900.000 -422.426 -72.243 -212.920 6.846E+003 3.835
3000.000 -412.717 -68.952 -205.861 3.843E+003 3.585

Al Extrapolated from 2790.000 K

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
TiO2 79.899 68.953 3.000 239.696 56.666 ml
Al 26.982 31.047 4.000 107.926 39.973 ml
g/mol wt-% mol g l or ml
Ti 47.900 41.338 3.000 143.700 31.891 ml
Al2O3 101.961 58.662 2.000 203.923 51.431 ml
Ti Titanium
T Cp H S G Reference
K J/(mol*K) kJ/mol J/(mol*K) kJ/mol 300 3000 1
300.000 25.095 0.046 30.875 -9.216 Landolt 99, Knacke 91, Nasa 93
400.000 26.380 2.630 38.298 -12.689 Landolt 99, Knacke 91, Nasa 93
500.000 27.338 5.314 44.283 -16.828 Nasa 93
600.000 28.431 8.102 49.363 -21.516 Nasa 93
700.000 29.495 10.999 53.827 -26.680 Nasa 93
800.000 30.461 13.997 57.830 -32.266 Nasa 93
900.000 30.935 17.073 61.452 -38.234 Nasa 93
1000.000 32.806 20.234 64.780 -44.547 Nasa 93
1100.000 39.092 23.783 68.158 -51.191 Nasa 93
1200.000 28.565 31.531 74.893 -58.341 Nasa 93, Landolt 99
1300.000 29.952 34.457 77.234 -65.948 Nasa 93, Landolt 99
1400.000 31.402 37.524 79.507 -73.785 Nasa 93, Landolt 99
1500.000 32.916 40.739 81.724 -81.847 Nasa 93, Landolt 99
1600.000 34.494 44.109 83.899 -90.129 Nasa 93, Landolt 99
1700.000 36.136 47.640 86.039 -98.626 Nasa 93, Landolt 99
1800.000 37.841 51.338 88.152 -107.336 Nasa 93, Landolt 99
1900.000 39.611 55.210 90.245 -116.256 Nasa 93, Landolt 99
2000.000 46.800 73.757 99.788 -125.820 Nasa 93, Landolt 99
2100.000 46.800 78.437 102.072 -135.914 Nasa 93, Landolt 99
2200.000 46.800 83.117 104.249 -146.230 Nasa 93, Landolt 99
2300.000 46.800 87.797 106.329 -156.760 Nasa 93, Landolt 99
2400.000 46.800 92.477 108.321 -167.493 Nasa 93, Landolt 99
2500.000 46.800 97.157 110.231 -178.422 Nasa 93, Landolt 99
2600.000 46.800 101.837 112.067 -189.537 Nasa 93, Landolt 99
 2700.000 46.800 106.517 113.833 -200.833 Nasa 93, Landolt 99
2800.000 46.800 111.197 115.535 -212.302 Nasa 93, Landolt 99
2900.000 46.800 115.877 117.177 -223.938 Nasa 93, Landolt 99
3000.000 46.800 120.557 118.764 -235.735 Nasa 93, Landolt 99

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
Ti 47.900 100.000 1.000 47.900 10.630 ml
g/mol wt-% mol g l or ml

TiO2 Titanium(IV) oxide

T Cp H S G Reference 300 3000 1
K J/(mol*K) kJ/mol J/(mol*K) kJ/mol
300.000 55.175 -944.644 50.632 -959.834 Barin 93, Saxena 93
400.000 63.331 -938.665 67.778 -965.776 Barin 93, Saxena 93
500.000 67.425 -932.108 82.393 -973.304 Barin 93, Saxena 93
600.000 69.902 -925.233 94.921 -982.185 Barin 93, Saxena 93
700.000 71.599 -918.153 105.831 -992.235 Barin 93, Saxena 93
800.000 72.866 -910.927 115.478 -1003.309 Barin 93, Saxena 93
900.000 73.871 -903.588 124.121 -1015.297 Barin 93, Saxena 93
1000.000 74.701 -896.159 131.948 -1028.106 Barin 93, Saxena 93
1100.000 75.406 -888.652 139.102 -1041.664 Barin 93, Saxena 93
1200.000 76.017 -881.080 145.690 -1055.908 Barin 93, Saxena 93
1300.000 76.552 -873.451 151.796 -1070.786 Barin 93, Saxena 93
1400.000 77.024 -865.772 157.487 -1086.253 Barin 93, Saxena 93
1500.000 77.442 -858.048 162.815 -1102.271 Barin 93, Saxena 93
1600.000 77.810 -850.285 167.825 -1118.806 Barin 93, Saxena 93
1700.000 78.133 -842.488 172.552 -1135.827 Barin 93, Saxena 93
1800.000 78.415 -834.660 177.027 -1153.308 Barin 93, Saxena 93
1900.000 78.658 -826.806 181.273 -1171.225 Barin 93, Saxena 93
2000.000 78.863 -818.930 185.313 -1189.555 Barin 93, Saxena 93
2100.000 79.032 -811.035 189.165 -1208.281 Barin 93, Saxena 93
2200.000 100.416 -734.967 224.834 -1229.601 Barin 93
2300.000 100.416 -724.926 229.297 -1252.309 Barin 93
2400.000 100.416 -714.884 233.571 -1275.454 Barin 93
2500.000 100.416 -704.842 237.670 -1299.018 Barin 93
2600.000 100.416 -694.801 241.608 -1322.983 Barin 93
2700.000 100.416 -684.759 245.398 -1347.334 Barin 93
 2800.000 100.416 -674.718 249.050 -1372.058 Barin 93
2900.000 100.416 -664.676 252.574 -1397.140 Barin 93
3000.000 100.416 -654.635 255.978 -1422.569 Barin 93

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
TiO2 79.899 100.000 1.000 79.899 18.889 ml
g/mol wt-% mol g l or ml
 Delta Delta
T(K) P(ATM) Activity X Delta H (J) Delta G (J) Delta Vol (l) S (J/K) Cp (J/K)
300 3000 1
------ TiO2(s1) Al(s) Ti(s1) Al2O3(s4) ------
300.00 -517202.4 -495980.9 0.00E+00 -70.738 -2.83E+01
400 -519609.1 -488521.5 0.00E+00 -77.719 -2.01E+01
500 -521317.9 -480540.6 0.00E+00 -81.555 -1.46E+01
600 -522638.9 -472257 0.00E+00 -83.97 -1.22E+01
700 -523829.2 -463765.4 0.00E+00 -85.805 -1.19E+01
800 -525050 -455102.5 0.00E+00 -87.434 -1.27E+01
900 -526380.6 -446280.5 0.00E+00 -89 -1.40E+01
933.45 -526854.5 -443294.8 0.00E+00 -89.517 -1.44E+01
------ TiO2(s1) Al(l) Ti(s1) Al2O3(s4) ------
Al(1 mol): DH° = 10711.0 DG° = 0 ------ DS° = 11.475
933.45 -569698.5 -443294.8 0.00E+00 -135.416 -9.55E+00
1000 -570176.9 -434264.3 0.00E+00 -135.913 -4.70E+00
1100 -570222.6 -420663.5 0.00E+00 -135.963 4.12E+00
1166 -569726.4 -411702.3 0.00E+00 -135.527 1.11E+01
------ TiO2(s1) Al(l) Ti(s2) Al2O3(s4) ------
Ti(1 mol): DH° = 4172.0 DG° = 0 ------ DS° = 3.578
1166 -557210.4 -411702.3 0.00E+00 -124.793 -9.76E+00
1200 -557520.9 -407454.8 0.00E+00 -125.055 -8.50E+00
1300 -558181.5 -394919.8 0.00E+00 -125.586 -4.67E+00
1400 -558448.1 -382348.6 0.00E+00 -125.785 -6.17E-01
1500 -558296.4 -369772.8 0.00E+00 -125.682 3.69E+00
1600 -557700 -357221.5 0.00E+00 -125.299 8.28E+00
1700 -556630.4 -344721.8 0.00E+00 -124.652 1.32E+01
1800 -555057.8 -332299.4 0.00E+00 -123.755 1.83E+01
1900 -552950.9 -319978.8 0.00E+00 -122.617 2.38E+01
1939 -551977.5 -315206.5 0.00E+00 -122.11 2.61E+01
------ TiO2(s1) Al(l) Ti(l) Al2O3(s4) ------
Ti(1 mol): DH° = 14146.0 DG° = 0 ------ DS° = 7.296
1939 -509539.5 -315206.5 0.00E+00 -100.223 5.42E+01
2000 -506217.3 -309144.6 0.00E+00 -98.536 5.47E+01
2100 -500701.5 -299426.2 0.00E+00 -95.845 5.56E+01
2130 -499030.6 -296562.7 0.00E+00 -95.055 -1.40E+01
------ TiO2(l) Al(l) Ti(l) Al2O3(s4) ------
TiO2(1 mol): DH° = 46024.0 DG° = 0 ------ DS° = 21.608
2130 -637102.6 -296562.7 0.00E+00 -159.878 -1.40E+01
2200 -638060.1 -285355.6 0.00E+00 -160.32 -1.33E+01
2300 -639348.8 -269294.4 0.00E+00 -160.893 -1.24E+01
2327.02 -639681.2 -264945.9 0.00E+00 -161.037 9.84E+01
------ TiO2(l) Al(l) Ti(l) Al2O3(l) ------
Al2O3(1 mol): DH° = 118407.2 DG° = 0 ------ DS° = 50.884
 2327.02 -402866.7 -264945.9 0.00E+00 -59.269 9.84E+01
2400 -395686 -260731.6 0.00E+00 -56.231 9.84E+01
2500 -385847.3 -255310.7 0.00E+00 -52.215 9.84E+01
2600 -376008.6 -250283.4 0.00E+00 -48.356 9.84E+01
2700 -366169.9 -245634.6 0.00E+00 -44.643 9.84E+01
2793.71 -356949.6 -241609.2 0.00E+00 -41.286 9.84E+01
------ TiO2(l) Al(g) Ti(l) Al2O3(l) ------
Al(1 mol): DH° = 293969.2 DG° = 0 ------ DS° = 105.225
2793.71 -1532826.3 -241609.2 -9.17E+02 -462.187 1.42E+02
2800 -1531932.4 -238705.1 -9.19E+02 -461.867 1.42E+02
2900 -1517708.9 -192769.4 -9.52E+02 -456.876 1.42E+02
3000 -1503485 -147324.3 -9.85E+02 -452.054 1.42E+02

T(K) P(ATM) Activity X H (J) G (J) Vol (l) S (J/K) Cp (J/K)

300 3000 1
------ Ti(s1) ------
300.00 46.8 -9227.8 0.00E+00 30.915 25.288
400 2653.4 -12707.9 0.00E+00 38.403 26.855
500 5399.8 -16863.7 0.00E+00 44.527 27.963
600 8228.4 -21581.1 0.00E+00 49.682 28.552
700 11104.8 -26776.1 0.00E+00 54.116 28.977
800 14029 -32386.6 0.00E+00 58.019 29.554
900 17028.8 -38367.7 0.00E+00 61.552 30.524
1000 20152.7 -44688.9 0.00E+00 64.842 32.06
1100 23464 -51331.5 0.00E+00 67.996 34.291
1166 25788 -55886.9 0.00E+00 70.047 36.192
------ Ti(s2) ------
Ti(1 mol): DH = 4172.0 DG = 0 ------ DS = 3.578
1166 29960 -55886.9 0.00E+00 73.625 29.245
1200 30957.9 -58404.6 0.00E+00 74.469 29.459
1300 33938.5 -65971.9 0.00E+00 76.854 30.175
1400 36997.3 -73771.5 0.00E+00 79.121 31.023
1500 40147.5 -81792.9 0.00E+00 81.294 32.003
1600 43402.3 -90027.8 0.00E+00 83.394 33.115
1700 46774.9 -98469.8 0.00E+00 85.438 34.359
1800 50278.6 -107114 0.00E+00 87.44 35.736
1900 53926.4 -115956.8 0.00E+00 89.412 37.244
1939 55391.1 -119458.8 0.00E+00 90.175 37.868
------ Ti(l) ------
Ti(1 mol): DH = 14146.0 DG = 0 ------ DS = 7.296
1939 69537.1 -119458.8 0.00E+00 97.471 47.237
2000 72418.5 -125449.3 0.00E+00 98.934 47.237
2100 77142.2 -135458.9 0.00E+00 101.239 47.237
2200 81865.9 -145693.5 0.00E+00 103.436 47.237
2300 86589.6 -156142.9 0.00E+00 105.536 47.237
2400 91313.3 -166797.7 0.00E+00 107.546 47.237
2500 96037 -177649.4 0.00E+00 109.475 47.237
2600 100760.7 -188690.1 0.00E+00 111.327 47.237
2700 105484.4 -199912.5 0.00E+00 113.11 47.237
2800 110208.1 -211309.9 0.00E+00 114.828 47.237
2900 114931.8 -222876.1 0.00E+00 116.485 47.237
3000 119655.5 -234605.1 0.00E+00 118.087 47.237

T(K) P(ATM) Activity X H (J) G (J) Vol (l) S (J/K) Cp (J/K)

300 3000 1
------ TiO2(s1) ------
300 -944647.8 -959888.3 0.00E+00 50.802 55.341
400 -938691.2 -965845 0.00E+00 67.884 63.085
500 -932138 -973382.4 0.00E+00 82.489 67.59
600 -925230.6 -982275.5 0.00E+00 95.075 70.348
700 -918100.3 -992344.2 0.00E+00 106.063 72.139
800 -910821.5 -1003445.8 0.00E+00 115.78 73.362
900 -903439.5 -1015466.2 0.00E+00 124.474 74.233
1000 -895982.7 -1028312.7 0.00E+00 132.33 74.873
1100 -888470.1 -1041909.1 0.00E+00 139.49 75.357
1200 -880914.9 -1056191.2 0.00E+00 146.064 75.732
1300 -873326.3 -1071105.1 0.00E+00 152.138 76.028
1400 -865711.2 -1086604.4 0.00E+00 157.781 76.266
1500 -858074.5 -1102648.8 0.00E+00 163.05 76.46
1600 -850420.3 -1119203.4 0.00E+00 167.989 76.62
1700 -842751.3 -1136237 0.00E+00 172.639 76.754
1800 -835070.1 -1153722.5 0.00E+00 177.029 76.867
1900 -827378.4 -1171635.1 0.00E+00 181.188 76.963
2000 -819677.9 -1189953.1 0.00E+00 185.138 77.046
2100 -811969.6 -1208656.4 0.00E+00 188.898 77.117
2130 -809655.7 -1214339.9 0.00E+00 189.993 100.416
------ TiO2(l) ------
TiO2(1 mol): DH = 46024.0 DG = 0 ------ DS = 21.607
2130 -763631.7 -1214339.9 0.00E+00 211.6 100.416
2200 -756602.7 -1229266 0.00E+00 214.847 100.416
2300 -746561.1 -1250975.5 0.00E+00 219.311 100.416
2400 -736519.5 -1273121.8 0.00E+00 223.584 100.416
2500 -726477.9 -1295686.6 0.00E+00 227.683 100.416
2600 -716436.3 -1318653.1 0.00E+00 231.622 100.416
2700 -706394.7 -1342006 0.00E+00 235.412 100.416
2800 -696353.1 -1365730.9 0.00E+00 239.064 100.416
2900 -686311.5 -1389814.4 0.00E+00 242.587 100.416
3000 -676269.9 -1414244.3 0.00E+00 245.991 100.416
Keq T

2.27E+86
6.21E+63
1.59E+50
1.30E+41
4.03E+34
5.18E+29
7.96E+25
6.39E+24

6.39E+24
4.82E+22
9.44E+19
2.77E+18

2.77E+18
5.44E+17
7.37E+15
1.84E+14
7.52E+12
4.59E+11
3.91E+10
4.39E+09
6.26E+08
3.10E+08

3.10E+08
1.19E+08
2.80E+07
1.87E+07

1.87E+07
5.96E+06
1.31E+06
8.85E+05
8.85E+05
4.73E+05
2.16E+05
1.07E+05
5.65E+04
3.29E+04

3.29E+04
2.84E+04
2.97E+03
3.67E+02

T
T
 TOMAMOS UN PUNTO

PARA DELTA H
T HSC FACTWEB TERMOCAL
300.000 -517201.501 -517202.4 -519437

COMPARAMOS LA TEMPERATURA PARA EL CAMBIO DE FAS

T(K) delta H
1939 FACTWEB 14146
1942 TERMOCAL 14146

COMPARAMOS LA TEMPERATURA PARA EL CAMBIO DE FAS

T(K) delta H
2130 FACTWEB 46024
2186 TERMOCAL 68000
ATURA PARA EL CAMBIO DE FASE DELTi

ATURA PARA EL CAMBIO DE FASE DELTiO2

Sn Tin
T Cp H S G Reference
K J/(mol*K) kJ/mol J/(mol*K) kJ/mol 300 3000 1
300.000 27.022 0.050 51.347 -15.354 Barin 77
400.000 28.832 2.843 59.369 -20.905 Barin 77
500.000 30.641 5.816 65.997 -27.182 Barin 77
600.000 28.663 15.919 85.546 -35.409 Landolt 99, Barin 77
700.000 28.249 18.762 89.929 -44.189 Landolt 99, Barin 77
800.000 28.043 21.575 93.686 -53.374 Landolt 99, Barin 77
900.000 27.957 24.375 96.983 -62.911 Landolt 99, Barin 77
1000.000 27.945 27.169 99.928 -72.759 Landolt 99, Barin 77
1100.000 27.979 29.965 102.593 -82.887 Landolt 99, Barin 77
1200.000 28.044 32.766 105.030 -93.270 Landolt 99, Barin 77
1300.000 28.130 35.575 107.278 -103.886 Landolt 99, Barin 77
1400.000 28.229 38.392 109.366 -114.720 Landolt 99, Barin 77
1500.000 28.339 41.221 111.317 -125.755 Landolt 99, Barin 77
1600.000 28.455 44.060 113.150 -136.979 Landolt 99, Barin 77
1700.000 28.575 46.912 114.878 -148.382 Landolt 99, Barin 77
1800.000 28.698 49.775 116.515 -159.952 Landolt 99, Barin 77
1900.000 28.822 52.651 118.070 -171.682 Landolt 99, Barin 77
2000.000 28.947 55.540 119.552 -183.564 Landolt 99, Barin 77
2100.000 29.071 58.441 120.967 -195.590 Landolt 99, Barin 77
2200.000 29.195 61.354 122.322 -207.755 Landolt 99, Barin 77
2300.000 29.318 64.280 123.623 -220.053 Landolt 99, Barin 77
2400.000 29.439 67.218 124.873 -232.478 Landolt 99, Barin 77
2500.000 29.559 70.168 126.077 -245.026 Landolt 99, Barin 77
2600.000 29.676 73.129 127.239 -257.692 Landolt 99, Barin 77
2700.000 29.792 76.103 128.361 -270.472 Landolt 99, Barin 77
2800.000 29.905 79.088 129.447 -283.363 Landolt 99, Barin 77
2900.000 30.015 82.084 130.498 -296.360 Landolt 99, Barin 77
3000.000 30.123 85.091 131.517 -309.461 Landolt 99, Barin 77

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
Sn 118.690 100.000 1.000 118.690 16.337 ml
g/mol wt-% mol g l or ml

SnO2 Tin(IV) oxide

T Cp H S G Reference
300 3000 1
 K J/(mol*K) kJ/mol J/(mol*K) kJ/mol 300 3000 1
300.000 53.540 -580.701 52.630 -596.490 Barin 92, Binnewies 02, Gurvich 90
400.000 65.087 -574.692 69.837 -602.627 Barin 92, Binnewies 02, Gurvich 90
500.000 70.827 -567.869 85.039 -610.388 Barin 92, Binnewies 02, Gurvich 90
600.000 74.281 -560.601 98.280 -619.569 Barin 92, Binnewies 02, Gurvich 90
700.000 76.656 -553.048 109.919 -629.991 Barin 92, Binnewies 02, Gurvich 90
800.000 78.456 -545.288 120.277 -641.510 Barin 92, Binnewies 02, Gurvich 90
900.000 79.922 -537.367 129.605 -654.012 Barin 92, Binnewies 02, Gurvich 90
1000.000 81.180 -529.311 138.092 -667.403 Barin 92, Binnewies 02, Gurvich 90
1100.000 82.302 -521.136 145.883 -681.607 Barin 92, Binnewies 02, Gurvich 90
1200.000 83.332 -512.854 153.089 -696.560 Barin 92, Binnewies 02, Gurvich 90
1300.000 84.297 -504.472 159.798 -712.209 Barin 92, Binnewies 02, Gurvich 90
1400.000 85.215 -495.996 166.079 -728.506 Barin 92, Binnewies 02, Gurvich 90
1500.000 86.097 -487.430 171.988 -745.412 Barin 92, Binnewies 02, Gurvich 90
1600.000 86.953 -478.777 177.572 -762.892 Barin 92, Binnewies 02, Gurvich 90
1700.000 87.789 -470.040 182.869 -780.917 Barin 92, Binnewies 02, Gurvich 90
1800.000 88.608 -461.220 187.910 -799.458 Barin 92, Binnewies 02, Gurvich 90
1900.000 89.415 -452.319 192.722 -818.491 Barin 92, Binnewies 02, Gurvich 90
2000.000 92.002 -419.725 209.734 -839.193 Gurvich 90
2100.000 92.002 -410.525 214.223 -860.393 Gurvich 90
2200.000 92.002 -401.325 218.503 -882.031 Gurvich 90
2300.000 92.002 -392.124 222.593 -904.087 Gurvich 90
2400.000 92.002 -382.924 226.508 -926.544 Gurvich 90
2500.000 92.002 -373.724 230.264 -949.384 Gurvich 90
2600.000 92.002 -364.524 233.872 -972.592 Gurvich 90
2700.000 92.002 -355.324 237.344 -996.154 Gurvich 90
2800.000 92.002 -346.124 240.690 -1020.056 Gurvich 90
2900.000 92.002 -336.923 243.919 -1044.288 Gurvich 90
3000.000 92.002 -327.723 247.038 -1068.836 Gurvich 90

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
SnO2 150.689 100.000 1.000 150.689 21.998 ml
g/mol wt-% mol g l or ml

SnO2 + 2CO(g) = Sn + 2CO2(g)

T deltaH deltaS deltaG K Log(K) 300 3000 1
K kJ J/K kJ
300.000 14.853 31.033 5.543 1.083E-001 -0.965
400.000 13.681 27.673 2.612 4.559E-001 -0.341
500.000 12.531 25.100 -0.019 1.005E+000 0.002
600.000 18.538 37.180 -3.770 2.129E+000 0.328
700.000 17.359 35.362 -7.395 3.563E+000 0.552
 800.000 16.213 33.832 -10.852 5.113E+000 0.709
900.000 15.087 32.506 -14.168 6.643E+000 0.822
1000.000 13.986 31.345 -17.359 8.069E+000 0.907
1100.000 12.904 30.314 -20.441 9.349E+000 0.971
1200.000 11.824 29.374 -23.425 1.047E+001 1.020
1300.000 10.735 28.502 -26.318 1.142E+001 1.058
1400.000 9.627 27.682 -29.127 1.221E+001 1.087
1500.000 8.496 26.902 -31.856 1.287E+001 1.109
1600.000 7.338 26.154 -34.508 1.339E+001 1.127
1700.000 6.149 25.433 -37.088 1.379E+001 1.140
1800.000 4.927 24.735 -39.596 1.410E+001 1.149
1900.000 3.670 24.055 -42.035 1.431E+001 1.156
2000.000 -21.234 10.988 -43.209 1.345E+001 1.129
2100.000 -22.702 10.271 -44.272 1.263E+001 1.101
2200.000 -24.129 9.608 -45.265 1.188E+001 1.075
2300.000 -25.518 8.990 -46.195 1.120E+001 1.049
2400.000 -26.874 8.413 -47.065 1.058E+001 1.024
2500.000 -28.202 7.871 -47.879 1.001E+001 1.000
2600.000 -29.502 7.361 -48.640 9.490E+000 0.977
2700.000 -30.780 6.878 -49.352 9.013E+000 0.955
2800.000 -32.032 6.423 -50.017 8.573E+000 0.933
2900.000 -33.256 5.994 -50.637 8.169E+000 0.912
3000.000 -34.455 5.587 -51.216 7.795E+000 0.892

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
SnO2 150.689 72.899 1.000 150.689 21.998 ml
CO(g) 28.010 27.101 2.000 56.021 44.827 l
g/mol wt-% mol g l or ml
Sn 118.690 57.419 1.000 118.690 16.337 ml
CO2(g) 44.010 42.581 2.000 88.020 44.827 l
 T(K) P(ATM) Activity X H (J) G (J) Vol (l) S (J/K) Cp (J/K)
300 3000 1
------ Sn(s1) ------
300.00 50 -15358.8 0.00E+00 51.362 27.022
400 2842.7 -20911 0.00E+00 59.384 28.832
500 5816.3 -27189.8 0.00E+00 66.012 30.642
505.06 5971.6 -27524.6 0.00E+00 66.321 30.732
------ Sn(l) ------
Sn(1 mol): DH = 7029.1 DG = 0 ------ DS = 13.918
505.06 13000.7 -27524.6 0.00E+00 80.239 29.694
600 15771.7 -35389.2 0.00E+00 85.268 28.805
700 18631.9 -44142.6 0.00E+00 89.678 28.471
800 21476.8 -53304.6 0.00E+00 93.477 28.451
900 24321.9 -62823.1 0.00E+00 96.828 28.451
1000 27167 -72658.4 0.00E+00 99.825 28.451
1100 30012.2 -82778.7 0.00E+00 102.537 28.451
1200 32857.3 -93157.9 0.00E+00 105.013 28.451
1300 35702.4 -103774.6 0.00E+00 107.29 28.451
1400 38547.5 -114610.3 0.00E+00 109.398 28.451
1500 41392.6 -125649.4 0.00E+00 111.361 28.451
1600 44237.8 -136878.4 0.00E+00 113.198 28.451
1700 47082.9 -148285.2 0.00E+00 114.922 28.451
1800 49928 -159859.6 0.00E+00 116.549 28.451
1900 52773.1 -171592 0.00E+00 118.087 28.451
2000 55618.2 -183474.3 0.00E+00 119.546 28.451
2100 58463.4 -195498.9 0.00E+00 120.934 28.451
2200 61308.5 -207659.1 0.00E+00 122.258 28.451
2300 64153.6 -219948.6 0.00E+00 123.523 28.451
2400 66998.7 -232361.8 0.00E+00 124.734 28.451
2500 69843.8 -244893.6 0.00E+00 125.895 28.451
2600 72689 -257539.3 0.00E+00 127.011 28.451
2700 75534.1 -270294.4 0.00E+00 128.085 28.451
2800 78379.2 -283154.9 0.00E+00 129.119 28.451
2876 80541.5 -292997.1 0.00E+00 129.881 28.451
------ Sn(g) ------
Sn(1 mol): DH = 295762.8 DG = 0 ------ DS = 102.839
2876 376304.3 -292997.1 2.36E+02 232.72 26.418
2900 376938.3 -298585 2.38E+02 232.939 26.418
3000 379580.1 -321923.9 2.46E+02 233.835 26.418

T(K) P(ATM) Activity X H (J) G (J) Vol (l) S (J/K) Cp (J/K)

300 3000 1
 300 3000 1
------ SnO2(s) ------
300.00 -577531.2 -592333.3 0.00E+00 49.34 53.54
400 -571522.7 -598141.4 0.00E+00 66.547 65.087
500 -564699.2 -605573.9 0.00E+00 81.749 70.827
600 -557431.5 -614425.7 0.00E+00 94.99 74.281
700 -549878.3 -624518.6 0.00E+00 106.629 76.656
800 -542119.1 -635708.9 0.00E+00 116.987 78.456
900 -534198 -647881.8 0.00E+00 126.315 79.922
1000 -526141.5 -660944 0.00E+00 134.802 81.18
1100 -517966.5 -674819.1 0.00E+00 142.593 82.302
1200 -509684.1 -689443.2 0.00E+00 149.799 83.332
1300 -501302.2 -704762.4 0.00E+00 156.508 84.297
1400 -492826.2 -720730.5 0.00E+00 162.789 85.215
1500 -484260.4 -737307.8 0.00E+00 168.698 86.098
1600 -475607.6 -754459.3 0.00E+00 174.282 86.954
1700 -466870.3 -772154.7 0.00E+00 179.579 87.789
1800 -458050.2 -790366.6 0.00E+00 184.62 88.609
1900 -449148.9 -809071.1 0.00E+00 189.433 89.416
1903 -448880.6 -809639.6 0.00E+00 189.574 89.44
------ SnO2(l) ------
SnO2(1 mol): DH° = 23400.0 DG° = 0 ------ DS° = 12.296
1903 -425480.6 -809639.6 0.00E+00 201.87 92
2000 -416556.6 -829444.7 0.00E+00 206.444 92
2100 -407356.6 -850315.3 0.00E+00 210.933 92
2200 -398156.6 -871624.3 0.00E+00 215.213 92
2300 -388956.6 -893351.5 0.00E+00 219.302 92
2400 -379756.6 -915478.9 0.00E+00 223.218 92
2500 -370556.6 -937989.7 0.00E+00 226.973 92
2600 -361356.6 -960868.6 0.00E+00 230.582 92
2700 -352156.6 -984101.5 0.00E+00 234.054 92
2800 -342956.6 -1007675.1 0.00E+00 237.399 92
2900 -333756.6 -1031577.5 0.00E+00 240.628 92
3000 -324556.6 -1055797.1 0.00E+00 243.747 92

Delta Delta
T(K) P(ATM) Activity X Delta H (J) Delta G (J) Delta Vol (l) S (J/K) Cp (J/K)
300 3000 1
------ SnO2(s) CO(g) Sn(s1) CO2(g) ------
300.00 11620.9 1233.6 0.00E+00 34.625 -1.04E+01
400 10426.6 -2053.9 0.00E+00 31.201 -1.23E+01
500 9273.1 -5036.7 0.00E+00 28.62 -1.05E+01
505.06 9220.2 -5181.3 0.00E+00 28.514 -1.04E+01
------ SnO2(s) CO(g) Sn(l) CO2(g) ------
Sn(1 mol): DH° = 7029.1 DG° = 0 ------ DS° = 13.918
505.06 16249.3 -5181.3 0.00E+00 42.432 -1.14E+01
600 15144.2 -9112.2 0.00E+00 40.427 -1.17E+01
700 13987.7 -13063.1 0.00E+00 38.644 -1.14E+01
800 12872.7 -16850.8 0.00E+00 37.154 -1.09E+01
900 11796.4 -20501.3 0.00E+00 35.886 -1.06E+01
1000 10741.7 -24033.3 0.00E+00 34.775 -1.05E+01
1100 9694.2 -27460.1 0.00E+00 33.777 -1.05E+01
1200 8642.1 -30791.4 0.00E+00 32.861 -1.06E+01
1300 7576.1 -34034.4 0.00E+00 32.008 -1.08E+01
1400 6488.6 -37194.5 0.00E+00 31.202 -1.10E+01
1500 5373.7 -40276 0.00E+00 30.433 -1.13E+01
1600 4226.5 -43282.1 0.00E+00 29.693 -1.16E+01
1700 3043.2 -46215.4 0.00E+00 28.976 -1.20E+01
1800 1814.1 -49077.7 0.00E+00 28.273 -1.26E+01
1900 529.3 -51870.3 0.00E+00 27.579 -1.31E+01
1903 489.9 -51953 0.00E+00 27.558 -1.32E+01
------ SnO2(l) CO(g) Sn(l) CO2(g) ------
SnO2(1 mol): DH° = 23400.0 DG° = 0 ------ DS° = 12.296
1903 -22910.1 -51953 0.00E+00 15.262 -1.57E+01
2000 -24420.6 -53395.4 0.00E+00 14.487 -1.54E+01
2100 -25949.8 -54806.4 0.00E+00 13.741 -1.52E+01
2200 -27452.7 -56145.2 0.00E+00 13.042 -1.49E+01
2300 -28931.2 -57416.2 0.00E+00 12.385 -1.47E+01
2400 -30387.4 -58623.4 0.00E+00 11.765 -1.45E+01
2500 -31823.1 -59770.3 0.00E+00 11.179 -1.43E+01
2600 -33240.2 -60860.2 0.00E+00 10.623 -1.41E+01
2700 -34640.1 -61895.9 0.00E+00 10.095 -1.39E+01
2800 -36024.4 -62880 0.00E+00 9.591 -1.38E+01
2876 -37066.8 -63594.9 0.00E+00 9.224 -1.37E+01
------ SnO2(l) CO(g) Sn(g) CO2(g) ------
Sn(1 mol): DH° = 295762.8 DG° = 0 ------ DS° = 102.838
2876 258696 -63594.9 2.36E+02 112.062 -1.57E+01
2900 258319.7 -66282.8 2.38E+02 111.932 -1.57E+01
3000 256759.9 -77449.4 2.46E+02 111.403 -1.55E+01
T

T
Keq T

6.10E-01
1.85E+00
3.36E+00
3.43E+00
3.43E+00
6.21E+00
9.44E+00
1.26E+01
1.55E+01
1.80E+01
2.01E+01
2.19E+01
2.33E+01
2.44E+01
2.53E+01
2.59E+01
2.63E+01
2.66E+01
2.67E+01
2.67E+01

2.67E+01
2.48E+01
2.31E+01
2.15E+01
2.01E+01
1.89E+01
1.77E+01
1.67E+01
1.58E+01
1.49E+01
1.43E+01

1.43E+01
1.56E+01
2.23E+01
Mn Manganese
T Cp H S G Reference
K J/(mol*K) kJ/mol J/(mol*K) kJ/mol 300 3000 1
300.000 26.347 0.049 32.383 -9.666 Nasa 93
400.000 28.526 2.798 40.276 -13.313 Nasa 93
500.000 30.292 5.741 46.836 -17.677 Nasa 93
600.000 31.898 8.851 52.502 -22.650 Nasa 93
700.000 33.427 12.118 57.535 -28.157 Nasa 93
800.000 34.916 15.535 62.096 -34.142 Nasa 93
900.000 36.383 19.100 66.293 -40.564 Nasa 93
1000.000 37.680 25.036 72.473 -47.437 Nasa 93
1100.000 38.123 28.827 76.085 -54.867 Nasa 93
1200.000 38.536 32.660 79.420 -62.645 Nasa 93
1300.000 38.948 36.534 82.521 -70.743 Nasa 93
1400.000 43.429 42.727 87.094 -79.205 Nasa 93
1500.000 45.972 49.141 91.553 -88.189 Nasa 93
1600.000 46.024 66.653 103.022 -98.182 Nasa 93, Landolt 99, Barin 77
1700.000 46.024 71.255 105.812 -108.625 Nasa 93, Landolt 99, Barin 77
1800.000 46.024 75.857 108.443 -119.339 Nasa 93, Landolt 99, Barin 77
1900.000 46.024 80.460 110.931 -130.309 Nasa 93, Landolt 99, Barin 77
2000.000 46.024 85.062 113.292 -141.521 Nasa 93, Landolt 99, Barin 77
2100.000 46.024 89.665 115.537 -152.964 Nasa 93, Landolt 99, Barin 77
2200.000 46.024 94.267 117.678 -164.625 Nasa 93, Landolt 99, Barin 77
2300.000 46.024 98.869 119.724 -176.496 Nasa 93, Landolt 99, Barin 77
2400.000 46.024 103.472 121.683 -188.567 Nasa 93, Landolt 99, Barin 77
2500.000 46.024 108.074 123.562 -200.830 Nasa 93, Landolt 99, Barin 77
2600.000 46.024 112.676 125.367 -213.277 Nasa 93, Landolt 99, Barin 77
2700.000 46.024 117.279 127.104 -225.901 Nasa 93, Landolt 99, Barin 77
2800.000 46.024 121.881 128.778 -238.696 Nasa 93, Landolt 99, Barin 77
2900.000 46.024 126.484 130.393 -251.655 Nasa 93, Landolt 99, Barin 77
3000.000 46.024 131.086 131.953 -264.772 Nasa 93, Landolt 99, Barin 77

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
Mn 54.938 100.000 1.000 54.938 7.394 ml
g/mol wt-% mol g l or ml
MnO2 Manganese(IV) oxide
T Cp H S G Reference
K J/(mol*K) kJ/mol J/(mol*K) kJ/mol
300.000 54.479 -521.999 53.385 -538.014 Barin 89, Knacke 91, Binnewies 02 300 3000 100
400.000 63.392 -516.049 70.441 -544.225 Barin 89, Knacke 91, Binnewies 02
500.000 68.065 -509.456 85.134 -552.023 Barin 89, Knacke 91, Binnewies 02
600.000 70.795 -502.501 97.806 -561.185 Barin 89
700.000 72.743 -495.320 108.872 -571.531 Barin 89
800.000 74.322 -487.965 118.691 -582.918 Barin 89
900.000 75.687 -480.463 127.526 -595.236 Barin 89
1000.000 76.918 -472.832 135.565 -608.396 Barin 89
1100.000 78.062 -465.082 142.950 -622.327 Barin 89
1200.000 79.146 -457.222 149.789 -636.968 Barin 89
1300.000 80.189 -449.254 156.165 -652.270 Barin 89
1400.000 81.202 -441.185 162.145 -668.188 Barin 89
1500.000 82.192 -433.015 167.782 -684.687 Barin 89
1600.000 83.165 -424.747 173.117 -701.734 Barin 89
1700.000 84.125 -416.382 178.188 -719.302 Barin 89
1800.000 85.074 -407.922 183.023 -737.364 Barin 89
1900.000 86.016 -399.368 187.648 -755.899 Barin 89
2000.000 86.951 -390.719 192.084 -774.888 Barin 89
2100.000 87.880 -381.978 196.349 -794.311 Barin 89
2200.000 88.805 -373.143 200.458 -814.152 Barin 89
2300.000 89.726 -364.217 204.426 -834.398 Barin 89
2400.000 90.644 -355.198 208.264 -855.033 Barin 89
2500.000 91.560 -346.088 211.983 -876.046 Barin 89
2600.000 92.474 -336.886 215.592 -897.426 Barin 89
2700.000 93.385 -327.593 219.099 -919.161 Barin 89
2800.000 94.295 -318.209 222.512 -941.243 Barin 89
2900.000 95.204 -308.734 225.837 -963.661 Barin 89
3000.000 96.111 -299.169 229.080 -986.407 Barin 89

MnO2 Extrapolated from 800.000 K

Formula FM Conc. Amount Amount Volume

 g/mol wt-% mol g l or ml
MnO2 86.937 100.000 1.000 86.937 17.114 ml
g/mol wt-% mol g l or ml

MnO2 + 2C = Mn + 2CO(g)
T deltaH deltaS deltaG K Log(K) 300 3000 100
K kJ J/K kJ
300.000 301.041 363.092 192.114 3.525E-034 -33.453
400.000 301.632 364.879 155.680 4.661E-021 -20.331
500.000 301.239 364.034 119.222 3.498E-013 -12.456
600.000 300.265 362.270 82.903 6.054E-008 -7.218
700.000 298.963 360.267 46.776 3.230E-004 -3.491
800.000 297.486 358.297 10.849 1.957E-001 -0.708
900.000 295.936 356.471 -24.888 2.784E+001 1.445
1000.000 296.580 357.076 -60.497 1.446E+003 3.160
1100.000 294.926 355.502 -96.125 3.673E+004 4.565
1200.000 293.183 353.985 -131.599 5.356E+005 5.729
1300.000 291.364 352.529 -166.924 5.101E+006 6.708
1400.000 291.754 352.803 -202.170 3.497E+007 7.544
1500.000 292.261 353.186 -237.519 1.870E+008 8.272
1600.000 303.763 360.777 -273.480 8.491E+008 8.929
1700.000 302.257 359.864 -309.512 3.243E+009 9.511
1800.000 300.651 358.947 -345.453 1.061E+010 10.026
1900.000 298.947 358.026 -381.302 3.045E+010 10.484
2000.000 297.142 357.100 -417.058 7.823E+010 10.893
2100.000 295.235 356.170 -452.721 1.827E+011 11.262
2200.000 293.224 355.235 -488.292 3.931E+011 11.594
 2300.000 291.110 354.295 -523.768 7.873E+011 11.896
2400.000 288.893 353.351 -559.150 1.481E+012 12.171
2500.000 286.574 352.405 -594.438 2.637E+012 12.421
2600.000 284.152 351.455 -629.631 4.472E+012 12.651
2700.000 281.628 350.503 -664.729 7.262E+012 12.861
2800.000 279.000 349.547 -699.732 1.134E+013 13.055
2900.000 276.268 348.589 -734.639 1.712E+013 13.233
3000.000 273.433 347.627 -769.449 2.503E+013 13.398

MnO2 Extrapolated from 800.000 K

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
MnO2 86.937 78.351 1.000 86.937 17.114 ml
C 12.011 21.649 2.000 24.022 10.629 ml
g/mol wt-% mol g l or ml
Mn 54.938 49.512 1.000 54.938 7.394 ml
CO(g) 28.010 50.488 2.000 56.021 44.827 l
 T(K) P(ATM) Activity X H (J) G (J) Vol (l) S (J/K) Cp (J/K)
300 3000 1
------ Mn(s1) ------
300.00 48.7 -9603.2 0.00E+00 32.173 26.347
400 2797.7 -13228.8 0.00E+00 40.066 28.525
500 5740.5 -17572.3 0.00E+00 46.626 30.292
600 8850.9 -22524.4 0.00E+00 52.292 31.898
700 12117.7 -28009.7 0.00E+00 57.325 33.428
800 15535.2 -33973.7 0.00E+00 61.886 34.917
900 19100.3 -40374.8 0.00E+00 66.083 36.383
980 22057.4 -45788.5 0.00E+00 69.231 37.544
------ Mn(s2) ------
Mn(1 mol): DH° = 2226.0 DG° = 0 ------ DS° = 2.271
980 24283.4 -45788.5 0.00E+00 71.502 37.588
1000 25036.1 -47226.2 0.00E+00 72.262 37.678
1100 28826 -54635.5 0.00E+00 75.874 38.116
1200 32658.8 -62391.8 0.00E+00 79.209 38.54
1300 36533.6 -70469.5 0.00E+00 82.31 38.953
1361 38917.3 -75545.5 0.00E+00 84.102 39.202
------ Mn(s3) ------
Mn(1 mol): DH° = 2122.0 DG° = 0 ------ DS° = 1.559
1361 41039.3 -75545.5 0.00E+00 85.661 43.097
1400 42726.4 -78910.2 0.00E+00 86.883 43.421
1412 43248.1 -79955 0.00E+00 87.254 43.521
------ Mn(s4) ------
Mn(1 mol): DH° = 1879.0 DG° = 0 ------ DS° = 1.331
1412 45127.1 -79955 0.00E+00 88.585 45.238
1500 49140.1 -87872.7 0.00E+00 91.342 45.966
1519 50014.9 -89613.7 0.00E+00 91.921 46.123
------ Mn(l) ------
Mn(1 mol): DH° = 12058.0 DG° = 0 ------ DS° = 7.939
1519 62072.9 -89613.7 0.00E+00 99.86 46.024
1600 65800.9 -97800 0.00E+00 102.251 46.024
1700 70403.3 -108166 0.00E+00 105.041 46.024
1800 75005.7 -118802.8 0.00E+00 107.671 46.024
1900 79608.1 -129695.5 0.00E+00 110.16 46.024
2000 84210.5 -140830.5 0.00E+00 112.52 46.024
2100 88812.9 -152195.8 0.00E+00 114.766 46.024
2200 93415.3 -163780.2 0.00E+00 116.907 46.024
2300 98017.7 -175574 0.00E+00 118.953 46.024
2335.97 99673.1 -179865.5 0.00E+00 119.667 46.024
------ Mn(g) ------
Mn(1 mol): DH° = 225985.1 DG° = 0 ------ DS° = 96.742
2335.97 325658.2 -179865.5 1.92E+02 216.409 20.875
2400 326997.6 -193740.5 1.97E+02 216.974 20.96
2500 329099.7 -215481.1 2.05E+02 217.832 21.082
2600 331214.2 -237306 2.13E+02 218.662 21.209
2700 333342.1 -259212.5 2.22E+02 219.465 21.352
2800 335485.6 -281198.1 2.30E+02 220.244 21.522
2900 337647.7 -303260.7 2.38E+02 221.003 21.727
3000 339832.3 -325398.1 2.46E+02 221.743 21.972

T(K) P(ATM) Activity X H (J) G (J) Vol (l) S (J/K) Cp (J/K)

300 3000 100
300 -518099.7 -534243.4 0.00E+00 53.812 54.291
400 -512225 -540487 0.00E+00 70.655 62.669
500 -505645.8 -548301.5 0.00E+00 85.311 68.616
600 -498549.4 -557491.7 0.00E+00 98.237 73.123
700 -491052.2 -567903.1 0.00E+00 109.787 76.694
800 -483232.1 -579412.1 0.00E+00 120.225 79.616
900 -475144.6 -591917.6 0.00E+00 129.748 82.066
1000 -466830.7 -605336.2 0.00E+00 138.505 84.16
1100 -458321.9 -619597.1 0.00E+00 146.614 85.976
1200 -449642.9 -634640.4 0.00E+00 154.165 87.571
1300 -440813.6 -650413.9 0.00E+00 161.231 88.988
1400 -431850.2 -666872.4 0.00E+00 167.873 90.257
1500 -422766.3 -683976 0.00E+00 174.14 91.402
1600 -413573.2 -701689.3 0.00E+00 180.073 92.443
1700 -404280.6 -719980.5 0.00E+00 185.706 93.395
1800 -394896.8 -738821.4 0.00E+00 191.069 94.269
1900 -385429 -758186.2 0.00E+00 196.188 95.076
2000 -375883.6 -778051.6 0.00E+00 201.084 95.824
2100 -366266 -798396.2 0.00E+00 205.776 96.52
2200 -356581.1 -819200.6 0.00E+00 210.282 97.169
2300 -346833.5 -840446.8 0.00E+00 214.615 97.778
2400 -337026.9 -862118.2 0.00E+00 218.788 98.349
2500 -327164.9 -884199.5 0.00E+00 222.814 98.886
2600 -317276.3 -906676.1 0.00E+00 226.692 98.886
2700 -307387.6 -929533.1 0.00E+00 230.424 98.886
2800 -297499 -952756.4 0.00E+00 234.02 98.886
2900 -287610.4 -976333 0.00E+00 237.491 98.886
3000 -277721.8 -1000250.6 0.00E+00 240.843 98.886
 Delta Delta
T(K) P(ATM) Activity X Delta H (J) Delta G (J) Delta Vol (l) S (J/K) Cp (J/K)
300 3000 100
------ MnO2(s) C(s1) Mn(s1) CO(g) ------
300.00 297170.6 188503.8 4.92E+01 362.223 1.32E+01
400 297843.9 152145.9 6.56E+01 364.245 8.44E-01
500 297460.1 115747.5 8.21E+01 363.425 -7.97E+00
600 296344.7 79499.8 9.85E+01 361.408 -1.39E+01
700 294736 43480.6 1.15E+02 358.936 -1.80E+01
800 292799.2 7716.1 1.31E+02 356.354 -2.06E+01
900 290650.4 -27792 1.48E+02 353.825 -2.23E+01
980 288835.4 -56020.1 1.61E+02 351.893 -2.31E+01
------ MnO2(s) C(s1) Mn(s2) CO(g) ------
Mn(1 mol): DH° = 2226.0 DG° = 0 ------ DS° = 2.272
980 291061.4 -56020.1 1.61E+02 354.165 -2.30E+01
1000 290597.7 -63098.7 1.64E+02 353.696 -2.34E+01
1100 288178.4 -98352.6 1.81E+02 351.392 -2.50E+01
1200 285615.9 -133379.6 1.97E+02 349.163 -2.62E+01
1300 282937.5 -168188 2.13E+02 347.02 -2.73E+01
1361 281255 -189317.5 2.23E+02 345.755 -2.79E+01
------ MnO2(s) C(s1) Mn(s3) CO(g) ------
Mn(1 mol): DH° = 2122.0 DG° = 0 ------ DS° = 1.559
1361 283377 -189317.5 2.23E+02 347.314 -2.40E+01
1400 282439.1 -202849.4 2.30E+02 346.635 -2.41E+01
 1412 282149.2 -207007.8 2.32E+02 346.428 -2.42E+01
------ MnO2(s) C(s1) Mn(s4) CO(g) ------
Mn(1 mol): DH° = 1879.0 DG° = 0 ------ DS° = 1.331
1412 284028.2 -207007.8 2.32E+02 347.759 -2.25E+01
1500 282036.8 -237550 2.46E+02 346.391 -2.28E+01
1519 281603.4 -244128.7 2.49E+02 346.104 -2.28E+01
------ MnO2(s) C(s1) Mn(l) CO(g) ------
Mn(1 mol): DH° = 12058.0 DG° = 0 ------ DS° = 7.938
1519 293661.4 -244128.7 2.49E+02 354.042 -2.29E+01
1600 291766.5 -272756.7 2.63E+02 352.827 -2.38E+01
1700 289329.2 -307965.4 2.79E+02 351.35 -2.49E+01
1800 286794.2 -343027.7 2.95E+02 349.901 -2.58E+01
1900 284171.9 -377946.6 3.12E+02 348.483 -2.66E+01
2000 281466.3 -412725.3 3.28E+02 347.096 -2.75E+01
2100 278681.1 -447366.7 3.45E+02 345.737 -2.82E+01
2200 275819.8 -481873.7 3.61E+02 344.406 -2.90E+01
2300 272885.8 -516248.9 3.77E+02 343.102 -2.97E+01
2335.97 271813.3 -528581.7 3.83E+02 342.639 -2.99E+01
------ MnO2(s) C(s1) Mn(g) CO(g) ------
Mn(1 mol): DH° = 225985.1 DG° = 0 ------ DS° = 96.742
2335.97 497798.4 -528581.7 5.75E+02 439.381 -5.51E+01
2400 494259.8 -556667.5 5.91E+02 437.886 -5.54E+01
2500 488689.2 -600341.9 6.15E+02 435.612 -5.60E+01
2600 483092.6 -643792.6 6.40E+02 433.417 -5.60E+01
2700 477497.1 -687028.1 6.65E+02 431.306 -5.59E+01
2800 471904.7 -730056.4 6.89E+02 429.272 -5.59E+01
2900 466318.1 -772884.9 7.14E+02 427.311 -5.58E+01
3000 460741 -815521 7.39E+02 425.421 -5.57E+01
T
 T

T
T
T
T
T
Keq T

1.51E-33
1.36E-20
8.10E-13
1.20E-07
5.70E-04
3.13E-01
4.10E+01
9.68E+02

9.68E+02
1.98E+03
4.68E+04
6.39E+05
5.72E+06
1.84E+07

1.84E+07
3.70E+07
4.55E+07

4.55E+07
1.87E+08
2.48E+08

2.48E+08
8.02E+08
2.90E+09
9.00E+09
2.46E+10
6.01E+10
1.34E+11
2.76E+11
5.30E+11
6.60E+11

6.60E+11
1.30E+12
3.49E+12
8.58E+12 T
1.95E+13 T
4.16E+13 T
8.33E+13 T
1.58E+14 T