Final Revision – JEE (Main)

Subjective:

1. How is anhydrous magnesium chloride prepared from magnesium chloride hexahydrate?

2. Explain why halides of Be dissolve in organic solvents while those of Ba do not.

3. Why potassium can not be obtained by the electrolysis of fused potassium chloride?

4. Explain why halides of beryllium fume in moist air but other alkaline earth metals halides
do not.
5. A piece of burning magnesium ribbon continuous to burn in sulphur dioxide. Explain.
6. Explain
(a) Be does not react with water or steam.
(b) Mg does not react readily with water.
7. Blue colour of the solution of alkali metals in liquid ammonia fades on standing why?

8. Explain
(a) The hydroxides of alkaline earth metals are weaker bases than their corresponding
alkali metals.
(b) Ca, Br, Sr are stored in paraffin but Be & Mg are not?
9. Account for the following
(a) Be  OH 2 is insoluble but Ba  OH 2 is fairly soluble in water.
(b) Be  OH 2 is amphoteric while Mg  OH2 is basic.

10. Give reasons for following

(i) concentrated HNO3 turns yellow in sun light
(ii) A bottle of liquor ammonia should be cooled before opening
(iii) Nitrous oxide supports combustion more vigorously than air
(iv) NF3 is not hydrolysed but NCl3 is readily hydrolysed
(v) Red phosphorus is densor and chemically less reactive than yellow phosphorus
(vi) N2 is diatomic while phosphrus molecule is tetraatomic
(vii) PCl5 is ionic in solid state and conducts current in fused state
(viii)Orthophosphorus acid is diabsic while orthophosphoric acid is tribasic

11. What happens when?

(a) Phosphene is reacted with acidified cupric sulphate solution.
(b) Silver nitrate solution is treated with phosphene.
(c) Mercuric chloride solution is treated with phosphorous acid.

12. What happens when?

(a) Phosphorus acid is treated with an aqueous solution of silver nitrate.
(b) Carbon dioxide is passed through a concentrated aqueous solution of sodium
chloride saturated with ammonia.
(c) Methyl chloride is passed over silicon in the presence of copper catalyst at 275
375°C.
13. On the basis of the following reactions, identify A, B, C and D.

Rankers | Exclusively for IIT JEE | www.myrankers.com

 (A)aq  Al 
heat
(B)gas
(A)aq  (C) 
heat
 PH3
(A)aq  NH4 
heat
(D)gas

14. Explain the following

(i) Iodine dissolves more in KI solution, than impure water
(ii) KHF2 is well known, where as KHCl2 or KHBr2 does not exist
(iii) A mixture of He and O2 is used for respiration for deep see divers

15. What happens when?

(i) Sulphur is boiled with caustic soda solution.
(ii) Sulphur dioxide is bubbled through aqueous solution of copper sulphate in presence
of potassium thiocyanate.

16. 20 ml of a solution containing 0.2 g of impure sample of H2O2 reacts with 0.316 g of
KMnO4 (acidic). Calculate
(a) Purity of H2O2 .

(b) Volume of dry O2 evolved at 0 C and 750 mm P.

17. What happens when?

(i) Chromium hydroxide is treated with hydrogen peroxide in the presence of NaOH.
(ii) Hydrazinc reacts with hydrogen peroxide.
(iii) Hydrogen peroxide reacts with Ba  OH2 .
(iv) Sodium hypochlorite reacts with H2O2 .

In the reaction H2+I2  2HI the rate of disappearance of I2 is found to be 10 mole per
-6
18.
litre per second. What would be the corresponding rate of appearance of HI?

19. Rate of reaction A + B  product is given as a function of different initial concentration

of A and B Determine the order of reaction with respect to A and with respect to B. What
is the value of rate constant?
A (B) Initial rate
-1 -1 -1 -1
(mole L ) (mole L ) (mole L min )
0.01 0.01 0.005
0.02 0.01 0.010
0.01 0.02 0.005

Following equilibrium is setup when SCN ion is added to Fe

3+
20. in aqueous solution
Fe  SCN 
3  2
Fe  SCN 
Pale yellow Colourless
Deep red

When silver nitrate is added to the solution, AgCN gets precipitated. What will happen to
the equilibrium?

21. Which of the following reactions will get affected by increase in pressure? Also mention
whether the change will cause the reaction to go to the right or left direction.
(i) CH4  g  2S2  g  CS2  g  2H2S  g (ii) CO2  g  C  s   2CO  g
(iii) 4NH3  g  5O2  g  4NO  g  6H2O  g (iv) C2H4  g  H2  g  C2H6  g

22. Given these equilibrium constants at 25°C

Rankers | Exclusively for IIT JEE | www.myrankers.com

 2– 2–
S+S S2 K1 = 1.7
2– 2–
S + S2 S3 K2 = 3.1
2– 2–
Calculate K for 2S + S S3 at 25°C

23. At 540 K, 0.10 mole of PCl5are heated in a 8.0 L flask. The pressure of the equilibrium
mixture is found to be 1.0 atm. Calculate Kp and KC for the reaction.

24. In the reaction C(s) + CO2(g)  CO2(g) the equilibrium pressure is 12 atm. If 50% of CO 2
reacts calculate Kp.

25. Ammonium carbamate dissociates as: NH2COONH4 (s)  2NH3 (g) + CO2 (g)
In a closed vessel containing ammonium carbamate in equilibrium with its vapour
ammonia is added such that the partial pressure of ammonia now equals to the original
total pressure. Calculate the ratio of the total pressure now to the total pressure of the
original mixture.
1
26. Calculate the equilibrium constant for reaction NO2    N2  O2 , if equilibrium
2
constant is 100 atm for equilibrium N2  2O2    2NO2 , at constant temperature
-1
  

27.    CaO s  CO2g Kp  1.16atm at 8000 C . If

For the reaction CaCO3 s  20.0 g of
0
CaCO3 were kept in a 10 lit container and heated up to 800 C , what percentage of
CaCO3 would remain unreacted at equilibrium.

28. N2O4 is 20% dissociated at 27C and 1 atm pressure. Calculate (i) Kp and (ii) the
percentage dissociation at 0.2 atm and 27C

29. When 0.10 mole of NH3 is dissolved in water to make 1.0 L solution, the solution is found
to have OH   1.34  103 M . Calculate Kb for NH3.
-6
30. An acid - base indicator, HIn(KIn= 10 ) displays the colour of its acid form only when it is
ionised to a maximum of 9.09%, while it displays its basic colour when it is ionised to the
extent of at least 95.24%. What is the pH - range of the indicator?
2+ 2+
31. When a solution containing Ca and Mg ions is at first saturated with NH 4Cl(s) and then
2+
treated with (NH4)2CO3, only Ca is precipitated as carbonate. Explain.

32. A weak acid type indicator was found to be 40% dissociated at pH = 9.1249. What be %
dissociation at pH = 9?

33. Calculate pH of 108 M HCl.

34. A buffer of pH 9.26 is made by dissolving x mole of ammonium sulphate and 0.1 mole of
ammonia into 100 mL solution. If pKb of ammonia is 4.74, calculate value of x.
+
35. Calculate [H ] in
(a) 0.01 M C6H5COOH solution and
(b) 0.01 M C6H5COOH in 0.01 M C6H5COONa; K a  C6H5COOH  6.5  105

36. Predict the direction of the following in aqueous solution:

HNO2  aq  CN  aq    HCN  aq  NO2 aq
K a HNO2   4.5  104 ,K a HCN  4.9  1010

Rankers | Exclusively for IIT JEE | www.myrankers.com

37. Calculate the pH at the equivalence point when a solution of 0.01 M CH 3COOH is titrated
with a solution of 0.01 M NaOH, pKa of CH3COOH is 4.74.

38. It is found that 0.1 M solution of three sodium salts NaX, NaY and NaZ have pH 7.0, 9.0
and 11.0 respectively. Arrange the acids HX, HY and HZ in order of increasing strength.
Where possible, calculate ionization constant of acids. 32. Concentration of HCN
and NaCN in a solution is 0.01 M each. Calculate H3O  and [OH]
K a HCN  7.2  1010

39. Concentration of HCN and NaCN in a solution is 0.01 M each. Calculate H3O  and
[OH] K a HCN  7.2  1010

40. Determine degree of dissociation of 0.05 M NH3 at 25C in solution of pH = 11.

IIT Level Questions

41. Explain the following

(a) Alkali metals are obtained by the electrolysis of the molten salts and not by the
electrolysis of their aqueous solutions.
(b) On exposure to air, sodium hydroxide becomes liquid and after sometimes it changes
to white powder.
(c) An aqueous solution of iodine becomes colourless on adding excess of sodium
hydroxide solution.

42. To a 25 ml H2O2 solution excess of acidify solution of potassium iodide was added. The
iodine liberated required 20 ml of 0.3 sodium thiosulphate solution. Calculate the volume
strength of H2O2 solution.
o
43. In a mixture of N2 and H2 initially in a mole ratio of 1:3 at 30 atm and 300 C, the
percentage of ammonia by volume under equilibrium is 17.8. Calculate the equilibrium
constant (KP) of the mixture, for the reaction, N2(g) + 3H2(g) 2NH3(g)

44. An equilibrium mixture at 300 K contains N2O4 and NO2 at 0.28 and 1.1 atm respectively.
If the volume of container is doubled, calculate the new equilibrium pressures of the two
gases.

45. The value of Kc for the reaction N2  g  3H2  g    2NH3  g is 0.50 at 400C. Find the
value of Kp at 400C when concentrations are expressed in mol 1 and pressure in
atmosphere.

46. Given N2  g  3H2  g    2NH3  g ; K1

N2  g  O2  g    2NO  g ; K 2
1
H2  g  O2  g    H2O  g ; K 3
2
5
The equilibrium constant for 2NH3  g  O2  g    2NO  g  3H2O  g will be.
2
47. 0.10 mol sample of AgNO3 is dissolved in 1.00 L of 1.00 M NH3. If 0.010 mol NaCl is
added to this solution, will AgCl(s) precipitate?
K sp  AgCl  1.8  1010 , K f  Ag NH3 2   1.6  107


 

Rankers | Exclusively for IIT JEE | www.myrankers.com

48. 30 ml solution of a weak monobasic acid requires 60 ml 0.25 M NaOH for the end point.
During titration the pH of the acid solution upon addition of 20 ml alkali (0.25M) was 4.6.
Calculate pH of the acid solution at the following two stages
(a) Before addition of any drop of alkali
(b) At the equivalence point, the contents of the conical flask having been diluted to
150 ml by the addition of distilled water (log 2=0.30) and pKw = 14)

49. A solution of volume V contains ‘a’ mole of MCl and ‘b’ mole of NCl where MOH and
NOH are two weak bases having dissociation constants K1, K2 respectively. Show that
1 K K V 
the pH of the solution can be expressed as pH = log10  1 2  
2  K W aK 2  bK1 

50. 0.025 moles of a hydrochloride salt of – amino acid (NH2 – CH2 – COOH) was dissolved
in 250 ml of water and the pH of the solution was 2.7. Same moles of sodium salt of this
acid is added to 250 ml water and the pH of solution now is 11, Calculate the pH of 
amino acid at which isoelectric point will occur.

Rankers | Exclusively for IIT JEE | www.myrankers.com

Objective:

Multiple choice questions with single correct options

1. When a substance (A) reacts with water, it produces a combustible gas (B) and a solution
of substance (C) in water. When another substance (D) reacts with the solution of (C), it
produces the same gas (B) on warming, but (D) can produce (B) on reaction with dilute
H2SO4 at room temperature. (A) imparts a golden yellow colour to brown flame. (A), (B),
(C) and (D) could be?
(A) K, H2, KOH, Al (B) Na, H2, NaOH, Zn
(C) CaC2, C2H2, Ca(OH)2, Fe (D) Ca, H2, Ca(OH)2, Sn

2+
2. If NaOH is added to an aqueous solution on Zn ions, a white ppt. appears and on
adding excess NaOH, the ppt. dissolves. In this solution zinc exist in the
(A) cationic part (B) anionic part
(C) both in cationic and anionic parts (D) there is no zinc left in the solution

3. Acidified solution of sodium thiosulphate is reactive because in thiosulphate

(A) the sulphur atoms are at unstable oxidation state of +2.
(B) the two sulphur atoms are at different oxidation states of +6 and – 2.
(C) the S – S bonds are less stable bonds.
(D) sulphur is in zero oxidation state.

4. When hydrated MgCl2.6H2O is strongly heated?

(A) MgO is formed (B) Mg(OH)2 is formed
(C) Mg(OH)Cl is formed (D) Anhydrous MgCl2 is formed

5. A metal (X) on heating in nitrogen gas gives (Y). (Y) on treatment with H 2O gives a
colourless gas which when passed through CuSO4 solution gives a blue colour .(Y) is
(A) Mg(NO3)2 (B) Mg3N2
(C) NH3 (D) MgO

6. Phosphorus when dissolved in alkali forms

(A) PH3 + NaH2PO2 (B) PH3 + Na3PO3
(C) P2H4 + NaH2PO2 (D) Both (A) and (C)

7. Match list – I with list – II and select the correct answer using the codes given below
List – I List – II
(a) Liquid Na metal 1. Breathing apparatus in submarine
(b) Potassium stearate 2. Explosive
(c) KNO3 3. Coolant in nuclear reactors
(d) KO2 4. Soft soap
Codes
a b c d
(A) 3 4 1 2
(B) 3 1 4 2
(C) 3 4 2 1
(D) 4 3 2 1

8. Which of the following is correct about the reaction, 3NaClO 

NaClO3  2NaCl ?
(A) It is a disproportionation.
(B) Oxidation number of Cl decreases as well as increases in this reaction.
(C) This reaction is used for the manufacture of halates.
(D) All of the above

Rankers | Exclusively for IIT JEE | www.myrankers.com

9. A greenish yellow gas reacts with an alkali metal hydroxide to form a halate, which can
be used in fire works and safety matches. The gas and halate respectively, are
(A) Br2, KBrO3 (B) Cl2, KCIO3
(C) I2, NaIO3 (D) Cl2, NaCIO3

10. Sodium nitrate decomposes above ~800C to give

(A) N2 (B) O2
(C) Na2O (D) All of the above
2 2
11. Which reagent would enable you to remove SO4 ion from solution containing both SO4
and Cl ions?
2+
(A) NaOH (B) Pb
(C) Ba(OH)2 (D) BaSO4
12. The main factor responsible for weak acidic nature of B – F bonds in BF3 is
(A) large electronegativity of fluorine
(B) three centred two electron bonds in BF3
(C) p-d back bonding
(D) p- p back bonding

13. Borax crystal contains

(A) Two triangular units (B) Two tetrahedral units
(C) (A) and (B) both (D) None of these

14. Borax is converted into B by steps


Borax  I
 H3BO3  B2O3 
II
B
I and II reagents are
(A) acid, Al (B) acid, C
(C) acid, Fe (D) acid, Mg
15. On strong heating lead nitrate gives
(A) PbO, NO, O2 (B) PbO, NO, NO 2
(C) PbO 2 , PbO, NO 2 (D) PbO, NO 2 , O 2

16. Hypo is used in photography because of its

(A) Reducing nature (B) Oxidising nature
(C) Complexing nature (D) Sensitivity towards light

17. Disodium hydrogen phosphate in presence of NH4Cl and NH4OH gives a white ppt. with a
2+
solution of Mg ions. The precipitate is
(A) Mg(H2PO4)2 (B) Mg3(PO4)2
(C) MgNH4PO4 (D) MgHPO4
18. Commercial 10 volume H2O2 is a solution with a strength of approximately
(A) 30% (B) 3%
(C) 1% (D) 10%
19. Hydrogen peroxide when added to a solution of KMnO 4 acidified with H2SO4
(A) forms water only (B) acts as an oxidizing agent
(C) acts as a reducing agent (D) reduces H2SO4

20. In basic medium, H2O2 acts as an oxidizing agent in its reaction with
(A) Cr2(SO4)3 (B) Ag2O
(C) K3[Fe(CN)6] (D) K2Cr2O7

21. The reaction H2 S  H2 O2  S  2H2 O , shows

Rankers | Exclusively for IIT JEE | www.myrankers.com

 (A) acidic nature of H2O2 (B) alkaline nature of H2O2
(C) reducing action of H2O2 (D) oxidizing action of H2O2
22. For the reaction: CO2(g) + H2(g) CO(g) + H2O(g)
The Kp for the reaction is 0.11. If the reaction was started with 0.45 moles of CO 2 and
0.45 moles of H2 at 700K, the concentration of CO when 0.34 mole of CO2 and 0.34 mole
of H2 are added when the first equilibrium is attained, is
(A) 0.52M (B) 0.17M
(C) 0.34M (D) 0.26M
23. For the given reaction:
2A(s) + B(g) C(g) + 2D(s)+ E(s)
the degree of dissociation of B was found to be 20% at 300K and 24% at 500K the rate of
backward reaction
(A) increases with increase in pressure and temperature
(B) increases with increase in pressure and decrease in temperature
(C) depends on temperature only and decreases with increase in temperature
(D) increases with increasing the concentration of B and increasing the temperature
24. For the given equilibrium
L(g) M(g)
–4
The Kf = 5  10 mole/litre/seconds
–2
and Kb = 3  10 litre/mole/seconds
the equilibrium concentration of M is
(A) 0.13M (B) 0.3M
(C) 0.8M (D) Can’t be calculated
25. For the following reaction
A 2  g  4B2  g 
   2AB4  g, H < 0. On increasing the temperature at constant
pressure, which of the following effect will be observed? (K = equilibrium constant)
(A) K will decrease
(B) K will increase
(C) the degree of dissociation () of A2(g) & B2 (g) will increase.
(D) none of these
26. AB2 dissolves as
   AB(g)  B(g)
AB2(g) 
When the initial pressure of AB2 is 500 mm Hg, the total pressure is 700 mm Hg.
Calculate equilibrium constant Kp for the reaction, assuming that the volume of the
system remains unchanged.
(A) 100 mmHg (B) 133.3 mm Hg
(C) 200 mm Hg (D) 214.6 mm Hg
27. For this reaction at equilibrium, which changes will increase the quantity of Fe(s)?
Fe3O4(s) + 4 H2(g) 3 Fe(s) + 4 H2O(g) H > 0
1. increasing temperature
2. decreasing temperature
3. adding Fe(s)
(A) 1 only (B) 1 and 2 only
(C) 2 and 3 only (D) 1,2, and 3
28. One mole each of CH3 CO 2H and CH3 CH2 OH are heated in presence of little conc.
H2 SO 4 so as to establish the following equilibrium
CH3 CO2H  CH3 CH2OH    CH3CO2CH2CH3  H2O
The moles of CH3 CO2 CH2 CH3 formed at equilibrium is
(A) 1 mol (B) 2 mol

Rankers | Exclusively for IIT JEE | www.myrankers.com

 1 2
(C) mol (D) mol
2 3
29. 24 mL of HI are produced from the reaction of 15 mL of H2 and 17.1 mL of I2 vapour at
4 44C . The equilibrium constant for the reaction: H2  I2    2HI at 444C is
(A) 27.5 (B) 37.647
(C) 73.647 (D) 57.25
30. The vessel has nitrogen gas and water vapours at a total pressure of 1 atm. The partial
pressure of water vapours is 0.3 atm. The content of this vessel are transferred to
another vessel having one third of original volume, completely at the same temperature,
the total pressure of the system in the new vessel is
(A) 3.0 atm (B) 1 atm
(C) 3.33 atm (D) 2.4 atm
31. A gaseous mixture of 2 moles of A, 3 moles of B, 5 moles of C and 10 moles of D is
contained in a vessel. Assuming that gases are ideal and the partial pressure of C is 1.5
atm the total pressure is
(A) 3 atm (B) 6 atm
(C) 9 atm (D) 15 atm
32. The rate of a reaction does not involve gases is not dependent on
(A) pressure (B) temperature
(C) concentration (D) catalyst

33. A reversible reaction is one which

(A) proceeds in one direction (B) proceeds in both directions
(C) proceeds spontaneously (D) all the statements are wrong

34. The law of mass action was proposed by

(A) Goldberg and Waage (B) Le chatelier and Braun
(C) Kossel and Lewis (D) Van’t Hoff
35. The rate at which a substance reacts, depend on its
(A) active mass (B) molecular mass
(C) equivalent mass (D) total volume

36. The state of equilibrium refers to

(A) state of rest (B) dynamic state
(C) stationary state (D) state inertness

37. A buffer solution contains 100 mL of 0.01 M CH3COOH and 200 mL of 0.02 M
CH3COONa. 700 ml water is added. pH before and after dilution are: (pKa = 4.74)
(A) 5.04, 5.04 (B) 5.04, 0.504
(C) 5.04, 1.54 (D) 5.34, 5.34
38. H2O  H3PO4  H3O  H2PO4 pK1  2.15
  2
H2O  H2PO  H3O  HPO
4 pK 2  7.20
4
Hence pH of 0.01 M NaH2PO4 is
(A) 9.35 (B) 4.675
(C) 2.675 (D) 7.350
O COCH 3

COOH
39.
(Aspirin) is a pain reliever with pKa = 2.

Rankers | Exclusively for IIT JEE | www.myrankers.com

 Two tablets each containing 0.09 g of asprin are dissolved in 100 mL solution. pH will be
(A) 0.5 (B) 1.0
(C) 0.0 (D) 2.0
40. Molarity of the liquid HCl if density of the solution is 1.176 g/cc is
(A) 36.5 (B) 18.25
(C) 32.05 (D) 42.10

41. A monoprotic acid in 1.00 M solution is 0.001% ionized. The dissociation constant of
formic acid is
(A) 1.0  103 (B) 1.0  106
8
(C) 1.0  10 (D) 1.0  1010

42. Formic acid is 4.5% dissociated in 0.1 N solution at 20C. The ionization constant of
formic acid is
(A) 21  104 (B) 21
(C) 0.21  104 (D) 2.1  104

43. What is the correct representation of solubility product of Ag2CrO4?

2
(A)  Ag  CrO24  (B)  Ag  CrO24 
2 2
(C) 2Ag  CrO24  (D) 2Ag  CrO24 

44. The precipitate of CaF2 (Ksp = 1.7  1010) is obtained when equal volumes of which of
the following are mixed?
(A) 104 M Ca + 104 M F (B) 102 M Ca + 103 M F
2+ 2+

2 5 
(D) 10 M Ca + 105 M F
3
2+ 2+
(C) 10 M Ca + 10 M F

45. Buffering action of a mixture of CH3COOH and CH3COONa is maximum when the ratio of
salt to acid is equal to
(A) 1.0 (B) 100.0
(C) 10.0 (D) 0.1

Multiple choice questions with more than one option correct

46. Which of the following illustrate/s the anomalous properties of Li?

(A) The m. pt. and b. pt of Li are comparatively high.
(B) Li forms a nitride Li3N unlike group metals.
(C) Li is much softer than the other group I metals.
+
(D) Li ion and its compounds are more heavily hydrated than those of the rest of the
group.

47. For two ionic solids CaO and KI, identify the correct statement/s among the following:
(A) Lattice energy of CaO is much higher than that of KI.
(B) KI is soluble in benzene.
(C) CaO has high m. pt.
(D) KI has high m. pt.

48. Boron readily dissolves in

(A) conc. HCl

Rankers | Exclusively for IIT JEE | www.myrankers.com

 (B) fused NaOH at 673 K
(C) fused Na2CO3 + NaNO3 at 1173 K
(D) a mixture of conc. HNO3 and conc. H2SO4 (1 : 2)
49. Which metal can be obtained from electrolysis?
(A) Ca (B) Mg
(C) Cr (D) Al

A reaction is catalysed by H ion. In presence of HA, rate constant is 2  103 min1 and
+
50.
in presence of HB rate constant is 1  103 min1, HA and HB both being strong acids, we
may conclude
(A) equilibrium constant is 2
(B) HA is stronger than HB
(C) relative strength of HA and HB is 2
(D) HA is weaker than HB and relative strength is 0.5
51. Which of the following statement(s) is(are) wrong?
(A) at equilibrium concentration of reactant and product become constant because the
reaction stops
(B) addition of catalyst speeds up the forward reaction more than the backward reaction
(C) equilibrium constant of an exothermic reaction decreases with increase of
temperature
(D) Kp is always greater than Kc

52. Which of the following will not affect the value of equilibrium constant of a reaction?
(A) change in concentration of the reactants (B) change in temperature
(C) change in pressure (D) addition of catalyst

1
53. The equilibrium constant of the reaction SO2  O2  SO3 and 2SO2  O2  2SO3 are
2
K1 and K2 respectively. The relationship between K1 and K2 is
(A) K1 = K2 (B) K 2  K12
(C) K1  K 2 (D) K 2  K1

54. For which of the following reactions is the equilibrium constant called an acidity constant?
(A) 2H2O    H3 O  OH

(B) H2S  H2O    H3O  HS

(C) HONO  H2O    ONO  H3O

(D) H3O  CH3NH2    CH3NH3  H2O

55. For the reaction CaCO3  s  

 CaO  s   CO2  g which is correct representation?


(A) K p  PCO2  (B) K p  K c RT 
(C) K c  CO2 (D) none of these

1 1
56. N2O2    2NO, K1; N2  O2    2NO, K 2 ;
2 2
1 1
2NO    N2  O2 , K 3 ; NO    N2  O2 , K 4 ;
2 2
Correct relation (s) between K1, K2, K3 and K4 is/are

Rankers | Exclusively for IIT JEE | www.myrankers.com

 (A) K1  K3 = 1 (B) K1  K 4  1
(C) K3  K2  1 (D) none of these

57. For the reaction, PCl5  g    PCl3  g  Cl2  g the forward reaction at constant
temperature is favoured by
(A) introducing an inert gas at constant volume
(B) introducing chlorine gas at constant volume
(C) introducing an inert gas at constant pressure
(D) introducing the volume of the container
(E) introducing PCl5 at constant volume

58. Which of the following will favour the formation of NH3 by Haber’s process?
(A) increase temperature (B) increase of pressure
(C) addition of catalyst (D) addition of promoter
59. Which of the following will not affect the volume of equilibrium constant of a reaction?
(A) change in the concentration of the reactants
(B) change in temperature
(C) change in pressure
(D) addition of catalyst
60. For the gas phase reaction,
C2H4  H2    C2H6 , H  136.8kJmol1
Carried out in a reaction vessel, the equilibrium concentration of C 2H4 can be increased
by
(A) increasing the temperature (B) decreasing the pressure
(C) removing some H2 (D) adding some C2H6
61. When NaNO3 is heated in a closed vessel oxygen is liberated and NaNO 2 is left behind.
At equilibrium which are not correct?
(A) Addition of NaNO2 favours reverse reaction
(B) Addition of NaNO3 favours forward reaction
(C) Increasing temperature favours forward reaction
(D) Increasing pressure favours reverse reaction
62. Zn  2H  Zn2  H2
Half life period is independent of concentration of Zn at constant pH. For the constant
concentration of Zn, rate becomes 100 times when pH is decreased from 3 to 2. Hence
dx
 k  Zn H 
 2
(A)
dt
dx
 k  Zn H 
2
(B)
dt
+
(C) rate is not affected if concentration of Zn is made four times and that of [H ] ion is
halved
+
(D) rate becomes four times if concentration of [H ] ion is doubled at constant Zn
concentration
63. All of the following are acid-base conjugate pairs.
(A) HONO, NO2 (B) H3O , OH
+

(C) CH3NH3 , CH3NH2 (D) HS, S

2

64. In the following reaction

 3 2 2
Cu H2O3  OH   Al H2O 6   Cu H2O 4    Al H2O 5 OH
A B   C D

Rankers | Exclusively for IIT JEE | www.myrankers.com

 (A) A is an acid and B the base
(B) A is a base and B the acid
(C) C is the conjugate acid of A, and D is the conjugate base of B
(D) C is conjugate base of A, and D is the conjugate acid of B
65. Which does not react with NaOH or which is not acid salt?
(A) NaH2PO2 (B) Na2HPO3
(C) Na2HPO4 (D) NaHCO3

66. An acid-base indicator has a Ka of 3.0  105. The acid form of the indicator is red and the
basic form is blue. Then
(A) pH is 4.05 when indicator is 75% red
(B) pH is 5.00 when indicator is 75% blue
(C) pH is 5.00 when indicator is 75% red
(D) pH is 4.05 when indicator is 75% blue

67. pH of the following solution is not affected by dilution

(A) 0.01 M CH3COONa
(B) 0.01 M NaHCO3
(C) buffer of 0.01 M CH3COONa and 0.01 M CH3COOH
(D) 0.01 M CH3COONH4
68. The term infinite dilution refers for
(A)   1for weak electrolytes
(B) an electrolyte is 100 % dissociated
(C) all interionic effects disappear
(D) when equivalent conductance of an electrolyte becomes constant
Comprehension - I

Read the paragraph carefully and answer the following questions:

Hydrogen bromide gas is one of the strongest acids available in gas form. In aqueous solution,
HBr has pKa value of approximately 12. A pKa value of 12 is indicative of a very strong acid.
By comparison, HCl has a pKa of approximately 9. Hydrobromic acid (HBr) can be produced by
reaction 1.
H2(g) + Br2(l)  2HBr(g) …Reaction 1
A student decides to study the equilibrium distribution for Reaction 1. Under ambient conditions,
Reaction 1 Reaction reaches equilibrium at some temperature T and pressure P. Once at
equilibrium, measurements are taken for the partial pressure of each gas and the mass of
bromine liquid. The values are listed in Table
Br2(l) 10.0 grams
H2(g) 1.36 atm
HBr(g) 2.72 atm
The student takes notice that Reaction 1 shifts with changes in the conditions of the system, such
as the addition of bromine liquid, the removal of hydrobromic acid, and increases in volume. The
student irreversibly increases the volume of the system by opening a valve on the reaction flask
that is connected to an evacuated column. Not all changes shift the reaction. Changes in the
equilibrium concentrations are not accurately recorded.
69. Evaluate the value of equilibrium constant K at ambient temperature & pressure as per
data shown in table for Reaction – 1

70. Addition of which of the either reactant or products to the equilibrium mixture will NOT
affect the partial pressure of H2(g)?

Rankers | Exclusively for IIT JEE | www.myrankers.com

71. If we put the HBr(g), H2(g) over bromine liquid having partial pressure 3 atm., 1.5 atm.
respectively in a closed container the gas whose pressure increases after attaining the
equilibrium is ………….

72. If there is an increase in mole percent of HBr(g) after increasing the temperature of the
above reaction is ……………… in nature.
Comprehension-II

Read the paragraph carefully and answer the following questions:

Consider an ionic solid that dissolves in water according to the equation:
Mn Xm (s)    nMm  (aq)  mXn  (aq)
m+ n n– m
The equilibrium constant for this reaction, Ksp = [M ] [X ] is known as the solubility product of
MnXm. The form of this equilibrium is important in understanding effects such as the influence of
pH, complex formation and common ion effect. Equilibrium constants in solution should be written
correctly using activities and not concentrations. The difference between these quantities is large
in concentrated ionic solutions and Ksp is quantitatively reliable as a guide of solubilities only for
–-10 o
very dilute solutions, if solubility product of AB type salt is 4 x 10 at 18 C.

73. If mol. wt. of AB is 143.5 g mol., then solubility in g/lit of AB is

-3
(A) 14.35 gm/lit (B) 2.87 x 10 gm/lit
(C) 1.43 gm/lit (D) 28.7 gm/lit
74. If ppt. of AB is washed with 5 lit water, loss in wt. of ppt. of AB is
–4 –4
(A) 10 mol/lit (B) 10 gm/mol
–4 –4
(C) 10 mol (D) 10 gm
75. The % error in washing of 2 mol of ppt. of AB with 100 cc of N/100 solution of BC2 is
–7 –2
(A) 4 x 10 % (B) 4 x 10 %
–3 –5
(C) 14 x 10 % (D) 2 x 10 %
o
76. The solubility of Calomel in water at 25 C is s moles/lit. Its solubility product is
3 3
(A) 4s (B) 12s
5 2
(C) 10s (D) s
77. The ionic product of water changes when
(A) an acid is added to water (B) a base is added to water
(C) an acid or a base is added to water (D) temperature is changed
Comprehension-III

Read the paragraph carefully and answer the following questions:

Aqueous calcium chloride solution is mixed with sodium oxalate and precipitate of calcium
oxalate formed filtered and dried. Its saturated solutions was prepared and 250 mL of this solution
was titrated with 0.001 M KmNO4 solution, when 6.0 mL of this was required.
78. Which is the indicator in the above titration?
(A) Methyl orange (B) Phenolphthalein
(C) Sulphuric acid (D) KMnO4 itself
79. Number of moles of KMnO4 required in this titration is
(A) 6  103 (B) 6  106
(C) 250 (D) 2.5  101
80. Number of moles of oxalate present in given saturated solution of calcium oxalate is
(A) 6  106 (B) 3  106
6
(C) 1.5  10 (D) 1.5  105
81. Equivalent of KMnO4 required in the titration is

Rankers | Exclusively for IIT JEE | www.myrankers.com

 (A) 3  105 (B) 3  106
(C) 1.2  105 (D) 1.8  105
82. Solubility product of calcium oxalate is
(A) 2.25  1010 (B) 4.0  109
(C) 2.25  1012 (D) 3.6  109
Comprehension – IV
Hydrogen peroxide was discovered by Thenard in 1818. Its molecular formula is H2O2. It is also
called as oxygenated water.
Strength of H2O2 solution is expressed either as percentage or as volume strength. By percent
strength we mean the amount of H2O2 by weight in 100 ml of the solution. By volume strength we
mean the volume of O2 (in litres) at NTP obtained by decomposition of 1  of the sample.
Now answer the following questions.

83. The oxide that gives hydrogen peroxide on treatment with dilute acid is
(A) PbO2 (B) Na2O2
(C) MnO2 (D) TiO2
.
84. 0.2 g sample of H2O2 required 10 ml of N KMnO4 in a titration in the presence of H2SO4
The purity of H2O2 is
(A) 25% (B) 65%
(C) 85% (D) 95%

85. The value strength of 1.5 N H2O2 solution is

(A) 4.8 (B) 8.0
(C) 3.0 (D) 8.4

86. 0.2 g of a sample of H2O2 required 10 ml of N KMnO4 solution in a titration in the

presence of H2SO4, the purity of H2O2 is
(A) 25% (B) 50%
(C) 85% (D) 100%

Match the following

87. Match the chemical reaction in equilibrium (in list I) with the pressure dependence of
degree of dissociation of the reaction (in list II):
List-I List-II
A. A 2  g  3H2  g    2NH3  g
   1. x p
B. 2SO2  g  O2  g    2SO3  g 2. 1
x
p
C. PCl5  g    PCl3  g  Cl2  g 3. xp
D. N2  O2    2NO 4. x  p0

88. Match the effect of addition of 1 M NaOH to 100 mL 1 M CH 3COOH (in list-I) with
pH (in list-II):
List-I List-II
(A) 25 mL of NaOH 1. pKa
(B) 50 mL of NaOH 2. pKa + log3
(C) 75 mL of NaOH 3. pKa  log3

Rankers | Exclusively for IIT JEE | www.myrankers.com

 (D) 100 mL of NaOH 4. 1
pK a  log2
2

89. Match the salt (in list-I) with its equation of pH (in list-II):
List-I List-II
(A) Weak acid and strong base 1. 1
pK w
2
(B) Strong acid and weak base 2. 1
pK w  pK a  pKb 
2
(C) Weak acid and weak base 3. 1
pK w  pKb  logC
2
(D) Strong acid and strong base 4. 1
pK w  pK a  logC
2

90. Match the list – I and list – II.

List-I List-II
(A) Washing soda 1. NaHCO3
(B) Baking soda 2. Pb3O4
(C) Litharge 3. Na2CO3.10H2O
(D) Red lead 4. PbO

Rankers | Exclusively for IIT JEE | www.myrankers.com

 ANSWERS TO
Subjective:

1. Anhydrous MgCl2 can not be prepared by simply heating MgCl2.6H2O because it get
hydrolysed by its own water of crystallization.
MgCl2  6H2 O  MgO  2HCl  5H2O
However if hydrated magnesium chloride is heated in an atmosphere of HCl gas at 650
K, it cheeks the above hydrolysis reaction and the hydrated magnesium chloride now
loses water of crystallization to form anhydrous MgCl2.
MgCl2  6H2O 
HCl gas
650 K
 MgCl2  6H2O

2. Halides of Be are covalent because of high I.E. of Be while those of Ba are ionic due to
low I.E. of Ba.

4. BeCl2 reacts with the moisture to form HCl while other halides do not.
BaCl2 + 2H2O  Ba(OH)2 + 2HCl

5. A piece of Mg ribbon continues to burn in SO2 since it reacts to form MgO and S
2Mg  SO2  heat
 2MgO  S
This reaction is so much exothermic that heat evolved keeps the Mg ribbon burning.

7. On standing the ammoniated ions and electrons combine to form metal amide, hence the
colour fades.

8. (a) Due to high ionization energies and less solubilities of alkaline earth metals as
compared to alkali metals.
(b) Ca, Ba, Sr are much reactive towards oxygen and forms respective oxide but Be &
Mg are not so reactive and they form a protective layer of oxide on their surface so
they are not stored in paraffin.
10. (i) HNO3 is partially decomposed in sun light to produce NO 2. The NO2 formed get
dissolved in HNO3 to produced yellow colour.
4HNO3  Sunlight
 4NO2 + 2H2O + O2
(ii) Liquor ammonia possess high vapour pressure at room temperature and thus before
opening a bottle of liquor ammonia, it should be cooled to lower the pressure of NH 3
inside the bottle, otherwise NH3 will bump out of the bottle.
(iii) Air has oxygen about 1/5 of volume, while N2O on decomposition produces oxygen
about 1/3 of the volume.
(iv) Nitrogen trifluoride is not hydrolysed because neither N nor fluorine possess vacant
d-orbitals to form extra bond with lone pair of electrons on oxygen of water molecule.
However, NCl3 has vacant d – orbitals on Cl atom and hydrolysis
NCl3 + 3H2O  NH3 + 3HOCl
(v) Red phosphorus is believed to exist as chains of P4 tetrahedron linked together,
whereas in yellow phosphorus individual P4 molecules are held together by week van
der Waals forces
(vi) The existence of nitrogen as diatomic molecule is due to its ability to form it bonds
which are not possible in case of other elements due to repulsion between non –
bonded electrons of the inner core.

Rankers | Exclusively for IIT JEE | www.myrankers.com

 (vii) X – Ray studies have shown that solid PCl5 is an ionic compound composed of
+
[PCl4] ; the cation being tetrahedral and anion being octahedral. Due to ionic nature
it conducts current on fusion.
(viii) The structure of orthophosphorus acid reveals that it has two –OH group whereas in
ortho phsophoric acid three OH group are present. In oxy acid only those H atoms
are replaceable which are attached to O atom

11. (a) O O

H O P OH H O P O H

H OH
(Phosphorus acid) (Phosphoric acid)
When phosphene is treated with acidified cupric sulphates, a black precipitate of
cupric phophide is precipitated.
3CuSO4 + 2PH3 = Cu3P2 + 3H2SO4
(b) PH3 + 6AgNO3 = Ag3P.3AgNO3 + 3HNO3
Ag3P.AgNO3 + 3H2O = 6Ag + 3HNO3 + H3PO3
When phosphene passed into silver nitrate solution phosphene forms a black ppt. of
metallic silver a yellow intermediate compound being first formed.
(c) 2HgCl2 + H3PO3 + H2O = Hg2Cl2 + 2HCl + H3PO4
Hg2Cl2 + H3PO3 + H2O = 2Hg(l) + 2HCl + H3PO4
When phosphorus acid is treated with mercuric chloride of given a white precipitate of
calomel in the cold.

12. (a) H3PO3 + 2AgNO3 + H2O = H3PO4 + 2HNO3 + 2Ag

(b) NH4OH + CO2  NH4HCO3
NaCl + NH4HCO3  NaHCO3 + NH4Cl
––––––––––––––––––––––––––––––––––––––––––
NaCl + NH4OH + CO2  NaHCO3 + NH4Cl
(c) 2CH3Cl + Si 
Cu
(CH3)2SiCl2

13. A is NaOH or KOH, B is H2, C is P4 and D is NH3.

14. (i) I2 is non polar nature and thus solubility in water ( a polar solvent) is less which
however becomes more if KI is present due to complex formation
I2 + KI  KI3 (soluble complex)
(ii) H2F2 exists as dimeric molecule due to H-bonding and thus shows dibasic nature.
+ – – +
Hence it gives two series of salts KHF2 as [K and F ----------- H — F ] and KF [K
–
and F ] where as HCl and HBr do not show hydrogen bonding and thus formation of
KHCl2 and KHBr2 is not possible.
(iii) Unlike O2, helium is not soluble in blood even under high pressure and a mixture of
He and O2(80 : 20) is used instead of ordinary air, by divers for respiration.
15. (i) 4S + 6NaOH  Na2S2O3 + 2Na2S
(ii) 2CuSO4 + SO2 + KCNS + 2H2O  2CuCNS + K2SO4 + 2H2SO4

16. (a) 85%

(b)124.79 ml

17. (i) Cr(OH)3 is converted into yellow coloured Na2CrO4

(ii) Hydrazine is oxidised to N2 and H 2 O .

Rankers | Exclusively for IIT JEE | www.myrankers.com

 (iii) H2O2  Ba  OH2  BaO2  2H2O
(iv) NaOCl  H2O2  NaCl  H2O  O 2

18. H2 + I2  2HI
d[H2 ] d[I ] 1 d[HI]
  2   10 6
dt dt 2 dt
Rate of disappearance of H2 per mole = rate of disappearance of I2 per mole = Rate of
appearance of HI per mole
d[HI]
  2  10 6 mol lt 1 sec 1
dt
x y
19. Let rate law can be given as rate = K[A] [B] . From the data given it is clear that by
doubling the concentration of A rate also becomes double, when B is kept constant. Thus
rate is directly proportional to conc. of A
 Rate  [A]  x= 1
When the concentration of A is kept constant and the concentration of B is doubled the
rate does not change.
 y=0
 dx  Rate
 Rate =    K[A] K
 dt  A
0.005
K=  0.5 min1
0.01

20. Equilibrium gets displaced to the left because with removal SCN ions from the
equilibrium mixture, more of the deep red complex (Product) will decomposes into the
reactants. Thus, the colour of the solution will slowly change from deep red to pale
yellow.

21. (i) Increase in pressure will not affect the equilibrium because there is no change in the
number of moles as a result of the reaction.
(ii) Increase in pressure will favour the backward reaction because number of moles per
unit volume(or pressure) decrease in the backward direction.
(iii) Increase in pressure will favour the backward reaction because the number of moles
per unit volume (or pressure) decrease in the backward direction.
(iv) Increase in pressure will favour the forward reaction because the number of moles
per unit volume (or pressure) decrease in the forward direction.

22. 5.27
–2
23. Kc = 4  10 , KP = 1.77

24. 16 atm
25. 31:27
26. 0.1

27. 34%

28. (i) 0.16 atm; (ii) 40%

29. NH3  H2O    NH4  OH

NH3 (aq) is a weak base hence ionization is feeble.

Rankers | Exclusively for IIT JEE | www.myrankers.com

 Also OH   NH4   1.34  103 M
NH3   0.10  1.34  103  0.10M
 
2
NH4  OH  1.34  10 3
Kb    = 1.8  105
NH3  0.1

30. pKIn = 6
In 
pH = pKIn + log
HIn
For acidic colour to prevail:
In  9.09 1
 
 
HIn 90.91 10
 pH  6 - 1 = 5
For basic colour to prevail:
In  95.24
  20
HIn 4.76
 pH  6 + 1.3 = 7.3
pH range : 5 - 7.3

31. Ksp of MgCO3 is more than Ksp of CaCO3

+
In the presence of NH4 ions, the following equilibria exists.
NH4  CO32     HCO3  NH3 , thereby converting CO32– into HCO3–.
2– 2+ 2–
The decreased conc. of CO3 is still sufficient to make the ionic product [Ca ] [CO3 ]
exceed the Ksp of CaCO3 whereas this is not so in the case of MgCO3.

- +
32. HIn In + H
C(1-) C C
C(1   )
pH = pKIn - log
C
6
9.1249 = pKIn – log   = pKIn - 0.1760
4
pKIn = 9.3010 at pH = 9
 1  
9 = pKIn - log  
  
 1  
9 = 9.3010 – log  ’
  
1  1 
0.3010 = log i.e. 2 = = 0.3
 
+
% dissociation = 33.3%33. If we do not consider [H ] from H2O, then
+ 8
[HCl] = [H ] = 10 M
pH = 8 which is not possible since acidic solution should have pH < 7
If we consider H   1 107 M
H2 O

Then total [H ] = 1  107 + 1  108 = 11  108 M

+

Then pH    log H   8  log11  8  1.04 = 6.96

34. NH4 2 SO4    2NH4  SO24

+
Thus, every one mole of (NH4)2SO4 gives two moles of NH4 .

Rankers | Exclusively for IIT JEE | www.myrankers.com

  millimoles of NH3, (NH4OH) = 100  0.1 = 10 millimol
millimoles of (NH4)2SO4 = 100  x = 100x millimol
millimoles of NH4 = 200  x = 200x millimol
+

 pH = 9.26
 pOH = 14 – 9.26 = 4.74
NH4 
 pOH  pK b  log
NH4OH
200x
4.74  4.74  log
10
log20x = 0
20x = 1
1
x  0.05
20

35. (a) 8.06  104 M (b) 6.5  105

39. Use equation for acidic buffer

 pH  pKa , H3O   Ka  7.2  1010

40. NH4 OH    NH4   OH

1 0 0
1  α α α
Given, pH = 11
[H ] = 1011
+

[OH] = 103 = C
Sin  = C = 0.05
103 103
 α   2  102  2%
C 0.05

IIT Level Questions

(a) The solutions of alkali metal salts contain metal cations, H , OH and the anions. The
+
41.
+
discharge potential of H ions is lower than the metal cations and thus, on electrolysis
of solutions of alkali metal salts, hydrogen is discharged at cathode rather than the
metal.
However, on electrolysis of molten salt, the metal cations only present gets
discharged at cathode.
(b) Sodium hydroxide continuously absorbs carbon dioxide of atmosphere and is
converted into sodium carbonate. A stage reaches when the solution becomes
saturated and the crystals are formed. These crystals, with the passage of time lose
water of crystallization (efflorescence) and crumble to white powder.
(c) Iodine reacts with NaOH forming colourless compounds. Thus, the colour of iodine
disappears on addition of NaOH.
2NaOH  I2  NaI
 NaIO  H2O
Colourless products

42. 1.344

Kp  Kc RT  , Kc = 0.50, R = 0.082 litre atm deg1 mol1

n
45.
T = (400 + 273) = 673 K, n = 2 – 4 = 2

Rankers | Exclusively for IIT JEE | www.myrankers.com

 Kp = 0.5 (0.082  673)2 = 1.66  104

NH3  ; NO ; K  H2O

2 2

46. K1  K2 
N2 H2 
3
N2 O2  3 H2 O2 1/ 2
The equilibrium constant for
5
2NH3  g  O2  g    2NO  g  3H2O  g
2
NO2  H2O
2 3
K 2  K 33
will be: 
NH3  O2 
2 5/2
K1

47. 9.8  1011  1.8  1010 K sp  AgCl

48. 30 ml HA = 60 mL 0.25 M NaOH, so [HA] = 0.5 M

No. of millimole of acid initially taken = 300.5 = 15
when 20 ml 0.25 M ( = 5 millimole) NaOH is added the salt formed = 5 millimole and acid
remaining unreacted = 10 millimole. The resulting mixture will be an acid buffer mixture
whose pH will be given by the equation

pH = pKa + log
salt   4.6 = pKa + log 5
acid 10
 pKa = 4.9
(i) pH of acid solution before addition of any drop of alkali
1 1
pH = [pKa - log C] = [4.9-log 0.5] = 4.6
2 2
(ii) pH of the solution at the end point which is diluted to 150 ml
No. of millimole of salt formed = 15
Volume of solutio = 150 ml
15
[salt] =  0.1 M
150
The salt formed will be hydrolysed to render the solution faintly alkaline. The pOH of
this solution may be calculated as
1 1
pOH = [pKa - pKw - log C] = [4.9-14+1] = 4.05
2 2
 pH = 9.95

MCl  M +
+ -
49. Cl
a/v a/v
NCl  N +
+ -
Cl
b/v b/v
+ +
Now M and N ions undergoes hydrolysis simultaneously
+ +
M + H2O MOH + H
a 
 v  x1  x1 x1 + x2 … (i)
 
+ + +
Similarity for N , N + H2O NOH + H
b 
 v  x2  x2 x1 + x2
 
K w  x1  x2  x1
From (i) KH1   ss … (iii)
K1 a/v

Rankers | Exclusively for IIT JEE | www.myrankers.com

 K w  x1  x2  x2
KH2   … (iv)
K2 b/ v
a a a b
 x1  and  x 2  because of lowser values of x1 and x2 due to common ion
V V V V
effect.
 [H ] = x1 + x2
+

By adding (iii) and (iv)

a K b K
[x1+x2] = . w  . w
2
V K1 V K 2
a Kw b Kw
x1  x 2  .  .
V K1 V K 2
a Kw b Kw

+
pH = -log H = - log [x1 + x2] = - log
V K1 V K 2
1 K a b  1  Kw 
=- log  w    = - log  K 2a  K1b
2  V  K1 K 2  2  VK1.K 2 
1  K K  V 
pH = log  1 2  
2  K w  aK 2  bK 1 

50. COOH COOH

 Cl
NH3Cl1 NH3
conjugate acid of amino acid

COOH COO 
K1
H2O   
 H3O
NH3 NH3
0.1  c 0.1 0.1
c  H   2  103

K1  C 2  4  10 5

NH 2 NH 2
Na
 
COONa COO
conjugate base of amino acid
NH2 NH2
Kw / K
H2O     2 OH1
COO 

COOH
0.1  c 0.1 0.1
Kw
c  103 ,  C2  105  K 2  109
K2
Now
COO COOH
H    1
1/ K
+  +
NH3 NH3

COOH COO
K2
  
  H
NH2 NH2
At isoelectric point [C.A.] = [C.B.]
[H ] = K1  K 2  pH = 6.7
+

Rankers | Exclusively for IIT JEE | www.myrankers.com

Objective:

Single Correct Questions

1. B 2. B 3. C 4. A
5. B 6. D 7. C 8. D
9. B 10. D 11. C 12. D
13. C 14. D 15. D 16. C
17. C 18. B 19. C 20. A
21. D 22. B 23. C 24. D
25. A 26. B 27. A 28. D
29. B 30. D 31. B 32. A
33. B 34. A 35. A 36. B
37. D 38. B 39. D 40. C
41. D 42. D 43. A 44. B
45. A

Multiple Correct Questions

46. A,B,D 47. A,C,D 48. C,D 49. A,B,D

50. B, C 51. A, B, D 52. A, C, D 53. B, C
54. B, C 55. A, B, C 56. A, B. C 57. C, D, E
58. B, C, D 59. A, B, D 60. A,B,C,D 61. A, B, D
62. B, C, D 63. A, C, D 64. B, C 65. A, B
66. A, B 67. B, C, D 68. B, C
Comprehension

69. 5.44 atm 70. Bromine liquid

71. Hydrogen gas 72. Endothermic 73. B 74. C
75. A 76. A 77. D 78. D
79. B 80. D 81. A 82. D
83. B 84. C 85. D 86. C

Match the following

87. A - 3; B - 1; C - 2; D – 4 88. A – 3; B – 1; C – 2; D – 4
89. A – 4; B – 3; C – 2; D – 1 90. A – 3; B – 1; C – 4; D – 2

Rankers | Exclusively for IIT JEE | www.myrankers.com