3010 William Nicol Drive, Bryanston Tel: +27(11) 840-4000 Fax: +27(11) 514-0084

PO Box 78056, Sandton 2146, Republic of South Africa

Safety Data Sheet

Dated 19/07/2007 – Revision 1

1. DESIGNATION OF PRODUCT AND COMPANY

Trade Name:
Doom Super Multi Insect

Supplier:
Tiger Consumer Brands Limited
Tigerbrands Corporate Hill
3010 William Nicol Drive
Bryanston
2194

Emergency telephone number and/or of an authorised advisory centre:

Tiger Consumer Brands : Tel: 0860101107
Red Cross Hospital (Children only), Cape Town : Tel: (021) 6895227
Tygerberg Hospital (Adults only), Cape Town : Tel: (021) 9316129
Pharmocolgy – Universitas Hospital Bloemfontein : Tel: 0824910160
St Augustines Hospital, Durban : Tel (031) 2685202
Garden City Poison Centre, Johannesburg : Tel: (011) 4955112
Pretoria Unitas Hospital, Pretoria : Tel: 0800333444

2. COMPOSITION / INFORMATION ON INGREDIENTS

Dangerous Substances:
D’ Phenothrin ) 0.92 g/kg
Prallethrin (ETOC) ) (Pyrethroid) 0.4 g/kg
Pralle (Imiprothrin) ) 0.25 g/kg

Description of the preparation:

An insect killing aerosol supplied in a pressurised container. Propelled by Butane / Propane
gas.

TIGER CONSUMER BRANDS LIMITED Registration No. 1972/006590/06

Directors: PB Matlare (Chairman), N G Brimacombe, N P Doyle (Irish), P M Roux, I W M Isdale, C F H Vaux

Company Secretary: I W M Isdale

3. HAZARDS IDENTIFICATION

As this is a poison, avoid contamination of food and feed stuffs.

4. FIRST-AID MEASURES

Contact with skin:

Wash thoroughly with soap and water.

Contact with eyes:

Wash thoroughly for at least 15 minutes with water.

Swallowing:
Seek medical attention immediately.

Inhalation:
Avoid excessive inhalation.

Note: If misuse results in accidental illness, get prompt medical aid.

5. FIRE FIGHTING MEASURES

Extinguishing Media
Water spray jet; CO²; foam; dry chemical

Special Hazards
In case of fire, the product emits toxic and irritating fumes.

Protective Clothing
Before intervention, wear protective clothing. Wear a self-contained breathing apparatus.

Other Recommendations
Cool with water and protect the container against excessive heat and flame, if possible. Avoid
rejection of extinguishing water into drainage system, surface or ground water.

6. MEASURES IN CASE OF ACCIDENTAL SPILLS

Measures for personal safety:

Before intervention, wear protective clothing.
Ensure adequate ventilation.

Environmental Measures:
Prevent product from entering sewerage system and ground water.

Safety Data Sheet 19/07/2007

 Cleaning Methods:
Do not touch spilled material. Stop or reduce leak if safe to do so. Contain spill with earth,
sand or absorbent material.

Small Spills
Soak up with absorbent material. Put material in suitable, covered labelled containers.

Large Spills
Contact fire and emergency services and supplier for advice.

Product must be disposed of according to local regulations.

7. HANDLING AND STORAGE

Handling precautions:
Do not eat or drink while working.

Incompatible materials:
Avoid contamination of food; feed stuffs and drinking water.

Storage Conditions:
Keep at ambient temperature. Keep away from food, drinking water and animal feeding stuffs.
Keep protected from direct sunlight. Store in a well ventilated place. Keep away from sparks,
flames and other ignition sources.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Precautionary measures:
Ensure adequate ventilation of premises where stored or handled.

Protection for respiratory tract:

Not required for normal use. Avoid excessive inhalation.

Protection for hands:

Not needed for normal use. Wash hands with soap and water after use.

Protection for eyes:

Not needed for normal use.

Protection for skin:

No special precautions are needed.

Safety Data Sheet 19/07/2007

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Pressurised can

Odour Pungent
Flammable limits in air by volume
180ml < 1328 lts / can
300ml < 2197 lts / can
Flash Point (LPG) -60°C
Auto Ignition (LPG) 405°C

10. STABILITY AND REACTIVITY

Condition to avoid:
Stable under normal conditions (maintain between 4°C and 30°C).

Substances to avoid:
Unknown

Hazardous decomposition products:

No decomposition under normal conditions.

11. TOXICOLOGICAL INFORMATION

See data on toxicology of D’ Phenothrin; Prallethrin and Pralle (See Appendix A).

12. ECOLOGICAL INFORMATION

Ecological data is not available.

When used for the purpose for which it is intended, no ecological problems are to be expected
from Doom Super Deadly Multi Insect.

Avoid contamination of the earth as well as surface and ground water.

13. DISPOSAL CONSIDERATIONS

The product and its packaging should be disposed of in accordance with the instructions of the
local authorities. It should not be emptied into sewage systems, nor be disposed of in the
environment.

Safety Data Sheet 19/07/2007

14. TRANSPORT INFORMATION

UN No. 1950
Packaging Group III
Hazard Group 2
Risk Phrase R20 / R21 / R22
Danger Symbol XN
Refer to ERG 126

Classified as dangerous for transport.

15. OTHER INFORMATION

The above mentioned statements are based on our knowledge and information at the date
stated on this Safety Data Sheet.

These statements are only for the above mentioned product and should help to ensure that
adequate safety precautions are taken.

This “Safety Data Sheet” replaces all previous ones.

Note: Please note that all information is given in good faith but without guarantee in respect of
accuracy. No responsibility is accepted for errors or omissions or the consequences thereof.

Printing date : 19th July 2007

Safety Data Sheet 19/07/2007