Q. 1 Gold atoms form f.c.c. structure and impurities occupy tetrahedral and octahedral voids.

Closest
distance between impurity atom and gold atom in tetrahedral void is

      1.
a

      2.
A

      3.
a

      4.
a/2

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Q. 2 In a cubic unit cell, atoms A occupy seven of the eight corners and atoms B occupy centers of
faces. The general formula of the compound is

      1.
A7B6

      2.
A7B12

      3.
A7B24

      4.
A24B7

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Q. 3 Which of the following compounds will react with two moles of CH 3MgBr?

      1.
CH3COOH

      2. CH3 - C   C - CH3

       3.
HC   C - CH2OH

      4.
CH3 - CH2 - CH2OH

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Q. 4 For 5d type of orbital, the number of radial nodes and total nodes are, respectively,

      1.
2 and 1

      2.
1 and 2

      3.
1 and 1

      4.
2 and 4

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Q. 5 The correct increasing bond angle order is:

      1.
BF3 < NF3 < PF3 < ClF3

      2.
ClF3 < PF3 < NF3 < BF3

      3.
BF3   NF3 < PF3 < ClF3

      4.
NF3 < BF3 < ClF3 < PF3
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Q. 6 For 4d type of orbital, the number of radial and angular nodes are, respectively,

      1.
2 and 1 

      2.
1 and 2

      3.
1 and 1

      4.
2 and 2

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Q. 7 The correct structure of PCl3F2 is

      1.

      2.

      3.
       4.

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Q. 8 Which of the following compounds have the same no. of lone pairs with their central atom 

[I]   (II) BrF3 (III) XeF2 (IV) H3S+

      1.
III and IV

      2.
I and III

      3.
I and II

      4.
II and IV

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Q. 9 Match List - I (molecule) with List - II (shape) and select the correct answer using the codes given
below the lists : 
Column - I (Molecule) and Column - II (Shape)
Column - I                                                            Column - II

1. (CH3
A. Square planar
Ans : )3
2. NH4 B. Trigonalbipyram
Cl id
3. [ICl4
C. Tetrahedral
]-
4. PCl5 D. Trigonal planar
A B C D
1
2
 3
4
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Q. 10
The correct order of bond length of Si-O, P-O, S-O and Cl-O in  ,  ,  and  is

      1.
>  >  > 

      2.
>  >  > 

      3.
>  >  > 

      4.
>  >  > 

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Q. 11 The correct increasing bond angle order is:

      1.
BF3 < NF3 < PF3 < ClF3

      2.
ClF3 < PF3 < NF3 < BF3

      3.
BF3   NF3 < PF3 < ClF3

      4.
NF3 < BF3 < ClF3 < PF3

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Q. 12 The correct order of dipole moment is

      1. CH4 < NF3 < NH3 < H2O  

       2.
NF3 < CH4 < NH3 < H2O

      3.
NH3 < NF3 < CH4 < H2O

      4.
H2O < NH3 < NF3 < CH4

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Q. 13 The decreasing order of polarity of the bond in NH3, PH3, AsH3 and SbH3 is in the order

      1.
NH3 > PH3 > AsH3 > SbH3

      2.
SbH3 > AsH3 > PH3 > NH3

      3.
NH3 > AsH3 > PH3 > SbH3  

      4.
NH3 > SbH3 > AsH3 > PH3

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Q. 14 The substance with the highest boiling point out of the following H 2, He, Ne, Xe, CH4 is

      1.
Xe

      2.
CH4

      3.
Ne
       4.
H2

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Q. 15 Which of the following contains both polar and non polar bonds?

      1.
NH4Cl

      2.
HCN

      3.
H2O2

      4.
CH4

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Q. 16 Among KO2, AlO2-, BaO2, NO2+ unpaired electron is present in

      1.
NO2+ and BaO2

      2.
KO2 and AlO2-

      3.
KO2 only

      4.
BaO2 only

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Q. 17 The correct order of increasing C - O bond length of CO, CO 3-2, CO2 is

      1. CO3-2 < CO2 < CO

       2.
CO2 < CO3-2 < CO

      3.
CO < CO3-2 < CO2

      4.
CO < CO2 < CO3-2

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Q. 18 The atomic number of Sn is 50. The shape of the gaseous SnCl2 molecules is

      1.
Cl - Sn - Cl

      2.

      3.

      4.

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Q. 19 Which of the following molecular orbital has the lowest energy?

       1.
2pz

      2.
*2pz

      3.
*2px

      4.
*2py

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Q. The structure of IF5 can be best described by

20

      1.

      2.

      3.

      4.
None of these