Beruflich Dokumente
Kultur Dokumente
SKO25
MAPPING COGNITIVE
TOPIC SUBTOPIC LEARNING OUTCOMES DOMAINS
C1 C2 C3 C4
a) Define reaction rate √
b) Write differential rate equation √
c) Determine reaction rate based on differential rate equation
√
of a reaction
d) Define rate law, order of reaction and half life √
e) Write rate law with respect to the order of reaction √
1.1 Reaction f) Write the integrated rate equation for zero, first and second
√
Rate order reactions
g) Determine the order of reaction involving single reactant
using:
i. Initial rate method
√ √
ii. Half-life based on graph of concentration against time
iii. Linear graph method based on the integrated rate
equation and rate law
h) Perform calculation using integrated rate equations √
a) Explain collision theory √
Reaction b) Define activation energy √
1.2 Collision
Kinetics
Theory c) Explain transition state theory √
d) Draw energy profile diagram of a reaction √
a) Explain the effect of the following factors on the reaction
rate:
i. Concentration or pressure
√
ii. Temperature
iii. Catalyst
iv. Particle size
1.3 Factors b) Illustrate the effect of temperature on the reaction rate using
√ √
Affecting Maxwell Boltzmann Distribution curve
Reaction Rate c) Compare the curve of the energy profile diagram for a
√
reaction with and without catalyst
d) State Arrhenius equation √
e) Explain the relationship between temperature and activation
√
energy to the rate constant based on Arrhenius equation
f) Determine k, Ea, T and A using Arrhenius equation by
√ √
calculation and graph
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CHAPTER 1: REACTION KINETICS
SKO25
4 A reaction in which A, B and C react to form products is first order in A, second order in B and zero
order in C.
a) Write the rate equation.
b) What is the overall order of the reaction?
c) By what factor does the reaction rate change if [A] is doubled (and the other reactant
concentrations are held constant)?
d) By what factor does the reaction rate change if [B] is doubled (and the other reactant
concentrations are held constant)?
e) By what factor does the reaction rate change if [C] is doubled (and the other reactant
concentrations are held constant)?
[ LO : 1.1(f)]
5 The reaction of nitric oxide with hydrogen at 1280°C is
2NO(g) + 2H2(g) ⎯→ N2(g) + 2H2O(l)
The following data was collected at this temperature :
1 5.00×10 3−
2.00×10 3 −
1.25×10 5
−
2 10.00×10 3 −
2.00×10 3 −
5.00×10 5
−
3 10.00×10 3 −
4.00×10 3 −
10.00×10 5 −
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CHAPTER 1: REACTION KINETICS
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6 The data below were obtained from the following reaction at 27oC .
CH3CH(Cl)CH3 + NaOH ⎯→ CH3CH(OH)CH3 + NaCl
Exp [CH3CH(Cl)CH3] / M [NaOH] / M Reaction rate / M min 1−
7 The data listed in the table below were obtained from the following decomposition :
A ⎯→ products
1
Time/min [A]/M ln [A]
[A ]
0 1.00 0.00 1.00
5 0.63 −0.46 1.60
10 0.46 −0.78 2.20
15 0.36 −1.02 2.80
25 0.25 −1.39 4.00
CH2
⎯
⎯→ H2C CH CH3
H2C CH2
a) If the initial concentration of cyclopropane was 0.25M, calculate the concentration after 8.8 min.
b) How long will it take for the concentration of cyclopropane to decrease from 0.25M to 0.15M?
c) How long will it take to convert 74% of the starting material to propene?
[LO : 1.1(i)&(g)]
(ANS : (a) 0.176M (b) t =762.43s (c) t =2010.56s )
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CHAPTER 1: REACTION KINETICS
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9 The decomposition of dinitrogen pentoxide with the rate constant of 5.1×10–4 s–1 at 45oC is given
below: 2N2O5(g) ⎯→ 4NO2(g) + O2(g)
a) Calculate the concentration of N2O5 after 3.2 min if the initial concentration is 0.25 M.
b) If the initial concentration of N2O5 is 0.35 M, calculate the time needed for the concentration
to be reduced to
i. to 0.08 M.
ii. by 62%. [ LO : 1.1(h)(i)&(f)]
(ANS : (b)250M-2s-1)
10 a) What are the conditions for an effective collision to occur between reactant molecules to form
products?
[ LO : 1.2(a)]
b) State the factor that affect the rate constant, k ? Explain. [ LO : 1.3(e)]
11 Explain the effect of temperature on reaction rate based on Maxwell-Boltzmann distribution curve.
[ LO : 1.3(b)]
14 Rate constants, k for decomposition of hydrogen iodide at different temperatures are given in the
table below :
Rate constant, k ( mol 1 dm3 s 1)
− −
Temperature (K)
3.75×10 9−
500
6.65×10 6−
600
1.15×10 3−
700
7.75×10 2−
800
OBJECTIVE QUESTIONS
B. 2.19×10 3 M s 1
− −
D. 2.19×10 2 M s 1
− −
d[ A]!
2. For the reaction: A + 2B ⎯→ C + 2D, the initial rate, − is 2.6×10 2 M s 1. What is the value of
− −
dt
d[ B ]!
− ?
dt
A. 6.5×10 3 M s 1
− −
C. 2.6×10 2 M s 1
− −
B. 1.3×10 2 M s 1
− −
D. 5.2×10 2 M s 1
− −
3. If a reaction is described as zero order with respect to reactant A, this means that
A. A is a catalyst in the reaction.
B. A is not involved in the rate determining step.
C. the value of the rate constant is independent of A.
D. the rate of reaction is inversely proportional to the concentration of A
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CHAPTER 1: REACTION KINETICS
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(mol dm 3 hr 1) NO
− −
Cl2
1.19 0.50 0.50
4.79 1.00 0.50
9.59 1.00 1.00
Choose the rate equation for the reaction.
A. rate = k[NOCl]2 C. rate = k[NO]2[Cl2]
B. rate = k[NO][Cl2] D. rate = k[NO][Cl2]0.5
5. The initial concentration of an active substance in an aqueous solution of medicine is 5.0×10 3 mol
−
dm 3. After 20 months, an analysis shows that its concentration becomes 4.2×10 3 mol dm 3.
− − −
Determine the decay duration of this medicine by assuming the decomposition of the active
substance is a first order reaction.
[Decay duration of the medicine is the time required as it decomposes 10% of the initial
concentration].
A. 9 months C. 18 months
B. 12 months D. 23 months
6. The reaction A + 2B ⎯→ products was found to have the rate law, rate = k[A] [B]2. Predict by what
factor the rate of reaction will increase when the concentration of B is doubled and the concentration
of A remained unchanged.
A. 2 C. 6
B. 4 D. 8
8. The half-life of a radioactive element is 50 minutes. How long will it take for the element to decay by
87.5%?
A. 1.67 hours C. 2.25 hours
B. 2.00 hours D. 2.50 hours
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CHAPTER 1: REACTION KINETICS
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t
II
[Q]
t
III
Rate
[Q]
74