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Material Balance
28
Material balance for production 30% NaOH from 28% NaoH on the
basis of 50 ton production per day.
Basis: 50 MT
=52.083 kmol/hr
= 2083.32 kg/hr
29
= 37.91 m3/h
= 193 kmol/h
= 11309.805 kg/h
= 141.247 kmol/h
= 8262.9495 kg/h
H2Oin =
H2Oout =
Production of Chlorine
= 26.046 kmol/h
= 1478.75 kg/h
= 9.7263 – 8.988
= 73.253 m3/hr
= 658.39 kmol/h
= 26335.6 kg/h
= 658.39 + 52.083
= 28418.92 kg/h
= 710.473 kmol/h
= ½ *710.473
=355.2365 kmol/h
= 710.473 kg/h
= 3046.85 kg/h
!:.
So for production of 50 MT NaOH, amount of Raw salt needed =
.(!
= 3192.71 kg/h
!(.'
& for production of 1 kg NaOH, amount of Raw salt needed = kg
!.!
!:.
& amount of NaCl needed = kg =1.46 kg NaCl
!.!
H2 710.473 355.2365
33
Sludge Calculation
From our material balance we found that 2083.32 kg NaOH is produced from
3192.75 kg raw material (raw salt).
And we found from material balance that 1 kg NaOH is produced from 1.46 kg
NaCl . Thus 1 kg raw salt produced some sludge due to unnecessary other
component in raw salt. The amount of raw salt produced net amount sludge is
found as
= 0.0725 kg
Ca2+ 0.227%
Mg2+ 0.049%
SO42- 0.645%
Total Iron 13.2 ppm
NaCl 95.43%
Moisture 3.649%
For Ca2+ removing we add NaCO3 which show the following reaction
= (1.5325 × 0.00227) kg
=0.00347 kg
=0.0075 kg
= 0.00988 kg
=0.0531 kg
=0.00002022 kg
= 0.00812 kg
Our plant supervisor gave us the plant capacity is 50 ton per day.
So we can take a decision that Global Heavy Chemicals Ltd. Produce 3625 kg
sludge per day.