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Reading No Time Type Duration Units Sequence SAMPLE LOCATION

1 11/30/2011 6:56 System Check 57.71 cps Final


2 11/30/2011 7:01 Soil 120 ppm Final Blank Si02 Malambo
3 11/30/2011 7:04 Soil 120 ppm Final GBM398-2 Malambo
4 11/30/2011 7:08 Soil 120 ppm Final GBM906-2 Malambo
5 11/30/2011 7:11 Soil 120 ppm Final GBM908-5 Malambo
6 11/30/2011 7:28 Soil 120 ppm Final 30633 Malambo
7 11/30/2011 7:32 Soil 120 ppm Final 30633 Malambo
8 11/30/2011 7:36 Soil 120 ppm Final 30634 Malambo
9 11/30/2011 7:40 Soil 120 ppm Final 30635 Rappa B ext
11 11/30/2011 7:44 Soil 120 ppm Final 30636 Rappa B ext
12 11/30/2011 7:47 Soil 120 ppm Final 30637 Rappa B ext
13 11/30/2011 7:50 Soil 120 ppm Final 30638 Rappa B ext
14 11/30/2011 7:53 Soil 120 ppm Final 30639 Rappa B ext
15 11/30/2011 7:56 Soil 120 ppm Final 30640 Rappa B ext
16 11/30/2011 7:58 Soil 120 ppm Final 30641 Rappa B ext
17 11/30/2011 8:01 Soil 120 ppm Final 30642 Rappa B ext
18 11/30/2011 8:04 Soil 120 ppm Final 30643 Rappa B ext
19 11/30/2011 8:07 Soil 120 ppm Final 30644 Rappa B ext
20 11/30/2011 8:10 Soil 120 ppm Final 30645 Rappa B ext
21 11/30/2011 8:13 Soil 120 ppm Final 30646 Rappa B ext
22 11/30/2011 8:16 Soil 120 ppm Final 30646 Rappa B ext
23 11/30/2011 8:20 Soil 120 ppm Final GBM398-2 Rappa B ext
24 11/30/2011 8:22 Soil 120 ppm Final GBM906-2 Rappa B ext
25 11/30/2011 8:25 Soil 120 ppm Final GBM908-5 Rappa B ext
26 11/30/2011 8:30 Soil 120 ppm Final Blank Sio2 Rappa B ext
INSPECTOR COR 1 COR 2 MISC NOTE User Login Res EScale Flags Ba Ba Error
god 166.04 7.44
Hashim god < LOD 152.58
Hashim god ModCF July 2011 745.74 134.85
Hashim god ModCF July 2011 895.48 149.27
Hashim god ModCF July 2011 2650.3 154.1
Hashim god ModCF July 2011 1831.57 145.64
Hashim god ModCF July 2011 2159.08 200.21
Hashim god ModCF July 2011 2221.95 156.11
Hashim god ModCF July 2011 822.62 146.58
Hashim god ModCF July 2011 1482.17 278.5
Hashim god ModCF July 2011 2430.1 161.79
Hashim god ModCF July 2011 1290.34 172.15
Hashim god ModCF July 2011 2123.82 170.96
Hashim god ModCF July 2011 1583.3 168
Hashim god ModCF July 2011 607.58 110.16
Hashim god ModCF July 2011 760.04 115.24
Hashim god ModCF July 2011 1976.64 158.51
Hashim god ModCF July 2011 765.9 118.93
Hashim god ModCF July 2011 675.71 117.73
Hashim god ModCF July 2011 2911.15 193.5
Hashim god ModCF July 2011 2172.85 140.73
Hashim god ModCF July 2011 639.36 140.57
Hashim god ModCF July 2011 686.56 151.01
Hashim god ModCF July 2011 2391.77 160.51
Hashim god < LOD 152.93
Sb Sb Error Sn Sn Error Cd Cd Error Ag Ag Error Pd Pd Error Zr Zr Error

35.54 18.72 < LOD 27.28 < LOD 15.43 < LOD 9.95 < LOD 10.56 < LOD 13.21
66.57 23.75 35.69 23.46 < LOD 19.33 < LOD 12.46 < LOD 13.24 181.81 14.73
84.1 26.28 52.32 26.08 24.41 14.35 23.83 9.65 < LOD 14.55 98.85 14.78
< LOD 36.13 < LOD 36.41 < LOD 19.67 57.01 9.77 < LOD 13.42 336.71 17.88
84.41 24.34 73.61 24.39 < LOD 19.7 < LOD 12.99 < LOD 13.44 120.86 14.26
89.33 32.98 < LOD 48.51 < LOD 27.02 33.9 12.37 < LOD 17.55 234.72 21.32
76.89 25.5 53.83 25.46 27.84 14.03 < LOD 13.73 < LOD 14.45 138.33 17.92
92.42 26.06 < LOD 38.21 22.07 14.15 15.41 9.34 < LOD 14.29 25.72 14.01
< LOD 68.53 < LOD 68.79 < LOD 38.08 < LOD 26.29 < LOD 26.37 < LOD 43.26
63.62 25.96 < LOD 38.72 30.16 14.4 < LOD 14.06 < LOD 14.47 31.71 19.36
112.12 29.99 50.13 29.66 < LOD 24.1 16.63 10.71 < LOD 16.66 71.2 17.91
73.96 28.01 < LOD 41.36 24.15 15.37 23.16 10.31 < LOD 15.01 291.76 23.47
124.29 29.01 64.74 28.75 28 15.63 20.47 10.4 < LOD 16.06 38.55 14.59
119.78 20.16 53.25 19.39 20.59 10.8 < LOD 10.55 < LOD 11.05 < LOD 13.93
105.97 20.77 59.08 20.16 30.42 11.32 13.3 7.35 < LOD 11.33 23.98 9.88
82 26.2 45.17 25.93 < LOD 20.91 < LOD 14.06 < LOD 14.29 60.77 18.23
119.75 21.56 86.86 21.21 31.87 11.7 22.81 7.77 < LOD 11.93 75.53 10.9
138.58 21.65 59.66 20.76 31.66 11.64 15.79 7.6 < LOD 11.8 148.44 11.92
276.19 33.39 92.46 32.12 60.65 17.47 27.54 11.44 < LOD 17.59 83.28 16.86
84.06 23.1 37.38 22.63 < LOD 18.69 < LOD 12.16 < LOD 12.73 84.64 13.21
90.6 25.22 < LOD 36.92 < LOD 20.49 < LOD 13.42 < LOD 13.87 187.35 15.56
65.41 26.68 < LOD 39.54 23.53 14.68 24.76 9.89 < LOD 14.34 96.45 15
48 25.62 < LOD 38.48 < LOD 21.1 57.26 10.31 < LOD 14.23 363.36 19.19
38.04 18.92 < LOD 27.55 < LOD 15.67 < LOD 10.24 < LOD 10.62 < LOD 13.25
Sr Sr Error Rb Rb Error Pb Pb Error Se Se Error As As Error Hg Hg Error

< LOD 4.02 < LOD 2.48 < LOD 6.61 < LOD 2.97 < LOD 4.72 < LOD 7.3
186.08 8.39 155.72 7.19 67.73 11.83 < LOD 4.82 182.44 14.09 < LOD 11.76
156.57 8.69 1261.31 21.41 30.18 11.79 < LOD 5.35 < LOD 12.38 < LOD 14.2
396.36 12.01 103.95 6.23 361.1 23.22 < LOD 5.35 < LOD 24.07 < LOD 12.08
243.21 9.54 55.94 4.74 < LOD 11.5 < LOD 4.86 < LOD 7.71 < LOD 12.14
228.51 12.38 113.5 8.45 < LOD 16.04 13.79 6.06 < LOD 11.38 < LOD 17.58
994.15 19.19 21.73 3.83 < LOD 12.39 < LOD 4.36 < LOD 8.77 < LOD 12.18
333.36 11.68 5.77 2.85 < LOD 11.23 < LOD 4.83 < LOD 7.42 < LOD 11.84
873.5 31.2 21.68 7.15 < LOD 30.39 25.25 10.94 53.79 17.84 < LOD 29.26
1705.68 25.63 25.12 4.28 < LOD 12.95 < LOD 4.89 < LOD 8.94 < LOD 12.38
562.75 16.82 6.43 3.4 < LOD 13.2 < LOD 6.26 < LOD 8.87 < LOD 15.65
1536.04 25.95 32.36 4.84 < LOD 14.35 < LOD 5.94 < LOD 9.54 < LOD 14.38
120.5 8.3 6.17 3.09 < LOD 13.94 < LOD 5.45 < LOD 8.77 < LOD 14.94
16.11 3.32 < LOD 2.79 < LOD 7.23 < LOD 3.24 < LOD 5.16 < LOD 7.88
31.72 3.94 5.48 2.11 < LOD 7.67 < LOD 3.38 < LOD 5.35 < LOD 7.64
1233 21.94 14.72 3.68 < LOD 12.94 < LOD 5.11 < LOD 8.67 < LOD 13.36
8.34 3.29 < LOD 2.89 < LOD 7.88 < LOD 3.7 < LOD 5.3 19.79 6.68
19.29 3.64 < LOD 3.04 < LOD 7.98 < LOD 3.94 < LOD 5.55 < LOD 7.93
166.36 10.13 37.13 5.13 < LOD 13.89 < LOD 6.6 < LOD 10.22 < LOD 15.78
300.23 9.97 54.3 4.48 < LOD 10.78 < LOD 4.57 < LOD 7.18 < LOD 10.5
193.24 8.93 154.67 7.51 72.96 12.72 < LOD 5.35 180.19 14.83 < LOD 12.63
134.93 8.39 1189.96 21.3 23.76 11.54 < LOD 5.41 14.75 8.31 < LOD 14.79
397.43 12.65 104.27 6.56 351.92 24.17 < LOD 5.83 < LOD 25.73 < LOD 12.92
< LOD 4.07 < LOD 2.42 < LOD 7.5 < LOD 3.05 < LOD 4.88 < LOD 7.25
Au Au Error Zn Zn Error W W Error Cu Cu Error Ni Ni Error Co Co Error

< LOD 8.25 < LOD 8.76 < LOD 51.17 < LOD 17.66 < LOD 31.51 < LOD 21.74
< LOD 13.72 97.63 17.26 < LOD 86.51 207.13 28.65 312.6 45.34 228.62 119.75
< LOD 13.39 55.62 17.68 < LOD 119.68 494.47 44.12 1086.3 79.9 326.98 149.49
< LOD 13.63 216.62 23.52 < LOD 93.59 414.02 37.36 433.63 51.83 204.18 115.73
< LOD 11.09 439.59 30.76 < LOD 92.35 49.82 21.54 153.46 37.61 < LOD 180.91
< LOD 17.46 834.99 55.85 < LOD 145.05 < LOD 50.16 281.95 70.19 < LOD 398.56
< LOD 12.08 40.64 15.28 < LOD 93.95 < LOD 32.71 410.17 53.02 < LOD 211.82
< LOD 12.81 < LOD 18.52 < LOD 83.47 < LOD 31.14 248.56 45.86 < LOD 186.78
< LOD 33.03 < LOD 102.19 < LOD 231.44 4040.48 184.68 < LOD 247.21 < LOD 1674.59
< LOD 13.58 32.27 15.73 < LOD 86.84 < LOD 31.44 169.02 43.73 < LOD 241.26
< LOD 14.9 < LOD 27.94 < LOD 121.14 < LOD 39.61 157.16 53.84 < LOD 320.36
< LOD 14.74 < LOD 22.11 < LOD 106.72 < LOD 36.89 196.52 48.77 < LOD 195.02
< LOD 14.76 < LOD 25.76 < LOD 119.59 < LOD 37.84 592.1 70.31 < LOD 310.79
< LOD 7.79 < LOD 9.26 < LOD 53.83 < LOD 17.38 98.65 22.31 < LOD 38.52
< LOD 7.36 < LOD 9.54 < LOD 55.47 < LOD 19.38 67.89 21.53 < LOD 42.07
< LOD 12.97 21.49 13.99 < LOD 95.6 < LOD 31.78 140.78 40.97 < LOD 177.95
< LOD 8.81 < LOD 10.59 < LOD 60.32 < LOD 20.62 116 26.2 < LOD 110.24
< LOD 10.04 < LOD 9.94 < LOD 56.86 < LOD 20.84 116.73 25.96 < LOD 79.1
< LOD 17.81 < LOD 27.65 < LOD 121.5 50.18 30.74 264.57 65.74 < LOD 456.71
< LOD 12.07 52.81 12.99 < LOD 70.53 < LOD 26.96 113.11 31.13 < LOD 120.46
< LOD 14.35 79.56 17.34 < LOD 98.01 204.67 30.38 316.24 48.17 < LOD 188.34
< LOD 14.41 63.76 18.55 < LOD 120.37 491.9 45.03 934.82 77.14 283.85 148.68
< LOD 13.66 209.69 24.52 < LOD 101.12 409.73 39.54 433.61 54.58 < LOD 177.8
< LOD 8.39 < LOD 8.26 < LOD 51.91 < LOD 17.54 < LOD 28.71 < LOD 18.64
Fe Fe Error Mn Mn Error Cr Cr Error V V Error Ti Ti Error Sc

99.26 33.6 < LOD 45.49 < LOD 35.08 < LOD 22.17 < LOD 65.67 < LOD
31585.48 428.75 425.43 89.07 186.58 35.48 67.41 37.03 3272.03 150.48 < LOD
41083.08 534.23 612.38 109.94 51.72 31.6 125.03 44.64 6173.3 190.13 122.48
27927.87 413.63 373.47 89.64 108.43 33.17 < LOD 72.83 3061.02 185.72 < LOD
32771.97 443.25 409.16 92.27 255.89 39.49 375 53.28 4900.66 193.32 < LOD
92533.34 984.23 912.46 170.05 136.06 32.5 158.77 40.95 3327.12 155.62 106.46
41162.95 527.29 10422.3 334.4 211.76 45.31 225.27 79.13 8584.97 304.85 < LOD
30798.29 457.91 478.34 99.75 261.68 35.85 84.54 29.46 1615.91 112.29 206.36
892065.19 4142.05 < LOD 685.98 2337.51 145.03 1225.61 116.48 2808.32 335.13 < LOD
51885.27 599.45 759.13 121.84 195.85 38.75 102.71 56.25 9216.41 242.4 < LOD
71446.66 786.3 1340.13 167.7 396.48 43.8 183.84 38.99 2082.14 142.61 203.88
28647.29 475.53 231.6 93.41 108.7 29.71 < LOD 68.99 6502.8 195.62 < LOD
72424.77 763.79 3904.67 245.18 1291.43 66.86 121.41 39.42 1146.85 139.54 178.18
1689.91 87.5 < LOD 60.44 432.75 39.86 73.81 31.14 2105.3 118.68 < LOD
2077.06 99.4 < LOD 64.54 273.26 34.9 114.65 34.91 2435.48 130.6 < LOD
27146.96 435.81 359.58 92.54 107.91 29.18 55.69 36.6 3829.34 152.5 < LOD
16979.98 279.82 < LOD 74.79 290.77 37.63 72.75 37.09 3977.99 152.85 < LOD
8207.23 194.91 < LOD 67.35 88.02 27.65 < LOD 44.01 2400.91 118.39 < LOD
139969.67 1131.91 < LOD 191.77 56.23 35.2 < LOD 45.39 643.74 109.41 < LOD
15578.71 292.52 301.15 76.28 115.21 30.48 < LOD 56.68 2554.03 148.77 < LOD
32163.02 452.82 373.95 89.72 141.92 31.77 51.89 33.63 2858.78 137.29 < LOD
38935.39 532.64 559.24 108.97 69.23 30.38 114.11 41.57 5400.32 175.43 131.81
27574.66 432.4 403.58 95.9 83.88 29.63 < LOD 64.19 2793.78 165 < LOD
90.61 33.41 < LOD 44.42 < LOD 35.24 < LOD 22.82 < LOD 65.07 < LOD
Sc Error Ca Ca Error K K Error S S Error

22.78 < LOD 134.14 198.47 106.34 < LOD 277.8


107.09 26592.69 490.57 19139.66 583.45 < LOD 556.48
76.1 28041.13 527.59 45794.63 892.44 < LOD 590.64
83.7 15839.86 396.45 34234.44 752.78 < LOD 549.2
73.62 10979.14 332.05 21912.27 608.35 3403.67 546.44
41.08 6054.39 252.45 15439.9 512.3 17035.34 1041.24
115.1 26741.49 508.22 14206 530.95 < LOD 510.1
90.72 45599.1 605.29 4911.3 328.14 < LOD 540.2
112.36 4342.22 367.3 4645.72 527.48 2329.32 907.78
125.28 34839.45 558.79 6940.91 387.4 < LOD 544.89
132.81 93361.55 904.23 7614.05 429.26 < LOD 647.15
108.3 32331.79 501.62 11820.31 445.29 < LOD 505.23
114.67 68367.2 774.52 4373.05 347.04 < LOD 621.33
24.65 352.9 112.43 5477.99 302.49 < LOD 374.86
29.38 884.92 132.3 7870.28 353.69 < LOD 359.94
112.04 33892.32 511.75 8000.37 378.15 < LOD 436.83
29.29 308.64 112.68 3926.39 275.44 < LOD 368.86
28.04 344.65 104.61 3043.21 239.67 < LOD 294.08
70.44 7004.57 285.53 4570.73 341.96 29842.98 1507.41
81.72 16837.44 391.37 31454.36 700.2 1621.26 431.12
97.85 23055.57 446.2 17031.46 538.36 < LOD 530.12
69.89 24591.99 481.49 41302.24 825.05 < LOD 562.12
77.61 13734.26 358.24 29744.65 681.95 < LOD 462.16
22.32 < LOD 122.59 189.53 102.55 < LOD 261.91
SAMPLE LOCATION Analyzer # Ag As Au Ba Ca_% Cd Co Cr
30633 Malambo 50404 0 0 0 1832 1.10 0 0 256
30633 Malambo 50404 34 0 0 2159 0.61 0 0 136
30634 Malambo 50404 0 0 0 2222 2.67 28 0 212
30635 Rappa B ext 50404 15 0 0 823 4.56 22 0 262
30636 Rappa B ext 50404 0 54 0 1482 0.43 0 0 2338
30637 Rappa B ext 50404 0 0 0 2430 3.48 30 0 196
30638 Rappa B ext 50404 17 0 0 1290 9.34 0 0 396
30639 Rappa B ext 50404 23 0 0 2124 3.23 24 0 109
30640 Rappa B ext 50404 20 0 0 1583 6.84 28 0 1291
30641 Rappa B ext 50404 0 0 0 608 0.04 21 0 433
30642 Rappa B ext 50404 13 0 0 760 0.09 30 0 273
30643 Rappa B ext 50404 0 0 0 1977 3.39 0 0 108
30644 Rappa B ext 50404 23 0 0 766 0.03 32 0 291
30645 Rappa B ext 50404 16 0 0 676 0.03 32 0 88
30646 Rappa B ext 50404 28 0 0 2911 0.70 61 0 56
30646 Rappa B ext 50404 0 0 0 2173 1.68 0 0 115
Cu Fe_% Hg K_% Mn Ni Pb Pd Rb S Sb Sc
50 3.28 0 2.19 409 153 0 0 56 3404 84 0
0 9.25 0 1.54 912 282 0 0 114 17035 89 106
0 4.12 0 1.42 10422 410 0 0 22 0 77 0
0 3.08 0 0.49 478 249 0 0 6 0 92 206
4040 89.21 0 0.46 0 0 0 0 22 2329 0 0
0 5.19 0 0.69 759 169 0 0 25 0 64 0
0 7.14 0 0.76 1340 157 0 0 6 0 112 204
0 2.86 0 1.18 232 197 0 0 32 0 74 0
0 7.24 0 0.44 3905 592 0 0 6 0 124 178
0 0.17 0 0.55 0 99 0 0 0 0 120 0
0 0.21 0 0.79 0 68 0 0 5 0 106 0
0 2.71 0 0.80 360 141 0 0 15 0 82 0
0 1.70 20 0.39 0 116 0 0 0 0 120 0
0 0.82 0 0.30 0 117 0 0 0 0 139 0
50 14.00 0 0.46 0 265 0 0 37 29843 276 0
0 1.56 0 3.15 301 113 0 0 54 1621 84 0
Se Sn Sr Ti_% V W Zn Zr
0 74 243 0.49 375 0 440 121
14 0 229 0.33 159 0 835 235
0 54 994 0.86 225 0 41 138
0 0 333 0.16 85 0 0 26
25 0 874 0.28 1226 0 0 0
0 0 1706 0.92 103 0 32 32
0 50 563 0.21 184 0 0 71
0 0 1536 0.65 0 0 0 292
0 65 121 0.11 121 0 0 39
0 53 16 0.21 74 0 0 0
0 59 32 0.24 115 0 0 24
0 45 1233 0.38 56 0 21 61
0 87 8 0.40 73 0 0 76
0 60 19 0.24 0 0 0 148
0 92 166 0.06 0 0 0 83
0 37 300 0.26 0 0 53 85
Reading No Time Type Duration Units Sequence SAMPLE LOCATION
1 11/30/2011 6:56 System Check 57.71 cps Final
2 11/30/2011 7:01 Soil 120 ppm Final Blank Si02 Malambo
3 11/30/2011 7:04 Soil 120 ppm Final GBM398-2 Malambo
4 11/30/2011 7:08 Soil 120 ppm Final GBM906-2 Malambo
5 11/30/2011 7:11 Soil 120 ppm Final GBM908-5 Malambo
6 11/30/2011 7:28 Soil 120 ppm Final 30633 Malambo
7 11/30/2011 7:32 Soil 120 ppm Final 30633 Malambo
8 11/30/2011 7:36 Soil 120 ppm Final 30634 Malambo
9 11/30/2011 7:40 Soil 120 ppm Final 30635 Rappa B ext
11 11/30/2011 7:44 Soil 120 ppm Final 30636 Rappa B ext
12 11/30/2011 7:47 Soil 120 ppm Final 30637 Rappa B ext
13 11/30/2011 7:50 Soil 120 ppm Final 30638 Rappa B ext
14 11/30/2011 7:53 Soil 120 ppm Final 30639 Rappa B ext
15 11/30/2011 7:56 Soil 120 ppm Final 30640 Rappa B ext
16 11/30/2011 7:58 Soil 120 ppm Final 30641 Rappa B ext
17 11/30/2011 8:01 Soil 120 ppm Final 30642 Rappa B ext
18 11/30/2011 8:04 Soil 120 ppm Final 30643 Rappa B ext
19 11/30/2011 8:07 Soil 120 ppm Final 30644 Rappa B ext
20 11/30/2011 8:10 Soil 120 ppm Final 30645 Rappa B ext
21 11/30/2011 8:13 Soil 120 ppm Final 30646 Rappa B ext
22 11/30/2011 8:16 Soil 120 ppm Final 30646 Rappa B ext
23 11/30/2011 8:20 Soil 120 ppm Final GBM398-2 Rappa B ext
24 11/30/2011 8:22 Soil 120 ppm Final GBM906-2 Rappa B ext
25 11/30/2011 8:25 Soil 120 ppm Final GBM908-5 Rappa B ext
26 11/30/2011 8:30 Soil 120 ppm Final Blank Sio2 Rappa B ext
INSPECTOR COR 1 COR 2 MISC NOTE User Login Res EScale Flags Ba Ba Error
god 166.04 7.44
Hashim god < LOD 152.58
Hashim god ModCF July 2011 745.74 134.85
Hashim god ModCF July 2011 895.48 149.27
Hashim god ModCF July 2011 2650.3 154.1
Hashim god ModCF July 2011 1831.57 145.64
Hashim god ModCF July 2011 2159.08 200.21
Hashim god ModCF July 2011 2221.95 156.11
Hashim god ModCF July 2011 822.62 146.58
Hashim god ModCF July 2011 1482.17 278.5
Hashim god ModCF July 2011 2430.1 161.79
Hashim god ModCF July 2011 1290.34 172.15
Hashim god ModCF July 2011 2123.82 170.96
Hashim god ModCF July 2011 1583.3 168
Hashim god ModCF July 2011 607.58 110.16
Hashim god ModCF July 2011 760.04 115.24
Hashim god ModCF July 2011 1976.64 158.51
Hashim god ModCF July 2011 765.9 118.93
Hashim god ModCF July 2011 675.71 117.73
Hashim god ModCF July 2011 2911.15 193.5
Hashim god ModCF July 2011 2172.85 140.73
Hashim god ModCF July 2011 639.36 140.57
Hashim god ModCF July 2011 686.56 151.01
Hashim god ModCF July 2011 2391.77 160.51
Hashim god < LOD 152.93
Sb Sb Error Sn Sn Error Cd Cd Error Ag Ag Error Pd Pd Error Zr Zr Error

35.54 18.72 < LOD 27.28 < LOD 15.43 < LOD 9.95 < LOD 10.56 < LOD 13.21
66.57 23.75 35.69 23.46 < LOD 19.33 < LOD 12.46 < LOD 13.24 181.81 14.73
84.1 26.28 52.32 26.08 24.41 14.35 23.83 9.65 < LOD 14.55 98.85 14.78
< LOD 36.13 < LOD 36.41 < LOD 19.67 57.01 9.77 < LOD 13.42 336.71 17.88
84.41 24.34 73.61 24.39 < LOD 19.7 < LOD 12.99 < LOD 13.44 120.86 14.26
89.33 32.98 < LOD 48.51 < LOD 27.02 33.9 12.37 < LOD 17.55 234.72 21.32
76.89 25.5 53.83 25.46 27.84 14.03 < LOD 13.73 < LOD 14.45 138.33 17.92
92.42 26.06 < LOD 38.21 22.07 14.15 15.41 9.34 < LOD 14.29 25.72 14.01
< LOD 68.53 < LOD 68.79 < LOD 38.08 < LOD 26.29 < LOD 26.37 < LOD 43.26
63.62 25.96 < LOD 38.72 30.16 14.4 < LOD 14.06 < LOD 14.47 31.71 19.36
112.12 29.99 50.13 29.66 < LOD 24.1 16.63 10.71 < LOD 16.66 71.2 17.91
73.96 28.01 < LOD 41.36 24.15 15.37 23.16 10.31 < LOD 15.01 291.76 23.47
124.29 29.01 64.74 28.75 28 15.63 20.47 10.4 < LOD 16.06 38.55 14.59
119.78 20.16 53.25 19.39 20.59 10.8 < LOD 10.55 < LOD 11.05 < LOD 13.93
105.97 20.77 59.08 20.16 30.42 11.32 13.3 7.35 < LOD 11.33 23.98 9.88
82 26.2 45.17 25.93 < LOD 20.91 < LOD 14.06 < LOD 14.29 60.77 18.23
119.75 21.56 86.86 21.21 31.87 11.7 22.81 7.77 < LOD 11.93 75.53 10.9
138.58 21.65 59.66 20.76 31.66 11.64 15.79 7.6 < LOD 11.8 148.44 11.92
276.19 33.39 92.46 32.12 60.65 17.47 27.54 11.44 < LOD 17.59 83.28 16.86
84.06 23.1 37.38 22.63 < LOD 18.69 < LOD 12.16 < LOD 12.73 84.64 13.21
90.6 25.22 < LOD 36.92 < LOD 20.49 < LOD 13.42 < LOD 13.87 187.35 15.56
65.41 26.68 < LOD 39.54 23.53 14.68 24.76 9.89 < LOD 14.34 96.45 15
48 25.62 < LOD 38.48 < LOD 21.1 57.26 10.31 < LOD 14.23 363.36 19.19
38.04 18.92 < LOD 27.55 < LOD 15.67 < LOD 10.24 < LOD 10.62 < LOD 13.25
Sr Sr Error Rb Rb Error Pb Pb Error Se Se Error As As Error Hg Hg Error

< LOD 4.02 < LOD 2.48 < LOD 6.61 < LOD 2.97 < LOD 4.72 < LOD 7.3
186.08 8.39 155.72 7.19 67.73 11.83 < LOD 4.82 182.44 14.09 < LOD 11.76
156.57 8.69 1261.31 21.41 30.18 11.79 < LOD 5.35 < LOD 12.38 < LOD 14.2
396.36 12.01 103.95 6.23 361.1 23.22 < LOD 5.35 < LOD 24.07 < LOD 12.08
243.21 9.54 55.94 4.74 < LOD 11.5 < LOD 4.86 < LOD 7.71 < LOD 12.14
228.51 12.38 113.5 8.45 < LOD 16.04 13.79 6.06 < LOD 11.38 < LOD 17.58
994.15 19.19 21.73 3.83 < LOD 12.39 < LOD 4.36 < LOD 8.77 < LOD 12.18
333.36 11.68 5.77 2.85 < LOD 11.23 < LOD 4.83 < LOD 7.42 < LOD 11.84
873.5 31.2 21.68 7.15 < LOD 30.39 25.25 10.94 53.79 17.84 < LOD 29.26
1705.68 25.63 25.12 4.28 < LOD 12.95 < LOD 4.89 < LOD 8.94 < LOD 12.38
562.75 16.82 6.43 3.4 < LOD 13.2 < LOD 6.26 < LOD 8.87 < LOD 15.65
1536.04 25.95 32.36 4.84 < LOD 14.35 < LOD 5.94 < LOD 9.54 < LOD 14.38
120.5 8.3 6.17 3.09 < LOD 13.94 < LOD 5.45 < LOD 8.77 < LOD 14.94
16.11 3.32 < LOD 2.79 < LOD 7.23 < LOD 3.24 < LOD 5.16 < LOD 7.88
31.72 3.94 5.48 2.11 < LOD 7.67 < LOD 3.38 < LOD 5.35 < LOD 7.64
1233 21.94 14.72 3.68 < LOD 12.94 < LOD 5.11 < LOD 8.67 < LOD 13.36
8.34 3.29 < LOD 2.89 < LOD 7.88 < LOD 3.7 < LOD 5.3 19.79 6.68
19.29 3.64 < LOD 3.04 < LOD 7.98 < LOD 3.94 < LOD 5.55 < LOD 7.93
166.36 10.13 37.13 5.13 < LOD 13.89 < LOD 6.6 < LOD 10.22 < LOD 15.78
300.23 9.97 54.3 4.48 < LOD 10.78 < LOD 4.57 < LOD 7.18 < LOD 10.5
193.24 8.93 154.67 7.51 72.96 12.72 < LOD 5.35 180.19 14.83 < LOD 12.63
134.93 8.39 1189.96 21.3 23.76 11.54 < LOD 5.41 14.75 8.31 < LOD 14.79
397.43 12.65 104.27 6.56 351.92 24.17 < LOD 5.83 < LOD 25.73 < LOD 12.92
< LOD 4.07 < LOD 2.42 < LOD 7.5 < LOD 3.05 < LOD 4.88 < LOD 7.25
Au Au Error Zn Zn Error W W Error Cu Cu Error Ni Ni Error Co Co Error

< LOD 8.25 < LOD 8.76 < LOD 51.17 < LOD 17.66 < LOD 31.51 < LOD 21.74
< LOD 13.72 97.63 17.26 < LOD 86.51 207.13 28.65 312.6 45.34 228.62 119.75
< LOD 13.39 55.62 17.68 < LOD 119.68 494.47 44.12 1086.3 79.9 326.98 149.49
< LOD 13.63 216.62 23.52 < LOD 93.59 414.02 37.36 433.63 51.83 204.18 115.73
< LOD 11.09 439.59 30.76 < LOD 92.35 49.82 21.54 153.46 37.61 < LOD 180.91
< LOD 17.46 834.99 55.85 < LOD 145.05 < LOD 50.16 281.95 70.19 < LOD 398.56
< LOD 12.08 40.64 15.28 < LOD 93.95 < LOD 32.71 410.17 53.02 < LOD 211.82
< LOD 12.81 < LOD 18.52 < LOD 83.47 < LOD 31.14 248.56 45.86 < LOD 186.78
< LOD 33.03 < LOD 102.19 < LOD 231.44 4040.48 184.68 < LOD 247.21 < LOD 1674.59
< LOD 13.58 32.27 15.73 < LOD 86.84 < LOD 31.44 169.02 43.73 < LOD 241.26
< LOD 14.9 < LOD 27.94 < LOD 121.14 < LOD 39.61 157.16 53.84 < LOD 320.36
< LOD 14.74 < LOD 22.11 < LOD 106.72 < LOD 36.89 196.52 48.77 < LOD 195.02
< LOD 14.76 < LOD 25.76 < LOD 119.59 < LOD 37.84 592.1 70.31 < LOD 310.79
< LOD 7.79 < LOD 9.26 < LOD 53.83 < LOD 17.38 98.65 22.31 < LOD 38.52
< LOD 7.36 < LOD 9.54 < LOD 55.47 < LOD 19.38 67.89 21.53 < LOD 42.07
< LOD 12.97 21.49 13.99 < LOD 95.6 < LOD 31.78 140.78 40.97 < LOD 177.95
< LOD 8.81 < LOD 10.59 < LOD 60.32 < LOD 20.62 116 26.2 < LOD 110.24
< LOD 10.04 < LOD 9.94 < LOD 56.86 < LOD 20.84 116.73 25.96 < LOD 79.1
< LOD 17.81 < LOD 27.65 < LOD 121.5 50.18 30.74 264.57 65.74 < LOD 456.71
< LOD 12.07 52.81 12.99 < LOD 70.53 < LOD 26.96 113.11 31.13 < LOD 120.46
< LOD 14.35 79.56 17.34 < LOD 98.01 204.67 30.38 316.24 48.17 < LOD 188.34
< LOD 14.41 63.76 18.55 < LOD 120.37 491.9 45.03 934.82 77.14 283.85 148.68
< LOD 13.66 209.69 24.52 < LOD 101.12 409.73 39.54 433.61 54.58 < LOD 177.8
< LOD 8.39 < LOD 8.26 < LOD 51.91 < LOD 17.54 < LOD 28.71 < LOD 18.64
Fe Fe Error Mn Mn Error Cr Cr Error V V Error Ti Ti Error Sc

99.26 33.6 < LOD 45.49 < LOD 35.08 < LOD 22.17 < LOD 65.67 < LOD
31585.48 428.75 425.43 89.07 186.58 35.48 67.41 37.03 3272.03 150.48 < LOD
41083.08 534.23 612.38 109.94 51.72 31.6 125.03 44.64 6173.3 190.13 122.48
27927.87 413.63 373.47 89.64 108.43 33.17 < LOD 72.83 3061.02 185.72 < LOD
32771.97 443.25 409.16 92.27 255.89 39.49 375 53.28 4900.66 193.32 < LOD
92533.34 984.23 912.46 170.05 136.06 32.5 158.77 40.95 3327.12 155.62 106.46
41162.95 527.29 10422.3 334.4 211.76 45.31 225.27 79.13 8584.97 304.85 < LOD
30798.29 457.91 478.34 99.75 261.68 35.85 84.54 29.46 1615.91 112.29 206.36
892065.19 4142.05 < LOD 685.98 2337.51 145.03 1225.61 116.48 2808.32 335.13 < LOD
51885.27 599.45 759.13 121.84 195.85 38.75 102.71 56.25 9216.41 242.4 < LOD
71446.66 786.3 1340.13 167.7 396.48 43.8 183.84 38.99 2082.14 142.61 203.88
28647.29 475.53 231.6 93.41 108.7 29.71 < LOD 68.99 6502.8 195.62 < LOD
72424.77 763.79 3904.67 245.18 1291.43 66.86 121.41 39.42 1146.85 139.54 178.18
1689.91 87.5 < LOD 60.44 432.75 39.86 73.81 31.14 2105.3 118.68 < LOD
2077.06 99.4 < LOD 64.54 273.26 34.9 114.65 34.91 2435.48 130.6 < LOD
27146.96 435.81 359.58 92.54 107.91 29.18 55.69 36.6 3829.34 152.5 < LOD
16979.98 279.82 < LOD 74.79 290.77 37.63 72.75 37.09 3977.99 152.85 < LOD
8207.23 194.91 < LOD 67.35 88.02 27.65 < LOD 44.01 2400.91 118.39 < LOD
139969.67 1131.91 < LOD 191.77 56.23 35.2 < LOD 45.39 643.74 109.41 < LOD
15578.71 292.52 301.15 76.28 115.21 30.48 < LOD 56.68 2554.03 148.77 < LOD
32163.02 452.82 373.95 89.72 141.92 31.77 51.89 33.63 2858.78 137.29 < LOD
38935.39 532.64 559.24 108.97 69.23 30.38 114.11 41.57 5400.32 175.43 131.81
27574.66 432.4 403.58 95.9 83.88 29.63 < LOD 64.19 2793.78 165 < LOD
90.61 33.41 < LOD 44.42 < LOD 35.24 < LOD 22.82 < LOD 65.07 < LOD
Sc Error Ca Ca Error K K Error S S Error

22.78 < LOD 134.14 198.47 106.34 < LOD 277.8


107.09 26592.69 490.57 19139.66 583.45 < LOD 556.48
76.1 28041.13 527.59 45794.63 892.44 < LOD 590.64
83.7 15839.86 396.45 34234.44 752.78 < LOD 549.2
73.62 10979.14 332.05 21912.27 608.35 3403.67 546.44
41.08 6054.39 252.45 15439.9 512.3 17035.34 1041.24
115.1 26741.49 508.22 14206 530.95 < LOD 510.1
90.72 45599.1 605.29 4911.3 328.14 < LOD 540.2
112.36 4342.22 367.3 4645.72 527.48 2329.32 907.78
125.28 34839.45 558.79 6940.91 387.4 < LOD 544.89
132.81 93361.55 904.23 7614.05 429.26 < LOD 647.15
108.3 32331.79 501.62 11820.31 445.29 < LOD 505.23
114.67 68367.2 774.52 4373.05 347.04 < LOD 621.33
24.65 352.9 112.43 5477.99 302.49 < LOD 374.86
29.38 884.92 132.3 7870.28 353.69 < LOD 359.94
112.04 33892.32 511.75 8000.37 378.15 < LOD 436.83
29.29 308.64 112.68 3926.39 275.44 < LOD 368.86
28.04 344.65 104.61 3043.21 239.67 < LOD 294.08
70.44 7004.57 285.53 4570.73 341.96 29842.98 1507.41
81.72 16837.44 391.37 31454.36 700.2 1621.26 431.12
97.85 23055.57 446.2 17031.46 538.36 < LOD 530.12
69.89 24591.99 481.49 41302.24 825.05 < LOD 562.12
77.61 13734.26 358.24 29744.65 681.95 < LOD 462.16
22.32 < LOD 122.59 189.53 102.55 < LOD 261.91

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