CHEMISTRY

JEE ADVANCED SAMPLE PAPER

Chapter 20. Electrochemistry

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1. How much silver will be obtained by that quantity of current which displaces 5.6 litre of H2?
(a) 54 g
(b) 13.5 g
(c) 20 g
(d) 108 g

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 JEE Advanced Sample Paper – 20. Electrochemistry

2. The conductivity of 0.01 mol/dm3 aqueous acetic acid at 300 K is 19.5×10–5 ohm–1 cm–1 and the
limiting molar conductivity of acetic acid at the same temperature is 390 ohm–1 cm2 mol–1. The
degree of dissociation of acetic acid is:
(a) 0.5
(b) 0.05
(c) 5×10–3
(d) 5×10–7

3. The half-cell reaction for the corrosion,


2H+ +  O2 + 2e– → H2O; Eo = 1.23V

Fe2+ + 2e– → Fe(s); Eo = –0.44 V
o
Find the ∆G (in kJ) for the overall reaction:
(a) –76 kJ
(b) –322 kJ
(c) –161 kJ
(d) –152 kJ

4. Consider the following cell reaction :

2Fe(s) + O2(g) + 4H+(aq.) → 2Fe2+(aq.) + 2H2O(l) Eo = 1.67 V
At [Fe2+] = 10–3 M, P(O2) = 0.1 atm and pH = 3, the cell potential at 25oC is :
(a) 1.47 V
(b) 1.77 V
(c) 1.87 V
(d) 1.57 V

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 JEE Advanced Sample Paper – 20. Electrochemistry

5. For the following electrochemical cell at 298 K, Pt(s) | H2(g,1bar)| H+ (aq,1M)

4+ 2+
∥M (aq), M (aq)| Pt(s)
    
Ecell = 0.092 V when   
    

Given : EoM4+/M2+ = 0.151 V; 2.303  = 0.059 V The value of x is

(a) – 2
(b) – 1
(c) 1
(d) 2

6. We observe blue colour if :

(a) Cu electrode is placed in the AgNO3
(b) Cu electrode is placed in the ZnSO4 solution
(c) Cu electrode is placed in the dil. HNO3
(d) Cu electrode is placed in dil. H2SO4

7. Fuel cell involves following reaction(s) :

(a) O2(g) + 2H2O(l) + 4e– → 4OH–(aq.) (at cathode)
(b) O2(g) + 2H2O(l) + 4e– → 4OH–(aq.) (at anode)
(c) 2H2(g) + 4OH–(aq.) → 4H2O(l) + 4e–(at anode)
(d) 2H2(g) + 4OH–(aq.) → 4H2O(l) + 4e–(at cathode)

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 JEE Advanced Sample Paper – 20. Electrochemistry

8. Match the Column-I Column-II

Column-I Column-II

(a) Kohlrausch law (p)  m/ m
 
(b)  m (q)  × 
 
(c) K(kappa) (r)  mCa3(PO4)2 = 3λoCa2+ + 2λoPO3–4

(d) α (s) K× 


9. The conductance of a 0.0015 M aqueous solution of a weak monobasic acid was determined by
using a conductivity cell consisting of platinised Pt electrodes. The distance between the electrodes
is 120 cm with an area of cross section of 1 cm2. The conductance of this solution was found to

be 5×10–7 S. The pH of the solution is 4. The value of limiting molar conductivity ( ) of this
weak monobasic acid in aqueous solution is Z×102 S cm–1 mol–1. the value of Z is

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 JEE Advanced Sample Paper – 20. Electrochemistry

Passage
10. The driving force ∆G diminishes to zero on the way to equilibrium, just as in any other

 ∆

spontaneous process. Both ∆G and the corresponding cell potential     are zero when

the redox reaction comes to equilibrium. The Nernst equation for the redox process of the cell may
be given as :

E = Eo   log Q

The key to the relationship is the standard cell potential Eo, derived from the standard free energy
changer as :
∆ 
Eo =  

At equilibrium, the Nernst equation is given as :

Eo =  log K


I. On the basis of information available for the reaction:

 
 Al + O2 →  Al2O3; ∆G = –827 kJ/mol of O2 the minium emf required to carry out an
 
electrolysis of Al2O3 is :
(Given: 1 F = 96500 C)
(a) 2.14 V
(b) 4.28 V
(c) 6.42 V
(d) 8.56 V

II. The equilibrium constant Kc will be equal to Q, When :

(a) E = Eo
(b) RT/nF = 1
(c) E = 0
(d) Eo = 1

III. The nature of graph of Eocell against log Kc is a/an :

(a) straight line
(b) parabola
(c) hyperbola
(d) elliptical curve

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 JEE Advanced Sample Paper – 20. Electrochemistry

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 JEE Advanced Sample Paper – 20. Electrochemistry

Answer Keys

Q1 Q2 Q3 Q4 Q5
(a) (b) (b) (d) (d)

Q6 Q7 Q8 Q9 Q10
(a), (c) (a), (c) (a) - r Z = 2 Ⅰ. (a)
(b) - s Ⅱ. (c)
(c) - q Ⅲ. (a)
(d) - p

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