Beruflich Dokumente
Kultur Dokumente
1. What energy changes occur when chemical bonds are formed and broken?
A. Energy is absorbed when bonds are formed and when they are broken.
B. Energy is released when bonds are formed and when they are broken.
C. Energy is absorbed when bonds are formed and released when they are broken.
D. Energy is released when bonds are formed and absorbed when they are broken.
A. 0.36
B. 2.3
C. 9.0
D. 11
A. 910
B. 130
C. –130
D. –910
III. The products are more energetically stable than the reactants.
A. I and II only
D. I, II and III
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5. A sample of a metal is heated. Which of the following are needed to calculate the heat absorbed
by the sample?
A. I and II only
D. I, II and III
6. The average bond enthalpies for O—O and O==O are 146 and 496 kJ mol–1 respectively.
What is the enthalpy change, in kJ, for the reaction below?
A. – 102 B. + 102
C. + 350 D. + 394
7. When the solids Ba(OH)2 and NH4SCN are mixed, a solution is produced and the
temperature drops.
Cu(s) + 1
2
O2(g) → CuO(s)∆Hο = –156 kJ
2Cu(s) + 1
2
O2(g) → Cu2O(s)∆Hο = –170 kJ
what is the value of ∆Hο (in kJ) for the following reaction?
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2CuO(s) → Cu2O(s) + 2
O2(g)
A. 142 B. 15
C. –15 D. –142
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9. Which combination of ionic charge and ionic radius give the largest lattice enthalpy for an ionic
compound?
10. The lattice enthalpy values for lithium fluoride and calcium fluoride are shown below.
Which of the following statements help(s) to explain why the value for lithium fluoride is less
than that for calcium fluoride?
A. I only
B. II only
C. I and II
D. Neither I nor II
12. Which type of reaction is referred to in the definition of standard enthalpy change of formation?
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13. What is the correct order of decreasing entropy for a pure substance?
15. Which is a correct equation to represent the lattice enthalpy of magnesium sulfide?
16. Which equation represents a change with a negative value for DS?
B. H2O(s) ® H2O(g)
17. The expression for the standard free energy change of a reaction is given by
What are the signs for DHӨ and DSӨ for a reaction that is spontaneous at all temperatures?
DHӨ DSӨ
A. + –
B. – +
C. + +
D. – –
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18. Which of the following is (are) important in determining whether a reaction occurs?
A. I only
B. II only
C. Both I and II
D. Neither I nor II
19. Consider the reaction between solid CaCO3 and aqueous HCl. The reaction will be speeded up
by an increase in which of the following conditions?
III. Temperature
A. I only
D. I, II and III
20. Excess magnesium was added to a beaker of aqueous hydrochloric acid on a balance. A graph
of the mass of the beaker and contents was plotted against time (line 1).
Mass
Time
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II. The same volume of a more concentrated solution of hydrochloric acid
A. I only
B. II only
C. III only
21. The rate of a reaction between two gases increases when the temperature is increased and a
catalyst is added. Which statements are both correct for the effect of these changes on the
reaction?
22. Which of the following is (are) altered when a liquid at its boiling point is converted to a gas at
the same temperature?
A. I only
B. II only
C. III only
D. I and II only
23. Based on the definition for rate of reaction, which units are used for a rate?
A. mol dm–3
B. mol time–1
C. dm time–1
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24. The reaction between NO2 and F2 gives the following rate data at a certain temperature.
What is the order of reaction with respect to NO2 and F2?
rate = k[A]2[B]2
III. Doubling the concentration of A would have the same effect on the rate of reaction
as doubling the concentration of B.
A. I and II only
D. I, II and III
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27. Values of a rate constant, k, and absolute temperature, T, can be used to determine the activation
energy of a reaction by a graphical method. Which graph produces a straight line?
A. k versus T
B. k versus 1
T
C. ln k versus T
D. ln k versus 1
T
Rate = k[P][Q]
29. The reaction 2X(g) + Y(g) ® 3Z(g) has the rate expression
rate = k [X]2[Y]0
A. 6 B. 9
C. 12 D. 18
30. A reaction occurs in four steps. The steps and their rates are shown in the table
Step Rate
1 0.01 mol dm–3 s–1
2 0.10 mol dm–3 s–1
3 0.01 mol dm–3 min–1
4 0.10 mol dm–3 min–1
A. Step 1 B. Step 2
C. Step 3 D. Step 4
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31. For the reaction below
A. 5.0 B. 10 C. 15 D. 100
is 0.25 at 440°C. What would the value of the equilibrium constant be for the following reaction
at the same temperature?
A. 0.25 B. 0.50
C. 2.0 D. 4.0
33. Hydrogen and carbon dioxide react as shown in the equation below.
Temperature / K Kc
500 7.76×10–3
700 1.23×10–1
900 6.01×10–1
B. H2O(g) and CO(g) are more stable than H2(g) and CO2(g).
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34. The expression for the equilibrium constant for a reaction is
Kc =
[B][C]
[A]2
At a certain temperature the values of [A], [B] and [C] are all 0.2 mol dm–3. What happens to
the value of Kc when all three values are doubled to 0.4 mol dm–3?
A. It is halved.
C. It doubles.
35. A 1.0 dm3 reaction vessel initially contains 6.0 mol of P and 6.0 mol of Q. At equilibrium 4.0
mol of R is present. What is the value of Kc for the following reaction?
A. 0.11 B. 0.25
C. 0.44 D. 4.00
A. 1.0×10–2
B. 10
C. 33
D. 1.0×102
37. A liquid and its vapour are at equilibrium inside a sealed container. Which change will alter the
equilibrium vapour pressure of the liquid in the container?
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38. I2(g) + 3Cl2(g) 2ICl3(g)
[ICl 3 ]
A. Kc =
[I 2 ][Cl 2 ]
2[ICl 3 ]
B. Kc =
3[I 2 ][Cl 2 ]
2[ICl 3 ]
C. Kc =
[I 2 ] + 3[Cl 2 ]
2[ICl 3 ] 2
D. Kc =
[I 2 ][Cl 2 ]3
According to the above information, what temperature and pressure conditions produce the
greatest amount of SO3?
Temperature Pressure
A. low low
B. low high
C. high high
D. high low
40. Which statement(s) is/are true for a mixture of ice and water at equilibrium?
III. The same position of equilibrium can be reached by cooling water and heating ice.
A. I only
C. II only
D. III only
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