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Terminologies
Introduction
Before you get into the thick of things, let us make sure you know some of the terminologies
You have learnt about the basic concept of physical changes in your Lower Secondary that are used throughout this module.
Science course, the arrangement of particles in Solids, Liquids, and Gases. For this module
you will be studying the particle theory to explain the behavior of gases and liquids, physical Boiling Is the change from liquid to a gas or vapor.
separation techniques, and the concept to separate different mixtures, and their solubility. Condensation Is the change from gas to a liquid.
You will also define the terms solute, solvent, saturated, unsaturated, and supersaturated Chromatography Is the most sensitive techniques that can be used for
solution. You will also interpret and calculate the solubility of substances using solubility identifying and separating components or mixture.
curves as well as given data.
Diffusion Is the rate at which gas travels across a room or particles mix
by colliding with each other and bouncing off in all direction.
Evaporation Is the change of a liquid into gas without boiling.
Fractional distillation This is to separate two or more liquids that are mixed or
separating two immiscible liquids.
Freezing Is the change from liquid to solid.
Learning outcomes Heterogeneous Is a mixture of more than one phase that can be observed in
the system.
Homogeneous Is a mixture of only one phase that can be observed in the
After going through the module, you are expected to: mixture.
Ideal gas A gas that behaves exactly as described by the gas laws.
define physical change, arrangement of particle and their shapes in three states of Matter Is anything that occupies space and has mass.
matter. Apply the particle theory to explain the behavior of gases and liquids. Melting Is the change from solid to liquid.
calculate the relationship between temperature, pressure, and volume using Boyles, Real gas A gas, especially at high pressure or low temperatures do not
Charles, Combined and Ideal gas laws. behave quite ideally.
demonstrate an understanding of various physical separation techniques and apply Residue Is the trapped solid particles in the filter.
the concept to separate different mixture. Saturated solution Is a solution that cannot dissolve anymore solute at a given
define the terms solubility, solute, solvent, saturated, unsaturated, and temperature.
supersaturated solutions. Investigate and collect data on solubility of various salts Simple distillation This is to collect the pure liquid from a solution.
and gases, plot the solubility curves.
Solubility Is the amount of solute that will dissolve in 100 grams of a
calculate the solubility of substances using solubility curves as well as given data.
solvent, at a given temperature.
Sublimation Is the change from solid directly to gas without going through
the liquid state.
Unsaturated solution Is a solution that contains less solute dissolved at that
temperature than a saturated solution.
Gases
The Kinetic theory model is used to explain how a substance changes from one state to
another. For example, if you open a bottle of perfume, the aroma soon reaches the nose of To here
From here
anyone nearby; it means the molecules of the fragrance have been diffused from the bottle. Movement of particles.
This diffusion is a simple evidence that molecules move. The word kinetic means motion.
States of Matter
The kinetic theory says that the tiny particles in all forms of matter are in constant motion. Matter is anything that occupies space and has mass. They can be solid, liquid, and gas.
These particles may be atoms, ions, or molecule of gases, liquids, or solids. For the present, They are also classified as:
let us concentrate on the kinetic theory as it applies to gases. We know that gas is easily metals, compounds and mixtures.
compressed and fills whatever container it is in. metals and non- metals.
James Clerk Maxwell (1813-79) and Ludwig Boltzmann (1844-1906) studied and found a How are particles arranged?
way to describe how gasses behave by considering them as made up of tiny particles. Their
ideas were into the Maxwell-Boltzmann kinetic theory of gasses. Later this theory was The particles in a solid are
expanded to include liquids and solid. Today this theory is simply known as the kinetic arranged in a fixed pattern or
theory. lattice. Strong forces hold them
together. So they cannot leave
their positions. The only
The kinetic theory states that: solid movements they make are tiny
matter is made from tiny particles. vibrations to and from.
the particles at a temperature above -273K (Kelvin) are moving all the time. They
possess the energy of motion, which is called kinetic energy. The particles in a liquid can move
the rate of movement of the particles is linked to their temperature. The particles about they slide past each other.
have low kinetic energy and move slowly at a low temperature, the particles with They are still close together, but
not in lattice. The forces that hold
higher kinetic energy move quickly at a higher temperature.
them together are weaker than in
particles can be attracted to each other and can be of different weights and sizes. liquid a solid.
heavier particles move slowly than lighter particles. The particles in a gas are far apart,
and they move about quickly.
Particles on the move There are almost no forces
holding them together. They
In rocks and other solids, the particles are not free to move around. However, in collide with each other and
liquids and gases, they moved freely. They collide with each other and bounce off in bounce off in all directions.
all directions. So the path of one particle, in a liquid or gas, could look like this:
gas
Chemical changes
Properties of matter Chemical changes are changes in the composition and structure of a substance. They
Particles are always moving. Rocks air and water look very different. They have one big thing are always accompanied by energy changes.
in common. They are all made of very tiny pieces. These pieces are called particles.
Everything around you is made of particles – and so are you !
CHEMICAL CHANGE PHYSICAL CHANGE
Matter exist in three states - solid, liquid and gas At least one new substance is formed. No new substance is formed.
Difficult to reverse (hard to un-boil an Easily reversed (melt an ice and freeze
Property Solid Liquid Gas egg). again).
Mass Definite Definite Definite Generally a large input or output of Relatively small energy changes
Shape Definite Indefinite Indefinite energy (Burning of natural gasses). involved
Volume Definite Indefinite Indefinite (Evaporate alcohol, dissolve sugar in
Compressibility Almost Almost Compressible
water).
incompressible incompressible
Arrangement of Compact Near each other Far from each Change of states of matter
Particles other
Motion of the Very little motion Moderate motion Fast moving
1. Melting is the change from solid to liquid
particles
When solid is heated, its particles get more energy and vibrate more. This makes the solid
Physical properties
expand. At the melting point, the particles vibrate so much that they break away from their
Physical properties of matter are those properties that can usually be observed with our
positions. The solid turns liquid.
senses. Some common examples are color, odor, solubility in water, density, melting point,
taste, boiling point and hardness.
Physical changes
In general physical changes alter the physical properties of matter, but the composition
remains constant. Some examples are breaking glass, cutting wood, melting ice and
magnetizing a piece of metal. In some cases, the process that caused the change can be
easily reversed and the substance regains its original form.
Chemical properties
Chemical properties are those properties that are observed in regard to whether or not a
substance reacts with other substances. For example, iron rusts in moist air, nitrogen does
not burn, gold does not rust, sodium reacts with water, and water can be decomposed by
an electric current.
4. Evaporation is the change of a liquid into gas without boiling
2. Boiling is the change from liquid to a gas or vapor
The particle in a liquid has different amounts of energy. Some have less kinetic energy than
When liquid is heated, its particles get more energy and move faster. They bump into each others and move more slowly than them. Others have more kinetic energy and move
other more often, and bounce further apart. This makes liquid expand. At the boiling point, quickly. At the surface of the liquid the particles with the largest amount of kinetic energy
the particles get enough energy to overcome the forces between them. They break away to move so fast that they can pull away from the force of attraction that exists between them
form gas. and other liquid particles and escape into the air as vapor. If a liquid is warmed the energy
of all particles is increased and more particles acquire enough energy to escape from the
surface. This increases the rate of evaporation. This is the opposite of condensation.
Boils
below
boiling point
liquid gas
3. Freezing is the change from liquid to solid
If a liquid is cooled its particles lose kinetic energy. This makes them move more slowly. If
The graph below shows the heating curve.
the liquid is cooled down enough each particles stops moving and vibrates about a fixed
point. When this happens the liquid frozen and turns into a solid .
Freezing point
Liquid Solid
The graph above shows the ice is melting. Once melting starts, the temperature stays at 0°C
until all ice has melted. When the water starts to boil, the temperature stays at 100°C until
all the water has turned to steam. So melting and boiling points are clear and sharp.
condensation
1. Kinetic theory
cool _____________________________________________________________________
2. Physical change
gas liquid
_____________________________________________________________________
6. Sublimation is the change from solid directly to gas without going through
the liquid state. 3. Chemical change
It occurs because particles at the surface of the solid have enough energy to break away _____________________________________________________________________
from the solid and escape as a gas. Iodine and ammonium chloride are two other examples
of solids that sublime.
The graph below shows the temperature of a liquid when heated from room
temperature.
solid gas
Now, check what you have just learnt by trying out the learning activity below!
C)
S
Temperat
Q R
Which part of the graph shows that liquid is boiling?
P
a) PQ b) QR
c) RS d) ST
The diagram below represents the physical changes between the three states of
matter.
Solid
A B C
A
D
Liquid A
Gas
A. __________
B. __________
C. __________
D. __________
E. __________
Thank you for completing your learning activity 1. Check your work. Answers are
at the end of this module.
Diffusion
Ammonia Hydrochloric
Diffusion is the rate at which gas travels across a room or particles mix by colliding with each gas (NH3) acid (HCl)
other and bouncing off in all directions.
Gases do not all diffuse at the same rate, every time. It depends on these two factors:
White dense fumes
1. The mass of the particles
The lower the mass of its particles, the faster a gas will diffuse.
2. The temperature The gases diffuse along the tube. White smoke forms where they meet.
The higher the temperature, the faster a gas will diffuse.
The relative rates at which two gasses diffuse is explained by Graham’s law, shown here:
The molar mass of an element is the mass of one mole of atoms of the
elements.
Look at the table below you will notice the relationship between the value of atomic mass
(Ar) and the molar mass of a substance. The molar mass is equal to the relative atomic mass
of the element in grams. Where:
RA = rate of effusion/diffusion of gas A
RB = rate of effusion/diffusion of gas B
Element Atomic mass (Ar) Molar mass
MA = molar mass of gas
aluminium 27 27g MB = molar mass of gas B
carbon 12 12g
neon 20 20g
oxygen 16 16g
Molar mass of some elements.
Examples:
The particle of hydrogen chloride gas is twice as heavy as those in ammonia gas. So which
gas do you think will diffuse faster? Let us see:
Cotton wool soaked in ammonia solution is put into one end long tube. It gives off
ammonia gas.
At the same time, cotton wool soaked in hydrochloric acid is put into other end of
the tube. It gives off hydrogen chloride gas.
Now, check what you have just learnt by trying out the learning activity below!
Learning Activity 2
1. Define diffusion.
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___________________________________________________________________
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3. Which gas effuses faster, hydrogen or chlorine? How fast? Explain your
answer.
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___________________________________________________________________
Thank you for completing your learning activity 2. Check your work. Answers are
at the end of this module.
Gas laws Then P1V1 = P2V2 at a constant temperature.
Application of Graham’s Law of Diffusion/Effusion of Gases:
Where:
The rate of diffusion of a gas is inversely proportional to the square root of its molecular P1 = initial pressure
mass. P2 = new pressure
V1 = initial volume
V2 = new volume
Example:
Given the volume of a gas at 200mL at 1.05 atmospheric (atm) pressure, calculate the
volume of the same gas at 1.01atm. The temperature is held constant.
Boyle’s Law
Robert Boyle, a seventeenth-century English scientist, found that the volume of a gas
decreases when the pressure on it increases, and vice versa, when the temperature is held
constant.
If the temperature remains constant, the volume of a gas varies inversely as the
pressure changes.
Charles’ Law Example:
Jacques Charles’s, a French chemist of the early nineteenth century discovered that volume The volume of a gas at 20°C is 500mL. Find its volume at standard temperature if the
of a gas changes with temperature if the pressure is remained constant. pressure of the gas is held constant.
If the pressure remains constant, the volume of a gas varies directly as the absolute
temperature in Kelvin.
Where:
V1 = initial volume
V2 = new volume
T1 = initial temperature
T2 = new temperature
Zero corresponds to -2730 in Celsius scale. The scale is called the Kelvin or the Combined Gas Law
absolute zero. A degree Kelvin has the same magnitude as degree Celsius. However,
there are no negative readings on the Kelvin scale. A comparison of Celsius and the The volume of a gas is greatly affected by changes in pressure and temperature; hence,
Kelvin scale is shown below. temperature and pressure at the time of measurement must always be specified. In this
lesson, you will learn more about the Combined Gas Law, which connects the variables
To change pressure, temperature and volume of gas. Also, you will learn about Gay-Lussac's Law,
Kelvin to degree Celsius or degree Celsius to Kelvin: which describes how changing the temperature of a gas that is kept at constant volume
K= °C + 273 or °C = K - 273 affects the pressure of the gas.
Because pressure and temperature will change from day to day and from location to
Kelvin scale Degree Celsius scale
location, it is common to use more than one of the gas laws to determine the resulting
Absolute zero 00C -2730C volume of the gas. If we combine the relationships expressing Boyle’s Law, V α 1 / P, and
Freezing point of water 273K 00C Charles’ Law, V α T / P, we obtain the relationship: V α T / P.
Boiling point 373K 1000C
The formula for the Combined Gas Law can be expressed as: P 1V1T2 = P2V2T1, where the
subscript of 1 refers to the original conditions while 2 refers to the new conditions.
The Ideal Gas Law
Certain hair spray products are packaged in aerosol cans. Serious accidents could occur if
you throw the empty cans into the fire because the pressurized gas could explode. These
cans usually have a printed warning such as “Do not puncture or incinerate” but users
seldom read what is on the label.
Example:
A gas that behaves exactly as described by the gas laws is called an ideal gas. Many gases,
A cylinder of compressed oxygen gas has a volume of 30L and 100atm pressure at 27°C. The especially at high pressure or low temperatures do not behave quite ideally; hence, they are
cylinder is cooled until pressure is 5atm. What is the new temperature of the gas in the called real gases. This lesson applies the gas laws covered in Boyle’s and Charles’ law to
cylinder? derive the Ideal Gas Law and analyze how it governs ideal gas behavior.
Example:
A rigid steel cylinder with a volume of 20L is filled with nitrogen gas to a final pressure of
200atm at 27°C. How many moles of nitrogen gas does the cylinder contain?
Solution:
First we convert degrees Celsius to degrees Kelvin scale:
27°C + 273 = 300K
Since we want to find the moles of nitrogen (N 2) gas, we may rearrange the ideal gas law to
obtain the number of moles. (n)
Now, check what you have just learnt by trying out the learning activity below!
Learning Activity 3
4. A container of gas has a volume of 10L and is at a pressure of 2.0atm at 30°C.
What size of the container would be needed for the same amount of gas at a
Using the law of gases, calculate the following problem: pressure of 4.0atm at 20°C?
1. A balloon is filled with 30L of helium gas at 1atm. What is the volume when balloon
rises to an altitude where the pressure is only 0.25atm?
A pure substance has no particles of any other substance mixed with it. In real life, very
few substances are 100% pure. For example tap water contains small amount of many
different particles.
Thank you for completing your learning activity 3. Check your work. Answers are
at the end of this module.
Look at the example below.
Pure Substances and Mixtures
Elements cannot be broken down into simpler substances which are made up of same kind of atoms
or molecules and can be divided into metals or non-metals.
Compounds are made up of two or more elements chemically joined together. Mixture contains more than one substance. The substances
are just mixed together, and not chemically combined.
Pure and Impure Substances
For example:
What is a pure substance?
Air is a mixture of nitrogen, oxygen, and small amounts of amounts of other
gases. I likeyoubut we are from
We cannot be together.
Shampoo is a mixture of several chemicals and water. different states. It will
never work.
Oh but we can.
That was your
Two types of Mixture solution.
1. Homogeneous is mixture only one phase that can be observed in the mixture.
When you mix sugar with water, the sugar seems to disappear. It is because its particles
spread all through the water particles, like this as shown in the diagram below.
Muddy water The sugar has dissolved in the water, giving a mixture called solution.
Sugar is the solute and water is the solvent.
Solutions Solute plus solvent equals solution.
You cannot get sugar out again by filtering.
Sugar is more soluble in hot water than cold water.
A soluble solid usually gets more soluble as the temperature rises.
A solution is called saturated when it can dissolve no more solute at that given
temperature.
Solute is the substance that dissolves in the solution.
Solvent is the substance that has greater amount and dissolve the solute.
Thank you for completing your learning activity 4. Check your work. Answers are at the
end of this module.
Now, check what you have just learnt by trying out the learning activity below! Separating Mixture
As you have learnt in the previous topic, most of the things around us are not pure. They
are mixed with other substances. What method is used to separate different substances? It
Learning Activity 4 depends on whether the solid dissolved, and how its solubility changes with temperature.
_____________________________________________________________________
Separation of a Solid – Liquid Mixture
3. Homogeneous
Let us look at some different ways to separate mixture.
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1. By filtering
For example, chalk is insoluble in water. So it is easy to separate by filtering. The chalk is
trapped in the filter paper, while the water passes through. The trapped solid particles in
the filter is called the residue. The water is the filtrate.
4. By sublimation
2. By crystallization
It is the process of solid changing directly into gas without going through the liquid state.
You can obtain many solids from their solutions by letting crystals form. The process is called Ammonium salts, iodine and naphthalene are examples of solids that sublime. Sublimation
crystallization. It works because soluble solids tend to be less soluble at lower can be used to separate mixtures containing substances that will sublime and those that will
temperatures. For example: not sublime.
2. Heat the mixture gently. The ammonium chloride will sublime and condense on the
cooler parts of the funnel as solid crystal. The sodium chloride crystals will remain
inside the evaporating dish.
For some substances, the solubility changes very little as the temperature falls. So
crystallization does not work for these. For example, salt.
5. By distillation
Ways on how to separate two or more liquids with different boiling points.
In the last process of separation, you got salt from the mixture of salt and water. What
happened to the water? If we want to collect it, we can distil the mixture. The water is
evaporated. The steam given off is condensed and collected as pure water.
6. Chromatography
One of the most sensitive techniques that can be used for identifying and separating
components or mixture is chromatography. We can use chromatography to:
Example:
You could separate how many different dyes are there in black ink.
Now, check what you have just learnt by trying out the learning activity below!
Learning Activity 5
4. Paper chromatography
. . . . .
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. . . .
5. Explain how fractional distillation works.
. . . .
__________________________________________________________________
__________________________________________________________________
. . . . . . . .
A B C D E RED BLUE YELLOW
6. How would you obtain pure water from sea water?
__________________________________________________________________
7. Choose from the list the most suitable method for each of the following _______________1. Which of the substances A - E contains one basic
separations: color?
chromatography dissolving _______________2. Which contains all three basic colors?
distillation evaporation
_______________3. The solvent was propanone. Which of the three basic
filtration fractional distillation colors is the most soluble in propanone?
_________________4. To obtain a sample of pure water from the tap water. Thank you for completing your learning activity 5. Check your work. Answers are
at the end of this module.
Solubility
Solids solute usually gets more soluble in water as the temperature rises. The opposite is
Solubility is the amount of solute that will dissolve in 100 grams of a solvent, at a given true for gases.
temperature.
Solubility of Solids and Gases Look at the graph below: Gases have different solubilities at different temperatures.
The solubility of a substance is the quantity of a substance that will dissolve in a certain Generally, as the temperature increases, the solubilities decrease. Notice that Oxygen,
volume of a solvent in a given temperature. Nitrogen, and Nitric oxide is insoluble at 100°C.
For example:
solubility of solids usually increases with temperature.
solubility of decreases with the increasing temperature.
Factors affecting solubility of solids in liquids
The solubility of a solid in a liquid depends on the nature of the solid and the liquid.
It also depends on the temperature. Most solids dissolve more quickly at higher
temperature.
The solubility of most substances increases as the temperature of the solvent increased.
For example:
At 25°C the solubility of sodium chloride (NaCl) in water is 36.2g per 100 g of water. When
the temperature is raised to 100°C, the solubility is increased to 39.2g of NaCl per 100g of
water. As shown in the diagram below. For some substances, however, the reverse occurs.
The solubility of sodium sulphate (Na 2SO4) in water drops from 50 g per 100 g at 40°C to 41g Calculating Solubility
per 100g at 100°C. Measuring the solubility of solid in water.
Take potassium sulphate as our example. This is what to do:
The table below shows the list of common substances at various temperatures.
Solubility of Gases
Since you know the mass of solute and the volume of water you used, you can work out the
solubility as shown in the calculation below:
2 grams of potassium sulphate were dissolved in 12.5cm 3 of water. On cooling, the first
crystal appeared at 60°C. What is the solubility of potassium sulphate in water at 60°C?
Now look at the last step again. If you add a little more water, heat the solution again to
make sure all the crystal have dissolved. Let it cool, you will find the solubility at a lower We call the lines on the graph solubility curves. They show us how much salt dissolves at
temperature. You can repeat this for a range of temperatures. different temperatures.
Solubility Curves Now, check what you have just learnt by trying out the learning activity below!
Thank you for completing your learning activity 6. Check your work. Answers are
at the end of this module.