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Body armour – New materials, new systems

Article · February 2019


DOI: 10.1016/j.dt.2019.02.002

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Defence Technology xxx (xxxx) xxx

Contents lists available at ScienceDirect

Defence Technology
journal homepage: www.elsevier.com/locate/dt

Body armour e New materials, new systems


Ian G. Crouch*
Armour Solutions, Trentham, Victoria, 3458, Australia

a r t i c l e i n f o a b s t r a c t

Article history: This is a very timely review of body armour materials and systems since new test standards are currently
Received 27 November 2018 being written, or reviewed, and new, innovative products released. Of greatest importance, however, is
Received in revised form the recent evolution, and maturity, of the Ultra High Molecular Weight Polyethylene fibres enabling a
21 January 2019
completely new style of system to evolve e a stackable system of Hard Armour Plates. The science of
Accepted 22 February 2019
body armour materials is quickly reviewed with emphasis upon current understanding of relevant
Available online xxx
energy-absorbing mechanisms in fibres, fabrics, polymeric laminates and ceramics. The trend in on-
going developments in ballistic fibres is then reviewed, analysed and future projections offered. Weak-
Keywords:
Body armour
nesses in some of the ceramic grades are highlighted as is the value of using cladding materials to
Body armor improve the robustness, and multi-strike performance, of Hard Armour Plates. Finally, with the drive for
Ceramic armour lighter, and therefore smaller, soft armour systems for military personnel the challenges for armour
Reaction sintered silicon carbide designers are reported, and the importance of the relative size of the Hard Armour Plate to the Soft
UHMWPE Armour Insert is strongly emphasised.
Fibres © 2019 The Author. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND
Fabrics license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
Strike-face materials
Aramids
Small-arms ammunition
Hard armour plates
Soft vests

1. Background (4) The UK MOD is soon to appoint the preferred tenderer for
VIRTUS, their completely new body armour system e an
It is extremely timely for a review of body armour materials and example of fit, form and function dominating evolution,
systems for the following reasons: especially in response to changes in the military operational
environment [5].
(1) The National Institute of Justice, in the US, are currently in (5) In Australia, Victoria Police have recently appointed ADA to
the final phase of revising their standard, with NIJ 0101.07 supply 14,000 completely new ballistic vests in 2019 [6], e
[1], expected to be issued in 2019 [2]. This new standard will another example of fit, form and function dominating design,
include guidance for testing of female body armour, and a not new materials!
radical step change in the range of small arms ammunition (6) And finally, as a warning to armour technologists keen on
used to test future systems, as well as a significant relaxation developing new body armour materials, the case against
of critical blunt trauma measurements. Second Chance, for selling defective vests in the early 2000s,
(2) The UK Home Office has recently, in July 2017, issued a has just been settled, after nearly twenty years [7]. These
further revision of their body armour test standard [3]. vests were constructed of a man-made fibre called Zylon
(3) The latest in the series of Personal Armour Systems Symposia which, whilst offering a very attractive set of initial proper-
has recently been held in Washington D.C [4]. ties, were found to environmentally degrade to the point
where the vests seriously underperformed leading to tragic
loss of life.

* Managing Director, Armour Solutions Pty Ltd, PO Box 42, Trentham, Victoria, This review is also extremely timely because there has been a
3458, Australia.
quantum shift in the market place in 2018. Armour solutions, based
E-mail address: ianarmoursolutions@gmail.com.
Peer review under responsibility of China Ordnance Society upon Ultra High Molecular Weight Polyethylene (UHMWPE), have

https://doi.org/10.1016/j.dt.2019.02.002
2214-9147/© 2019 The Author. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Please cite this article as: Crouch IG, Body armour e New materials, new systems, Defence Technology, https://doi.org/10.1016/j.dt.2019.02.002
2 I.G. Crouch / Defence Technology xxx (xxxx) xxx

Nomenclature HM High Modulus


HP High Purity
ADA Australian Defence Apparel HT High Tensile (strength)
ADF Australian Defence Force HV High Velocity
AP Armour Piercing IED Improvised Explosive Device
BABT Behind Armour Blunt Trauma KED Kinetic Energy Density
BAS Body Armour System MCC Modern Ceramics Company (Australia)
BFD Back Face Deformation MS Multi Strike
BFS Back Face Signature NIJ National Institute of Justice (USA)
CNT Carbon Nano Tube PoS Point of Strike
COD Crack Opening Displacement RDOP Residual Depth of Penetration
CSIRO Commonwealth Scientific and Industrial Research RSSC Reaction Sintered Silicon Carbide
Organisation (Australia) SAI Soft Armour Insert
DMTC Defence Materials Technology Centre (Australia) SS Single Strike
DSTG Defence Science and Technology Group (Australia) TD Theoretical Density
DSTL Defence Science and Technology Laboratory (UK) UHHS Ultra High Hardness Steel
FFV Forsvarets Fabriksverk (Sweden) UHMWPE Ultra High Molecular Weight Polyethylene
FSP Fragment Simulating Projectile VIRTUS UK Body Armour System, circa 2016 onwards
HAP Hard Armour Plate VPP Viscous Plastic Processing
HEL Hugoniot Elastic Limit V-50 Velocity at which probability is 50% for perforation of
HHS High Hardness Steel an armour

now become the systems of choice for many police and miltary 2.2. Fundamental principles
users, replacing the aramid-based solutions that have dominated
the market for the past three decades or so. Even though UHMWPE By definition, a ballistic impact is a dynamic event and is usually
armour materials have been available for the past forty years, since completed within 50e200ms. It is not too surprising, therefore, that
they were invented by DSM in The Netherlands in 1979, it is only effective, resistive responses by an armoured structure, including
now, in 2018, that developers and producers of this high- the armour material itself, need to occur within this timeframe. For
performance material can claim supremacy, and market accep- example, mechanisms associated with novel auxetic structures [17]
tance [8,9]. need to operate in a timely fashion in order to be effective, and the
This paper will therefore cover major advances in both fibres, popular addition of shear thickening fluids to textiles [18] also need
and fabrics, as well as armour-grade ceramics. The main emphasis to possess the appropriate kinetic behaviour to be beneficial.
is placed upon protective materials for the torso but some mention Futhermore, with strain rates of up to 105 s1, any material whose
will be made of new helmet technologies, as well as new, smarter elastic and/or plastic behaviour is time-dependent will also
uniform materials. Essential background reading to this review is respond differently under ballistic impact conditions. The flow
contained within a recent publication covering the science of ar- strength and tensile modulii of polymeric materials like the
mour materials [10], especially Chapter 5 (Polymers and Fibre- UHMWPE and aramid fibres are particularly sensitive to strain rate.
Reinforced Plastics) [11], Chapter 6 (Fibres, textiles and protective The high strain rate testing of all armour materials is covered, in
apparel) [12], and Chapter 7 (Glasses and Ceramics) [13]. detail, elsewhere [19].
All bullet-resistant, protective apparel is designed to arrest an
attacking projectile without serious insult to the human body. This
2. Introduction is achieved by various means and through the use of various con-
ventional materials, depending upon the perceived threat. For hand
2.1. Basic description gun bullets it is common practice to use a pack of layered fabrics,
loosely held or stitched together to form a comfortable wrap
The wearing of body armour is known to reduce fatalities in around the torso. For knife and spike attack, additional, or different,
military environments [14]. It has also been very effective in packs are used which contain various “stiffer” materials like lami-
reducing injuries and fatalities within the police force and correc- nated fabrics, or metallic elements e a recent review covers this
tional services. In an earlier review of some of the key issues [15],
Horsfall describes some of the injury mechanisms associated with
these attacks, and in a more recent historical review, Yadav et al.,
[16] cover the evolution of body armour systems and introduce
some futuristic material options. However, there is still a constant,
and purposeful, drive to reduce the weight of such systems even
further, as well as improve levels of comfort and fit. Cost reduction
is also a commercial driver, especially when standard body armour
systems can be priced as high as several thousand dollars per set.
Each of these challenging requirements are being met through
development of new materials, innovative designs and lighter
weight systems. This paper reviews all important aspects of body
armour and reports on the evolution of exciting new materials
which are enabling new systems to come to market. Fig. 1. Images of miltary body armour systems.

Please cite this article as: Crouch IG, Body armour e New materials, new systems, Defence Technology, https://doi.org/10.1016/j.dt.2019.02.002
I.G. Crouch / Defence Technology xxx (xxxx) xxx 3

very important group of body armour materials [20] and testing conical) will also affect the bullet's penetration capability. The
techniques [21]. For high-velocity rifle rounds, including armour- effectiveness of each of these small arms rounds can be best
piercing (AP) ammunition, a hard armour plate (HAP) is appreciated, therefore, if one calculates a Kinetic Energy Density
commonly added to the front of the system to work in conjunction (KED) value based upon core dimensions, rather than calibre. This is
with the soft armour pack and prevent perforation and serious the kinetic energy of the core, divided by the contact area projected
blunt trauma (see Fig. 1). These HAPs normally contain two basic onto the target. The data contained within Fig. 4, for example, has
families of materials: a strike-face which is designed to blunt, erode been calculated using the tip geometry of each of the respective
or shatter the incoming round, and a laminated, polymeric backing cores, together with their respective muzzle velocities. The pene-
material which is designed to support the strike-face material, trative power of the tunsgten-carbide-cored, FFV round is quite
during initial impact, and then act as an efficient absorber, and clear. However, it should be noted that this particular round is not
arrestor, of the damaged projectile. Therefore there are three major currently included in any military or civilian body armour threat
groups of armour materials which require description, under- spectrum although it is an established part of the threats covered
standing and review: (a) formable, technical textiles, (b) fibre- by STANAG Level 3 [26]. It has, however, been used extensively for
reinforced polymeric laminates, and (c) hard, brittle, strike face research purposes for the past decade or so and is included here for
materials like ceramics and high hardness steels. Fig. 2 shows these completeness.
three elements, together with camouflage uniform material.
Material advances in armour systems are normally driven by the 2.4. Energy-absorbing mechanisms
need for either a weight and/or cost reduction. But, as recently
witnessed in operational theatres like Afganhistan, reduced When designing advanced, lightweight body armour systems,
coverage can also lead to significant weight reductions. And in and/or developing armour materials, the guiding principle is al-
more recent times, October 2018, the US Army started fielding a ways to maximise energy absorbing mechanisms whilst designing-
very lightweight, narrower system [22]. This highlights the con- out, or minimising, low energy failure mechanisms [27]. This
ventional trade-off between weight, comfort and protection, and fundamental approach to design is based upon a thorough under-
whilst this paper will naturally be covering the areal density standing of the science of armour materials. In this following sec-
(weight per unit area) and protection levels associated with tion, the reader is reminded, therefore, of the conventional energy-
advanced systems, it will not be covering comfort issues. Fit, form absorbing mechanisms already identified during ballistic impact of
and function are very dependent upon operational roles and differ body armour materials and systems.
markedly between civilian and military theatres [23]. Human factor In soft, textile-based armour systems, there are two deformation
studies, based upon anthropometric data, are a hugely important processes involved, as illustrated in Fig. 5:
set of parallel activities and, in combination with advances in ar-
mour materials, lead to much improved, and comfortable, body (1) The formation of a cruciform of stretched fibres, pulling-in
armour systems. In recent years, more serious attention has material from the whole “width” of the soft armour pack e
rightfully been given to the needs of the female combatant and it is this mechanism introduces a size-effect in Soft Armour In-
very clear that such studies [24], and methodologies, will lead to serts (SAIs) e see Sections 4.1 and 4.2.
improved body armour systems generally. (2) Out-of-plane deformation around the Point-of-Strike (POS)
e the extent of this z-movement will control the Back Face
2.3. Threats Signature/Deformation and the degree of behind-armour
blunt trauma (BABT).
The threats considered in this review are confined to small arms
ammunition that range from 9 mm hand-gun bullets to 7.62 mm In terms of energy absorbing mechanisms, Cunniff [29] identi-
hard-cored, armour-piercing rounds. These are thoroughly fied two major contributors: the first relates to the strain wave
reviewed in a recent publication [25], and only briefly discussed velocity in the fibres, V; the second relates to the Work Done by the
here. Images of selected rounds are shown in Fig. 3. fibres as they are stretched, defined as the Elastic Stored Energy, Es.
It is important to note that it is the core of the bullet that con- These two terms are defined by the following two equations
trols its penetration behaviour, not the calibre. The hardness of the
core materials and the sharpness of the nose (blunt, ogival, or V ¼ (E/r)1/2 (1)

ES ¼ s.ε / 2r (2)

where V ¼ strain wave energy, E ¼ elastic modulus of the fibre,


r ¼ the bulk density of the fibre, ES ¼ elastic stored energy in the
fibre, and s and ε are the stress and strain values up to the yield
stress of the fibre. Following the pioneering work of Cunniff, an
extended examination of these influential parameters has recently
been published by Guo et al. [30].
With fibre-reinforced plastics, and therefore in laminated
backing materials for HAPs, the energy-absorbing mechanims and
failure modes have very recently been reviewed [12], and can be
collated into two main areas:

(1) The dynamic, through-thickness, compressive strength and


modulii of the laminate, during the initial phase of the
Fig. 2. Typical sub-systems and material groups used in a body armour system. Note
penetration behaviour
that, for photographic purposes, the UHMWPE backing material has been off-set from (2) Membrane stretching of the rear fibres and plies of fabric, in
the ceramic tile. the arresting, final phase of the penetration process. It should

Please cite this article as: Crouch IG, Body armour e New materials, new systems, Defence Technology, https://doi.org/10.1016/j.dt.2019.02.002
4 I.G. Crouch / Defence Technology xxx (xxxx) xxx

Fig. 3. Schematic table of selected small arms ammunition.

Fig. 4. Kinetic Energy Density values for the cores of selected small arms ammuntion.

be noted that delamination, an interlaminar fracture process, impact energy absorption. Their formation and presence, however,
does not, in itself, absorb much energy (it is a fracture pro- is very important when designing mult-hit HAPs e these issues will
cess) e it just allows the separated plies to stretch and be discussed in Section 4. So, for ceramic materials there are two
deform. highly influential material properties e both of which govern its
ballistic properties:
For brittle, strike face materials, Crouch and co-workers recently
reported the range of energy-absorbing mechanisms involved (1) Dynamic, through-thickness compressive strength (i.e. dy-
during a typical ballistic impact and listed the step-wise failure namic hardness).
mechanisms that occur during the penetration process [13]. These (2) The stiffness of the material (a combination of the materials
are captured by the x-ray image shown in Fig. 6. Conoidal fracture is elastic modulii, its sectional modulii, and the support con-
absolutely essential if a strike face material is going to be effective. ditions confered on the ceramic).
On the other hand, radial cracking is a secondary event and
circumferential cracking a tertiary event e both absorb minimal After decades of research investigating relationships between
impact energy (being fracture processes) and contribute little to the mechanical and ballistic properties of ceramics, the one

Please cite this article as: Crouch IG, Body armour e New materials, new systems, Defence Technology, https://doi.org/10.1016/j.dt.2019.02.002
I.G. Crouch / Defence Technology xxx (xxxx) xxx 5

Fig. 5. Photographic evidence of physical damage to a single ply of aramid fabric when
impacted by a high velocity steel fragment [28].

Fig. 7. Relationship between specific tensile modulus and specific tensile strength of a
broad range of both structural and ballistic fibres.

continues to advance, and set new standards. In a laminated form,


they are now able to arrest a mild-steel-cored, 7.62 mm, high-
velocity bullet at point blank range - a feat that few thought was
ever possible.
In 1991 [34], Pervorsek first published a diagram showing the
relationship between the specific tensile modulus of ballistic fibres
Fig. 6. High resolution x-radiograph of an impacted HAP showing damage from a and their tenacity. Based upon this work, and an earlier publication
7.62 mm APM2 round. Note the symmetry of the field of damage, with the arrested
[12], Crouch has recently updated this important relationship by
round captured in the centre of the conoidal fracture zone, as well as radial cracks
extending to the edge of the plate, and circumferential bending cracks [31].
including data for newly-developed fibres, including the family of
natural fibres e see Fig. 7. The upward trend for the ballistic fibres
(glass, aramid and UHMWPE) is very clear and shows that the most
singular material parameter that is found, consistently, to be recently developed variants of UHMWPE have now surpassed the
strongly related to ballistic performance is the simple indentation values for Zylon, a PBO fibre claimed in the 2000s to be the “fibre of
hardness measurement. This fundamental relationship was, once the future”. It is also clear from this new diagram that the more
again, confirmed in the latest research carried out by DSTL in the UK structural fibres, like K149, the steels, and the carbon fibres
when studying the penetration behaviour of spark plasma sintered (especially the HM variants) lie consistently above the trend line for
boron carbide [32]. At this juncture, it should be emphasised that the ballistic fibres. It also confirms that the “goal” data, originally
whilst the fracture toughness of ceramics has an influence upon the laid down for the development of the M5 fibre, was probably
cracking behaviour of a HAP, it does not significantly affect its erroneously set! The data point for HT-700 carbon fibre suggests
ballistic performance. Research aimed at improving fracture that these HT variants might be the most suitable in hybrid lami-
toughness of brittle materials is therefore ill-founded if the moti- nates designed to cope with both structural loads and ballistic
vation is simply to improve the penetration resistance of an armour impacts. At the bottom end of this trend line, lies the family of
material. natural fibres, like curaua, a plant fibre from South America. From
their measured properties [35], it is clear from this diagram, that
3. Material developments the natural fibres will never become high-performance fibres but,
as the latest research states [36], they do benefit from being envi-
3.1. Fibres ronmentally friendly and low cost.
Both strength and modulus values are important e not one, but
One of the most noteworthy and significant advances in body an optimised balance of both parameters. Using the data for the
armour materials in the past 20 years has been the evolution, and ballistic fibres, as indicated by the trend line in Fig. 7, one can assign
extended development, of the Ultra-High Molecular Weight Poly- a power law relationship between the two which has an R2 value of
Ethylene (UHMWPE) fibres and fabrics. In the early days of devel- 0.86.
opment, in the 1980s, they were an excellent ballistic material,
1.44
especially against high-velocity fragments, but an extremely poor y ¼ 0.0185 x (3)
structural material. About ten years ago, the structural properties
had been improved sufficiently to consider manufactuing combat Since Fig. 7 is a plot of specific values, and with reference back to
helmet shells from this material [12,33]. However, whilst this field Equations (1) and (2),
of application has not quite matured yet, within the global
marketplace, the ballistic properties of this family of fibres y ¼ E/r ¼ V2 (4)

Please cite this article as: Crouch IG, Body armour e New materials, new systems, Defence Technology, https://doi.org/10.1016/j.dt.2019.02.002
6 I.G. Crouch / Defence Technology xxx (xxxx) xxx

x ¼ s/r ¼ 2ES/ε (5) scrutiny. However, most researchers, like those researching the
effects upon 3D structures [47] still believe that there are en-
In other words, a high value of wave velocity (sonic velocity) is hancements to be gained.
essential, as is the work done in physically stretching the fibres, if One further group of fabrics has been receiving more attention
the ballistic performance of these fibres is to be maximised. Further recently e knitted fabrics. These fabrics have poor structural
improvements in any ballistic fibre, therefore, would be expected to properties but, when impacted, they do demonstrate very large
sit close to this trend line as described by Equation (3). Time will tell out-of-plane deformations. This has perceived benefits when
whether this relationship is valid. looking to improve wound ballistics by capturing small fragments,
In recent work published by Harm van der Werff and colleagues and soil particles, from Improvised Explosive Devices (IEDs) thus
at DSM [37], the authors claim that the strength of such fibres may reducing the need for multiple operations and improving healing
never be bettered. Supported by some excellent work from re- times. Recent modelling work at ARL [48], is looking to optimise the
searchers at the Ernst Mach Institute in Germany, they argue that knit architecture and thereby ballistic performance of these fabrics.
amongst all of the leading fibres, including the sp2 family of gra- If successful, knitted fabrics could replace the very fine, woven silk
phenes and carbon nanotubes, it is the UHMWPE fibres that show fabrics that have been reportedly used in groin protective wear
maximum potential, achieving about 44% of their theoretical [49].
strength. However, no mention was made of tensile modulus Advances in fabric technologies are not restricted just to the
which, as this review paper has shown, is equally important as ultra-lightweight fabrics used for backing materials. Ashok Bhat-
tensile strength. The dynamic modulus and strain wave velocity of nagar and his team at Honeywell have developed a new range of
fibres can also be measured very easily, as presented by Menghe hybrid fabrics for use in load carriage equipment [50] and claim
Miao of the CSIRO, Australia [38], and should be used more regu- that up to 40% saving in weight can come from the use of a lami-
larly to measure sonic velocities in yarns, and tows, as well as single nated hybrid fabric combining UHMWPE fibre-reinforced films
fibres. with thin, low denier CORDURA fabrics. The authors reported that
the weight-saving laminates can also be laser cut to a more precise
3.2. Fabrics shape compared to conventional webbing attachments.

It is normal, and conventional, practice for body armour de- 3.3. Strike-face materials
signers to use multiple layers of dry fabric, like a woven aramid
fabric. However, some researchers have investigated the effects of Even with the advent of ultra-lightweight laminates based upon
adding an elastomeric matrix to the fabrics. Gopinath [39], for UHMWPE, with their remarkable ability to arrest some of the mild-
example, showed that such additions can reduce the maximum steel-cored ammunition, ceramics remain the most important and
deflection of the armour but increased the deformed area. How- influencial group of armour materials because they are very effec-
ever, the mass efficiency of the soft armours, with and without a tive against hard-cored, armour-piercing ammunition. This is
matrix, was not calculated. Earlier work in this area has regularly because for glasses and ceramics, the hardness of the strike-face
shown that there is little to be gained, ballistically, in using a matrix material by and large governs its ballistic performance. High
material for soft armour applications. hardness steels (HHS), like AR500 [51], and most recently Ultra
Woven fabrics are still very popular for soft vests because they High Hardness steels (UHHS), like Armox Advance from SSAB, have
conform extremely well and provide maximum levels of comfort. been a popular stand-alone HAP for decades, and still represent the
They are however, not very efficient, ballistically [11], since by lowest cost option. Advances in metallurgical practices have
design most of the fibres/tows/yarns are not straight. Recognising enabled thinner and thinner products to be produced. However, on
this fact, the global producers like DuPont, Honeywell and DSM, a weight-for-weight basis, they do not compete very favourably
have been developing fabrics using unidirectional fibres. DuPont with the ceramic grades e see Table 1.
produce an elegant, stitched, non-crimp, aramid fabric, whilst the For body armour applications, three main grades have estab-
UHMWPE producers have focused upon manufacturing plies of lished themselves in the market place: high-purity aluminas, sili-
fibre-reinforced, thermoplastic films. In both cases, the finished con carbides and boron carbides, increasing in ballistic merit rating,
fabrics consist of either two or four cross-plied layers. These layers and price, in that ascending order.
are then normally stitched, as in the case of dry, aramid fabrics, or Nowadays, little attention is being given to the well-established
tack-bonded, as with the range of the thermoplastic UHMWPE families of aluminas whilst the glass-ceramics continue to play only
preimpregnated fabrics. Crouch et al. [11] cover the general effects a small part in body armour systems. This latter family has recently
of stitching and quilting, and, whilst some researchers, like Carr been thoroughly reviewed by Benetez and co-workers from Brazil
[40], report likely improvements in ballistic performance of quilted and Germany [54] since they offer great potential for transparant
fabrics, others, like Abtew [41], only report expected findings. For armours. The family of silicon carbides are also well established and
example, decreases in formabilty and draw-in with an increase in the hot-pressed, SiCeN variant (see Table 1) still represents the
the stitch density of the quilting. ceramic of choice, in tile form, for many vehicular systems. How-
Over the past two decades, it has become very popular to ever, for body armour applications, Reaction Sintered Silicon Car-
research the benefits of adding shear thickening fluids, either as bide (RSSC) grades have become more popular because of their
fabric coatings or as discreet pockets of fluid [11,42e45], as high- ability to be near-net shaped and, over the past 15 years or so, both
lighted in a recent review of soft body armours by Arora and Ghosh US and Australian-made HAPs, incorporating this material, have
[18]. However, in another study by Gurgen et al., [46], whilst been fielded. In support of such acquisitions, these inherently more
application of STFs, applied as a coating, was found to be beneficial, defective grades have been extensively researched, new quality
they determined that the advantages were not driven by any shear control procedures adopted, and improved NDI techniques devel-
thickening effect e instead, they identified that the STFs were oped, [53]. A wide variety of siliconized silicon carbide grades, like
responsible for simply increasing the inter-fibre friction which Silit® SKDH, are now available through suppliers like St. Gobain,
enhanced fibre-yarn coupling, spreading the impact load over a [55].
greater area thus reducing the penetration depth. This suggests that For most ballistic applications, boron carbide remains the ulti-
any claimed benefits of shear-thickening fluids require deeper mate armour material of choice e it is one of the hardest ceramic

Please cite this article as: Crouch IG, Body armour e New materials, new systems, Defence Technology, https://doi.org/10.1016/j.dt.2019.02.002
I.G. Crouch / Defence Technology xxx (xxxx) xxx 7

Table 1
Summary of important properties of a range of strike-face materials.

Class of material Source, grade, (reference) Density/(kg$m3) Hardness/GPa Elastic modulus/GPa Flexural strength/MPa Fracture toughness/(MPa$m1/2)

UHH Steel SSAB, Armox Advancea 7780 2.3 208 NK 15e20


Glass Ceramics Silceramb 2900 7.0 122 180 NK
Alumina CoorsTek, AD85,c 3420 9.4 221 296 3e4
Alumina CoorsTek, AD998,c 3920 14.1 370 375 4e5
AlON Surmet,d 3695 18.5 323 380 ~2
TiB2 CoorsTek, PADc 4480 26.4 555 275 ~7
SiC CoorsTek, SiCeN, PADc 3200 23.5 460 570 ~5
SiC MCC, RSSC,e 3106 24.5 399 504 NK
B4C CoorsTek, PADc 2500 25.5 460 410 4

Sources.
a
SSAB, general data sheets, and advice.
b
Carter, S., et al., 1988 [52].
c
http://www.coorstek.com/resource-library/library/8510-1364_ceramic_properties_mp.pdf.
d
http://www.surmet.com/products-and-applications/ALON-Transparent-Armour/.
e
MCC data sheet, 2009, as reported by Ref. [53].

Fig. 8. VPP boron carbide impacted by a 7.62 mm tungsten carbide cored FFV round
[58]. Fig. 9. RDOP data, into AA6082-T651, for impacts from FFV rounds against various
6 mm thick ceramic tiles [59].

materials (see Table 1), falling just short of diamond and cubic
boron nitride, and, because of its low density (~2,520 kg m3), it
has a very attractive set of specific properties for body armour premature failure mechanism is favouring the notion of a phase
systems [56]. Its structure, properties and stability under stress transformation although the proposition that it might be related to
have recently been reviewed in a highly recommended paper by catastrophic propagation of microcracks is still mooted. Chen [61]
Domnich et al. [57]. had reported shock-induced localised amorphisation in boron
It is well known to armour technologists that boron carbide carbide as early as 2003. Since then deeper understanding and
strike face materials behave in a more glass-like manner when prevention of this shear localization effect has been the subject of
impacted by high velocity rifle rounds, as compared with SiC and much research as typified in a 2016 paper by Subnash et al., entitled
Al2O3 materials e see Fig. 8. However, this does not affect their “In search of amorphisation-resistant boron carbide” [62], and
excellent ballistic performance except against some specific more recently through the work of Xie et al., in 2017 [63], and that
armour-piercing threats, like the tungsten carbide-cored FFV round of Parsard and Subnash [64].
(see Fig. 3). In previously unreported work by Crouch [58], boron Despite the absence of a deep understanding of the amorph-
carbide targets, using 10 mm thick VPP B4C tiles with an UHMWPE isation issue, boron carbide continues to be used with confidence in
backing, in combination with a standard Soft Armour Insert, high-end, weight-driven armour applications, but it does have
exhibited the following V₅₀ values against three different 7.62 mm several natural drawbacks: cost of manufacture and, like all ce-
AP rounds: 949 m s1 against the APM2; 1,002 m s1 against the ramics, shapeability. These aspects have been addressed in a
B32; but only 598 m s1 against the FFV round. This unexpected number of ways through the adoption of liquid phase sintering and
drop in ballistic performance was first identified by Colin Roberson, pressureless sintering [13], or by utilising the reaction bonding (or
and others, in a landmark paper given at the “Cocoa Beach” con- sintering) process as reported by Chhillar in 2008 [65], Karandikar
ference in 2005 [59], in which RDOP measurements were recorded in 2010 [66], and more lately, by Hayan [67]. However, the most
for three different materials; AD99 alumina, sintered SiC, as well as exciting developments in recent years have been those that couple
a HP version of B4C e see Fig. 9. Against this specific threat, the a shaping process with a pressureless sintering operation. Re-
RDOP measurements for B4C are very similar to the considerably searchers at Georgia Institute of Technology, led by Robert Speyer,
less hard alumina targets. reported [68] success with the use of pre-formulated, dry powders
This under-performance appears to be due to shear localization being forged into final shapes, followed by pressureless sintering,
occurring within the material under shock loading. As reported by and the Israeli researchers from Haifa filed a patent in 2005 [69],
Volger in 2004 [60], the shear strength of boron carbide in the which relied upon similar technology. These works were followed
shocked state decreases rapidly above the HEL, indicating prema- by a relevant PhD thesis published in 2011, by Charles Wiley,
ture failure of the material as the shock stress reaches a threshold entitled “Synergistic methods for production of high-strength and
of ~20 GPa e but why is this? Current understanding of this low cost boron carbide” [70]. However, one of the most successful

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8 I.G. Crouch / Defence Technology xxx (xxxx) xxx

advances in this field was led by the DMTC in the development, and UHMWPE backing laminates are produced by subjecting dry
full-scale commercialisation, of a unique shaping process (Viscous stacks of the prepregs to a time/temperature/pressure cycle, either
Plastic Processing, VPP), especially effective for thin boron carbide, in an autoclave, hydroclave or between heated, high-pressure
armour-grade ceramics [71]. platens. Choice of manufacturing route is critical and the pros
Improving the ballistic performance of ceramics through the and cons of these processes have recently been reviewed by Crouch
addition of reinforcing particles has always attracted the attention et al., [13]. Processing temperatures are normally about 130e140  C,
of researchers. For example, in a very recent study Alexander et al., but the one strongly influential parameter that has emerged in the
[72], looked at the effects of adding graphene nano platelets (GNP) last ten years is consolidation pressure. Little can be found in the
to boron carbide matrices. The addition of 2% (by volume) of GNP open literature but both leading suppliers recommend as high a
was found to improve bulk density by acting as a sintering aid but pressure as possible on the basis that this improves ballistic per-
apart from a small increase in fracture toughness levels, there was a formance. Whilst this may be true for monolithic laminates, the
reported decrease in flexural strength e a common finding when relationship may not carry over into the production of HAPs.
working towards a ceramic matrix composite. Furthermore, the fundamental reason behind this has never been
Others, over the past two decades, have focussed their devel- published, although verbal advice suggests that an increase in
opment work on creating optimal blends of boron carbide and consolidation presssure leads to an increase in the in-plane flexural
silicon carbide, using reaction bonding (sometimes called reaction modulus of the laminate. This author goes one step further and
sintering) techniques [67,73]. The resultant products possess bulk suggests that if this is the case, then it is probably due to an increase
densities between 2,650 and 2,950 kg m3 (compared with typical in volume fraction of fibres, which is known to increase both in-
values for boron carbide of 2,520 kg m3 and silicon carbide of plane properties, and ballistic performance [12], e however, the
3,150 kg m3). In a recent in-depth study by Williams [74], in 2015, scientific community awaits the evidence in the case of highly
compositions were varied between 20% and 80% (by weight) of compressed UHMWPE products.
boron carbide. Optimum ballistic perfomance was achieved with a Alternative backing materials are constantly being developed/
boron carbide content of ~40%, coupled with Theoretical Density assessed because the UHMWPE stock material is a very expensive
(TD) values of greater than 96.5% and the use of coarse B4C particles. option, and often in short supply. In 2018, Benzait et al. [75] pub-
In reaction bonded materials, residual silicon contents can be as lished a review of a range of polymer-matrix composites for body
low as 10% by weight thus maximising hardness values. Commer- armor applications. This is a very broad-based review but focusses,
cially available blends are available through Paxis (in Israel) and almost exclusively, on futuristic materials like CNTs, graphene and
Precision Ceramics (in UK), to name but two. It is believed that such natural fibres, without any reference to, or acknowledgement of,
companies use a 40/60 blend of B4C/SiC to obtain optimum ballistic the critical properties required of a backing material, namely
performance at an affordable price. This blending approach also through-thickness, compressive strength, and modulus, and in-
circumvents any issues arising from amorphisation of the pure plane tensile properties of the rear plies. What is very clear
boron carbide grades e the author suspects that this may be one of though is that use of a low volume fraction (30%) of a low strength,
the drivers for their development and recent adoption. low modulus natural fibre, like curaua, is simply not going to be
adequate as a stand-alone ballistic material e see Fig. 7. However,
3.4. Backing materials hybridisation may provide more scope.
The use of hybrid fabrics is not new to the armour technologist
Ideally, backing materials need to be as rigid as possible and [11], especially when attempting to design a backing material with
therefore metal-based systems are instinctively attractive. Unfor- graded properties: combinations of carbon/aramid and aramid/
tunately, they cannot be shaped very easily. Hence, mouldable, UHMWPE fabrics are quite common e see recent published work
fibre-reinforced plastics are the obvious choice. Functionally, they by Bhatnagar and co-workers for some typical examples [50]. This
also need to be very effective at arresting blunt projectiles, since the is also the approach taken by Ali and co-workers [76] who reported
strike-face material will blunt the core of any bullet. Fibre- their attempts to integrate bamboo fibres into a conventional E-
reinforced plastics are exceptionally good at absorbing energy in glass/polyester laminate for armour materials offering 9 mm
this way, so polymer-based laminates are ideal as backing mate- handgun protection. The results were rather cursary and incon-
rials. Generally, the most effective backing materials are those that clusive e nevertheless, this is the necessary approach for natural
have the greatest ballistic efficiency against FSPs, and these are fibres, I believe e integration through hybridisation, rather than by
presently those based upon UHMWPE fibres, which is why many substitution.
HAPs are manufactured using either Spectra® or Dyneema® prod-
ucts. They are expensive though, which is why the aramid- 3.5. Cladding materials
reinforced plastics, and even glass-fibre reinforced thermosets,
are still in use. Second only in importance to the families of strike-face and
As the UHMWPE fibres and fabrics have been refined, the matrix backing materials, is the existence of cladding materials, which
material plays a significant part in their ballistic behaviour. Kraton have grown in recognition over the past decade. The effects of
was one of the first matrix materials used in 3rd generation cladding ceramic tiles with a layer, or layers, of polymeric materials
UHMWPE products, but now the two main global suppliers offer have been investigated by a number of researchers. Early results of
two, totally different matrices. For example, Honeywell's SR5143 Nunn et al. [77] showed a significant improvement in the ballistic
product, a 4-ply, cross-plied prepreg with an areal density of performance of ceramic armours based upon 100 mm square, sin-
163gsm, has a fairly compliant, rubber-like matrix, useful for BFS- gle tiles of 6 mm boron carbide, against the 7.62 mm AP M61 round,
controlled HAPs. In contrast, their SR5231 product, a 4-ply, cross- when layers of UHMWPE were bonded onto the surface of the
plied prepreg with a mean areal density of 167gsm, has a PU- ceramic. This was in line with parallel work by Sarva et al. [78] who
based matrix, which is a lot stiffer and is useful when HAP de- also showed that the ballistic efficiency of silicon carbide tiles,
signs are limited by a critical perforation velocity. These represent impacted with tungsten penetrators at ~900 m s1, could also be
5th generation products and DSM provide a very similar set of enhanced through the use of E-glass/epoxy cladding layers. How-
diverse products for different applications, including those for use ever, in more recent work by Crouch, Appleby-Thomas and Hazell
in the production of combat helmet shells. [79], it was clearly demonstrated that, for single impacts of a

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I.G. Crouch / Defence Technology xxx (xxxx) xxx 9

7.62 mm M43 (AK47) round, a cladding of aramid-fibre reinforced


epoxy, bonded to the surface of thin boron carbide tiles, had no
measurable effect upon penetration resistance. This latest view has
been reinforced by some elegant work of Rhabek et al. [80] who
demonstrated that there was no difference in the degree of core
erosion of the M61 7.62 mm AP round against 98% alumina targets
whether a cladding layer was present or not. Further research is
quite clearly required in this area.
However, this lack of understanding is not the case with multi-
strike behaviour and ballistic performance. In 2014, Crouch et al.
reported a detailed investigation into the effects that cladding has
upon the ballistic performance of a series of tightly-controlled
HAPs, constructed of 9 mm thick, silicon carbide tiles, and tested
using the 7.62 mm APM2 round at a nominal velocity of 870 m s1,
[31]. They also investigated the effect that various cladding mate-
rials had upon radial crack formation, Crack Opening Displacement
(COD), and ballistic resistance, as measured by Back Face Signature
Fig. 10. Variations in mean BFS values for UHMWPE-based soft vests, of different sizes,
(BFS). What they found was that a cladding of aramid-fibre rein- as a function of shot location.
forced epoxy resulted in a lowering of the mean BFS values, and a
reduction in Crack Opening Displacements (COD) but an increase in
the number of radial cracks. Research continues in this area [81],
location. As military vests have shrunk in size quite dramatically
especially to gain a complete understanding of the acceptance, or
over the past ten years, the significance of edge performance and
otherwise, of HAPs containing cracks. Table 2 illustrates how the
shot placement have started to take effect, and affect design. By
presence of cracks has been shown to reduce the measured V-50 of
example, consider the data shown in Fig. 10. This is a standard set of
a plate but that the degree of degradation depends upon the
ballistic testing data using 9 mm handgun ammunition, in accor-
function, and therefore the design, of the HAP itself. As one might
dance with NIJ 0101.06 [82], against a series of soft vests of various
expect, multi-strike HAPs do not degrade as severely as HAPs
sizes (Tiers). There are two things to notice; (i) that the BFS values
designed to withstand just one strike.
for shot number six is significantly lower than for shots 1, 2 and 3
In summary, for multi-strike HAPs, therefore, it would appear
(noting that shots 4 and 5 occur at 30 obliquity), and (ii) that for
that the presence of an appropriate cladding layer does not improve
shot six in particular, there is a distinct decrease in mean value for
the ballistic performance of the first strike but does improve multi-
BFS with a decrease in size of vest. These effects are discussed in
hit performance by ensuring that the cracks, emanating from the
detail elsewhere [11]. Suffice to say that because of these quanti-
first strike, are kept as closed as possible. In future, therefore, the
fiable edge effects, the effective coverage for soft vests decreases
use of thin plies of 5th generation UHMWPE or nano-layers of ultra-
with size of vest and not simply because the vests are physically
strong fibres like the sheet-like graphenes, may prove beneficial, as
smaller. As proposed in a recent paper by Robinson and Horlick
cladding layers, since these materials possess very attractive in-
[83], there is a current need for a systematic, large-scale study to
plane properties.
fully understand, and further quantify, these effects.
It should also be noted that cladding the ceramic increases the
For hard armours, edge effects become even more complex and
general robustness of the finished HAP. In fact, with the advent of
far more significant. It is well known that any armour product will
stacked systems (see Section 5) the cladding/wrapping of backing-
not confer a perfect level of protection right up to the edge of that
free, ceramic-only HAPs may well take on a more major role in
product, even for a free-standing piece of armour steel. What is not
future systems.
fully recognised yet is that the relative sizes of the HAP and the soft
vest is crucial in dictating the ballistic performance of the system
4. Design aspects [84]. Whilst little has been published in this area, the drive during
the past decade to reduce the weight and therefore size of the vest,
Before completing this review and discussing the evolution of has had severe consequences upon performance and is now
body armour systems, it is necessary to recognise that a number of limiting design. Fig. 11, taken from the work of Sandlin and Crouch
significant design issues have arisen from system development [85], illustrates the point and introduces the following three
activities over the past decade. terms:
For soft armours, these issues centre on coverage and shot

Table 2
Measured V-50 values as a function of strike number, for a triangular shot pattern, in which the distance between strikes from a 0.3” APM2 was recorded to be between 100 and
125 mm.

Threat V-50 value/(m$s1) Reference, Year

1st strike 2nd strike (% reduction) 3rd strike (% reduction)

MS AP(Steel) 1075 1005 965 Crouch [27], 2009


(7%) (10%)
SS AP(Steel) 880 750 700 Azevedo [81], 2018
(15%) (20%)

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10 I.G. Crouch / Defence Technology xxx (xxxx) xxx

5. Body armour systems, old and new

Over the past five decades, as covered in Fig. 13, through all of
the changing demands imposed by the different military and
civilian theatres of operation, it is the design, form and function of
the Hard Armour Plate that has seen most dramatic changes. And,
even though these changes have been brought about by the con-
stant drive for lighter and lighter systems, most of the material
options are still available in the market place, even the heavier
systems based upon high hardness steels.
In the 1970s, it was fairly common to simply use a lightly clad
plate of high grade alumina positioned in front of the soft vest to
offer protection against both lead-filled and armour-piercing vari-
ants of the 7.62 mm rounds. During the 1980s better designed, SiC-
Fig. 11. BFS values as a function of Total Edge Distance (TED) for a series of an impacts
from a 0.300 APM2 round against a multi-strike HAP supported by vests of different containing plates became more popular with accompanying weight
sizes. savings - armour designers recognised that the ceramic tiles
behaved more efficiently if they were backed by a stiff, fibre-
reinforced polymer. However, during the period 2000e2010,
(1) Edge Distance, ED, the distance between the PoS and the body armour systems became more complex, more protective, and
edge of the HAP purchase specifications far more demanding with more and more
(2) Overlap Length, OL, the distance between the edge of the multiple strikes defined. As a result, and as the red arrow shows in
HAP and the edge of the vest. Fig. 13, the weight of these systems started to escalate, until the
(3) Total Edge Distance, TED, the distance between the PoS and systems designed to stop the tunsgten carbide cored rounds were
the edge of the vest, such that TED ¼ ED þ OL. considered too heavy for some users. Then came a strategic shift in
the need for HAPs and body armour systems generally e the con-
It is quite clear from Fig. 11 that BFS generally increases as TED flict in Iraq was subsiding but the war in Afganhistan was height-
decreases - an effect not previously reported. In this case, however, ening. Rather than big, bulky and fully protective systems that were
the effect was not overly significant because all BFS values were required to patrol the streetscapes of Iraq, body armour systems
below the maximum allowable value of 44 mm. However, during needed to be lighter and smaller, enabling greater mobility for
development of a much lightweight plate, designed to take three soldiers covering the ground in Afganhistan. From 2010 onwards,
strikes from a range of high-velocity 7.62 mm rounds, the effect therefore, systems have become smaller and smaller, specifications
started to dictate design. Fig. 12, like Fig. 11, shows a very obvious less demanding and, as a consequence, weights began to fall
relationship between BFS values and the size of the soft vest. through either specification changes, improved designs or through
However, on this occasion, at small values of TED, the BFS values are the use of boron carbide materials. The lowest of the three green
well above the allowable maximum of 44 mm. At least they were at arrows in Fig. 13 illustrates the weight saving that was possible
the time since this work was carried out circa 2010. With the when the number of required strikes was reduced from six to three.
advent of NIJ 0101.07 this maximum value will be relaxed such that As systems have become smaller with the size of the HAP
some BFS values can be up to 50 mm. Furthermore, there are recent approaching, if not matching, the size of the soft vest, stand-alone
reports that the US Army are considering raising the maximum systems have emerged, as illustrated by the top green arrow in
values to 58 mm [22]. If this were the case, then the data presented Fig. 13. Whilst this is a heavy example of a HAP designed to with-
in Fig. 12 would need to be revisited, and the beneficial conse- stand multiple strikes from an AP round, the principle also applies
quences realised: greater effective coverage and/or much lighter at lower threat levels: stand-alone plates, if designed correctly,
weight HAPs. should be lighter in weight than a combination of a HAP and a SAI of
the same size.
And finally, since 2015, the rapid development of highly com-
pressed forms of UHMWPE UD fabrics has seen a dramatic reduc-
tion in the weight of body armour systems against both lead-filled
and mild steel cored ammunition [37]. Refer to the blue arrow in
Fig. 13. This latest evolution in high performance armour materials
has brought about a shift change in the form and function of HAPs e
stacked systems are now possible, and fielded.
In summary, therefore, Fig. 14 presents the full suite of body
armour systems that are currently available to the designer and
user. Modular systems, as represented by the Modular Combat
Body Armour System (MCBAS) developed for the Australian mili-
tary, have a fixed shape and a soft vest that provides near maximum
coverage e these are very functional when carrying out patrolling
duties e they are also popular with the police services since they
offer comprehensive coverage against handgun rounds and offer
the ability to be upgraded for protection against high-velocity rifle
rounds, by using a supplementary HAP in front of the vest. Tiered
systems, on the other hand, utilise smaller vests that differ in size
Fig. 12. BFS values as a function of Total Edge Distance (TED) for a series of an impacts
depending upon the operational requirements. It is these systems
from a 7.62 mm M80 round against a multi-strike HAP supported by vests of different that have brought the biggest challenges to the armour designer
sizes. because of the consequential effects of size, as described in Section

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I.G. Crouch / Defence Technology xxx (xxxx) xxx 11

Fig. 13. An historical chart showing the evolution of HAPs and, in particular, the effects that new materials, as well as threat level, have upon the areal density of the finished
product. For reference, the SS AP(Steel) contour line is equivalent to the threat described in NIJ 0101.06 Level IV.

ceramic-rich HAP which, in combination with the first HAP, offers


protection against the high-velocity armour-piercing rounds [87]. It
also appears that the Canadian DND have acquired a similar stacked
system from PRE Labs [88]. These are highly comendable systems
but they do come with their own set of drawbacks: from a logistical
point of view, they have an increased number of protective items to
control; from a ballistic performance aspect, some concerns have
been expressed about controlling the fit between the two HAPs;
and, from this author's perspective, if the second, complimentary
HAP is ceramic-rich, then one needs to be careful of the robustness
and crack-tolerance of such a product in the field. Presumably, the
suppliers, and users alike, have accepted and/or overcome these
potential issues.

6. Conclusions and final words

As the reader can now appreciate from this review, the evolution
of new body armour systems is very dependent upon, not only new
armour materials being developed but also, on the well-informed,
and judiscous, use of strict, and evolving, design principles.
From this study, the following general conclusions can be made:
Fig. 14. A schematic, overhead view of the four different groups of Body Armour
Systems.
(1) Significant advances in materials will continue to enable the
development of different body armour concepts, like the
stacked systems currently available. It is strongly emphasised
that these systems would not have been possible had it not
4 above. When the size of the plate matches the size of the vest, it is
been for the development of the latest generation of
often more beneficial to use a Stand-alone system e these HAPs
UHMWPE materials.
will be thicker than normal but can function without a soft vest.
(2) The full gamut of body armour systems is now available to
They are naturally more convenient in the field since only one
the civilian and military Users and it is definitely a case of
article is required rather than two. Global suppliers of body armour
horses for courses: i.e. operational requirements will
systems, like Morgan Defence Systems [86], offer a very compre-
continue to dictate which particular system is employed in
hensive range of both stand-alone and lightweight, tiered systems.
the field, and the choice is now very wide.
Of greatest significance, however, are the Stacked systems e these
(3) Lessons learnt from the consequences of a reduction in the
are totally new and would not have been possible had it not been
size of the soft vests, without changing the size of the hard
for the rapid development of the UHMWPE laminates described
armour plate, should now be fully appreciated and more
above. Tencate Advanced Armour launched such a system at Mil-
informed design-decisions made in the future.
ipol, France, in November 2017 e these utilise two, stackable, HAPs
(4) Material developments across fibres, fabrics, amd strike-face
e the first is UHMWPE based and offers protection against both
materials, will continue to refine, and improve, body armour
lead-filled and mild-steel-cored ammunition; the second is a
systems but only in small, incremental steps.

Please cite this article as: Crouch IG, Body armour e New materials, new systems, Defence Technology, https://doi.org/10.1016/j.dt.2019.02.002
12 I.G. Crouch / Defence Technology xxx (xxxx) xxx

(5) The perceived threat spectrum, as specified by the User, will testing. In: Crouch IG, editor. The science of armour materials. Cambridge:
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