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PHYSICS
Chapter 3
Thermal Properties of
Material
Learning Objectives:
• explain using a simple kinetic model for matter:
> the structure of solids, liquids and gases
> why melting and boiling take place without a change in temperature
> why the specific latent heat of vaporisation is higher than specific latent heat of fusion for the
same substance
> why a cooling effect accompanies evaporation
• define and use the concept of specific heat capacity, and identify the main principles of its
determination by electrical methods
• define and use the concept of specific latent heat, and identify the main principles of its
determination by electrical methods
• understand that internal energy is determined by the state of the system and that it can be
expressed as the sum of a random distribution of kinetic and potential energies associated with the
molecules of a system
• relate a rise in temperature of a body to an increase in its internal energy
• recall and use the first law of thermodynamics ΔU = q + w expressed in terms of the increase in
internal energy, the heating of the system (energy transferred to the system by heating) and the
work done on the system
SUMMARY
1. Kinetic Model of Matter • Melting & boiling occurs without change in
temp.:
- Temp. is a measure of random K.E. of the
particles
- At phase transition all energy used to break
bonds
- No change in K.E. occurs so temp. does NOT
change
• Cooling effect of evaporation:
- Particles which escape are those with
2. Melting, Boiling and Evaporating higher velocity so average KE of remaining
substance decreases
- Temp. = average KE ∴ overall temperature
decreases
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• Specific latent heat of sim: energy required to calculate heat of fusion, now using Δ
per unit mass of a substance to change from solid to 0.095 × 129 × Δ = 1747
liquid phase without any change in temperature Δ = 142.6
• Specific latent heat of vaporization: energy
Initial temp. will obviously be above m.p. so
required per unit mass of a substance to change adding to the final temp. of gold
from liquid to gas phase without any change in
i.e. the m.p. Initial Temp. of Gold = 1340 +
temperature
142.6 = 1483 K
= Δ
0.005 × 235 × (1340 − (273 + 27))=1222 J
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the gas itself is heating, ( = −). Overall, increase constant as there is no temp. change but Ep
in work done is balanced by the gas heating so net changes because separation of atoms
remains 0 and internal energy unchanged ( = 0) increases so internal energy increases
because
Part (ii): Δ = +
The solid is being heated so ( = +). As the solid is
not expanding, ( = 0) and therefore there is an b) By reference to the first law and your
increase in internal energy ( = +) answer in (a), show that thermal energy must
be supplied to the water during the boiling
Part (iii): process
The melting of ice requires heat energy provided so Δ = +
( = +). No work is done on or by the system so
( = 0). Hence, there is a net increase so ( = +) Changing from a liquid to a gas, there is an
increase in internal energy. Work is done by
{S02-P04} Question 2: the liquid so is negative. For Δ to be
Some water in a saucepan is boiling. positive, must increase.
a) Explain why:
i. external work is done by the boiling water
Volume increases due to evaporation (turns into a
gas) hence work is done on pushing back the
atmosphere.
In state 1, the molecules are very far apart. They move about very quickly at
random in straight lines until they hit something.
In state 2, the molecules are quite closely packed together. They move about at
random. They do not have fixed positions.
Movement of
particles
Diagram
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Thermal (heat) Energy
Specific heat capacity
From the definition of specific heat, we can write the heat needed to increase the
temperature of m grams of a substance by T.
Q = mcΔt=mcΔθ
Thermal (heat) capacity
Q = CΔt=CΔθ
Calculate the value of the specific heat capacity of aluminium given by this
experiment.
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Metal Authenticity Test
In this experiment you will learn how to check the authenticity of metal by
measuring specific heat capacity of metal.
Introduction
Specific heat is defined as the amount of energy necessary to produce a
temperature change of 1°C per gram of substance. The specific heats of different
substances vary, and therefore this quantity may be useful in identifying an
unknown. The measurement of heat changes is called calorimetry. In this lab,
calorimetry will be used to determine the specific heat of an unknown metal.
There are five measurements that must be made to determine the specific heat of the
unknown metal:
1. Determine the mass of the piece of metal.
2. Heat the metal piece to a known temperature and measure this temperature
precisely. This is the initial temperature of the metal (around 70 0C-800C).
3. Determine the mass of the water in a calorimeter.
4. Measure the temperature of the water in the calorimeter. This is the initial
temperature of the water.
5. Place the metal piece into the water of the calorimeter and measure the highest
temperature reached by the water. This is the final temperature of both the metal
and the water.
Data
Mass of metal = __________________
Mass of water = __________________
Initial temperature of metal = __________________
Initial temperature of water = __________________
Final temperature = __________________
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Analyze of Data
Spesific heat capacity
Percentage authenticity:
Conclusion:
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
Latent heat
Phase Change
Matter on earth is normally found in three states: solid, liquid and gas. Transition
between these states is called phase change.
Spesific Latent heat of fusion (Lf) is the amount (quantity) of heat energy required to
convert unit mass of solid to liquid without any change in temperature. The unit of
Spesific Latent heat of fusion (Lf) is J/kg.
Q = mLf
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Spesific Latent heat of vaporisation (Lv) is the amount (quantity) of heat energy
required to convert unit mass of liquid to vapor without any change in temperature.
The unit of Spesific Latent heat of vaporisation (Lv) is J/kg.
Q = mLv
1. a. State what is meant by the specific latent heat of fusion (melting) of a substance.
.........................................................................................................................................
.........................................................................................................................................
b. Ice cubes of total mass 70 g, and at 0 °C, are put into a drink of lemonade of mass
300 g. All the ice melts as 23 500 J of thermal energy transfers from the
lemonade to the ice. The final temperature of the drink is 0 °C.
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specific latent heat of fusion = ...........................(Ans: 340J/kg OR 336J/g)
(ii) The thermal energy that causes the ice to melt is transferred from the
lemonade as it cools. The loss of this thermal energy causes the temperature of
the 300 g of the lemonade to fall by 19 °C. Calculate the specific heat capacity of
the lemonade.
1. In a heat calculation problem, if the problem asks about melting/freezing you would
multiply the mass times _______________________.
a. heat of fusion
b. heat of vaporization
c. or specific heat
2. In a heat calculation problem, if the problem asks about a change in temperature, you
would multiply the mass times ___________________ times the change in
temperature.
a. Heat of fusion
b. Heat of vaporization
c. Specific heat
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Substance Hf(J/g) HV(J/g) Cp(J/g°C)
5. How many joules must be added to 10.0 g of water to raise its temperature from 10 oC
to 15oC?
7. A 5.0 g piece of metal is heated to 100oC, then placed in a beaker containing 20.0 g of
water at 10oC. The temperature of the water rises to 15oC. Assuming that heat
lost by the metal = heat gained by the water. Calculate the specific heat of the
metal.
8. How many joules are released as 5.00 g of Pb cool from 75oC to 25oC?
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9. How many joules are needed to completely melt 25 g of ice at 0 oC?
10. How many joules are released as 10.0 g of steam at 110oC cools to produce water at
25oC?
B. Internal Energy
In GCSE, you probably did an experiment where you took some ice, heated it
steadily with an electric heater and measured the temperature as time passed. You should
have got these results:
Even though you heated constantly, the temperature only rose sometimes. So where
was the heat going when the temperature wasn't rising?
Answer: it was being used to change the state of the water.
Remember in the energy topic we said that the energy of an atom was made up of two
components - Ek (kinetic energy) and Ep (potential energy). Well:
So during times of increase of temperature (e.g. a, c and e from the graph) the heat
energy supplied is going into the Ek component of the internal energy.
And during changes of state (e.g. b and d) it's going to Ep. Because Ek isn't
changing during these times, the temperature remains the same.
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Internal Energy of gases
Kinetic energy can be in different forms. A diatomic gas molecule can have three
types of kinetic energy:
Translational kinetic energy: Energy due to the motion of molecule as a whole.
This is the kinetic energy we are already familiar with. Formula is:
, where m0 is the total mass of molecule.
Rotational kinetic energy: Energy of molecule due to the rotation about the center
of mass.
Vibrational kinetic energy: Kinetic energy of oscillations about the center of mass.
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C. Laws of Thermodymanics
Closed system means there is no matter transfer between the system and its surroundings.
For an isolated system neither matter nor energy is transferred between the system and
surroundings. An open system allows both matter and energy transfers.
State of system
Three variables: pressure, volume and temperature are enough to describe the exact
condition of a gas sample. Specified values of P, V and T is called the state of a gas.
State variables are the variables which always have the same value when the system is in
a given state. Pressure, volume and temperature are state variables for a gas. Internal
energy is also a state variable as we shall see in this chapter.
Equilibrium state for a gas means temperature (hence the pressure and density) of the
gas sample have the same value throughout all the volume. When a gas sample is in
equilibrium, microscopic parameters - such as speed of a certain molecule- will change in
time. But macroscopic parameters involving average effects of many molecules - such as
pressure, temperature and volume - stay constant in time.
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1st Law of Thermodynamics
Two ways of transferring energy to or from a system are heat and work. Using
conservation of energy, we can write,
Written in symbols:
Or
All terms in the expression can be positive or negative. Consider the gas sample above as
our system:
ΔU is positive if internal energy increases. (Temperature increases).
ΔU is negative if internal energy decreases. (Temperature decreases).
Q is positive, if heat is added to system.
Q is negative, if heat flows out of the system.
W by gas is positive, if work is done by the gas, lifting the piston.
W by gas is negative, if work is done on the gas, decreasing the volume.
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Extra note: find work based on the graph and carnot engine.
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Typical Exam Question:
A. Multiple Choice
1. Phase changes occur
A) as the temperature decreases.
B) as the temperature increases.
C) as the temperature remains the same.
D) all of the above
2. The heat required to change a substance from the solid to the liquid state is referred to
as the
A) heat of fusion.
B) heat of vaporization.
C) heat of melting.
D) heat of freezing.
3. The heat required to change a substance from the liquid to the vapor state is referred
to as the
A) heat of fusion.
B) heat of vaporization.
C) heat of evaporation.
D) heat of condensation.
5. How much heat is needed to raise the temperature of 100 g of lead (c = 0.11 kcal/kg∙
C°) by 15C°?
A) 16.5 cal
B) 165 cal
C) 1500 cal
D) 15 kcal
7. Equal masses of water at 20°C and 80°C are mixed. What is the final temperature of
the mixture?
A) 40°C
B) 50°C
C) 60°C
D) 70°C
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8. A person tries to heat up her bath water by adding 5.0 L of water at 80°C to 60 L of
water at 30°C. What is the final temperature of the water?
A) 34°C
B) 36°C
C) 38°C
D) 40°C
9. A person tries to heat up her bath water by adding 5.0 L of water at 80°C to 60 L of
water at 30°C. What is the final temperature of the water?
A) 34°C
B) 36°C
C) 38°C
D) 40°C
10. A 0.600-kg piece of metal is heated to 100°C and placed in an aluminum can of mass
0.200-kg which contains 0.500 kg of water initially at 17.3°C. The final equilibrium
temperature of the mixture is 20.2°C, what is the specific heat of the metal?
A) 140 J/kg∙C°
B) 270 J/kg∙C°
C) 450 J/kg∙C°
D) 900 J/kg∙C°
11. When the first law of thermodynamics, Q = ΔU + W, is applied to an ideal gas that is
taken through an isothermal process,
A) ΔU = 0
B) W = 0
C) Q = 0
D) none of the above
12. During an isothermal process, 5.0 J of heat is removed from an ideal gas. What is the
change in internal energy?
A) zero
B) 2.5 J
C) 5.0 J
D) 10 J
13. During an isothermal process, 5.0 J of heat is removed from an ideal gas. What is the
work done in the process?
A) zero
B) 5.0 J
C) -5.0 J
D) none of the above
14. An ideal gas is compressed isothermally from 30 L to 20 L. During this process, 6.0 J
of energy is expended by the external mechanism that compressed the gas. What is
the change of internal energy for this gas?
A) 6.0 J
B) zero
C) -6.0 J
D) none of the above
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15. When the first law of thermodynamics, Q = ΔU + W, is applied to an ideal gas that is
taken through an isochoric process,
A) ΔU = 0.
B) W = 0.
C) Q = 0.
D) none of the above
16. In an isochoric process, the internal energy of a system decreases by 50 J. What is the
work done?
A) zero
B) 50 J
C) -50 J
D) none of the above
17. In an isochoric process, the internal energy of a system decreases by 50 J. What is the
heat exchange?
A) zero
B) 50 J
C) -50 J
D) none of the above
18. A gas is taken through the cycle illustrated here. During one cycle, how much work is
done by an engine operating on this cycle?
A) PV
B) 2PV
C) 3PV
D) 4PV
B. ESSAY
1. (a) The first law of thermodynamics can be represented by the expression ΔU = q
+ w. State what is meant by the symbols in the expression.
+ΔU............................................................................................................................
+q................................................................................................................................
+w...............................................................................................................................
(b) A fixed mass of an ideal gas undergoes a cycle ABCA of changes, as shown in
Fig. 2.1.
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(i) During the change from A to B, the energy supplied to the gas by heating is
442 J. Use the first law of thermodynamics to show that the internal energy of the
gas increases by 265 J.
(ii) During the change from B to C, the internal energy of the gas decreases by 313
J. By considering molecular energy, state and explain qualitatively the change, if
any, in the temperature of the gas.
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
(iii) For the change from C to A, use the data in (b)(i) and (b)(ii) to calculate the
change in internal energy
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(iv) The temperature of the gas at point A is 227 °C. Calculate the number of
molecules in the fixed mass of the gas.
number = ...........................................................[2]
2. A constant mass of an ideal gas has a volume of 3.49 × 103 cm3 at a temperature
of 21.0 °C. When the gas is heated, 565 J of thermal energy causes it to expand to
a volume of 3.87 × 103 cm3 at 53.0 °C. This is illustrated in Fig. 2.1.
(a) Show that the initial and final pressures of the gas are equal.
(b) The pressure of the gas is 4.20 × 105 Pa. For this heating of the gas,
(i) calculate the work done by the gas
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(c) Explain why the change in kinetic energy of the molecules of this ideal gas is
equal to the change in internal energy.
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UN 2017/2018
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UN 2016/2017
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Jika kalor yang diserap (Q1) =10.000 joule maka besar usaha yang dilakukan mesin Carnot
adalah ...
A. 1.500 J
B. 4.000 J
C. 5.000 J
D. 6.000 J
E. 8.000 J
6. Pemanas A dapat menaikkan suhu 200 gram air sebesar 200C dalam waktu 105 detik.
Pemanas B yang berdaya 200 watt digunakan untuk memanaskan 200 gram air sebesar 20 0C
dalam waktu 140 detik. Jika pemanas B memiliki efisiensi 75% dari efisiensi pemanas A dan
kalor jenis air 4,2 J.g–1K–1 , daya pemanas A adalah ….
(A) 300 watt
(B) 280 watt
(C) 250 watt
(D) 220 watt
(E) 200 watt
7. Suatu bejana kokoh yang berisi gas ideal dikocok berulang-ulang. Manakah pernyataan
yang benartentang keadaan gas tersebut setelah dikocok?
(A) Temperatur gas bertambah meskipun energi dalamnya tetap.
(B) Temperatur gas bertambah tanpa gas melakukan usaha.
(C) Energi dalam gas berkurang karena sebagian berubah menjadi kalor.
(D) Gas melakukan usaha sebesar penambahan energi dalamnya.
(E) Temperatur gas bertambah sebanding dengan penambahan kelajuan molekul gas.
SBMPTN 2018
6. Sejumlah kalor diserap oleh es dengan massa 2 kg dan suhu -10°C. Jika kalor jenis es 2000
J/ kg°C dan massa air yang terbentuk 0,6 kg serta kalor lebur es 340 kJ/kg setelah terjadi
kesetim-bangan termal, maka kalor yang diserap adalah ....
(A) 516 kJ
(B) 476 kJ
(C) 244 kJ
(D) 204 kJ
(E) 40 kJ
7. Sebuah mesin kalor riil menyerap kalor 1250 joule dari reservoir yang temperaturnya T1 =
327°C dalam satu siklusnya. Dalam setiap siklus-nya, kalor sebesar 700 joule dilepaskan ke
reser-voir dengan temperatur T2 = 27°C. Nilai efisiensi mesin tersebut dibandingkan dengan
nilai efisiensi mesin Carnot yang bekerja pada reservoir yang sama adalah ....
(A) 0,22
(B) 0,44
(C) 0,53
(D) 0,63
(E) 0,88
SBMPTN 2017
51
ENRICHMENT
Contoh Soal:
2. UN 2014
Gelas kaca yang berisi penuh dengan air
bersuhu 25 oC dipanaskan hingga
o
suhunya naik menjadi 100 C. Jika Pemuaian panjang, menentukan panjang
-5 o -
koefisien muai linear gelas 2 x 10 C awal:
1
dan koefisien muai volume air ( ) adalah
2,1 x 10-4 oC-1 maka volume air yang
tumpah adalah ….
A. 1,125 cm 3 D. 15,75 cm 3
52
2. Perpindahan kalor
a. Konduksi b. Konveksi
Perpindahan kalor secara konduksi Perpindahan kalor secara konveksi
adalah perpindahan kalo dimana zat adalah perpindahan kalor dimana zat
perantaranya tidak ikut berpindah. perantaranya ikut berpindah akibat
Konduksi terjadi pada zat padat adanya perbedaan massa jenis atau
Besar kalor yang merambat persatuan kerapatan zat.
waktu Perpindahan kalor secara konveksi
terjadi pada fluida (zat cair dan gas)
Keterangan :
= kalor yang merambat tiap detik (J/s)
= konduktivitas termal (W/m.K)
= koefisien konveksi (J/s.m2.K)
= luas permukaan (m2)
Jika maka: = perubahan suhu (°C)
= panjang penghantar (m)
= emisivitas : e = 1; penyerap sempurna
0<e<1
e = 0; penyerap paling jelek
= konstanta boltzman (5,67x10-8 W/m2K4)
Contoh Soal:
53
UN 2016/2017
UN 2017/2018
54