Reaction Condition: Partial Pressure (kPa):

Date: dd/mm/yyyy CH4 30

Catalyst 10%Ni-Al2O3 N2 71.325
Catalyst Weight (g) 0.1 Feed Ratio:
Reaction Temp. (K) CH4 0.30
Total Flow (ml/min) 60 N2 0.70
Total Pressure (kPa) 101.325

Colour Indicator:
To be filled for each run
Standards
Automated Analytical data

Bubble Flow Meter Inlet Flow Rates Measurements:

Vol. (ml) Time (s)
Tổng lưu lượng đầu vào 20 0
của tất cả các khí 20 0
20 0
Average 20 0

Theoretical Results
Species Inlet Flow Rate
ml/min mol/s
CH4 17.7646188008882 1.21164258E-05 17.764618801 1.2116425766E-05
N2 42.2353811991118 2.88068023E-05
H2 0 0
Others 0 0
Total: 60 4.0923228E-05

Inlet Flow Rates Measurements from GC

Species Area Volume Fraction
CH4 y = 1.1738x + 0.0025 (CH4/N2)
N2
H2 y = 1.9956x (H2/N2)
Others
Total:
 Outlet Flow Rates Measurements: Bubble Flow Meter

Volume (ml)
Time Taken (s)
0.5h 1h 1.5h
20
20
20
Average 20

GC Analysis: Outlet
Species Area
0.5h 1h 1.5h
H2
CH4
N2

Experimental Results - từ tổng "Total 26" suy ra các giá trị nhỏ lẻ thông qua tỷ
Species Inlet Flow Rate Outlet Flow Rate (m
ml/min mol/s 0.5h 1h 1.5h
CH4
N2
H2 0.000 0
Others 0.000 0
Total: 0.000

Inlet Flow Rate by GC measurement RetTime

Time (min)
Species ml/min mol/s 3.482 3.73
CH4 1 0 0 743088.8
N2 2 15 4125.7 730926.9
H2 3 30 756.296 717061.3
Others 4 45 925.8 718197
Total: 5 60 1083.4 724333
6 75 880.347 718785
7 90 6251.494 724813
8 105 1121.551 736041.2
 9 120 786.9 724839.3
10 135 856.8 721147.4
11 150 933 726529
12 165 993.2 725790.7
13 180 1104.9 727601
14 195 941.1 723093.2
15 210 930.7 723766.2
16 225 953.6 721510.8
17 240 1018.5 725507.4
18 255 1064 726582
19 270 968 725163
Bubble Flow Meter Tổng lưu lượng đầu ra của tất cả các khí

2h 2.5h 3h 3.5h 4h

Area Volume Fraction

2h 2.5h 3h 3.5h 4h 0.5h 3h 3.5h

á trị nhỏ lẻ thông qua tỷ lệ Area

Outlet Flow Rate (ml/min) Outlet Flow Rate (mol/s)
2h 2.5h 3h 3.5h 4h 0.5h 3h 3.5h

tTime F total (out) %AREA FROM GC OUT FLOW RATE (ml/min)

Time (s)
4.391 (ml/min) H2 N2 CH4 H2 N2
258394.5 15.11 59.56 0.0000 74.1988 25.8012 - 44.19519
253400.1 14.85 60.61 0.4174 73.9466 25.6360 0.25296 44.81611
221046 15.06 59.76 0.0806 76.3755 23.5440 0.04814 45.64270
239386.1 15.02 59.92 0.0966 74.9286 24.9748 0.05788 44.89728
254739 14.94 60.24 0.1105 73.8998 25.9897 0.06659 44.51796
250085 15.04 59.84 0.0908 74.1206 25.7886 0.05432 44.35410
257227 14.74 61.06 0.6326 73.3400 26.0274 0.38623 44.78019
257290.5 14.92 60.32 0.1128 74.0147 25.8726 0.06803 44.64691
256231.8 15.05 59.80 0.0801 73.8232 26.0966 0.04793 44.14678
252373.9 15.07 59.72 0.0879 74.0110 25.9010 0.05251 44.20036
259010 14.98 60.08 0.0946 73.6492 26.2562 0.05682 44.24853
259087.4 15.04 59.84 0.1007 73.6192 26.2800 0.06029 44.05405
259323.5 15.08 59.68 0.1118 73.6416 26.2465 0.06674 43.95058
256647.8 15.05 59.80 0.0960 73.7337 26.1703 0.05739 44.09324
256797 14.95 60.20 0.0948 73.7413 26.1639 0.05709 44.39275
250309.7 14.93 60.28 0.0980 74.1704 25.7315 0.05909 44.71091
257980.5 15.02 59.92 0.1035 73.6925 26.2040 0.06199 44.15663
258996 15.02 59.92 0.1078 73.6419 26.2503 0.06462 44.12631
258388 15.05 59.80 0.0983 73.6566 26.2451 0.05880 44.04712
action
4h

ate (mol/s)
4h

FCH4 in anh lấy số liệu của

CH4 conv. = [F in - F out]/F in
XH2 = FH2/[2F CH4 in]*100%
W RATE (ml/min) Rate of carbon deposition = [F
CH4 CH4 conv. XH2 Carbon balance (%) Carbon balance (%) = [FCH4
15.36800874 13.490917 - 86.51
15.53699213 12.539682 0.71199 88.17
14.07011665 20.796968 0.13549 79.34
14.96495297 15.759786 0.16289 84.40
15.65641825 11.867412 0.18741 88.32
15.43200563 13.130668 0.15290 87.02
15.89192552 10.541703 1.08707 90.55
15.60677127 12.146883 0.19148 88.04
15.60595513 12.151478 0.13489 87.98
15.46842806 12.925640 0.14781 87.22
15.77474927 11.201307 0.15993 88.96
15.72608947 11.475221 0.16968 88.69
15.66437872 11.822601 0.18785 88.37
15.65003478 11.903346 0.16152 88.26
15.75083775 11.335909 0.16067 88.82
15.5113066 12.684270 0.16632 87.48
15.70149167 11.613686 0.17447 88.56
15.72917827 11.457834 0.18187 88.72
15.69474442 11.651668 0.16549 88.51
FCH4 in anh lấy số liệu của B26 đó
CH4 conv. = [F in - F out]/F in *100%
XH2 = FH2/[2F CH4 in]*100%
Rate of carbon deposition = [FCH4 in - FCH4 out]/ W catalyst (mol/g.s)
Carbon balance (%) = [FCH4 out + FC]/[FCH4 in] * 100% = [FCH4 out + 1/2FH2]/[FCH4 in] * 100%