Datos:

T2: 0°c a:32.24 b:0.1923 x 10-2

T1:-8°c c:1.055 x 10-5
ΔH: ?
Cp: 4.217 KJ/K. Kg d: -3.595 x 10-9
Fórmulas:
𝑚𝐶𝑝
𝛥𝑠2 =
𝛥𝑇
𝑐𝑃 = 𝑎 + 𝑏𝑇 + 𝑐𝑇 + ⅆ𝑇
𝛥𝑠𝑖𝑠 = 𝛥𝑆1 + 𝛥𝑆2 + 𝛥𝑆3

Diagrama:

𝐻2 𝑂 (l) 𝐻2 𝑂 (s)
-8°c 0°c

ΔS1 ΔS3

𝐻2 𝑂 (l) 𝐻2 𝑂 (s)
0°c ΔS2 0°c

Sustitución:
ΔS1
273.15𝐾
𝑏𝑇 2 𝑐𝑇 3 ⅆ𝑇 4
𝐶𝑝 = ∫ 𝑎𝑇 + + +
265.15 𝐾 2 3 4
273.15𝐾
0.1923𝑥10−2 𝑇 2 1.055𝑥10−5 𝑇 3 −3.595𝑥10−9 𝑇 4
𝐶𝑝 = ∫ 32.24𝑇 + + +
265.15 𝐾 2 3 4
 273.15𝐾
0.1923𝑥10−2 (273.15𝐾 2 − 265.15𝐾 2 )
𝐶𝑝 = ∫ 32.24(273.15 𝐾 − 265.15 𝐾) +
265.15 𝐾 2
−5 3 3
1.055𝑥10 (273.15𝐾 − 265.15𝐾 )
+
3
−3.595𝑥10 (273.15𝐾 4 − 265.15𝐾 4 )
−9
+
4

273.15𝐾
0.1923𝑥10−2 (4306.4) 1.055𝑥10−5 (1738729.34)
𝐶𝑝 = ∫ 32.24(8) + +
265.15 𝐾 2 3
−9
−3.595𝑥10 (624063872.3)
+
4

273.15𝐾
𝐶𝑝 = ∫ 257.92 + 4.1406036 + 5.824743289 + (−0.5608774052)
265.15 𝐾

𝐶𝑝 = 267.3244695

ΔS2

𝑚𝐶𝑝
𝛥𝑠2 =
𝛥𝑇

𝑘𝐽
4.217 𝐾. 𝐾𝑔
𝛥𝑠2 =
(273.15 − 265.15)𝐾

4.217
𝛥𝑠2 = = 0.527125 𝐾𝐽
9

ΔS3
 265.15𝐾
𝑏𝑇 2 𝑐𝑇 3 ⅆ𝑇 4
𝐶𝑝 = ∫ 𝑎𝑇 + + +
273.15 𝐾 2 3 4

273.15𝐾
0.1923𝑥10−2 𝑇 2 1.055𝑥10−5 𝑇 3 −3.595𝑥10−9 𝑇 4
𝐶𝑝 = ∫ 32.24𝑇 + + +
265.15 𝐾 2 3 4
273.15𝐾
0.1923𝑥10−2 (265.15𝐾 2 − 273.15𝐾 2 )
𝐶𝑝 = ∫ 32.24(265.15 𝐾 − 273.15 𝐾) +
265.15 𝐾 2
−5 3 3
1.055𝑥10 (265.15𝐾 − 273.15𝐾 )
+
3
−3.595𝑥10−9 (265.15𝐾 4 − 273.15𝐾 4 )
+
4
273.15𝐾
0.1923𝑥10−2 (−4306.4) 1.055𝑥10−5 (−1738729.34)
𝐶𝑝 = ∫ 32.24(−8) + +
265.15 𝐾 2 3
−9
−3.595𝑥10 (−624063872.3)
+
4
273.15𝐾
𝐶𝑝 = ∫ −257.92 + (−4.1406036) + (−6114531512) + 0.5608774052
265.15 𝐾

𝐶𝑝 = −6114531773

𝛥𝑠𝑖𝑠 = 𝛥𝑆1 + 𝛥𝑆2 + 𝛥𝑆3

𝛥𝑠𝑖𝑠 = 267.3244695 + 0.527125 + (−6114531773)

𝛥𝑠𝑖𝑠 =-6114531505