Beruflich Dokumente
Kultur Dokumente
Hour Exam 3
Fall, 2004
There are 120 points on this exam. All multiple choice questions are worth 5 points each.
Point values are given in parentheses at the end of each problem. For problems show all
work, including the equation used. Correct units must be specified. No work = no credit.
1. The heat of reaction for one of the following is the enthalpy of formation for the
substance. Which Hrxn is Hf ?
a. 2 Cl(g) + C(graphite) + O(g) Cl2CO(g)
b. Cl2(g) + C(graphite) + 0.5 O2(g) Cl2CO(g)
c. Cl2(g) + CO(g) Cl2CO(g)
d. 2 Cl2(g) + 2 C(graphite) + O2(g) 2 Cl2CO(g)
e. 2 Cl(g) + C(diamond) + O(g) Cl2CO(g)
2. Write electron configurations for each of the following. Indicate whether the
species is paramagnetic (P) or diamagnetic (D). (3 each)
a. 14Si ___1s22s22p63s23p2_____________________ P D
b. 56Ba2+ ___[Xe]_____________________________ P D
c. 47Ag ____[Kr]5s14d10____________________ P D
d. 23V2+ ____1s22s22p63s23p63d3________________ P D
e. 32Ge _____[Ar]4s23d104p2____________________ P D
b. What is the energy of the light in part (a)? h = 6.63 x 10-34 J. s (4)
E = h
= (6.63 x 10-34 J.s)(5.09 x 1014 Hz)
E = 3.37 x 10-19 J
4. The lightest atom with a FILLED 3d-subshell in the ground state is
a. zinc
b. gallium
c. krypton
d. copper
e. rubidium
5. In the ground state of a cobalt atom, there are ______unpaired electrons and the
atom is __________________.
a. 3, paramagnetic
b. 5, paramagnetic
c. 2, diamagnetic
d. 0, diamagnetic
e. 2, paramagnetic
Reverse equation 1.
2 Al(s) + 6 HCl(aq) 2 AlCl3(aq) + 3 H2(g) H = - 1049 kJ
Multiply equation 2 by 6.
6 HCl(g) 6 HCl(aq) H = (- 74.8 kJ) x 6 = - 448.8 kJ
Multiply equation 3 by 3.
3 H2(g) + 3 Cl2(g) 6 HCl(g)H = ( - 185 kJ) x 3 = - 555 kJ
c. Will light in the visible region (8.8 x 1014 s-1 – 4.2 x 1014 s-1) eject an
electron from a lithium atom? Support your answer with an appropriate
calculation. (5)
c
3.0 x108 m s 1 2.31x107 m
1.3 x1015 s 1 Light in the visible region
is at too low frequency to eject an electron.
a. Write the balanced chemical equation for the combustion of picric acid.(3)
2 C6H3N3O7(s) + 6.5 O2 12 CO2(g) + 3 H2O(l) + 3 N2(g)
b. Hcomb for picric acid is –2.560 x 103 kJ/mol picric acid. Calculate
Hf(picric acid). Hf(water liquid) = -285.8 kJ/mol (6)
Hf(CO2) =-393.5 kJ/mol was supplied in class.
H combustion nH f ( prod ) nH f (react )
2(2560) [3(0) 3(285.8) 12(393.5)] [2H f 6.5(0)]
857.4 4722 2H f
2H f 857.4 4722 5120 459.4
kJ
H f 229.7
mol
d. Calculate the heat involved in the detonation of 175.0 g picric acid. Use
dimensional analysis for the second part of this problem. Hf(carbon
monoxide) = -110.5 kJ/mol, Hf(water vapor) = -241.8 kJ/mol. Graphite
is the standard state of carbon. (8)
11. and 13: refer to your textbook for drawings of orbitals and to class notes for
probability distribution sketches. A 3d orbital has 2 nodal planes (= l, the secondary
quantum number) and a 6d orbital has 3 radial nodes (n – l – 1)