TB1539B

September 18, 2012

Three Bond Co., Ltd.

Technical Data
ThreeBond 1539B
(Single Component Low Temperature
Fast Curing Elastic Adhesive)

1. Product description 5. Curing ability

ThreeBond 1539B is a single component low
temperature fast curing elastic adhesive. The adhesive 5.1 Curing behavior
can be cured by heating at a relatively low 10 6
0,000 100

Lap shear strength (Pa⋅s)

temperature (approx. 60°C) in a short time and does Viscosity
粘度 90
10 5
Temperat
0,000 温度 80
not require a long-time curing process. Since it uses a ure

70
plant-derived polymer as the main component, it is an 10 4
0,000 60
environment-friendly adhesive. The cured material is 50
an elastic body, which is resistant to vibration and 10 3
1,000 40
impact and excels in relaxation of stress caused by 30
10 2
expansion and contraction of parts. In addition, it has 100 20
excellent adhesion to various materials. 10
10101 0
Hereinafter, ThreeBond is abbreviated to TB. 0 100 200 300 400 500
Time (s)

2. Features Fig. 1 Curing ability of TB1539B

(1) Single component low temperature fast Test method: 3TS-4200-007 Oscillation strain control
curing (in 1 min or more at approx. Rotor: 25φ4° cone
60°C) type
Rate of temperature rise: 5°C/min,
* The curing conditions vary depending
on the heat capacity of the parts used. Strain: 1%, Frequency: 1Hz
(2) Use of plant-derived polymer as main
component 5.2 Curing characteristics
(3) Elastic in wide temperature range 7.0
Lap shear strength (MPa)

6.0
(-35°C to 100°C)
5.0
(4) Excellent adhesion to various materials
4.0
3.0
3. Applications 2.0
Bonding, sealing and potting of various 1.0
materials 0.0
0 5 10 15 20 25 30

4. Properties Time (day)

Table 1 Properties of TB1539B Fig. 2 Curing time and lap shear strength of
TB1539B
Test item Unit Result Test method
Curing conditions: 60°C × 1.5h
Main — Urethane —
component prepolymer Curing conditions: 23°C, 50%RH
Appearance — White 3TS-2100-002 Test method: 3TS-4100-013
Viscosity Pa⋅s 100* 3TS-2F00-007
Application of aluminum (A1050P) test
Specific gravity — 1.34 3TS-2500-002
pieces after application to both surfaces
* Measuring conditions: Shear rate:5 (s-1)

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8.0 200 Tensile MPa

Lap shear strength (MPa)
Tensile strength
引張強さ 3.5 3TS-4190-001
7.0 strength
伸び率
Elasticity
6.0 150 Elongation % 140 3TS-4190-001
5.0 Cure % 0.02 3TS-2600-001*1
4.0 100 shrinkage
3.0 *1 Dimensions of cured adhesive: φ20 mm × 2 mm
2.0 50
Curing conditions:
1.0
(60°C × 1.5h) + (23°C, 50%RH) × 3 days
0.0 0
0 5 10 15 20 25 30
Time (day) 6.2 Electrical characteristics of cured
adhesive
Fig. 3 Curing time, tensile strength and elongation
of TB1539B Table 3 Electrical characteristics of TB1539B
Curing conditions: 60°C × 1.5h Test item Unit Result Test method
Volume resistivity Ω⋅m 6.5×1010 3TS-5200-001
Curing conditions: 23°C, 50%RH Surface resistivity Ω 1.9×1014 3TS-5200-002
Test method: 3TS-4190-001 Dielectric 1kHz 5.8
—
constant 1MHz 5.0
100 3TS-5220-001
Dielectric 1kHz 0.034
90
Hardness (Durometer A)

loss —
80 1MHz 0.055
tangent
70
Dielectric breakdown
60 kV/mm 22 3TS-5230-002
strength
50
40
30 7. Adhesive strength
20
10
0 7.1 Lap shear strength
0 5 10 15 20 25 30
Table 4 Lap shear strength of TB1539B
Time (day) Test material Unit Result Failure type
Fig. 4 Curing time and hardness of TB1539B Aluminum (A1050P) 4.1 CF
Metals

Iron (SPCC-SD) 3.6 CF

Curing conditions: 60°C × 1.5h Stainless steel(SUS304)
MPa
2.5 CF
Curing conditions: 23°C, 50%RH Copper(C1100P) 3.0 CF
Phenolic resin 4.0 CF
Test method: 3TS-2B00-004 Glass epoxy 4.3 CF
Acryl 0.7 AF
Note: The curing conditions are 1.5 hrs at 60°C to ABS 0.9 AF
make a reference cured material for the test by PC (Polycarbonate) 1.4 AF
using jigs*.
Plastics

6,6-Nylon 0.7 AF
Such curing conditions are used because the PET(Polyethylene MPa
4.1 CF
terephthalate)
heating temperature and time are required to
PBT(Polybutylene
warm up the jigs. 2.5 CF
terephthalate)
* Dimensions of jigs and supplementary explanation PPS(Polyphenylene
1.8 AF
sulfide)
Two aluminum plates (Teflon-treated surfaces) Hard PVC 2.6 CF
having a length of 200 mm, a width of 230 mm and Glass 3.3 CF
Others

a thickness of 8 mm and spacers are used to make a Philippine mahogany MPa

3.1 CF
cured material 2 mm in thickness. After the plywood
adhesive is applied to one of the aluminum plates,
the other plate is put on the adhesive, and pressure
AF: Interfacial failure
is applied to the plate to uniform the thickness of
the adhesive during heating. CF: Cohesive failure
Curing conditions:
6. Characteristics of cured sealant (60°C × 1.5h) + (23°C, 50%RH) × 3 days
Test method: 3TS-4100-013Lamination of test pieces
6.1 Characteristics of cured sealant of the same material after application of
Table 2 Characteristics of TB1539B after curing adhesive to both surfaces
Unit Result Test method * Surface treatment of test pieces used in tests
Hardness - A70 3TS-2B00-004

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Metallic test pieces: Fig. 6 Heat resistance of TB1539 (lap shear

Degreasing with methylene chloride strength)
Plastic and rubber test pieces: Wiping with ethanol Curing conditions:
(60°C × 1.5h) + (23°C, 50%RH) × 3 days
7.2 Peel strength Test method: 3TS-4100-013
Table 5 Peel strength of TB1539B Lamination of aluminum (A1050P) test
Unit Result Failure type pieces after application to both surfaces
Iron (SPCC-SD) kN/m 1.3 AF
Aluminum (A1050P) 1.5 CF 8. Durability
Cotton canvas 2.3 CF
AF: Interfacial failure 8.1 Heat resistance
CF: Cohesive failure
80℃ 100℃ 120℃
Curing conditions: 7.0

Tensile strength (MPa)

(60°C × 1.5h) + (23°C, 50%RH) × 3 days 6.0
Test method: 3TS-4130-230 5.0
Lamination of test pieces of the same 4.0
material after application of adhesive to 3.0
both surfaces 2.0
* Surface treatment of test pieces used in tests 1.0

Metallic test pieces: 0.0

0 1 2 3 4 5 6
Degreasing with methylene chloride Time (Week)
Plastic and rubber test pieces: Wiping with ethanol
Fig. 7 Heat resistance of TB1539B (tensile
7.3 Lap shear strength while heated strength)
Curing conditions:
8.0
(60°C × 1.5h) + (23°C, 50%RH) × 3 days
Lap shear strength (MPa)

7.0
6.0 Test method: 3TS-4190-001
5.0
80℃ 100℃ 120℃
4.0
180
3.0
160
2.0
140
伸 率（ (%)

1.0 120
）

0.0
Elasticity

100
0 20 40 60 80 100 120 80
Temperature (°C) 60
40
Fig. 5 Lap shear strength of TB1539B while 20
heated 0
Curing conditions: 0 1 2 3 4 5 6
Time (Week)
(60°C × 1.5 h) + (23°C, 50%RH) × 3 days
Test method: 3TS-4100-013 Fig. 8 Heat resistance of TB1539B (elongation)
Application of aluminum (A1050P) test
pieces after application to both surfaces Curing conditions:
80℃ 100℃ 120℃ (60°C × 1.5h) + (23°C, 50%RH) × 3 days
7.0
Lap shear strength (MPa)

Test method: 3TS-4190-001

6.0
5.0
4.0
3.0
2.0
1.0
0.0
0 1 2 3 4 5 6
Time (Week)

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80℃ 100℃ 120℃ (60°C × 1.5h) + (23°C, 50%RH) × 3 days

80 Test method: 3TS-4190-001
70 40°C immersed in
40℃水浸漬 85℃,85%RH
Hardness (A)

60 180
water

50 160
40 140

Elongation (%)
30 120
20 100
10 80
0 60
0 1 2 3 4 5 6 40
Time (Week) 20
0
Fig. 9 Heat resistance of TB1539 (hardness) 0 1 2 3 4 5 6
Curing conditions: Time (Week)
(60°C × 1.5h) + (23°C, 50%RH) × 3 days Fig. 12 Elongation of TB1539B immersed in water
Test method: 3TS-2B00-004 at 40°C and exposed to environment at 85°C,
85%RH
8.2 Water resistance and moisture Curing conditions:
resistance (60°C × 1.5h) + (23°C, 0%RH) × 3 days
40℃水浸漬
40°C
water
immersed in 85℃,85%RH Test method: 3TS-4190-001
Lap shear strength (MPa)

6.0
40°C immersed in
40℃水浸漬
water 85℃,85%RH
5.0 80
4.0 70
60
Hardness (A)

3.0
50
2.0 40
1.0 30
20
0.0
10
0 1 2 3 4 5 6
Time (Week) 0
0 1 2 3 4 5 6
Fig. 10 Lap shear strength of TB1539B immersed Time (day)
in water at 40°C and exposed to environment at
Fig. 13 Hardness of TB1539B immersed in water
85°C, 85%RH
at 40°C and exposed to environment at 85°C,
Curing conditions: 85%RH
(60°C × 1.5h) + (23°C, 50%RH) × 3 days
Curing conditions:
Test method: 3TS-4100-013 (60°C × 1.5h) + (23°C, 50%RH) × 3 days
Application of aluminum (A1050P) test
Test method: 3TS-2B00-004
pieces after application to both surfaces
40°C immersed in
40℃水浸漬
water 85℃,85%RH 9. Usage
6.0
Tensile strength (MPa)

5.0
(1) Before applying the adhesive, cleanly
remove moisture, oil, rust and other
4.0 contaminants from the surfaces to be
3.0 bonded.
2.0 (2) Apply the appropriate amount to the
1.0
usage area.

0.0
(3) Until the adhesive cures, do not move. **
0 1 2 3 4 5 6
Cautions when curing
Time (Week)
* The curing conditions vary depending
Fig. 11 Tensile strength of TB1539B immersed in on the heat capacity of the parts used.
Carefully check the curing temperature
water at 40°C and exposed to environment at 85°C,
and curing time prior to use.
85%RH
Curing conditions:

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10. Storage
14. Cautions
The adhesive deteriorates when it is exposed
to heat, moisture and UV light. After using it, fit the For Industrial (Do not use for household
cap tightly, and store it in a dark dry place at -5 to Use Only purposes.)
10°C avoiding direct sunlight. Before using this product, you must accept the
following sales terms.
11. Disposal
z The technical data given herein are not
After the adhesive has all been used, ask an guaranteed values, but examples of
authorized specialist to dispose of the container as experimental values obtained by our specified
industrial waste. test methods. We do not guarantee that the uses
described herein do not conflict with any
12. Laws and regulations intellectual property right.
Fire Service Act: Non-hazardous material z Users are asked to examine whether the product
is appropriate to the purpose of use and can be
13. Directions for use used safely before they use it and bear all
responsibilities and hazards involved in its use.
z Do not inhale or swallow. Harmful to
Never use the product for medical implants that
health. Do not inhale or ingest.
may be embedded, injected or left in the body.
z When handling this product, wear
protective equipment. z We are not liable for personal injury or property
damage caused by improper handling of this
z Keep out of reach of children. product. If the properties or usage of the product
z If in eyes, rinse with clean water for over to be used are unclear, never use it.
15 minutes, and get medical attention.
z For detailed safety information of the product,
z If on skin, wipe off with cloth, and wash see the material safety data sheet (MSDS). To
the skin well with soap. obtain the MSDS, contact our sales office or
z If any bodily abnormalities occur, customer service center.
discontinue use, and get medical z Information in this technical document is
attention. subject to change at our discretion without
z For industrial use. Do not use for notice.
household purposes.
z Do not use on human body.
z To prevent condensation, unseal the
container after reaching room
temperature.
z Before using, sufficiently confirm
whether the method of application and
the purpose are appropriate.
z The effects on the substrates should be
confirmed in advance. If there are any
problems, do not use.
z For hazard and toxicity information not
mentioned herein, see the material safety
data sheet (MSDS).

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