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ABOUT EDUCATORS
PIYUSH MAHESHWARI
• BE (Hons.)
• 11 year experience of IIT JEE in InorganicChemistry
• Author of 'Super Problems in Inorganic Chemistry',
• Ex. HOD Bansal Classes, Kota
• Ex. Senior Faculty of Vibrant Academy, Kota and Allen Career Institute, Kota
BRIJESH JINDAL
• BTech Jaipur MNIT
• 11 year experience of IIT JEE in Physical Chemistry
• Ex. Senior Faculty of Vibrant Academy, Kota, Allen Career Institute, Kota and Bansal
Classes, Kota
ELECTROCHEMISTRY
e r
Electrode potential and standard electrode potential
p x
Q.1 For the cell reaction
E is 1.89 V. If E
x is – 0.28 V, what is the value of E ? try
2Ce4+ + Co 2Ce3+ + Co2+
E
o
tr y Eo
Co 2 | Co
i s o
s standard reduction potential for the half reactionh: eClm+ 2e 2Cl
cell
Ce 4 | Ce 3
m i
e = – 0.15 V C
Q.2 Determine the – –
h
2
C Pt + 2e Pt
o
Given Pt + 2Cl Pt + Cl ,
2+ – E 2 Cell
2+ – E° = 1.20 V
Is 1.0 M H+ solution under H2SO4 at 1.0 atm capable of oxidising silver metal in the presence of 1.0 M
s
Q.3
Ag+ ion?
ts r t
Eo
o
p
= 0.80 V, E H |H
x
r
e = 0.0 V x pe
Ag |Ag
E
yreactions:
2 ( Pt )
r yV E
r
If for the halftcell E°s=t0.15
Q.4
i s Cu + e Cu ;
i
Cu + 2e Cu ; mE° = 0.34 V
2+ – +
m Cu + e Cu he
2+ –
e
ChAlso predict whether Cu undergoes disproportionation orCnot.
Calculate E° of the half cell reaction + –
+
o o
Q.5 If E Fe 2 | Fe = – 0.44 V, E oFe3 | Fe 2 = 0.76 V. Calculate E Fe3 | Fe .
r ts ts
e r
xp pe
Q.6 Consider the following E° values
r y E
E°Fe3+/Fe2+ = + 0.76 V E° = –0.44 V E° = –0.14 V
Fe2+/Fe
E x Sn2+/Sn
i st conditions,
Under standard
3Sn + 2Fe (aq) 2Fe(aq) + 3Sn (aq) is
calculate the EMF for the cell reaction.
t r y
e m (s)
3+
m
2+
h e
Ch the potentials and
Q.7C From the standard potentials shown in the following diagram, calculate E1 E 2 .
r t s
x pe ts
Q.8
E
Calculate the equilibrium
y
constant for the reaction
r
Fe +Ce
2+
i s t r4+ Fe + Ce , 3+ [Given : 3+
xE 0 0
pe]
Ce 4 / Ce3 1.44V;E Fe3 / Fe 2 0.68V
e m 2.303 RT
ryE
C h
Take
F
= 0.06 at 25°C, log 4.68 = 0.67
i s t
Q.9
h m
Calculate the equilibrium constant for the reaction Fe + CuSOe FeSO + Cu at 25°C.
Given : E (Fe/Fe ) = 0.44V, E (Cu/Cu ) = 0.337V.
0 2+ 0
C 2+
4 4
2.303 RT
Take = 0.06 at 25°C, log 7.94 = 0.9
F Page # 1
ELECTROCHEMISTRY
Q.10 At 25°C the value of K for the equilibrium Fe3+
+ Ag Fe2+ +
+ Ag is 0.531mol/litre. The standard
electrode potential for Ag+ + e – Ag is 0.8V. What is the standard potential for
r ts
Fe3+ + e– l Fe2+ ?
e r ts x pe
= 0.06, p log (0.531) = – 0.275 E
2.303RT
Given :
E x tr y
s
F
t r y m i
i s Hg constant
Q.11 Calculate equilibrium for :
h e
e
h :E m (aq)2
2+ Hg(l) + Hg (aq)
C
2+
CGiven
0.8V
Hg 22 ( aq ) / Hg (l )
E
0.92 V
Hg22 (aq) / Hg2 ( aq)
Nernst Equation
Q.12
ts
Calculate the EMF of a Daniel cell when the concentration of ZnSO4 and CuSO4 are 0.001 M and
r ts
er
0.1M respectively. The standard EMF of the cell is 1.1V.
x p x pe
Q.13
y E r yE
For a cell Mg(s) | Mg2+(aq) || Ag+ (aq) | Ag, calculate the equilibrium constant at 25°C. Also find the
st r
maximum work per mole of Mg that can be obtained by operating the cell.
i s t
i
E0 (Mg2+/Mg) = 2.38V, E0 (Ag+/Ag) = 0.8 V.
m e m
Q.14 he h
C valency of the metal if the standard oxidation potential of theCmetal is 0.76V.
n+ +
The EMF of the cell M | M (0.01M) || H (1M) | H (g) (1 atm), Pt at 25°C is 0.82V. Calculate the
2
2.303 RT
Take = 0.06 at 25°C.
s
F
er t ts
Q.15
xp
Calculate E0 and E for the cell Sn | Sn2+ (1M) || Pb2+(103M) | Pb, E0 (Sn2+| Sn) = 0.14V,
per
r y E
E0 (Pb2+| Pb) = 0.13V. Is cell representation correct?
E x
i s t tr y
s
Q.16 At what concentration 2+
of Cu in a solution of CuSO will the electrode potential be zero at 25°C?
m i
4
e
Given : E (Cu | Cu ) = 0.34 V.
0 2+
h e m
C Ch
2.303 RT
Take = 0.06 at 25°C, log 4.68 = 0.67
F
Q.17 The magnitude of standard reduction potentials of two metals 'X' and 'Y' are
Y2+ + 2e– Y |E1| = 0.34V
X + 2e X
2+ –
r ts |E2| = 0.25V
xpe
When two half cells of X and Y are connected to construct a galvanic cell, electrons flow in the external
ts
E r
circuit from X to Y. When X is connected to a standard SHE, electrons flow in the external circuit from
y
is tr
galvanic cell at 25ºC, Calculate the EMF of cell :
x pe
X to SHE. If a half cell X2+ (0.1M) | X is connected to another half cell Y2+ (1.0 M) | Y to construct a
em 2.303 RT
r y E
C h (Given : At 25°C ;
F
0.06 )
i s t
Q.18 Two students use same stock solution of ZnSO and a solution
h e mof CuSO . The e.m.f of one cell is
C
4 4
0.03 V higher than the other. The conc. of CuSO in the cell
4 with higher e.m.f value is 0.5 M. Find out
2.303 RT
the conc. of CuSO4 in the other cell 0.06
F Page # 2
ELECTROCHEMISTRY
s
Q.19 If potential of the cell is 0.98 V at 25°C. Then calculate the pH in anodic compartment.
r t
s pe
Pt(s) | H2(1 atm) | H+(aq) | | Ag+ (0.1 M) | Ag(s)
e r t x
p
2.303RT
[Given : E oAg / Ag
x 0.8 V and
F
= 0.06]
r y E
r E
yPt, H (1 atm)|HOCN (10 M)||Ag (0.8 M)|Ag(s) i t
s0.98V . Calculate the K for
i
Q.20 Voltage of thet
s [H ] because of oxidation of H (g) . hem
cell 3 is +
m
2 a
e C
HOCN . Neglect +
h
2
e Ag(s) = 0.8 V.
+
CGiven :
Ag +
2.303RT
= 0.06
F
ts r ts
r pe
Q.21 Calculate the potential of an indicator electrode versus the standard hydrogen electrode, which originally
p e x
contained 0.1M MnO4 and 0.5M H+ and which was treated with 50% of the Fe2+ necessary to reduce
x
all the MnO4 to Mn+2.
E yE
r y
MnO4 + 8H+ + 5e Mn2+ + 4H2O, E0 = 1.51V
t = 0.06 i s t r
Given : is m
2.303RT
e m F
h e
ChA zinc electrode is placed in a 0.1M solution at 25°C. Assuming
Q.22
C that the salt is 20% dissociated at this
dilution, calculate the electrode potential. E0 (Zn2+| Zn) = 0.76V. [log 2 = 0.3]
r t s CONCENTRATION CELLS
t s
Q.23 Calculate the EMF of the p e cell at 298 K. e r
E x following
x p
y E
Zn | Zn (0.01M) 2+ || Zn (0.1 2+
M) | Zn
i r
stSolutions of two weak acids, HA (pK = 3) and HB (pK =i5)saretreach y placed in contact
withm
Q.24 Equinormal
e equal pressure of hydrogen electrode at 25°C. When a cell is econstructed
a a
h h m by interconnecting them
r ts
pe
Q.26 Calculate pH using the following cell :
E x
Pt (H2) | H+ (x M) | | H+ (1 M) | Pt (H2) if Ecell = 0.2364 V.
r ts
1 atm
C Given :
5 6
i
em
a b 2
2.303RT
= 0.06
F
C h
Page # 3
ELECTROCHEMISTRY
CELL CONSISTING SPECIAL HALF-CELLS
r ts
Q.28
r ts
The standard reduction potential for Cu2+ / Cu is 0.34 V. Calculate the reduction potential at
e x pe
p
pH = 14 for the Pt, KOH / Cu(OH)2 / Cu couple. Ksp of Cu(OH)2 is 1 × 1019.
E
2.303RT
=E
x
s try
try i
Given : 0.06
F
i sstorage cell is represented as Fe(s) | FeO(s) | KOH(aq)
e m
h | Ni O (s) | NiO(s) The halfcell
e m
Q.29 The Edison
h C 2 3
Creaction
2
are
3 2
Ni O (s) + H O(l) + 2e 2NiO(s) + 2OH
E = + 0.40V 0
E x E
y constants of AgBr
Q.30 Consider the celly
r
& AgCl ares5t× 10 & 1 × 10 respectively. For what ratio of the concentrations
Ag|AgBr(s)|Br
t r
s of Br & Cl ions
||AgCl(s), Ag | Cl at 25º C . The solubility product
i
m i 13 10
e m
e
would the emf of the cell be zero ?
h
ChThe pK of AgI is 16.5. If the Eº value for Ag Ag is 0.80VC. Find the Eº for the half cell reaction AgI
Q.31
(s) +
sp
e Ag + I.
+
2.303 RT
Given :
F
0.06
r t s ts
e
p|| KCl(0.002M), AgCl | Ag er
x
Eof given cell at 25°C :
Q.32 Ag | AgBr , KBr(0.01M)
x p
ry(s)
E
(s) (s)
[Given :iK
2.303RT
e m sp(AgCl)
–10 2
m sp(AgBr)
–14 2
h
F
r ts
p e
[Given : C oCd 2 / Cd 0.39V and = 0.06 ]
2.303RT
E x F
r t s
t r y reduction potential of CuS/Cu electrode. p e
is
Q.34 Calculate the standard
= 0.06 ] yE
x
h e m
[Given K of CuS is 10 M , –36 2 E oCu 2 / Cu
= 0.34 volt,
t r
.303 RT
s
sp F
C m i
h e AgBr(s) | Ag,
Q.35 For the galvanic cell : Ag|AgCl(s)| KCl (0.2M) || K Br (0.001 M)|
Calculate the EMF generated and assign correct polarity Cto each electrode for a spontaneous process
after taking into account the cell reaction at 25°C. [Ksp(AgCl) = 2.64 ×10–10; Ksp(AgBr) = 3.3 ×10–13]
Page # 4
ELECTROCHEMISTRY
Q.36 For the cell : Pt/Hg(l)/Hg2Cl2(s)/Cl–(0.1M)||Cl–(0.01M)/Cl2(1 atm)/Pt
Ecell is equal to 1.16V. What will be the value of E°cell?
r t s
Q.37 Given, E° = –0.276V for the Cl r ts | Pb couple and – 0.126 V for the Pb | Pb couple,
p e
p e | PbCl –
E x determine 2+
x [Given : y
2
y E 2.303RT
i s t r
r
K for PbCl at 25°C? = 0.06]
t
sp 2 F
i s product of a saturated solution of Ag CrOhinewater mat 298 K if the emf of the cell
h e m
Q.38 Find the
(satd.Ag CrO soln.) || Ag (0.1 M) | Ag is 0.164C
solubility 2 4
C Ag|Ag + + V at 298K.
2 4
Q.39 The standard potential of the following cell is 0.23 V at 15° C & 0.21 V at 35° C
Pt | H2(g) | HCl (aq) | AgCl(s) | Ag(s)
(i) Write the cell reaction.
ts r ts
(ii)
x p er
Calculate H0 ,S0 for the cell reaction by assuming that these quantities remain unchanged in
x pe
E
the range 15°C to 35°C.
(iii)
y E r y
Calculate the solubility of AgCl in water at 25°C. Given standard reduction potential of the
r t
+
s t
Ag /Ag couple is 0.80 V at 25°C.
i i s
e m
Q.40 Calculate the equilibrium constant for the reaction:
hem
h
C E for Sn/Sn =0.136 V E for Sn /Sn = – 0.156 VC
3Sn(s) + 2Cr O + 28H 3Sn + 4Cr + 14H O
0
2
2+
7
2– +
0 2+
4+
4+
3+
2
couples. st r y
reduction potentials
y
3+
3
2+
r
3
Q.42 For m
i i t
s ] ; E = 2.73 V. If
h e the reaction, 4Al(s) + 3O (g) + 6H O + 4 OH 4 [Al(OH)
= –237.2 kJ mol e
2
m 2
–
4
–
cell
C G f (OH )
= –157 kJ mol and –1
C h
G f ( H 2 O)
, determine [Al (OH) ]. –1
G f 4
–
. ELECTROLYTIC CELL
Q.43 Calculate the no. of electrons lost or gained during electrolysis of
(a) 3.55 gm of Cl– ions
(b) 1 gm Cu2+ ions
r t s
(c) 2.7 gm of Al3+ ions
x pe ts
r
Q.44 How many faradays E
yAl is converted to Al.
of electricity are involved in each of the case
e r
(a) 0.25tmole
is
3+
x p
(b) m24 gm of SO is convered to SO
e The Cu in 1100 ml of 0.5 M Cu is converted to Cu. istry
2
E
h
3 3
C (c) 2+ 2+
Page # 5
ELECTROCHEMISTRY
Q.46 The electrosynthesis of MnO2 is carried out from a solution of MnSO4 in H2SO4 (aq). If a current of 25
ampere is used with a current efficiency of 80%, how long would it take to produce
r ts
0.870 kg of MnO2?
r ts
eat the cathode, how much O gas is formed at theyanode pe
xunder identical
x p
Q.47 If 0.224 litre of H gas is formed
r E
y
2
E 2
i s t
stCras one unit of electricity. If cost of electricity ofhproducing
conditions?
i e m x gm Al is Rs x, what is the
ofm
Q.48 Assume 96500
coste C
h electricity of producing x gm Mg?
Q.49CChromium metal can be plated out from an acidic solution containing CrO according to following equation:
3
CrO3(aq) + 6H+ (aq) + 6e– Cr(s) + 3H2O
Calculate :
(i)
ts
How many grams of chromium will be plated out by 24000 coulombs and
r ts
(ii)
er
How long will it take to plate out 1.5 gm of chromium by using 12.5 ampere current
x p x pe
y E r y E
t
Q.50 Calculate the quantity of electricity that would be required to reduce 12.3 g of nitrobenzene to aniline, if
i st r i s
the current efficiency for the process is 50 percent. If the potential drop across the cell is 3.0 volts, how
Q.52 A metal is known to form fluoride MF2. When 10A of electricity is passed through a molten salt for 330
r ts
sec., 1.98g of metal is deposited. Find the atomic weight of M. What will be the quantity of electricity
ts
e r
xp pe
required to deposit the same mass of Cu from CuSO4?
ry E E x
y
Q.53 Cadmium amalgam is prepared by electrolysis of a solution of CdCl2 using a mercury cathode. How
i st tr
long should a current of 5A be passed in order to prepare 12% CdHg amalgam on a cathode of 2gm
i s
e m
Hg (Cd=112.4)
m
Q.54 h
A solution of Ni(NO ) is electrolysed
3 2 between platinum e
C 20 mintue. What mass of Ni is deposited at the cathode? [NiC=h58.71]using a current of 5 ampere for
electrodes
Q.55 A current of 3.7A is passed for 6hrs. between Ni electrodes in 0.5L of 2M solution of Ni(NO3)2.
What will be the molarity of solution at the end of electrolysis?
r ts
Q.56
xpe
Copper sulphate solution (250 mL) was electrolysed using a platinum anode and a copper cathode. A
constant current of 2 mA was passed for 16 mintue. It was found that after electrolysis, the absorbance
ts
yE r
r pe
(concentration) of the solution was reduced to 50% of its original value. Calculate the concentration of
i s t
copper sulphate in the solution to begin with.
x
e m of a solution of HSO ¯ ions produces S O , assuming 75%rcurrent
E
y efficiency, what
h
Q.57 Electrolysis
C current should be employed to achieve a production rate of 1 mole
4 2 8
2–
t
ofiSsO per hour? 2–
em
2 8
h
Cof the process.
Q.58 A current of 3 amp was passed for 2 hour through a solution of
as Cu at cathode. Calculate percentage current efficiency
2+
CuSO ,3 g of Cu ions were deposited
4
Page # 6
ELECTROCHEMISTRY
Q.59 Dal lake has water 8.2 ×1012
litre approximately. A power reactor produces electricity at the rate of
1.5×106coulomb per second at an appropriate voltage.How many years would it take to electrolyse the
r ts
lake?
r t s
e CONDUCTANCE x pe
x p r yE
r
Q.60 The resistancetof
E iss
ayconductivity cell filled with 0.01N solution of NaCl i
t
s m
i conductivity of the solution. The cell constanthofethe conductivity cell is 0.88 cm .
210 ohm at18 C.Calculate o
m
the equivalent -1
Q.62 The conductivity of pure water in a conductivity cell with electrodes of cross sectional area 4 cm2
ts r ts
r pe
and 2 cm apart is 8 × 10-7 S cm-1.
p e
(i) What is resistance of conductivity cell ?
x
x E
y and equivalent
(ii) What current would flow through the cell under an applied potential difference of 1 volt?
r ts
Q.65 A solution containing 2.08 g of anhydrous barium chloride is 400cm3 of water has a conductivity
ts
e r
xp pe
0.0058 ohm–1cm–1. What are molar and equivalent conductivities of this solution.
ry E E x
st electroytes yCalculate
APPLICATION OF KOHLRAUSCH'S LAW
i
Q.66 For the strong
tr
NaOH, NaCl and BaCl the molar ionic conductivities
2
i s
at infinite dilution
m –4 –4
C hconductivity 2
h e
Q.67 Equivalent conductance of 0.01 N Na SO solution C
2 is 117 ohm cm eq . The equivalent
4
–1 2 –1
–1 2 –1
conductance at infinite dilution is 130 ohm cm eq . What is the degree of dissociation in 0.01 N
Na2SO4 solution?
Q.68
r ts
The value of m for HCl, NaCl and CH3CO2Na are 426.1, 126.5 and 91 S cm2 mol–1 respectively..
x pe
Calculate the value of m for acetic acid. If the equivalent conductivity of the given acetic acid is 48.15
t s
E
at 25° C, calculate its degree of dissociation.
h e m
conductance –6
t r–1 –1
C 2 –1
i s
are 137.4 , 133 , 131 ( S cm mol ) respectively. Calculate the solubility
m
of AgBr in gm/litre.
3 3
of AgCl at 25°C.
Page # 7
ELECTROCHEMISTRY
Q.71 Hydrofluoric acid is weak acid. At 25°C, the molar conductivity of 0.002M HF is
r ts
s pe
176.2 ohm–1 cm2 mole–1. If its m = 405.2 ohm–1 cm2 mole–1, calculate its degree of dissociation
e r t
and equilibrium constant at the given concentration.
x
p
x of 0.10 N solution of MgCl is 90 mho cm equi r E
yat 25°C. a cell with
E
y1.5 cm in surface area and 0.5 cm apart is filled
Q.72 The equivalent conductance
r
2
i t
s 0.1 N MgCl solution.
2 –1
How muchis t
electrode that are 2
e m with 2
ts r ts
x p er x pe
E
stryE
i s try
mi em
e h
Ch C
r ts ts
e r
E xp x pe
ry yE
i st i s tr
em m
Ch Ch
e
r ts
xpe ts
yE r
is tr x pe
em ryE
C h i s t
hem
C
Page # 8
ELECTROCHEMISTRY
EXERCISE-2
r ts
Single correct
e r t s x pe
Q.1
p E
The potential of hydrogen electrode in contact with a solution whose pH is 6, pressure of H2 is 1 bar will
x) 0.06 ] r y
be -[Given :
r yF E
RT ( 2.303
i s t
(A) 0.36 Vis
t e m
m (B) 0.72V
ehalf cell reaction : Ag (aq) + 1e
(C) 0.3V
C h (D) 0.21V
Q.2 h
CWhich of the following line represent variation of reduction potential with concentration of Ag ?
For + –
Ag(s)
+
ts
1
r ts
r pe
Ered 2
p e x
x
E (B) 2
3
E
yand (C) both
r y log[Ag ] +
s tr
(A) 1
i st (C) 3
mi
(D) (A)
e m h e
ChGiven : E C
Q.3 Which of the following reaction is spontaneous?
= 1.51 V,, E = – 2.87 V F / F2
MnO 4 / Mn 2
r ts t s
e
pl F (aq) + Mn (aq)
E oI2 / I ¯ 0.535 V
e r
E x x p
y
–
(A) MnO (aq) + F (aq) – 2+
r y E
i 4
mare spontaneous
(C) Ag (aq)+
2
3+
i s t
h e
(D) All
e m
C One gm metal M was discharged by the passage of 1.81 C
Q.4 +2 h 22
× 10 electrons. What is the atomic weight
of metal?
(A) 33.35 (B) 133.4 (C) 66.7 (D) 55
Q.5
t s
One mole of electron passes through each of the solution of AgNO3, CuSO4 and AlCl3 then Ag, Cu and
r
pe
Al are deposited at cathode. The molar ratio of Ag, Cu and Al deposited are
(A) 1 : 1 : 1
E x (B) 6 : 3 : 2 (C) 6 : 3 : 1 (D) 1 : 3 : 6
r t s
t r yweight = 7), B (atomic weight =27) and C (atomic weight = 48) werepelectrolysed
e
Q.6
s conditions using the same quantity of electricity. It was found thatEwhen
Salts of A (atomic
i x 2.1 g of A was
h m
under identical
e tr
deposited, the weights of B and C deposited were 2.7 and 7.2 g. The valenciesy of A, B and C
C (A) 3, 1 and 2 (B) 1, 3 and 2 (C) 3, 1 and 3 emis(D) 2, 3 and 2
respectively are
e
2
m
helectrodes. The products at the cathode
(C) 2.5 g of (D) a decrease of 2.5 g of mass takes place
e m
h anode are respectively. C
Cand
Q.10 A solution of sodium sulphate in water is electrolysed using inert
Q.11
ts
A standard hydrogen electrode has zero electrode potential because
r ts
(A) hydrogen is easier to oxidise
x p er x pe
(B) this electrode potential is assumed to be zero
y E
(C) hydrogen atom has only one electron
r y E
s t r
(D) hydrogen is the lighest element.
i s t
Q.12 If them
i e m
e h
pressure of H gas is increased from 1 atm to 100 atm keeping +
H concentration constant at 1 M,
r ts
Pt | H2(0.4 atm) | H+(pH=1) || H+(pH = 2) | H2 (0.1 atm) | Pt
ts
e r
xp
The measured potential at 25°C is
(A) –0.1 V
yE
(B) –0.5 (C) –0.041
x
(D) none
pe
r E
y kJ/mol
t reaction 2H (g) + O (g) 2H O(l) ; H (H O, l) t=r–285.5
scell
i
o
Q.14 For the fuel
hWhat o
e m
C Given: Ch V (D) – 0.322 kJ/K
298
O (g) + 4H (aq) + 4e 2H O(l)
2
+ –
2 E° = 1.23
(A) – 0.322 J/K (B) – 0.635 kJ/K (C) 3.51 kJ/K
Q.15 The standard reduction potentials of Cu2+/ Cu and Cu2+ / Cu+ are 0.337 and 0.153 V respectively. The
r ts
standard electrode potential of Cu+ / Cu half cell is
i2
(in S m mols –1
) of the solution is x
Eof these
h e m
(A) 0.2 (B) 0.02 (C) 0.002
r y
(D) None
t
C dilution is 200 Scm equivalent Hence pH of HA solution is em
Q.17 Equivalent conductance of 0.1 M HA(weak acid) solution is 10 Scm i s 2
equivalent –1
and that at infinite
Ch (D) 3.7
2 –1
Page # 10
ELECTROCHEMISTRY
Q.18 –1
The electrical resistance of a column of 0.07 mol L NaOH solution of diameter 1 cm and length 55 cm
22
r ts
e r ts
is 5 × 103 ohm. What will be its molar conductivity.
7
x pe
2
(A) 50 S cm mol –1
p 2
(B) 100 S cm mol
x
–1
E
(C) 150 S cm2 mol–1 (D) 200 S cm2 mol–1
r y conductivities of
ofE
Q.19 If the conductivityy
r i s t
t
–5
0.001 M propionic acid is 3.83 × 10 S-cm and limiting molar–1
i
HCl, KCl and m then acid dissociation
s potassium propionate are 426, 126, 83 S cm molherespectively 2 –1
h e m
constant of propionic acid is -
C10 (D) 10
C (A) 10 –6 (B) 1.11 × 10 –5
(C) 1.11 × –4 –3
Q.20 If x is specific resistance of the electrolyte solution and y is the molarity of the solution, then ^m is given
ts
by [x is in ohm cm–1 & m in –1 cm2 mol–1]
r ts
1000 x
xp
er y 1000 xy
x pe
(A) (B) 1000 (C) (D)
E
E try
y x xy 1000
r y is is at infinite dilution is
st constant of n-butyric acid is 1.6 × 10 and the molarsolution
380 × 10i Sm mol . The specific conductance of the 0.01 M acidm
Q.21 The dissociation –5
conductivity
e m –4 2 –1
Q.22 The conductivity of a saturated solution of Ag3PO4 is 9 × 10–6 S m–1 and its equivalent conductivity is
1.50 × 10–4 S m2 equivalent–1. The Ksp of Ag3PO4 is
(A) 4.32 × 10–18
r ts
(B) 1.8 ×10–9 (C) 8.64 × 10–13 (D) None of these
t s
inp
Q.23 A saturated solution x
e r
e of
y Eand limiting molar conductivity of Ag and A¯ are 60EScmx mol and
–14
AgA (K = 3×10 ) and AgB (K = 1×10 ) has conductivity
sp p
sp
–14
375 × 10
80 Scm i
r
st respectively then what will be the limiting molar conductivity
Scm–10 –1
e m
2
mol –1
i s270 2 –1
h
(A) 150 (B) 180 (C) 190
e m (D)
r ts
Q.25
xpe
Equal volumes of 0.015 M CH3COOH & 0.015 M NaOH are mixed together. What would be molar
ts
E
conductivity of mixture if conductivity of CH3COONa is 6.3 ×10–4 S cm–1
y r
t
(A) 8.4 S cm2 mol–1
is r (B) 84 S cm2 mol–1
x pe
e m
(C) 4.2 S cm2 mol–1 (D) 42 S cm2 mol–1
ry E
Q.26 h MtX and 1 M Z at 25°C. If the
A gas Y at 1 atm is bubbled through a solution containing a mixture of i1s
C reduction potential of Z > Y > X, then emZ and X
(A) Y will oxidise X and not Z
(C) Y will oxidise both X and Z
h
Creduce both X and Z.
(B) Y will oxidise
(D) Y will
Page # 11
ELECTROCHEMISTRY
Q.27 + – + –
For the electrochemical cell, M | M || X | X, E° (M /M) = 0.44 V and E° (X/X ) = 0.33V. From this
data , one can deduce that
r ts
er ts
(A) M + X M+ + X– is the spontaneous reaction
x pe
p
(B) M+ + X– M + X is the spontaneous reaction
E
x try
(C) Ecell= 0.77 V
E s
try i
(D) Ecell= –0.77 V
Conductance
ts r ts
(A)
x p er (B)
x pe
E
E try
Volume of NH4OH solution Volume of NH4OH solution
ry s
i st i
m em
Conductance
Conductance
e h
Ch(C) (D) C
Volume of NH4OH solution Volume of NH4OH solution
Q.29
r ts
The correct order of equivalent conductance at infinite dilution of LiCl, NaCl and KCl is
ts
e r
xp pe
(A) LiCl > NaCl > KCl (B) KCl > NaCl > LiCl
r y E
(C) NaCl > KCl > LiCl
x
(D) LiCl > KCl > NaCl
E
i s t of KNO is used to make salt bridge because
Q.30 Saturated solution
try
e m of K is greater than that of NO
3
i s
m
+
(A) velocity
C h h e 3
C
+
(B) velocity of NO is greater than3that of K
+
(C) velocities of both K and NO are nearly the same 3
(D) KNO3 is highly soluble in water
Q.31
r ts
Standard electrode potential data are useful for understanding the suitablilty of an oxidant in a redox
p e
titration. Some half cell reactions and their standard potentials are given below:
E x
r ts
y(aq) + 14 H (aq) + 6e 2Cr (aq) +7H O (l); E° = 1.38 V pe
MnO (aq) + 8H (aq) + 5e Mn (aq) + 4H O (l); E° = 1.51 V
+ – 2+
r
4 2
CrsO
i t 2 + –
x 3+
m
2 7
h
C Identify the only incorrect statement regarding quantitative estimation
– –
i saqueous Fe(NO )
em
2
of
(B) Cr O h
3 2
C
2
(A) MnO can be used in aqueous HCl
4 can be used in aqueous HCl 2 7
(C) MnO 4 can be used in aqueous H2SO4 (D) Cr2 O 72 can be used in aqueous H2SO4
Page # 12
ELECTROCHEMISTRY
More than one may be correct :
Q.32 Which of the following arrangement will produce oxygen at anode during electrolysis ?
r ts
er ts
(A) Dilute H2SO4 solution with Cu electrodes.
x pe
p
(B) Dilute H2SO4 solution with inert electrodes.
E
E x
(C) Fused NaOH with inert electrodes.
s try
i s try
(D) Dilute NaCl solution with inert electrodes.
emi
e m Ch
C(A)h Molar conductance ( ) is intensive quantity.
Q.33 Identify the correct statement :
m
(B) During discharging of lead storage battery density of electrolyte solution decrease.
(C) Cell constant values of a cell are independent of electrolyte used.
ts r ts
r pe
(D) Fresh water corrodes much faster than sea water.
p e x
x E
E try
Q.34 Following data is obtained for aqueous solution of NaCl at 25°C
ry s
i st conc.(M) 0.25 1.00
mi
em 0.015 he
h C
–1 2 –1
(ohm m mol ) 0.016
C
m
r ts
(B) The value of m for 0.16 M - NaCl solution is 0.0162 ohm–1 m2 mol–1.
ts
e r
xp pe
(C) The conductivity of 0.04 M - NaCl solution is 0.664 ohm–1 m–1, when the conductivity of water is
E x
neglected.
ry E
y430, 120 & 90 S cm
stmolar conductance of HCl, NaCl and CH COONa is given r
(D) Conductivity of NaCl solution increases on dilution.
m i
Q.35 The limiting 0m
i s t by 2
h e em
3
C h
–1
mol respectively. If conductance of a 0.1 M solution of CH COOH –3
is 4 ×10 S in a conducting cell
3
1 –1
C
of cell constant cm then identify the correct statement(s).
10
(A) Specific conductance of 0.1 M CH3COOH solution is 4 ×10–4 S cm–1
r ts
(B) pH of 0.1 M CH3COOH solution is 3.
pe
(C) Degree of dissociation of CH3COOH 1%.
(D) Specific conductance of 0.2 M solution of CH3COOH will be less than 3 × 10–4 S cm–1
E x r ts
t r
Q.36 Choose the correctyvalues of conductivity cells are independent of the solution filled into thepcell.
statement(s). e
is law is valid for strong electrolyte but not for weak electrolyte yEx
(A) Cell constant
m
h e
(B) Kohlrausch
i s tr
C dilution. e m
(C) In general conductivity decreases on dilution whereas equivalent and molar conductivity increase on
C
(D) Salt bridge is employed to maintain the electrical neutralityhand to minimize the liquid - liquid junction
potential.
Page # 13
ELECTROCHEMISTRY
s
Q.37 If 270.0 g of water is electrolysed during an experiment performed by miss Abhilasha with 75% current
r t
s pe
efficiency then
er t
(A) 168 L of O2 (g) will be evolved at anode at 1 atm & 273 K
x
p E
x try
(B) Total 504 L gases will be produced at 1 atm & 273 K.
E s
try i
(C) 336 L of H2 (g) will be evolved at anode at 1 atm & 273 K
i s
(D) 45 F electricity will be consumed
e m
h of standard reduction potentials
m
Q.38 Pickeout the correct statements among the following from C
h standard state conditions). inspection
C(Assume
Cl (aq.) + 2e 2Cl (aq.) – E o
= + 1.36 volt
2 Cl 2 / Cl
m i
(A) Cl can oxidise
2 SO 24
e m
e
– –
h
(B) Cl can oxidise Br and I from aqueous solution
r ts
Ag(s) | AgCl(s) | KCl (1M) | H+(1M) | H2(g) (1atm) ; Pt(s).
ts
e r
xp pe
Which of the following will decrease the EMF of cell.
r y E
(A) increasing pressure of H2(g) from 1 atm to 2 atm
(B) increasing Cl– concentration in Anodic compartment
E x
i st
(C) increasing H+ concentration in cathodic compartment
t r y
m
(D) decreasing KCl concentration in Anodic compartment.
e i s
h e m
C
Assertion & Reasoning type questions
Cforhlong period of time.
Q.40 Statement -1 : The voltage of mercury cell remains constant
Statement -2 : It is because net cell reaction does not involve active species.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
r ts
(C) Statement-1 is true, statement-2 is false.
x pe
(D) Statement-1 is false, statement-2 is true.
t sso
r E
y power of ions is C > A > B . e r
t p
Q.41 Statement -1 : The SRP of three metallic ions A +
,B , C 2+
are –0.3, 3+
–0.5, 0.8 volt respectively,
E x
yfor statement-1.
h eStatement-1 is true, statement-2 is true and statement-2 is correct explanation
Statement
(A)
i t r
s explanation for statement-1.
C (B) m
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct
e
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true. C h
Page # 14
ELECTROCHEMISTRY
Q.42 Statement -1 : We can add the electrode potential in order to get electrode potential of net reaction.
Statement -2 : Electrode potential is an intensive property.
r ts
er ts pe
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
x
p E
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
E x
(C) Statement-1 is true, statement-2 is false.
s try
i s try
(D) Statement-1 is false, statement-2 is true.
e mi
e m
Comprehension :
Paragraph for Question Nos.C
h
CAhsample of water from a large swimming pool has a resistance of 10000 at 25°C when placed in a
43 to 45
certain conductance cell. When filled with 0.02 M KCl solution, the cell has a resistance of 100 at
25°C. 585 gm of NaCl were dissolved in the pool, which was throughly stirred. A sample of this solution
s
gave a resistance of 8000 . [Given : Molar conductance of NaCl at that concentration is 125 –1 cm2
t r ts
r pe
mol–1 and molar conductivity of KCl at 0.02 M is 200 –1 cm2 mol–1.]
p e x
x
Q.43 Cell constant (in cm–1) of conductance cell is:
E
y E try
(A) 4 (B) 0.4 (C) 4 ×10–2 (D) 4 ×10–5
i s r
Q.44 Conductivityt(Scm ) of H O is:
–1
i s
m em(D) None of these
2
e h
(A) 4 × 10 –2 (B) 4 × 10 –3 (C) 4 × 10–5
Q.45 h C
C Volume (in Litres) of water in the pool is:
(A) 1.25 × 105 (B) 1250 (C) 12500 (D) None of these
r ts ts
Match the column :
e r
E xp x pe
Q.51
r y
Column I Column II
y E
st solution of HCl r
(Electrolysis product using inert electrode)
(A) i
Dilute
mDilute solution of NaCl
(P)
i t
sat cathode
O2 evolved at anode
e em
Ch(C) Concentrated solution of NaCl
(B) (Q) H evolved
(R) hCl evolved at anode
2
Q.53 Column-I
r ts Column-II
y E x
h e
(C) Conductivity
tr
(R) increases with dilution
(S) temperatures
i concentration
C (D) G° cell
e m
dependent
C h
(T) increases with
Page # 15
ELECTROCHEMISTRY
Q.52 List-I List-II
(Solutions mixed) (Conductance vs Volume of
r ts
e r ts solution added curve)
x pe
x p r yE
E t
Conductance
r y solution is added to a solution
WhentNaOH i s
(A)
i s h e
(P)
m
em C
Ch containing equimolar mixture of HCl + CH COOH
Volume
Conductance
ts r ts
(B)
er
BaCl2 solution is added to Na2SO4 solution
x p
(Q)
x pe
E
E try
Volume
ry s
i st mi
Conductance
e m h e
Ch(C) NaHCO solution is added to HCl solution
3 C (R)
Volume
r t s s
Conductance
t
is p
CaCl solutionx
e er
(D)
y
2
E added to NaOH solution (S)
x p
r
st Ca(OH) is completely insoluble in water) ryE
i t
Volume
e m
(Assume
i s
m
2
h e
C Ch
r ts
xpe ts
yE r
is tr x pe
em ryE
C h i s t
hem
C
Page # 16
ELECTROCHEMISTRY
ANSWER KEY
r ts
e r t s EXERCISE-1
x pe
Q.2p 1.35 V E
x try
Q.1 1.61 V Q.3 No
r y E i s
Q.4
i s t
0.53 V, undergo disproportionation Q.5
em – 0.04 V
Q.6 Vm
0.1 e
h Q.7 0.522 V, 0.613 V ChK = 4.68 × 10
Q.8 12
Q.12 E =1.159V
ts
Q.13
r t
Kc = 1.0 × 10106, G0 = – 613.74 kJ
s
Q.15erNo, E = 0.078V Q.16 [Cu ] = 4.68 × 10 M pe
Q.14 n = 2
x p cell
E x 2+ 12
i s t Q.19 4
i s
Q.20 K =m Q.22 Ee=m
e h
3.2 × 10 3
Q.21 1.414V 0.81 V
Ch0.0295 V
a
r ts ts
pe 0.3 Volt r
Q.29 (ii). 1.27 V, (iii) 245.1 kJ Q.30 [Br ] : [Cl] = 1 : 200
E0 = 0.19V
yE xQ.32 10–15 x pe
E
Q.31 Q.33
i r
st Q.35 try
m
Q.34 – 0.74 Volt
e
– 0.036V Q.36 1.1V
i s
Q.37 h e m
C 10 M Ch
–5 3 Q.38 Ksp = 2.287 × 1012
Q.39 H0 = – 49987 Jmol–1 , S0 = – 96.5 J mol–1 K–1 , s = 1.47 ×10–5 M
r ts
Q.43
p e
(a) 6.02 × 1022 electrons lost, (b) 1.89 × 1022 electrons gained, (c) (b) 1.80 × 1023 electrons gained
E x r ts
tr y
Q.44 (a) 0.75 F, (b) 0.6F, (c)1.1 F Q.45 (i) 54 gm, (ii) 16.35 gm
pe
i s E x
e m
Q.46 96500 sec Q.47 0.112 litre Q.48 Rs. 0.75 x
tr y kJ
Q.49 h i s
C (i) 2.1554 gm ; (ii) 1336. 15 sec Q.50 115800C, 347.4
et =m93.65 sec.
Q.51 t = 193 sec Q.52 A=115.8, Q=6018C
C h
Q.53
r ts
Q.60 419 S cm2 equivalent –1
r ts
e× 10 amp pe
Q.61 0.00046 S cm-1 ; 2174 ohm cm
x
x p
Q.62 (i) 6.25 × 10 ohm, (ii) 1.6
r yE
E t
5 -6
r y m , 0.141 mho m
Q.63 0.0141 mho gtequiv Q.64 0.002 i
s
i s –1 2
e
–1
m
e m Mho cm mol , (ii) 116 Mho cm equivalent Ch
C h
Q.65 (i) 232
–4
2 –1
2 –1
2 –1
i s i
h e m h em
C
EXERCISE-2
C
Q.1 A Q.2 A Q.3 B Q.4 C Q.5 B
Q.6 B
r ts Q.7 B Q.8 D Q.9 D Q.10 A
s
Q.12 Ape rCt
Q.11 B
E
y C
x Q.13 C Q.14 D
xQ.20 pe
Q.15
tr ryE
is Q.22 A
Q.16 C Q.17 Q.18 D Q.19 B C
Q.21 B m i s t
h e Q.23 D
m
Q.24 B
e
Q.25 B
CA
Q.26 Q.27 B Q.28 C
C hQ.29 B Q.30 C
Dp e
Q.41 A
x
Q.42
EQ, R, (D) P,S
Q.43 B Q.44 C Q.45
r ts A
t r y
Q.46 (A) P, Q (B) P, Q (C)
pe
i s E x
e m
Q.47 (A) PRS
h
(B) PS (C) PST (D)QS
try
C i s
Q.48 (A) P (B) Q (C) R (D) S
hem
C
Page # 18