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H++OH−⇌H2O
5. Buffered solutions
By definition, a buffer solution is one that does not show and resists changes in pH by
adding small amounts of an acid or an alkali to it. Simply, an acidic buffer solution that has a pH
of less than 7. Acidic buffer solutions are usually made from a weak acid and one of its salts-
mostly a salt of sodium. A common example of that would be a solution mixture of ethanoic acid
and sodium ethanoate. In this case it would have a pH of 4.76 if the solution had equal molar
concentrations of both the acid and the salt. As long as they were the same, it wouldn't matter
what the concentrations were. In contrary, a solution to an alkaline buffer has a pH greater than
7. Usually its solutions are made from a weak base and one of its salts. A widely used example
is a mixture of a solution of ammonia and ammonium chloride. The solution would have a pH of
9.25 if these were combined in equal molar proportions. Again, whatever concentrations you
pick, it doesn't matter as long as they are the same. But how does a buffer solution works? To
answer this, a buffer solution must contain things that will remove any ions of hydrogen or
hydroxide that you may add to it-otherwise the pH will change. This is achieved in various ways
by acidic and alkaline buffering solutions.
6. Titration
Titration is a method of chemical analysis in which the quantity of some constituent of a
sample is calculated by applying a precisely known quantity of another component to the
measured sample with which the desired constituent reacts in a definite, known proportion. The
chemist must have a way of visually detecting that the neutralization reaction has occurred in
order to conduct an acid-base titration. An indicator is a substance in an acidic or basic solution
which has a distinctly different colour. Phenolphthalein is a widely used proxy for high baseline
titrations with acids. At the beginning of a titration the pH increases very slowly as the base is
added to acid. The pH starts to rise quickly, closer to the equivalence point. If the titration is a
strong acid with a strong base the pH is equal to 7 at the equivalence point. A little past the
equivalence point, the pH shift rate slows down once again. The term titration curve refers to a
graphical representation of the pH of a solution during a titration.