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3D Printing and Electronics to some of these cultural gems in my

country but we're also home to the think


box one of the first 3d printing
hello everyone my name is rich Ottinger makerspace institutes in a major
and i am the marketing programs manager university where the access is utterly
for park systems welcome to the fifth free and we have some endowed programs
installment of Park systems 2019 that allow the students and outsiders to
material science research and afm you said so at the macro molecular
webinar series today's presentation is sizing during Department I'm one of the
titled 3d printing and electronics this professor's there and located the fifth
month we have run into a schedule floor and you have an opportunity to
conflict that has both dr. bicular visit please do so
myself out traveling as we speak so we I'm also editor the emergence
had to pre-record today's session in communications if you're in chief and I
order to keep our regular schedule the welcome your best contribution such
presentation is expected to take research letter and invited perspective
approximately 40 to 45 minutes but we articles so back in 2016 I gave this
will not be able to hold our usual live talk at the World Economic Forum where I
question-and-answer session at the end discussed the possibilities of using 3d
please ask any questions that you have printing from outer space to inner space
using the question module on the to advanced manufacturing robotics
GoToWebinar dashboard the system will tissue engineering and so the series
save your questions in our event report really has been geared towards
and dr. McCullar will answer them in a explaining the possibilities of 3d
follow-up email to today's attendees it printing an additive manufacturing
is now my pleasure to introduce to you process that can supply and perhaps
dr. Rigoberto a big EULA dr. Miguel is a formative and subtracting on a battery
professor of macro molecular science and in the future in fact one can purchase
engineering at Case Western Reserve their own 3d printer and you can have
University and the editor-in-chief of high-volume Hydrabad printers with
mrs communications is a fellow of the various starting materials from polymers
American Chemical Society two methods to ceramics all accessible
is the author of more than 250 these days because of the interest in
peer-reviewed publications advanced and additive manufacturing in
please welcome dr. Roberto lavendula fact twenty years ago my first encounter
thank you very much Richard and good with 3d printing was a two-photon
morning good afternoon and good evening polymerization high-resolution stereo
to all of you and we have to say upfront lithography printing in this case you
that we cannot have this on a live can see how high resolution is achieved
recorded session because of some in the micron scale all because the
schedule conflict but we will be able optics as well as the photochemical and
and I will be able to get your questions the photonic approaches enable a very
and answer them once they are forwarded efficient use of what we call two photon
to me so today's topic is on 3d printing resonance in this type of printing using
printed electronics I'm going to give in fact almost the same resin that we
you an overview of our 3d printing has use today in a technique
the potential to change how called SLA or stereo lithography
manufacturing is done in 3d printing apparatus actually there's a lot of
beyond prototyping and possibly towards interest in robotics 3d printing and
Kayla so I with Case Western Reserve soft robotics means that in the future
University in Cleveland Ohio a major gears arms other mechanical parts in a
research university in a very cultural traditional robotic machine will be
part northeast of Ohio where we are home replaced by 3d printed parts and there's
to the Cleveland Orchestra Cleveland a lot of interest in soft robotics where
Museum of Art and in the city we have you have stimuli response leading to the
asked combination of actuators and sensors
with 3d printed objects that work in the possibility of printed electronics
different media I like this example of be a 3d printing so when we talk about
the possibility from 2d to 3d 240 in electronics we can be looking at the
that you can program various types of motherboards the integrated circuits
assemblies and origami like type of chips micro processors or we are talking
architectures so that in a about RF IDs and other printed
two-dimensional - 3 dimensional design electronics flexible electronics that
one can incorporate the are being manufactured today in a way an
three-dimensional architecture after the integrated box such as your desktop
fact or after the object has been computer your notebook computer or other
printed and this could be from metals to types of displays and devices audio
polymers or even programmable soft devices have a lot of parts but the
materials in other words there's a room brain or or the motherboard controls a
there's lots of room really for applying lot of the device function and there you
intelligence artificial intelligence and will integrate of course resistors
machine machine learning together with capacitors electronic storage or energy
3d printing so here you can see the storage or batteries sensors and
advantage of 3d printing that it various electro mechanical and
provides for complexity and the mechanical parts these days there's a
difference between formative lot of interest on flexible devices
manufacturing is that you are able to flexible and printed electronics are
include high performance or different becoming synonymous because a lot of
types of stimuli response with complex these layered systems actually combine
geometries in a limited production basis both passive and active elements let's
in a way additive manufacturing really say on a flexible plastic substrate
complements formative and subtractive which makes them more conformal and
manufacturing in that you can lightweight and has a lot of high
incorporate multi materials and functionality so a lot of these flexible
different architectures in a 3d or electronics of course we can classify as
digital design are together with CNC 2d has their origin in the 3d so most of
type of movement CNC type of movement is what we still have today in terms of
actually what they use for subtractive gadgets appliances different types of
manufacturing or machining which is a electrical and electromechanical devices
mature type of manufacturing method rely on the common PCB or printed
widely used in the metal industry circuit board which we can say or call a
as well as plastics here you have a track three-dimensional architecture
summary and it's important for me to that involves soldering and a PCB board
show this to you of the various 3d typical of that of a thermoset or an
printing methods out there there's about epoxy or other polymers where you have
10 here that I can name because part of placement and patterning of different
our discussion with 3d printing metals and dielectrics as well as
electronics today is a review of the interconnects to make up your circuit
possibility of applying SLA FDM SLS and board and a lot of this can be
other binder jazz and other types of classified basically as active or
traditional or are getting to be passive in a way electricity or
traditional additive manufacturing electronic devices really depend on the
methods into 3d printed electronics and control of the flow of electrons now
so you have a lot of possible different printing methods are beginning
applications from aerospace to marine to make their way in flexible electronic
and of course electronics means want in but for large large part this is true
the past PCB boards transistors micro whole a devices or surface mount
optics displays interconnects and other technologies or as M DS and the SMT
types of high value high end electronic means that one has to pick in place or
manufacturing so let's review and let's to fabricate and solder these components
go back to the basic of what it means to whether it's a resistor capacitor an LED
have electronic devices or in particular device or your microprocessor in a
constructed circuit driven means you have a piezo resistor
so a little more on the traditional that delivers the droplet precisely for
manufacturing method one can say that it a thermally activated delivery based on
all begins on a substrate or flat a vapor bubble or an electrostatic
material surface especially when we go deposition based on charge attraction as
to the microprocessor level the all of these variations are basically
microprocessor level technology really what involves a printing head which is a
is a subtractive technology in that you type of micro electronic mechanical
have your substrate you add your system that allows very high resolution
material you then add what we call a of printing such type of printing of
photoresist typically these are polymers course is variable in a higher
that are capable of converting into an resolution printing for flexible
acid or an edible component by UV electronics now what I'm going to do
masking or photo lithography so by us right now is to give you an overview of
masking a pattern or photolithography the various 3d printing printing
under this resist material this creates technologies out there in a way what I
a pattern in this case edging allows us want to synthesize in this talk is to
to remove the photoresist material and give you or I'll show you the
end up with a pattern added material or possibilities that some of the 3d
even a methyl now what we want to printing technologies we have today can
achieve in an additive technology is to be used for delivering the passive
really do away with this wasteful active component of your printed circuit
process in the sense that it uses a lot it could be used for delivering the
of water washing cleaning drying into a conducting ink method or even creating
more additive process that may simply the pattern that can be later on use
involve printing embossing or other or electroless deposition or the
non-lethal graphic patterning methods on addition of a another material based on
a substrate now a very common term of a printed pattern or geometry so forgive
course is VLSI manufacturing or very me for again giving this overview on 3d
large-scale integration so it's very printing methodologies for those of you
similar to the manufacture additional are familiar but I want to make sure
manufacturing we just covered which is that our other listeners who are not
subtractive again starts with the wafer familiar with 3d printing gains this
you deposit your substrate then you appreciation of these various methods so
apply a little graphic mask which then SLA or stereo lithography apparatus
creates a pattern and then after almost similar to DLP or digital light
stripping wretching the photoresist mask projection makes use of a resin material
then you can remove residues particles that is photo polymerize one photon
clean it up and then apply your methyl efficiency such that the photo curing or
and then that creates essentially cross-linking of the resin whether it's
the pattern of using a digital projection or micro lens
a methyl on your substrate now gaining with a photo initiator sensitive to life
traction especially in flexible results really in quite a high
electronics is the use of 2d printing resolution of printed material and it's
technologies when I apply whether use one of my favorite methods that allow us
the fine term 2d printing I'm referring to look at formulations of the resin or
of course to delivery of inks conductive photo polymerize about resin with
inks or conductive metal as solutions on various methyl conducting polymers
substrate surfaces carbon nanotubes or other nano materials
this can be classified into two types a for fabrication now there are several
continuous inkjet or a drop on demand variations of what we call laminated
inkjet sort of how you would use digital object manufacturing
printing today with inkjet technology which can involve foils or metal foils
the dod or drop on demand inkjet can be or polymer foils that are curable with
further divided into piezo driven laser hitting or tearing a very familiar
thermally driven or electrostatic piezo one called
FFF or freeform fabrication otherwise temperature without the application of
known as use deposition modeling is one heat or even without the application of
of the easiest ways to 3d print a UV light similar to this with the term
polymer could be a passive polymer or ink or less viscous more less viscous
conducting polymer simply by extrusion ink is direct right technology almost
methods to a CNC movement heating similar to your 2 dimensional printing
element in a hand and as you have except that you build again the material
produced this part of course you are because as you deposited a curing or a
depositing the polymer material thixotropic behavior is achieved
SLS or selective laser sintering or building upon layer upon layer of the
sometimes known as the MLS or activated or delivered ink and in this
essentially methods for polymer and manner 2 one can deliver a result or use
methyl powder 3d printing in both start of aerogel aerosol materials basically
of a sintering method of a CNC movement spray jetting the material on top of
head based on a powder bed the powder is another and again with sufficient yield
replenished every after printing of a stress and curing behavior one can build
layer such that the end of the printing your three-dimensional object
you will have an object that's embedded another one that is quite popular with
on the powder originally and be metal and I apologize if I'm not going
recovered after printing in this poly to cover in this case more about a metal
jet printing technology which is again a tray 3d deposition techniques is that
platform that's popular and important one can deliver patterns in foils of
the inkjet heads deliver deliver the metal basically the foil is welded on
various materials from resin to curing top of another previously the deposited
resin to others and you have a support foil or metal base plate with the foil
material and what happens is there's a on top of it and then ultrasonic ation
UV curing mechanism that basically or oscillation provides a very effective
produces a thermoset or cures the surface contact between the metals
combination of materials and a leveling resulting in additive layering of metals
roller to make sure that an even amount on a pattern and like FDM and other
of let's say the powder component layering methods of course this can be
component is spread with the fresh subject to defects or voids and
printing almost similar is a powder bed ultrasonic oscillation
base printing the again the powder other improves the fusion of the metals
supply leveling roller allows you to on top of metals perhaps one that is
give a uniform fresh layer however closer to a three-dimensional system the
instead of a UV light or a UV curing 3d molded interconnect device or 3d mi d
mechanism you deliver the curing plus one to create first additively the
component with the printhead so again object shape again which could be based
this combination of materials mean that on a plastic or the metal or a passive
the active component to be part of the or active device so let's say one can
powder or it could be part of the resin employ FDM or other methods SLS etc and
material that is delivered by the then once this can be done this can be
printhead or is cured by UV light either integrated with the addition of
perhaps one of the easiest way to 3d conductive pads during printing itself
print conductive paste or inks is or other embedded electronic components
basically to formulate your your base or and then once so the difference here is
or a viscous solution and then force we are getting into the regime of multi
them through a plunger material additive manufacturing in other
or is arranged with a CNC movement head words your printhead or machine is
and then he takes a tropic behavior capable of depositing both the active
together with sufficient yield stress or and passive component for a circuit
shear thinning behavior prints the design or conductive path design during
material or extruded out of the material the structure fabrication so once you
even at room temperature so in this way have your embedded partners then of
you can actually 3d print at room course you can employ SMT component
deposition or big plug in place type of components on top of this pattern so you
connection or even the use of printing can have this and then finally you can
or printed electric components as an print other components that are
inlay on the surface of the molded part accessible on the surface so let me
so this is approaching closer to what distinguish it with this previous one
would be maybe an alternative towards a the previous one we were talking about
PCB board or even three dimensionally printing patterning creation of
designed devices based on the conductive parts on the object itself
versatility of putting an internal internally here we are talking now about
conductive path and an outside functionalization of a 3d printed object
patterning or placing of your electronic surface so one can envision or design
components now let's start looking at the inside of the 3d printed object and
some possibilities here for indeed then finally use this 3d surface
integrating the functionalisation method to complete the
building process for the 3d device so device now from here on I want to review
perhaps one can start with a powder bed some of the possible components that can
base printing which creates the passive come from current research or reported
component but at the same time one can research that can go towards this
embed the electronic component so you interconnected system concepts that I
can either have both the passive powder just described first there's a lot of
and active embedded component delivered interest on devices such as the older
on the surface during printing or one sensors curvilinear printing on surfaces
can use a first pattern a powdered bed 3d printed passive electronics
base printing passive component and then components for batteries printed
bring this to another section of the resistors inductors capacitors and so on
printer or a design tree depending so in principle some of the native
equipment or actually place this on elements that can use methyl or methyl
another printer and then create your hybrid or conductive inks that can be
embedded electronic component and you incorporated in the current methods of
can also create the conductive path 3d printing has actually been
basically by another method which allows demonstrated and let's review some of
you to deposit the metal or cure the these possibilities first of all
delivery of a conductive ink on a antennas so antennas can be of course
pattern on the 3d printed object and produced using an RFID method and flat
then finally one can connect the surfaces and that's a current commercial
conductive pads to the electronic manufacturing protocol however the
components and you so you can create possibility of
this internal structure built on a printing on a curvy linear object or
essentially a three dimensional device conformal printing on let's say a 3d
by the combination of both passive and printing object has been demonstrated
active material and a series of steps that means that you can 3d print let's
that allows you to make this conductive say this antenna or have basically a
path so this is one concept by which an molded object but then be able to
integrated device can be built by a deliver the conductive silver epoxy in a
combination of methods another is that surface printing process resulting in
once you build your three-dimensional this antenna now the design of and then
component one can focus on the surface of course has to do with geometry and
functionalisation now one possibility is surface as well as the active component
to use an aerosol aerosol jet printing that is used means that it is possible
method to create patterns on the surface to use various types of designs or 3d
or deliver a functional Arizona printed object designs and then on that
ink and then the other method is to object deposit as a last step your
print 3d conductive patterns directly conductive ink or develop your antenna
with metals on as a last step in the production process
services and then finally the assembly another is in flexible electronics so
and interconnection of other SNP device flexible electronics means that you
ink is such a popular if not a well
start with a substrate a flexible studied composition these days that one
substrate typically this is plastic and can change the viscosity the resistance
then one can then 3d print the pattern or the stimuli response of those
or conductive ink on top of this and then finally 3d printed as well on
substrate so for example gloves or other the surface or embedded as a conductive
types of activating devices can have path in a 3d printing process here in a
embedded strain sensors or electronic way there's also a possibility of
sensors 3d printed on top of it or even patterning printing and using let's say
some of the elastomers we've had a lot 3d printing to create areas by which you
of opportunities to 3d print silicones have a surface functionalisation capable
and poly urethanes and other of hosting what we call an electro less
thermoplastic elastomers in our lab deposition so in a electro less metal
using the 3d printing process and then deposition one can create or pattern the
on top of those materials one can surface so that you have an attraction
envision our 3d printing your conductive for the oxidized state of the metal it
materials or dielectrics that means that could be a copper iron nickel ion
there's a high possibility that in the platinum or gold iron and then once you
future flexible and wearable electronics deposit them on the surface one can
is better access with 3d printing ok so activate them or reduce them or methyl
here you have several examples you know eyes them as part of the pattern in
a tree layers train and other words in electro less the position
censored in in the answer it stay state there is the possibility of using 3d
and stretch state and I'll give you an printing to create the pattern and again
example of a recent publication we have as a final step deposit a reduced methyl
with this area and of course with on that pattern are using an electro
flexible electronics one can use this less deposition method when I say
for detecting motion or actuation let's electro last this means that it does not
say with different hand gestures so what involve the use of electro chemistry or
I'm pointing here is it is possible other electro deposition or application
today to replace traditionally of a current to deposit the layer but
informative molded objects injection rather the metal is reduced by chemical
molded thermal form or photochemical methods without the
blown film plastic materials with 3d application of a current or a bias
printing and the advantage to that is voltage in the development of batteries
one does not have to go to the there could be interest on making inter
traditional tooling method in that you digitated electrodes let's say in a
can come up with your design or lithium ion micro battery architecture
prototype quite easily by 3d printing one can first deposit the current
and then add your electronics on top of collector which could be gold or other
that 3d printed object another interest by conducting metal and then one can
is on soft robotics so for example the deposit the lithium ion substrate
active component can be printed together followed by the membrane
really soft component or soft matter lfp
component another term is sometimes used [Music]
for polymers and this can be integrated without going to further deep dive on
in let's say this design which actually lithium-ion batteries or lithium super
shows what we call stimuli response and batteries one that needs to have this
sensing response as well this octopus enclosed in a packaging unit and then
means that you have actuation you have finally accessed through the anode or
movement based on light or stimuli and the cathode where the lithium ion
this can all be integrated in device by exchanger mobility facilitates its
3d printing another is one can look at action in energy storage and this is
various types of ink compositions just one example in that with the
whether it be none of crystal inks or development of batteries or energy
conducting polymer inks the chemistry of storage device 3d printing can play an
important role in making very efficient process is of course the norm and it
and lightweight batteries so in summary will still be a challenge to incorporate
what I have here are some possibilities 3d printing and vice-versa majority of
with features that can go to 3d printed this original equipment manufacturers or
electronics this some of this OMS are still not equipped or allow
information are probably 5 years old access on model and modification of
even some of the manufacturers and I can their current manufacturing processes in
suggest that you google them their in a way a lot of these companies are of
current state of ability to make devices course interested in recovering their
or tools or machines for 3d printing and investment on their traditional
what is the current configuration or manufacturing method another is that
materials usage so in fact what I will from the additive manufacturing side the
do at this point is review some of these current 3d instrum
technologies but better yet we actually design stool are not yet designed or
wrote a review paper that was recently solely intended for electronics in other
published the printing system for 3d words was actually what I have actually
printed electronics one can actually buy done for you today is demonstrated some
some of this multi material or multi of the possibilities for looking at this
task type of printing technologies one additive manufacturing methods and then
in particular is buy bought factory converting them more closely to
another is by nano dimension dragon and electronics in fact there's a materials
some of the elements that I described gap or opportunity to develop the
here in terms of pick-and-place or the chemistry or conductive inks or curing
position of multi materials or methods or thermosets specifically for
conductive inks have been incorporated additive manufacturing in printed
in some of these devices but here you electronics also it's possible to get
can see how printed electronics can lead more companies to focus on new 3d
to mass production you don't have to use printers or neutral printed electronic
3d printing as a whole step in the design tools not just for prototyping
production of but even for scalability or mass
let's say an electronic device one can production and then finally we envision
perhaps take baby steps that is you can the integrated integration of these
incorporate 3d printing on current materials or different methods for
manufacturing materials either as a last fabrication together with Internet
step or as part of the creation of the connectivity or Internet of Things so
board or a creation of your flexible that one can realize their current
device here's one example that was possibilities not only with flexible
demonstrated by optimal in that they electronics wearable electronics but the
have placed the printed arrow sole replacement of our Curie
method of your circuit on a plastic tank truely manufacturable concurrent printed
and this was deposited basically by a 3d circuit boards so as I mentioned a lot
printing type of technique one can look of these things
at other types of conformal surfaces we recently summarized and wrote a
there's a lot of interest it's a on the review article I posted here the
additive manufacturing side being reference to a review article that we
applied towards traditional molded recently published in progress in
objects let's say in automotive additive manufacturing so so those of
manufacturing so one can envision you who have access to this journal of
producing the part by injection molding course can download the journal and then
and then finishing the electronic part you can find a lot of the things that I
by additive manufacturing or 3d printing reviewed today as well so I'll be
come out with a electronic circuit or closing with some of our recent work
design on a molded or plastic injection that may lead to possible application
molded object so important points and and 3d printed electronics our group has
perspectives one is that we have a lot of focus these days on 3d printing
reviewed conventional electronic design of polymer in nano composite materials
including thermoplastics thermoplastic mechanical property however by
elastomers thermoset elastomers and converting it we're removing the Nano
thermosets and some of our recent clay to produce a polar porous substance
publications are listed here let me just this resulted in the formation of a
demonstrate one or two material systems highly compressible and elastic foam and
one is this polyurethane thermoplastic we can change the geometry and the
elastomer that we published two years composition to give get a different
ago the thermoplastic TPU material owes elasticity as shown here okay so from
its properties because of the hard and here why am i showing this and why is
soft segments afforded by the isocyanate this a good example of an electronic so
and following all components and in fact actually we took this material it showed
there's a lot of interest for this in various compress abilities up to a
biomedical application and I dare to say thousand cycles but interestingly will
of course wearable electronics so what be coated with a conductive material
we have done and this was a paper that such as a carbon nanotube containing
was published last year is we use TPU a paint we can actually use it as a switch
plastic as a precursor for making foams an LED switch in a printed circuit board
so foam here was generated by making so by turning it on and off on and off
origins based on the Nano clay the 3d printing allowed us to change the
incorporated and we use fiscal solution thermo mechanical properties and made
printing to prepare this material so we for it a very durable switch for turning
printed a viscous space with the right led so with these two last examples we
shinning T's cheer thinning viscosity recently published a 3d printed electric
yield stress I'm showing here that we model so this was done by using a nylon
can 3d print ketchup like this we can't powder together with a graphene
really print cement like this or we can composition that we made together with a
see the big chocolate like this but in pen circle so what happened is basically
this case we made a 3d printable a plastic that behaved as a motor a DC
thermoplastic polyurethane and I'll show motor in AC motor that we applied a high
you the electronic application of this voltage though but still is a moving
so once we converted the base into an motor where we incorporated the
extruder ball printable material we then conductive material together with the
3d printed various shapes and sizes in plastic and then finally we recently
particular we produce these grids that published a conductive elastomeric foam
displayed various openings and then for strain and gas sensing so the active
finally we incorporated porosity through ingredient was part of the formulation
the Nano clay namely graphene and we also added carbon
was the part of the formulation and the black and as you can see here in this
removal of the nano play by hydrofluoric very busy slide we are able to control
acid etching to reveal actually a porous or detect the change in conductivity or
material that was present on these 3d resistivity as a function of compression
printed objects so in this case we or release of compression or ecclesia
actually made the object by 3d printing so in other words this material as
we imbued the various thermo mechanical reported has been used as a motion
properties so what I mean is the 3d sensor where we can distinguish between
printing drives the opening size but the running walking and standing or jumping
procedure we use for making the foam and at the same time this material also
allowed it to be more elastomeric so in is a good gas sensor so in this case 3d
this movie you'll see the 3d printed printing allowed us to make the object
object as we prepared it no conversion and Composition at the same time but we
to the elastomer simply based on the embedded the electrical or resistance
geometry and the opening size so it's a function on the material so with that
plastic and then if we change the I'd like to thank you and I hope to hear
opening size you can see that we can from you or you can again access the
compress it somewhat again it still is a review material and I hope this webinar
plastic but you get a different has been useful to all of you thank you
thank you doctor vanilla okay so as we
talk to the top of webinar we had some
unfortunate travel timing this week and
pre-recorded this month session so if
you have any questions for dr. vinculum
please type them into the questions
module as you're watching this now and
we will send out a follow-up email with
any questions that we receive I will
still take the opportunity to ask my
usual question doc can you give us a
brief preview of next month's webinar
topic polymers in medicine and
introduction thank you Richard that is
an exciting topic but what I will do of
course is reach out to all types of
listeners and viewers in that this is
somewhat of a polymer 101 in that women
do and various polymers that has been
applied to may be seen biomedical
engineering whether it's drug delivery
by implants and so on so I hope that
would be of interest to our viewers or
interested in the various polymers using
medicine today all right thank you
doctor please join us for that session
on Wednesday June 19th when we fully
expect to be back to our usual live
format and thank you all for joining us
for this session of Park systems 2019
material science research and AFM
webinar series you can find more
information about Park systems afm at
park system's calm and please direct any
AFM questions you have to inquiry at
Park systems comm if you have any
questions specific to this webinar
series or if you come up with another
question about today's session after
we've signed off please do not hesitate
to reach out to me directly at Richard
at Park systems comm thanks again and we
will see you next month

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