3D Printing and Electronics to some of these cultural gems in my
country but we're also home to the think
box one of the first 3d printing hello everyone my name is rich Ottinger makerspace institutes in a major and i am the marketing programs manager university where the access is utterly for park systems welcome to the fifth free and we have some endowed programs installment of Park systems 2019 that allow the students and outsiders to material science research and afm you said so at the macro molecular webinar series today's presentation is sizing during Department I'm one of the titled 3d printing and electronics this professor's there and located the fifth month we have run into a schedule floor and you have an opportunity to conflict that has both dr. bicular visit please do so myself out traveling as we speak so we I'm also editor the emergence had to pre-record today's session in communications if you're in chief and I order to keep our regular schedule the welcome your best contribution such presentation is expected to take research letter and invited perspective approximately 40 to 45 minutes but we articles so back in 2016 I gave this will not be able to hold our usual live talk at the World Economic Forum where I question-and-answer session at the end discussed the possibilities of using 3d please ask any questions that you have printing from outer space to inner space using the question module on the to advanced manufacturing robotics GoToWebinar dashboard the system will tissue engineering and so the series save your questions in our event report really has been geared towards and dr. McCullar will answer them in a explaining the possibilities of 3d follow-up email to today's attendees it printing an additive manufacturing is now my pleasure to introduce to you process that can supply and perhaps dr. Rigoberto a big EULA dr. Miguel is a formative and subtracting on a battery professor of macro molecular science and in the future in fact one can purchase engineering at Case Western Reserve their own 3d printer and you can have University and the editor-in-chief of high-volume Hydrabad printers with mrs communications is a fellow of the various starting materials from polymers American Chemical Society two methods to ceramics all accessible is the author of more than 250 these days because of the interest in peer-reviewed publications advanced and additive manufacturing in please welcome dr. Roberto lavendula fact twenty years ago my first encounter thank you very much Richard and good with 3d printing was a two-photon morning good afternoon and good evening polymerization high-resolution stereo to all of you and we have to say upfront lithography printing in this case you that we cannot have this on a live can see how high resolution is achieved recorded session because of some in the micron scale all because the schedule conflict but we will be able optics as well as the photochemical and and I will be able to get your questions the photonic approaches enable a very and answer them once they are forwarded efficient use of what we call two photon to me so today's topic is on 3d printing resonance in this type of printing using printed electronics I'm going to give in fact almost the same resin that we you an overview of our 3d printing has use today in a technique the potential to change how called SLA or stereo lithography manufacturing is done in 3d printing apparatus actually there's a lot of beyond prototyping and possibly towards interest in robotics 3d printing and Kayla so I with Case Western Reserve soft robotics means that in the future University in Cleveland Ohio a major gears arms other mechanical parts in a research university in a very cultural traditional robotic machine will be part northeast of Ohio where we are home replaced by 3d printed parts and there's to the Cleveland Orchestra Cleveland a lot of interest in soft robotics where Museum of Art and in the city we have you have stimuli response leading to the asked combination of actuators and sensors with 3d printed objects that work in the possibility of printed electronics different media I like this example of be a 3d printing so when we talk about the possibility from 2d to 3d 240 in electronics we can be looking at the that you can program various types of motherboards the integrated circuits assemblies and origami like type of chips micro processors or we are talking architectures so that in a about RF IDs and other printed two-dimensional - 3 dimensional design electronics flexible electronics that one can incorporate the are being manufactured today in a way an three-dimensional architecture after the integrated box such as your desktop fact or after the object has been computer your notebook computer or other printed and this could be from metals to types of displays and devices audio polymers or even programmable soft devices have a lot of parts but the materials in other words there's a room brain or or the motherboard controls a there's lots of room really for applying lot of the device function and there you intelligence artificial intelligence and will integrate of course resistors machine machine learning together with capacitors electronic storage or energy 3d printing so here you can see the storage or batteries sensors and advantage of 3d printing that it various electro mechanical and provides for complexity and the mechanical parts these days there's a difference between formative lot of interest on flexible devices manufacturing is that you are able to flexible and printed electronics are include high performance or different becoming synonymous because a lot of types of stimuli response with complex these layered systems actually combine geometries in a limited production basis both passive and active elements let's in a way additive manufacturing really say on a flexible plastic substrate complements formative and subtractive which makes them more conformal and manufacturing in that you can lightweight and has a lot of high incorporate multi materials and functionality so a lot of these flexible different architectures in a 3d or electronics of course we can classify as digital design are together with CNC 2d has their origin in the 3d so most of type of movement CNC type of movement is what we still have today in terms of actually what they use for subtractive gadgets appliances different types of manufacturing or machining which is a electrical and electromechanical devices mature type of manufacturing method rely on the common PCB or printed widely used in the metal industry circuit board which we can say or call a as well as plastics here you have a track three-dimensional architecture summary and it's important for me to that involves soldering and a PCB board show this to you of the various 3d typical of that of a thermoset or an printing methods out there there's about epoxy or other polymers where you have 10 here that I can name because part of placement and patterning of different our discussion with 3d printing metals and dielectrics as well as electronics today is a review of the interconnects to make up your circuit possibility of applying SLA FDM SLS and board and a lot of this can be other binder jazz and other types of classified basically as active or traditional or are getting to be passive in a way electricity or traditional additive manufacturing electronic devices really depend on the methods into 3d printed electronics and control of the flow of electrons now so you have a lot of possible different printing methods are beginning applications from aerospace to marine to make their way in flexible electronic and of course electronics means want in but for large large part this is true the past PCB boards transistors micro whole a devices or surface mount optics displays interconnects and other technologies or as M DS and the SMT types of high value high end electronic means that one has to pick in place or manufacturing so let's review and let's to fabricate and solder these components go back to the basic of what it means to whether it's a resistor capacitor an LED have electronic devices or in particular device or your microprocessor in a constructed circuit driven means you have a piezo resistor so a little more on the traditional that delivers the droplet precisely for manufacturing method one can say that it a thermally activated delivery based on all begins on a substrate or flat a vapor bubble or an electrostatic material surface especially when we go deposition based on charge attraction as to the microprocessor level the all of these variations are basically microprocessor level technology really what involves a printing head which is a is a subtractive technology in that you type of micro electronic mechanical have your substrate you add your system that allows very high resolution material you then add what we call a of printing such type of printing of photoresist typically these are polymers course is variable in a higher that are capable of converting into an resolution printing for flexible acid or an edible component by UV electronics now what I'm going to do masking or photo lithography so by us right now is to give you an overview of masking a pattern or photolithography the various 3d printing printing under this resist material this creates technologies out there in a way what I a pattern in this case edging allows us want to synthesize in this talk is to to remove the photoresist material and give you or I'll show you the end up with a pattern added material or possibilities that some of the 3d even a methyl now what we want to printing technologies we have today can achieve in an additive technology is to be used for delivering the passive really do away with this wasteful active component of your printed circuit process in the sense that it uses a lot it could be used for delivering the of water washing cleaning drying into a conducting ink method or even creating more additive process that may simply the pattern that can be later on use involve printing embossing or other or electroless deposition or the non-lethal graphic patterning methods on addition of a another material based on a substrate now a very common term of a printed pattern or geometry so forgive course is VLSI manufacturing or very me for again giving this overview on 3d large-scale integration so it's very printing methodologies for those of you similar to the manufacture additional are familiar but I want to make sure manufacturing we just covered which is that our other listeners who are not subtractive again starts with the wafer familiar with 3d printing gains this you deposit your substrate then you appreciation of these various methods so apply a little graphic mask which then SLA or stereo lithography apparatus creates a pattern and then after almost similar to DLP or digital light stripping wretching the photoresist mask projection makes use of a resin material then you can remove residues particles that is photo polymerize one photon clean it up and then apply your methyl efficiency such that the photo curing or and then that creates essentially cross-linking of the resin whether it's the pattern of using a digital projection or micro lens a methyl on your substrate now gaining with a photo initiator sensitive to life traction especially in flexible results really in quite a high electronics is the use of 2d printing resolution of printed material and it's technologies when I apply whether use one of my favorite methods that allow us the fine term 2d printing I'm referring to look at formulations of the resin or of course to delivery of inks conductive photo polymerize about resin with inks or conductive metal as solutions on various methyl conducting polymers substrate surfaces carbon nanotubes or other nano materials this can be classified into two types a for fabrication now there are several continuous inkjet or a drop on demand variations of what we call laminated inkjet sort of how you would use digital object manufacturing printing today with inkjet technology which can involve foils or metal foils the dod or drop on demand inkjet can be or polymer foils that are curable with further divided into piezo driven laser hitting or tearing a very familiar thermally driven or electrostatic piezo one called FFF or freeform fabrication otherwise temperature without the application of known as use deposition modeling is one heat or even without the application of of the easiest ways to 3d print a UV light similar to this with the term polymer could be a passive polymer or ink or less viscous more less viscous conducting polymer simply by extrusion ink is direct right technology almost methods to a CNC movement heating similar to your 2 dimensional printing element in a hand and as you have except that you build again the material produced this part of course you are because as you deposited a curing or a depositing the polymer material thixotropic behavior is achieved SLS or selective laser sintering or building upon layer upon layer of the sometimes known as the MLS or activated or delivered ink and in this essentially methods for polymer and manner 2 one can deliver a result or use methyl powder 3d printing in both start of aerogel aerosol materials basically of a sintering method of a CNC movement spray jetting the material on top of head based on a powder bed the powder is another and again with sufficient yield replenished every after printing of a stress and curing behavior one can build layer such that the end of the printing your three-dimensional object you will have an object that's embedded another one that is quite popular with on the powder originally and be metal and I apologize if I'm not going recovered after printing in this poly to cover in this case more about a metal jet printing technology which is again a tray 3d deposition techniques is that platform that's popular and important one can deliver patterns in foils of the inkjet heads deliver deliver the metal basically the foil is welded on various materials from resin to curing top of another previously the deposited resin to others and you have a support foil or metal base plate with the foil material and what happens is there's a on top of it and then ultrasonic ation UV curing mechanism that basically or oscillation provides a very effective produces a thermoset or cures the surface contact between the metals combination of materials and a leveling resulting in additive layering of metals roller to make sure that an even amount on a pattern and like FDM and other of let's say the powder component layering methods of course this can be component is spread with the fresh subject to defects or voids and printing almost similar is a powder bed ultrasonic oscillation base printing the again the powder other improves the fusion of the metals supply leveling roller allows you to on top of metals perhaps one that is give a uniform fresh layer however closer to a three-dimensional system the instead of a UV light or a UV curing 3d molded interconnect device or 3d mi d mechanism you deliver the curing plus one to create first additively the component with the printhead so again object shape again which could be based this combination of materials mean that on a plastic or the metal or a passive the active component to be part of the or active device so let's say one can powder or it could be part of the resin employ FDM or other methods SLS etc and material that is delivered by the then once this can be done this can be printhead or is cured by UV light either integrated with the addition of perhaps one of the easiest way to 3d conductive pads during printing itself print conductive paste or inks is or other embedded electronic components basically to formulate your your base or and then once so the difference here is or a viscous solution and then force we are getting into the regime of multi them through a plunger material additive manufacturing in other or is arranged with a CNC movement head words your printhead or machine is and then he takes a tropic behavior capable of depositing both the active together with sufficient yield stress or and passive component for a circuit shear thinning behavior prints the design or conductive path design during material or extruded out of the material the structure fabrication so once you even at room temperature so in this way have your embedded partners then of you can actually 3d print at room course you can employ SMT component deposition or big plug in place type of components on top of this pattern so you connection or even the use of printing can have this and then finally you can or printed electric components as an print other components that are inlay on the surface of the molded part accessible on the surface so let me so this is approaching closer to what distinguish it with this previous one would be maybe an alternative towards a the previous one we were talking about PCB board or even three dimensionally printing patterning creation of designed devices based on the conductive parts on the object itself versatility of putting an internal internally here we are talking now about conductive path and an outside functionalization of a 3d printed object patterning or placing of your electronic surface so one can envision or design components now let's start looking at the inside of the 3d printed object and some possibilities here for indeed then finally use this 3d surface integrating the functionalisation method to complete the building process for the 3d device so device now from here on I want to review perhaps one can start with a powder bed some of the possible components that can base printing which creates the passive come from current research or reported component but at the same time one can research that can go towards this embed the electronic component so you interconnected system concepts that I can either have both the passive powder just described first there's a lot of and active embedded component delivered interest on devices such as the older on the surface during printing or one sensors curvilinear printing on surfaces can use a first pattern a powdered bed 3d printed passive electronics base printing passive component and then components for batteries printed bring this to another section of the resistors inductors capacitors and so on printer or a design tree depending so in principle some of the native equipment or actually place this on elements that can use methyl or methyl another printer and then create your hybrid or conductive inks that can be embedded electronic component and you incorporated in the current methods of can also create the conductive path 3d printing has actually been basically by another method which allows demonstrated and let's review some of you to deposit the metal or cure the these possibilities first of all delivery of a conductive ink on a antennas so antennas can be of course pattern on the 3d printed object and produced using an RFID method and flat then finally one can connect the surfaces and that's a current commercial conductive pads to the electronic manufacturing protocol however the components and you so you can create possibility of this internal structure built on a printing on a curvy linear object or essentially a three dimensional device conformal printing on let's say a 3d by the combination of both passive and printing object has been demonstrated active material and a series of steps that means that you can 3d print let's that allows you to make this conductive say this antenna or have basically a path so this is one concept by which an molded object but then be able to integrated device can be built by a deliver the conductive silver epoxy in a combination of methods another is that surface printing process resulting in once you build your three-dimensional this antenna now the design of and then component one can focus on the surface of course has to do with geometry and functionalisation now one possibility is surface as well as the active component to use an aerosol aerosol jet printing that is used means that it is possible method to create patterns on the surface to use various types of designs or 3d or deliver a functional Arizona printed object designs and then on that ink and then the other method is to object deposit as a last step your print 3d conductive patterns directly conductive ink or develop your antenna with metals on as a last step in the production process services and then finally the assembly another is in flexible electronics so and interconnection of other SNP device flexible electronics means that you ink is such a popular if not a well start with a substrate a flexible studied composition these days that one substrate typically this is plastic and can change the viscosity the resistance then one can then 3d print the pattern or the stimuli response of those or conductive ink on top of this and then finally 3d printed as well on substrate so for example gloves or other the surface or embedded as a conductive types of activating devices can have path in a 3d printing process here in a embedded strain sensors or electronic way there's also a possibility of sensors 3d printed on top of it or even patterning printing and using let's say some of the elastomers we've had a lot 3d printing to create areas by which you of opportunities to 3d print silicones have a surface functionalisation capable and poly urethanes and other of hosting what we call an electro less thermoplastic elastomers in our lab deposition so in a electro less metal using the 3d printing process and then deposition one can create or pattern the on top of those materials one can surface so that you have an attraction envision our 3d printing your conductive for the oxidized state of the metal it materials or dielectrics that means that could be a copper iron nickel ion there's a high possibility that in the platinum or gold iron and then once you future flexible and wearable electronics deposit them on the surface one can is better access with 3d printing ok so activate them or reduce them or methyl here you have several examples you know eyes them as part of the pattern in a tree layers train and other words in electro less the position censored in in the answer it stay state there is the possibility of using 3d and stretch state and I'll give you an printing to create the pattern and again example of a recent publication we have as a final step deposit a reduced methyl with this area and of course with on that pattern are using an electro flexible electronics one can use this less deposition method when I say for detecting motion or actuation let's electro last this means that it does not say with different hand gestures so what involve the use of electro chemistry or I'm pointing here is it is possible other electro deposition or application today to replace traditionally of a current to deposit the layer but informative molded objects injection rather the metal is reduced by chemical molded thermal form or photochemical methods without the blown film plastic materials with 3d application of a current or a bias printing and the advantage to that is voltage in the development of batteries one does not have to go to the there could be interest on making inter traditional tooling method in that you digitated electrodes let's say in a can come up with your design or lithium ion micro battery architecture prototype quite easily by 3d printing one can first deposit the current and then add your electronics on top of collector which could be gold or other that 3d printed object another interest by conducting metal and then one can is on soft robotics so for example the deposit the lithium ion substrate active component can be printed together followed by the membrane really soft component or soft matter lfp component another term is sometimes used [Music] for polymers and this can be integrated without going to further deep dive on in let's say this design which actually lithium-ion batteries or lithium super shows what we call stimuli response and batteries one that needs to have this sensing response as well this octopus enclosed in a packaging unit and then means that you have actuation you have finally accessed through the anode or movement based on light or stimuli and the cathode where the lithium ion this can all be integrated in device by exchanger mobility facilitates its 3d printing another is one can look at action in energy storage and this is various types of ink compositions just one example in that with the whether it be none of crystal inks or development of batteries or energy conducting polymer inks the chemistry of storage device 3d printing can play an important role in making very efficient process is of course the norm and it and lightweight batteries so in summary will still be a challenge to incorporate what I have here are some possibilities 3d printing and vice-versa majority of with features that can go to 3d printed this original equipment manufacturers or electronics this some of this OMS are still not equipped or allow information are probably 5 years old access on model and modification of even some of the manufacturers and I can their current manufacturing processes in suggest that you google them their in a way a lot of these companies are of current state of ability to make devices course interested in recovering their or tools or machines for 3d printing and investment on their traditional what is the current configuration or manufacturing method another is that materials usage so in fact what I will from the additive manufacturing side the do at this point is review some of these current 3d instrum technologies but better yet we actually design stool are not yet designed or wrote a review paper that was recently solely intended for electronics in other published the printing system for 3d words was actually what I have actually printed electronics one can actually buy done for you today is demonstrated some some of this multi material or multi of the possibilities for looking at this task type of printing technologies one additive manufacturing methods and then in particular is buy bought factory converting them more closely to another is by nano dimension dragon and electronics in fact there's a materials some of the elements that I described gap or opportunity to develop the here in terms of pick-and-place or the chemistry or conductive inks or curing position of multi materials or methods or thermosets specifically for conductive inks have been incorporated additive manufacturing in printed in some of these devices but here you electronics also it's possible to get can see how printed electronics can lead more companies to focus on new 3d to mass production you don't have to use printers or neutral printed electronic 3d printing as a whole step in the design tools not just for prototyping production of but even for scalability or mass let's say an electronic device one can production and then finally we envision perhaps take baby steps that is you can the integrated integration of these incorporate 3d printing on current materials or different methods for manufacturing materials either as a last fabrication together with Internet step or as part of the creation of the connectivity or Internet of Things so board or a creation of your flexible that one can realize their current device here's one example that was possibilities not only with flexible demonstrated by optimal in that they electronics wearable electronics but the have placed the printed arrow sole replacement of our Curie method of your circuit on a plastic tank truely manufacturable concurrent printed and this was deposited basically by a 3d circuit boards so as I mentioned a lot printing type of technique one can look of these things at other types of conformal surfaces we recently summarized and wrote a there's a lot of interest it's a on the review article I posted here the additive manufacturing side being reference to a review article that we applied towards traditional molded recently published in progress in objects let's say in automotive additive manufacturing so so those of manufacturing so one can envision you who have access to this journal of producing the part by injection molding course can download the journal and then and then finishing the electronic part you can find a lot of the things that I by additive manufacturing or 3d printing reviewed today as well so I'll be come out with a electronic circuit or closing with some of our recent work design on a molded or plastic injection that may lead to possible application molded object so important points and and 3d printed electronics our group has perspectives one is that we have a lot of focus these days on 3d printing reviewed conventional electronic design of polymer in nano composite materials including thermoplastics thermoplastic mechanical property however by elastomers thermoset elastomers and converting it we're removing the Nano thermosets and some of our recent clay to produce a polar porous substance publications are listed here let me just this resulted in the formation of a demonstrate one or two material systems highly compressible and elastic foam and one is this polyurethane thermoplastic we can change the geometry and the elastomer that we published two years composition to give get a different ago the thermoplastic TPU material owes elasticity as shown here okay so from its properties because of the hard and here why am i showing this and why is soft segments afforded by the isocyanate this a good example of an electronic so and following all components and in fact actually we took this material it showed there's a lot of interest for this in various compress abilities up to a biomedical application and I dare to say thousand cycles but interestingly will of course wearable electronics so what be coated with a conductive material we have done and this was a paper that such as a carbon nanotube containing was published last year is we use TPU a paint we can actually use it as a switch plastic as a precursor for making foams an LED switch in a printed circuit board so foam here was generated by making so by turning it on and off on and off origins based on the Nano clay the 3d printing allowed us to change the incorporated and we use fiscal solution thermo mechanical properties and made printing to prepare this material so we for it a very durable switch for turning printed a viscous space with the right led so with these two last examples we shinning T's cheer thinning viscosity recently published a 3d printed electric yield stress I'm showing here that we model so this was done by using a nylon can 3d print ketchup like this we can't powder together with a graphene really print cement like this or we can composition that we made together with a see the big chocolate like this but in pen circle so what happened is basically this case we made a 3d printable a plastic that behaved as a motor a DC thermoplastic polyurethane and I'll show motor in AC motor that we applied a high you the electronic application of this voltage though but still is a moving so once we converted the base into an motor where we incorporated the extruder ball printable material we then conductive material together with the 3d printed various shapes and sizes in plastic and then finally we recently particular we produce these grids that published a conductive elastomeric foam displayed various openings and then for strain and gas sensing so the active finally we incorporated porosity through ingredient was part of the formulation the Nano clay namely graphene and we also added carbon was the part of the formulation and the black and as you can see here in this removal of the nano play by hydrofluoric very busy slide we are able to control acid etching to reveal actually a porous or detect the change in conductivity or material that was present on these 3d resistivity as a function of compression printed objects so in this case we or release of compression or ecclesia actually made the object by 3d printing so in other words this material as we imbued the various thermo mechanical reported has been used as a motion properties so what I mean is the 3d sensor where we can distinguish between printing drives the opening size but the running walking and standing or jumping procedure we use for making the foam and at the same time this material also allowed it to be more elastomeric so in is a good gas sensor so in this case 3d this movie you'll see the 3d printed printing allowed us to make the object object as we prepared it no conversion and Composition at the same time but we to the elastomer simply based on the embedded the electrical or resistance geometry and the opening size so it's a function on the material so with that plastic and then if we change the I'd like to thank you and I hope to hear opening size you can see that we can from you or you can again access the compress it somewhat again it still is a review material and I hope this webinar plastic but you get a different has been useful to all of you thank you thank you doctor vanilla okay so as we talk to the top of webinar we had some unfortunate travel timing this week and pre-recorded this month session so if you have any questions for dr. vinculum please type them into the questions module as you're watching this now and we will send out a follow-up email with any questions that we receive I will still take the opportunity to ask my usual question doc can you give us a brief preview of next month's webinar topic polymers in medicine and introduction thank you Richard that is an exciting topic but what I will do of course is reach out to all types of listeners and viewers in that this is somewhat of a polymer 101 in that women do and various polymers that has been applied to may be seen biomedical engineering whether it's drug delivery by implants and so on so I hope that would be of interest to our viewers or interested in the various polymers using medicine today all right thank you doctor please join us for that session on Wednesday June 19th when we fully expect to be back to our usual live format and thank you all for joining us for this session of Park systems 2019 material science research and AFM webinar series you can find more information about Park systems afm at park system's calm and please direct any AFM questions you have to inquiry at Park systems comm if you have any questions specific to this webinar series or if you come up with another question about today's session after we've signed off please do not hesitate to reach out to me directly at Richard at Park systems comm thanks again and we will see you next month