1 Minimum third ionisation energy?

A. Fe B. CO C. Mn D. Ni

2 Correct order of first ionization energy of the following metals Na, Mg, Al, Si in KJ mol–1
respectively are

A. 497, 737, 577, 786 B. 497, 577, 737, 786

C. 786, 739, 577, 497 D. 739, 577, 786, 487

3 Given for H-bond Select the correct options regarding this formula for Balmer series.

a. n1 = 2

b. Ionization energy of H atom can be calculated from above formula.

c. is for n2 = 3.

d. If decreases then spectrum lines will converse.

A. a,b B. c.d C. a & c D. a,b,c & d

4 Calculate the mass of FeSO4.7H2O, which must be added in 100 kg of wheat to get 10 PPM of
Fe.

A)30.5 B)40.96 C)50.36 D)20.33

5 Determine wavelength of electron in 4th Bohr's orbit, If radius of first orbit is a0?

A. 4 πa0 B. 2 πa0 C. 8 πa0 D. 6πa0

6 Match the various sequences with the appropriate orders and select the correct option.
Sequences Orders
(a) Na+ Mg+2 Al+3 (p) increasing size of ion in gaseous state
(b) I– S2– N3– (q) decreasing size of ion in gaseous state
(c) O O– O–2 (r) increasing size of ion in aqueous state
(d) N F O (s) decreasing size of ion in aqueous state
(t) increasing order of IE2
(u) decreasing order of electron affinity

(A) a–q, b–r, c–t, d–u (B) a–r, b–q, c–p, d–u
(C) a–q, b–r, c–u, d–t (D) a–s, b–r, c–p, d–t
7 Which of the following can not act as both oxidising and reducing agent ?

A. H2SO3 B. HNO2 C. H3PO4 D. H2O2

8 There are two samples of HCl having molarity 1M and 0.25N. Find the volume of these
sample taken in order to prepare 0.75N HCl solution (Assume no water is used):

(A) 20 mL, 10 mL (B) 100 mL, 50 mL (C) 40 mL, 20 mL (D) 50 mL, 25 mL

9 Phosphorous has the oxidation state of + 3 in :

(A) Phosphorus acid (H3PO3) (B) Orthophosphoric acid (H3PO4)

(C) Metaphosphoric acid (HPO3) (D) Pyrophosphoric acid (H4P2O7)

10 In the reaction 2 Ag + 2 H2SO4 Ag2SO4 + SO2 + 2 H2O, H2SO4 acts as

(a) oxidising agent (b) reducing agent
(c) catalyst (d) acid as well as O.A.
11 For the redox reaction
MnO4– + C2O42– + H+ ¾ ¾ ® Mn2+ + CO2 + H2O
the correct coefficients of the reactants for the balanced reaction are
MnO4– C2O42– H+
(a) 2 5 16
(b) 16 5 2
(c) 5 16 2
(d) 2 16 5
12 Which of the following species are linear?

(a) ICl2– (b) I3– (c) N 3 (d) ClO3–

13 How many bonded electron pairs are present in IF7 molecule ?

(a) 6 (b) 7 (c) 5 (d) 8