M. Sc. I Chemistry Syllabus (10!05!2020)

S. N. Arts, D. J. Malpani Commerce and B. N.
Sarda
Science College, Sangamner, 422605
(Autonomous College)
SYLLABUS
FOR
M.Sc. Chemistry I,
Semester – I & II
To be implemented from
Academic Year 2020-2021
Prin. Dr. Keshav K. Deshmukh

Chairman, Board of Studies (Chemistry)
M.Sc. I Chemistry
Structure of M. Sc. I Chemistry Course
SEMESTER-I
Sr.
Subject Code Subject Credits
No.
Physical Chemistry-I 4 credit
1 CHP-110
(Fundamentals of Physical Chemistry) (48 L + 12T)
Inorganic Chemistry-I
4 credit
2 CHI-130 (Molecular Symmetry and Chemistry of Main
(48 L + 12T)
Group Elements)
Organic Chemistry-I 4 credit
3 CHO-150
(Basic Organic Chemistry) (48 L + 12T)
Section-I: General Chemistry-I
2 credit
(Synthesis of Material and their
(24 L + 6T)
4 CHG-190 Characterization Technique)
Section-II: General Chemistry Practical - I 2 credit
(Inorganic Chemistry Practical-I) (48 L + 12 T)
Basic Practical Chemistry-I
4 credit
5 CHP-107 1.Physical Chemistry Practical-I
(96 L + 24T)
2.Orgnaic Chemistry Practical
SEMESTER-II
Physical Chemistry-II
4 credit
1 CHP-210 (Molecular Spectroscopy & Nuclear
(48 L + 12T)
Chemistry)
CHI-230 Inorganic Chemistry-II 4 credit
2
(Coordination & Bioinorganic Chemistry) (48 L + 12T)
Organic Chemistry-II
4 credit
3 CHO-250 (Photochemistry, Pericyclic Reaction and
(48 L + 12T)
Organic Spectroscopy)
Section-I: General Chemistry-II
2 credit
(Organometallic and Inorganic reaction
(24 L + 6T)
4 CHG-290 Mechanism Theory Course)
Section-II: General Chemistry Practical - II 2 credit
(Physical Chemistry Practical-II) (48 L + 12T)
Basic Practical Chemistry-II
4 credit
5 CHP-227 1.Inorganic Chemistry Practical –II
(96 L + 24T)
2.Organic Chemistry Practical-II
Total Credits for M. Sc. I year 40
S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 2

M.Sc. I Chemistry
Semester- I

M.Sc. I Chemistry
SANGAMNER NAGARPALIKA ARTS, D.J. MALPANI COMMERCE & B.N.

SARDA SCIENCE COLLEGE, SANGAMNER 422 605, DIST- AHMEDNAGAR
(MS)
FORMAT FOR FRAMING SYLLABUS FOR FIRST YEAR PG AUTONOMOUS

COURSES
ANNEXURE - A
1) Name of Faculty : Science

2) Name of B.O.S : Chemistry
3) Name of Subject : Chemistry
4) Name of Course Title : Physical Chemistry - Paper I
5) Year & Semester : M.Sc. I, Semester- I
6) Type of Courses : Theory
SYLLABUS (AUTONOMOUS COLLEGE) FOR TWO YEARS M.Sc. DEGREE

COURSE UNDER CHOICE BASE CREDIT SYSTEM (CBCS)
Name of subject: Physical Chemistry-I (Fundamentals of Physical Chemistry)
Course Code: CHP- 110
No. of Credit: 04 Credit (48L & 12T)
Objectives:
1. To understand the fundamental, basic concept, principles, and recent

developments in the subject area.
2. To inspire and boost interest of the students towards Physical Chemistry.
3. To familiarize with current and recent developments in Chemistry.
4. To create foundation for research and development in Chemistry.
5. To know the fundamental concepts which govern the chemical thermodynamics,
chemical equilibrium, quantum chemistry, Schrödinger equation and chemical
bonding.
6. To become familiar with Physical Chemistry concept.
7. The students are expected to know important principles, concept, definition and
significance.
Unit No Unit Title Purpose skills to be developed

It is useful to understand Laws of
1 Thermodynamics
thermodynamics, concept of heat and

M.Sc. I Chemistry
work, chemical potential of a substance

in a mixture, partial molar quantities,
Phase equilibrium & phase diagrams.
It is helpful to study blackbody radiation,
photoelectric effect, de Broglie
hypothesis and uncertainty principle and
2 Quantum Chemistry
its experimental evidence. Schrödinger
wave equation, particle in one
dimensional box, Problems.
It is helpful to study Valence bond
theory, hybrid orbitals, geometry and
Chemical Bonding hybridization, Molecular orbital theory,
3
approximations underlying Huckel
theory, applications to simple π-
systems.
It is useful to understand basic concept,
the temperature dependent reaction
rates, Complex and simple reaction,
4 Rate Law reactions approaching equilibrium,
Approximate methods to solve complex
reactions, Lindeman mechanism for
unimolecular reactions.
It is helpful to study fast reactions: flash
5 Kinetics of Complex Reactions photolysis, flow technique, stopped flow
technique, relaxation method.
It is useful to understand Collision theory
of bimolecular gas phase reactions,
6 Molecular Reaction Dynamics diffusion controlled and activation
controlled reaction in solution, activated
complex theory of reaction rate, Eyrings
equation.
It is helpful to study Michaelis
mechanism, effect of pH and
7 Enzyme Catalysis temperature on enzyme catalyzed
reactions, Lineweaverburk and Eadie
equation and plots.
It is helpful to study molecular energy
levels, Boltzmann distribution law,
8 Molecular Thermodynamics
partition function, and Bose-Einstein
statistics.
Teaching Methodology:
Innovative
Methods Digital Tools/ Film
Unit Total
to be show and AV Project Expected Outcome
No Lecture
used/Teac Application
hing aids
1 09 - Videos of work, - The students are

M.Sc. I Chemistry
heat and phase expected to understand

diagram. heat and work relation
https://epgp.inflibne in daily life in physical
t.ac.in/ chemistry.
https://epgp.inflibne To become familiar
2 08 - -
t.ac.in/ quantum chemistry.
The students are
expected to understand
ppt related to VBT
Valence bond theory,
and MOT.
3 07 - - hybrid orbital’s,
https://shodhganga.
geometry and
inflibnet.ac.in/
hybridization, molecular
orbital theory.
The students are
basic concept,
https://epgp.inflibne
4 06 - - Complex and simple
t.ac.in/
reaction, Approximate
methods to solve
complex reactions.
To become familiar with
Fast reactions: flash
ppt related to fast photolysis, flow
reaction technique. technique, stopped flow
5 03 - -
https://shodhganga. technique, relaxation
inflibnet.ac.in/ method, the steady
state approximation,
chain reactions.
The students are
Collision theory of
bimolecular gas phase
https://vidwan.inflib reactions, diffusion
6 05 - -
net.ac.in/ controlled and
activation controlled
reaction in
solution,Eyrings
equation
The students are
expected to
ppt related to
understand, Michaelis
mechanism of
7 04 - mechanism, effect of
enzyme catalyst
pH and temperature on
swayam.gov.in
enzyme catalyzed
reactions.
The students are
https://epgp.inflibne
8 06 - - Boltzmann distribution
t.ac.in/
law, partition functions,
Maxwell- Boltzmann,

M.Sc. I Chemistry
Fermi-Dirac and Bose-

Einstein statistics.
References:
Sr.
Title of Books Name of Author/s Publication Place
No
Elements of Physical Peter Atkins and Julio 8th edition
1 India
Chemistry de Paula, (2010),
Pearson
2 Physical Chemistry T. Engel and P. Reid India
Education (2006)
Physical Chemistry and D. Mcquarie and J. (University
3 India
molecular approach Simon Science) (2000)
The Macmillan
4 Physical Chemistry Marron and Prouton Company; 4th India
edition (1965)
G.M. Barrow, Tata Tata Mc Graw
5 Physical Chemistry India
Mc Graw Hill 1988 Hill 1988
5th edition,
6 Quantum Chemistry I. Levine Prentice Hall, India
1999
4th revised
edition
7 Quantum Chemistry R. K. Prasad India
New Age
International Ltd
Puri, Sharma,
8 Physical Chemistry Vishal Publishing India
Pathania.
University
Chemical Kinetics Harper & Row,
9 K.J. Laidler of
3, illustrated, revised 1987
Michigan
Thermodyanamics for Read Books,
10 S.Glasstone India
Chemists 2007
Signature of HoD/ Chairman BOS
Date:
Place:

M.Sc. I Chemistry
Annexure- B
Semester- I
CHP-110 Physical Chemistry-I
SECTION - I (2 Credits, 24 L, 6T)
(Fundamentals of Physical Chemistry)
1. Thermodynamics (09L)
State function, path function, exact differential and inexact differential, internal
energy and enthalpy, temperature dependent internal energy and enthalpy,
reversible and irreversible adiabatic expansion. The entropy of irreversible changes,
the Helmholtz and Gibbs function, Entropy and entropy change in an ideal gas with
temperature and pressure, Clausius inequality, chemical potential, chemical potential
of a substance in a mixture.
Change of State I : Partial molar quantities, methods for determination of molar
quantities, ideal solutions, Raoult’s and Henery’s law, Partial molar Gibbs function.
The thermodynamics of mixing – the Gibbs function of mixing, thermodynamics
mixing functions. The chemical potential of liquid-liquid mixture Thermodynamics of
Gibbs function of mixing, colligative properties: Elevation in boiling point, depression
in freezing point and osmosis.
Changes of State II: Physical Transformation of pure materials, The stabilities of
phases, Phase equilibrium & phase diagrams. The solid – liquid boundary. The liquid
- vapor boundary. The solid-vapour boundary.
2. Quantum Chemistry (08 L)
Applications of quantum chemistry- blackbody radiation, photoelectric effect, de
Broglie hypothesis and uncertainty principle and its experimental evidence.
Schrödinger wave equation, particle in one dimensional box, Normalization and
orthogonality of wave function, particle in three dimensional boxes, hydrogen like
atoms (no derivation). Operators: algebra of operators, commutative property, linear
operators, commutator operator, the operator ∇ and ∇2.
3. Chemical Bonding (07 L)
Valence bond theory, hybrid orbitals, geometry and hybridization, molecular orbital
theory for di and tri atomic molecule, linear variation method, approximations
underlying Huckel theory, applications to simple π-systems.

M.Sc. I Chemistry
SECTION – II (2 Credits, 24 L, 6 T)
Chemical Kinetics and Reaction Dynamics
1. Rate Laws (06 L)
Recapitulations of basic concept, the temperature dependent reaction rates, reaction
moving towards equilibrium, consecutive reaction, parallel reactions, pre-equilibria,
unimolecular reactions., Complex and simple reaction: reactions approaching
equilibrium, consecutive reactions, opposing reactions, chain reaction- explosion,
photochemical reactions. Approximate methods to solve complex reactions: The
kinetics of complex reactions, the steady state approximations, pre equilibria
approximation, Lindeman mechanism for unimolecular reactions.
2. Kinetics of Complex Reactions (03 L)
Fast reactions: flash photolysis, flow technique, stopped flow technique, relaxation
method, the steady state approximation, chain reactions - free radical polymerization
reaction between H2 and Br2, explosive reaction.
3. Molecular Reaction Dynamics (05 L)
Collision theory of bimolecular gas phase reactions, diffusion controlled and
activation controlled reaction in solution, activated complex theory of reaction rate,
Eyrings equation.
4. Enzyme Catalysis (04 L)
Michaelis mechanism, effect of pH and temperature on enzyme catalyzed reactions,
limiting rate, Lineweaverburk and Eadie equation and plots, inhibition of enzyme
action, competitive inhibition and non- competitive inhibition.
5. Molecular Thermodynamics (06 L)
Molecular energy levels, Boltzmann distribution law, partition functions and
ensembles, translational, rotational and vibrational partition function of diatomic
molecule, obtaining energy, heat capacity, entropy and equilibrium constants from
partition functions, Maxwell- Boltzmann, Fermi-Dirac and Bose-Einstein statistics.
References
1. Physical Chemistry- P.W.Atkin and De Paule ,8th edition (2010), OUP Oxford,
2010
2. Physical Chemistry-T. Engel and P. Reid, Pearson Education (2006)
3. Physical Chemistry and molecular approach- D. Mcquarie and J. Simon
(University Science) (2000)

M.Sc. I Chemistry
4. Physical Chemistry – Marron and Prouton The Macmillan Company; 4th edition
(1965)
5. Physical Chemistry- G.M. Barrow, Tata McGraw Hill 1988
6. Quantum Chemistry- I. Levine 5th edition, Prentice Hall, 1999.
7. Quantum Chemistry- R. K. Prasad., 4th revised edition, New Age International Ltd
8. Physical Chemistry- Puri, Sharma, Pathania, Vishal Publishing.
9. Chemical Kinetics- K.J. Laidler,Harper & Row, 1987.
10. Thermodyanamics for Chemists- S.Glasstone, Read Books, 2007.

M.Sc. I Chemistry

(MS)
FORMAT FOR FRAMING SYLLABUS FOR FIRST YEAR UG / PG AUTONOMOUS

COURSES
ANNEXURE - A
1) Name of faculty : Science

4) Name of the course title : Inorganic Chemistry - I

Name of subject: Inorganic Chemistry-I (Molecular Symmetry and Chemistry

of Main Group Elements)
Course Code: CHI-130
Objectives:
1. Student should imagine the molecules in three dimensions.

2. To understand the concept of symmetry elements, symmetry operations, point
grops and able to pass various symmetry elements through the molecule.
3. To apply the concept of point group for determining optical activity, dipole moment
and apply great Orthogonality theorem for construction of character table.
4. To find out hybridization using reduction formula and learn SALC to apply
projection operator for normalization of SALC.

It is useful to understand the concept of
1 Molecular Symmetry symmetry elements, symmetry operations and
and Symmetry Groups classification of molecules into different point
groups.
It is helpful for matrix representation of
Representations of
2 symmetry elements and use of Great
Groups
Orthogonality theorem for construction of

M.Sc. I Chemistry
character table.
It is useful for construction of SALC for sigma
Symmetry Adapted
3 bonding molecular orbital and transformation
Linear Combinations
properties of atomic orbital.
It is helpful to find out normalized SALC for pi
4 Molecular Orbital Theory
bonding molecular orbital
Hydrogen and its It is useful to know synthesis, reaction and
5
compounds different compounds form by hydrogen.
Alkali and Alkaline Earth It is helpful to know solution states of alkali and
6
Metals alkaline earth elements.
It is useful to learn advance chemistry of
7 Boron Group
boranes, compounds of boron and STYX rule.
It is useful to know advance chemistry of
8 Carbon Group
fullerene and Zeolites
It is useful to know different method of N2
9 Nitrogen Group activation, compounds of nitrogen and their
applications.
It is helpful to get information of selenides and
tellurides, clusters and cage compounds of p
10 Oxygen Group
block elements and oxyacids and oxoanions of
S and N.
It is helpful to get information about different
11 Halogen Group compounds form by Halogens, Interhalogens
and pseudo halogens compounds.
It is helpful to know synthesis method,
12 Noble Gases
hybridization, geometry of noble gas.
Organomettalic It is useful to know various organomettalic
13
Compounds compounds of s and p block elements.
Innovative Digital Tools/

Unit Total
Methods Film show and Project Expected Outcome
No Lecture
to be used AV Application
Lecture related Students are expected
to group theory operate various symmetry
1 10 swayam.gov.in - operations in molecule and
Module No. classify molecules in
1,2,3,4. appropriate point groups.
Students are expected to
Use of
Videos related know great Orthogonality
2 06 model box -
theorem for construction of
to character character tables.
table, SALC Students are familiar with
SALC of sigma bonding MO
3 04 https://epgp.infl -
in AB4 and AB6 type of
ibnet.ac.in/ molecules.
4 04 Use of - Students are expected to

M.Sc. I Chemistry
model box find out MO for pi bonding.

Students are familiar with
Use of
synthesis, reaction of
5 02 Periodic Lecture related -
hydrogen and its
table to S and P
compounds.
block elements
Students are learn how
https://www.bri
extraction of these
ghtstorm.com
6 02 _ - elements by crown ethers
and their behavior in
solution states
To understand advanced
7 04 _ - chemistry of boranes &
zeolites.
To learn carbon allotropes,
8 03 _ -
carbon nanotube.
To learn the process of N2
activation, oxidation states
9 03 _ -
of nitrogen and PN and SN
Videos of
compounds.
halogens and
organomettalic
10 03 _ - oxyacids and oxoanions of
compounds
of S and N
https://shikshah
To learn interhalogen,
ouse.com
11 02 _ - pseudohalogen, oxyacids
and oxoanions of Halogens.
To understand synthesis
12 02 _ - hybridization and geometry
of noble gas elements.
13 03 _ - organomettalic compounds
of s and p block elements
References:
Sr.
No
3rd edition
Chemical applications United
1 F.A. Cotton John Wiley &
and group theory States
Sons
Symmetry and New age
2 spectroscopy of K. Veera Reddy international Delhi
molecules
2nd edition
Group theory and its
3 P.K Bhattacharya Himalaya India
chemical applications
Molecular symmetry A. Vincent. 2 nd edition United
4
and group theory Wiley States
Symmetry in H.H. Jaffe' & M. John Wiley &
5 New York
Chemistry Orchin Sons

M.Sc. I Chemistry
Douglas A. Skoog
CengageLearing
6 Instrumental analysis F. James Holler, New Delhi
India Pvt. Ltd.
Stanley R. Crouch
H.H. Willard , L.L.
Instrumental method Merritt. Jr. J. A. 7thedition
7 USA
of analysis Dean and F.A. CBS
Settle
4th edition
8 Inorganic Chemistry Shriver and Atkins Oxford University New York
Press
Concise Inorganic 4th edition
9 J. D. Lee New York
Chemistry Chapman & Hall
Inorganic chemistry
by Principle of Huheey Keiter, 4th edition
10 New York
Structures and Medhi Pearson
Reactivity
4th edition
11 Inorganic Chemistry Meissler and Tarr New York
Pearson
Christoph New Jersey,
12 Organometallics Wiley- VCH
Elschenbroich USA
Date :
Place :

M.Sc. I Chemistry
ANNEXURE – B
Semester- I
CHI-130 Inorganic Chemistry-I
SECTION –I (2 Credit, 24L,6T)
1) Molecular Symmetry and Symmetry Groups (10L)

Symmetry elements and operations, Symmetry planes and reflections, the
inversion centre, proper axes and proper rotations, improper axes and
improper rotation, products of symmetry operations, equivalent symmetry
elements and equivalent atoms, general relations among symmetry elements
and symmetry operations, classes of symmetry operations, symmetry elements
and optical isomerism, symmetry point groups, classification of molecular point
groups. Defining properties of a group, group multiplication table, some examples of
group, subgroups and classes.
2) Representations of Groups (06 L)
Matrix representation and matrix notation for geometric transformation, The Great
Orthogonality Theorem and its consequence, character tables (No
mathematical part),wave function as basis for irreducible representations.
3)Symmetry Adapted Linear Combinations (04L)
Projection operators and their use of construct SALC (Construction of SALC for
sigma bonding for molecules belonging point groups: D2h, D3h D4h, C4v, Td.,
Oh., normalization of SALC, transformation properties of atomic orbital, MO’s for
sigma bonding, ABn molecules, tetrahedral AB4 and Oh AB6 cases.
4) Molecular Orbital Theory (04L)
Transformation properties of atomic orbitals, Molecular orbitals for sigma bonding,
ABn molecules, tetrahedral AB4 and Oh AB6 cases. Molecular orbitals for pi bonding
in ABn molecules.
SECTION –II (2 Credit, 24L,6T) Main Group Elements
1. Hydrogen and its compounds (02L)

Classification of Hydrides, electron deficient, electron precise and electron rich
hydrides.; PH3, SbH3 , AsH3 , Selenides, Tellurides.
2. Alkali and Alkaline Earth Metals (02L)
Solutions in non-aqueous media, application of crown ether in extraction of alkali and
alkaline earth metal.

M.Sc. I Chemistry
3. Boron Group (04L)

Boron Hydrides, preparation, structure and Bonding with reference to LUMO,
HOMO, interconversion of lower and higher boranes, metalloboranes, carboranes,
reactions of organoboranes, STYX rules and structure of higher boranes.
4. Carbon Group (03L)
Allotropes of carbon, Diamond, Graphite, Graphene, fullerenes, carbon nanotube
with synthesis, properties, Structure- single walled and multi-walled and its
application ,Intercalation compounds of graphite, Silicates, including Zeolites.
5. Nitrogen Group (03L)
Nitrogen activation Boron nitride, Oxidation states of nitrogen and their
interconversion, PN and SN Compounds, Applications of PN and SN compounds.
6. Oxygen Group (03L)
Metal Selenides and Tellurides, oxyacid’s and oxoanions of Sulphur and nitrogen.
Ring, Cage and Cluster compounds of p-block elements.
7. Halogen Group (02L)
Interhalogens, pseudohalagen, Synthesis, Properties & Applications, Structure,
Oxyacid’s and Oxyanions of Halogens.
8. Noble Gases (2L)
Synthesis, properties, uses, structure & bonding with respect to VSEPR.
9.Organometallic Compounds (03L)
Organometallic Compounds of Li, Mg, Si, Pb, As with Classification, Nomenclature,
Synthesis, Structure Properties and Uses of Li, Mg, Si, Pb, As with Classification,
Synthesis, Structure Properties and Uses.
References:
1.Chemical applications and group theory F.A. Cotton, 3rd edition, John Wiley &
Sons Asia Pvt. Ltd. (1999).
2. Symmetry and spectroscopy of molecules by K. Veera Reddy, New age
international (2007)
3. Group theory and its chemical applications: P.K Bhattacharya, 2 nd ed.,
Himalayapub. India, (1989).
4. Molecular symmetry and group theory -A. Vincent.
5. Symmetry in Chemistry: H.H. Jaffe' and M. Orchin, Dover Publications Inc,
NewYork,(2002)

M.Sc. I Chemistry
6. Instrumental analysis – By Douglas A.Skoog, F. James Holler, Stanley R. Crouch

(Publisher:Cengage Learing India Pvt. Ltd . New Delhi , 2007)
7. Instrumental method of analysis ( 7th edition) By- H.H. Willard , L.L. Merritt. Jr. J.
A.Dean and F.A. Settle ,Jr (Publisher: CBS Publishers and distributors Pvt
.Ltd.(Copyright – Wordsworth publishing copy USA .2000).
8. Inorganic Chemistry: D. F. Shriver and P.W. Atkins, 4th edn. Oxford (2003).
9. Concise inorganic Chemistry, J.D.Lee 4th edition ( Chapman and Hall )
10. Inorganic chemistry of Structures and Reactivity by Huheey, Keiter, Medhi
11. Inorganic Chemistry by Meissler andTarr, 3rd edition.
12. Organometallics by Christoph Elschenbroich, Wiley – VCH publication.

Date :
Place :

M.Sc. I Chemistry

(MS)

COURSES
ANNEXURE - A

4) Name of Course Title : Organic Chemistry-I
5) Year & Semester : M.Sc. I, Semester I

Name of subject– Organic Chemistry I (Basic Organic Chemistry)
Course Code: CHO-150
No. of Credit – 4 (48L + 12T)
Objectives:
1) Students are expected to understand the criteria for aromaticity in non benzenoid
molecules and other advanced polycyclic aromatics.
2) To Understand the chemistry of monocyclic heterocycles, nomenclature and
reactions.
3) To learn the concept stereochemistry and its importance; their rules and the
concept of chirality
4) To Understand the role of various reaction intermediates like carbocation,
carbanion, carbenes, radicals, and nitrenes in organic reactions; concept of NGP
5) Able to describe mechanism of different rearrangement reactions. Appreciates the
various steps involved in the molecular rearrangements.
6) To understand the Chemistry of Ylides and various steps involved in the molecular
rearrangements.
7) Use of oxidizing and reducing agents for solving the problems.

M.Sc. I Chemistry
Unit
Unit Title Purpose skills to be developed
No
It is useful to understand Aromaticity of
1 Structure and Reactivity Benzenoid and non-benzenoid compounds,
Huckel’s rule, recent concepts of aromaticity
It is useful to understand Stereochemistry,
configuration, Prochiral relationship, topicity,
2 Stereochemistry
axial chirality, optical activity, Conformational
analysis of substituted cyclohexane
It is useful to understand Structure, Stability
Structure, Stability of Reactive of Reactive Intermediates such as
3
Intermediates Carbocation, Carbanion, Free Radical,
Carbenes, nitrenes and Benzynes
It is useful to understand substitution and
Neighbouring group
4 Neighbouring group participation by different
participation: NGP
groups
It is useful to understand different
5 Rearrangements Rearrangements like Beckmann, Hofmann,
Curtius etc.
It is useful to understand Ylide synthesis and
6 Ylides
their reaction.
It is useful to understand Oxidation and
Oxidation and Reduction
7 Reduction Reactions of some organic
Reactions
functional groups.
Innovative
Methods to Digital Tools/ Film
Unit Total
be show and AV Project Expected Outcome
No Lect.
used/Teach Application
ing aids
To learn the concept
https://epgp.inflibnet.
aromaticity, to
1 4 - ac.in/Home/ViewSu -
understand the various
bject?catid=5
types of aromaticity
To know
Use of
2 16 - - stereochemistry of
Model box
organic compounds
To study structure,
Use of formation, stability and
3 4 ac.in/Home/ViewSu -
Model box related name reaction
bject?catid=5
of intermediates
Use of
Model box https://epgp.inflibnet. To Recognize
4 6 for ac.in/Home/ViewSu - neighboring group
norbornyl bject?catid=5 participation
system
5 6 - https://epgp.inflibnet. - To study

M.Sc. I Chemistry
ac.in/Home/ViewSu rearrangement reaction

bject?catid=5 with specific
mechanism and
migratory aptitude of
different groups.
To study Ylides and
6 4 - - -
their reaction
To understands the
Use of basis of redox reaction;
7 8 ac.in/Home/ViewSu -
Model box acquire knowledge
bject?catid=5
about the reagents
References:
Sr.
No.
Stereochemistry
New Age New
1 conformations and P.S. Kalsi
International Delhi
mechanism (10th Edition)
J. Clayden, N. Oxford
Organic Chemistry
2 Greeves, S. Warren University England
(2nd Edition)
and P. Wothers Press
Advanced Organic
Chemistry: Reactions, Michael B. Smith and New
3 Wiley
Mechanisms, and Jerry March York
Structure (6th Edition)
Mechanism and structure Holt,Rinehart &
4 in Organic Chemistry New E. S. Gould Winston of Canada
impression edition (1969) Canada Ltd.
Advanced Organic
A. Carey and R.J. New
5 Chemistry (Part A) Springer
Sundberg York
(5th Edition)
Stereochemistry of New
6 Nasipuri New Age
organic compound Delhi
Organic Synthesis 2nd Mcgraw-Hill New
7 M.B. Smith
Edition International York
Stereochemistry of carbon Mcgraw-Hill New
8 E.L. Eliel
compound International York
Organic Reactions and
New Age New
9 Their Mechanisms (4th P.S. Kalsi
International Delhi
Edition)
Date :
Place :
ANNEXURE – B

M.Sc. I Chemistry
Semester – I
CHO-150, Organic Chemistry-I,
SECTION-I (2 Credits, 24 L, 6T)
Basic Organic Chemistry
1. Structure and Reactivity: (04 L)

Aromaticity: Benzenoid and non-benzenoid compounds, Huckel’s rule,
antiaromaticity, Application to carbocyclic and heterocyclic systems, annulenes,
azulenes, current concepts of aromaticity.
2. Stereochemistry: (16 L)
a) stereochemical principles, concept of chirality, centre of chirality, configuration and
their specification, enantiomeric relationship and diastereomeric relationship, R and
S, E and Z nomenclature in C, N, S, P containing compounds. Prochiral relationship,
topicity, axial chirality, optical activity in allenes, biphenyls, spiranes, exocyclic
alkylidene, planar chirality, ansa compounds, cyclophanes, helicity
b) Conformational analysis of cyclohexane and di, tri and tetra substituted
cyclohexanes.
3. Structure, Stability of Reactive Intermediates (04 L)
Carbocation, Carbanion, Free Radical, Carbenes, nitrenes and Benzynes
SECTION-II (2 Credits, 24 L, 6T)

1. Neighbouring group participation: NGP (06 L)
Recapitulation of substitution reaction, Neighbouring group participation by hetero
atom, sigma bond, double bond, phenyl ring and norbornyl system etc and their
examples.
2. Rearrangements: (06 L)
Beckmann, Hofmann, Curtius, Schmidt, Wolff, Lossen, Bayer-villiger, Sommelet,
Favorskii, Pinacol-pinacolone, Benzil-benzilic acid, Fries, Tiffeneau Demjanov,
Pummerer.
3. Ylides: (04 L)
Synthesis and their reaction of Phosphorus, Nitrogen and Sulphur ylides
4. Oxidation and Reduction Reactions: (08 L)

M.Sc. I Chemistry
Oxidising agents: CrO3, PDC, PCC, KMnO4, MnO2, Swern, SeO2, Pb(OAc)4, Pd-C,
RuO4, OsO4, m-CPBA, O3, NaIO4, HIO4, TEMPO, IBX, CAN, Dess-Martin, DDQ,
Ag2O
Reducing agents: Boranes and hydroboration reactions (B2H6 and 9-BBN), MPV
reduction and reduction with H2/Pd-C, Raney-Ni, NaBH3CN, Willkinsons catalyst,
DIBAL and Wolff-Kishner reduction, Clemenson, Birch, Dissolving metal
References:
1.Organic Chemistry by J. Clayden, N. Greeves, S. Warren and P. Wothers 2nd
Edition (Oxford).
2. Advanced Organic Chemistry – J. March 6th Edition, John Wiley & Sons.
3. Advanced Organic Chemistry (Part A) – A. Carey and R.J. Sundberg, 5th Edition
Springer.
4. Stereochemistry of carbon compound- E.L. Eliel, Mcgraw-Hill International.
5. Stereochemistry of organic compound- D. Nasipuri, New Age International
Publication.
6. Stereochemistry conformations and mechanism (10th Edition) by P.S. Kalsi, New
Age International Publication.
7. Organic Synthesis (2nd Edition) – M.B. Smith, Mcgraw-Hill International.
8. Mechanism and structure in Organic Chemistry – E. S. Gould, Holt, Rinehart &
Winston of Canada Ltd. New impression edition (1969)
9. Organic Reactions and Their Mechanisms (4th Edition) by P.S. Kalsi, New Age
International Publication.

M.Sc. I Chemistry
SANGAMNER NAGARPALIKA ARTS, D.J. MALPANI COMMERCE & B.N. SARDA

SCIENCE COLLEGE, SANGAMNER 422 605, DIST- AHMEDNAGAR (MS)
FORMAT FOR FRAMING SYLLABUS FOR FIRST YEAR PG
AUTONOMOUS COURSES
ANNEXURE – A

4) Name of Course Title : General Chemistry-I

Name of Subject: General Chemistry – I (Synthesis of Material and their
Characterization Techniques)
Course Code: CHG-190
Objectives:
1. Student are able to understand various methods for synthesis of solid materials.
2. Able to understand procedure of synthesis of some Nano particles.
3. Learn Braggs law and its relation to crystal structure
4. Students are able to identify and describe different diffraction methods
5. Students are able to interpret and assign X-ray and electron diffraction patterns.
6. Understand the theory behind X-ray microanalysis in SEM and TEM.
7. Student understand qualitative and quantitative analysis using SEM and TEM.
Unit
Unit Title Purpose skills to be se
No
1 Synthesis of Solids To get information of synthesis of solids.
To learn the Principle of XRD, instrumentation of
powder XRD, Brags law, applications of XRD for
2 X-Ray Diffraction Methods
crystal structure determination, numerical
problems.

M.Sc. I Chemistry
To understand the basics of X-rays, Principle of

Transmission Electron
3 XRF, types of XRF, instrumentation, qualitative
Microscopy
and quantitative analysis, numerical.
To learn the principle of SEM, instrumentation of
Scanning Electron
4 SEM and interpretation of surface morphology of
Microscopy
solid from SEM.
Innovative
Methods to Digital Tools/
Unit Total
be used/ Film show and Project Expected Outcome
No Lecture
Teaching AV Application
aids
Use of To get information of
1 10 - -
Charts synthesis of solids.
To learn the Principle of
XRD, instrumentation of
Use of powder XRD, Bragslaw,
2 6 - -
Model box applications of XRD
forcrystal structure
numerical problems.
To understand the basics
of X-rays, Principle of
Use of XRF, types of XRF,
3 4 - - instrumentation,
Charts
qualitative and
quantitative analysis,
numerical problems.
To learn the principle of
SEM, instrumentation of
4 6 - - - SEM and interpretation of
surface morphology of
solid from SEM.
References:
Sr. Name
Title of Books Publication Place
No of Author/s
Nanotechnology: Principles Third Ed.
1 S. K. Kulkarni, New York
and Practices, Springer
Essentialsof inorganic C.N.R. Rao, New York
2 Wiley, 2015
materialsbsynthesis Kanishka Biswas, US
Materials Characterization -
Second Ed. Ammerica
3 Introduction to Microscopic Yang Leng,
Wiley-VCH, US
and Spectroscopic Methods,
Introduction to Instrumental
4 R. D. Braun, Second Ed. New York
Analysis,

M.Sc. I Chemistry
Fourth Ed.
Solid State Chemistry - an Elaine A. Moore, London,
5 CRC Press
Introduction. Lesley E. Smart New York
(2012)
Date :
Place :

M.Sc. I Chemistry
ANNEXURE – B
Semester-I
CHG – 190, General Chemistry-I, Semester-I (2 Credits)
SECTION-I: Theory Course (2 Credits, 24 L, 6T)

Synthesis of Materials and their characterization techniques
1. Synthesis of Solids (10L)
Introduction, Common Reactions Employed in Synthesis B, Soft-Chemistry Routes,

Ceramic Methods, Decomposition of Precursor Compounds, Combustion Synthesis,
Mechano-chemical and Sono-chemical methods, Soft Chemistry Routes(Ion
Exchange Reactions, Use of Fluxes, Sol–Gel Synthesis, Electrochemical Methods,
Hydrothermal, Solvothermal and Ionothermal Synthesis), Chemical Vapour
Deposition and Atomic Layer Deposition, Procedures of synthesis of some nano-
materials- Gold and Silver nanoparticles, CdS nanoparticles, ZnO, TiO 2 and Fe2O3
nanoparticles and Porous Silica
2.X-Ray Diffraction Methods (6 L)

Miller and Weiss indices, X-Ray Radiation, Generation of X-Rays, X-Ray
Absorption, Theoretical Background of Diffraction, Diffraction Geometry, Bragg’s
Law, Reciprocal Lattice, Diffraction Intensity, Structure Extinction, X-Ray
Diffractometry, Instrumentation, System Aberrations, Samples and Data Acquisition,
Sample Preparation, Acquisition and Treatment of Diffraction Data, Distortions of
Diffraction Spectra, Crystallite Size, Applications, Crystal-Phase Identification,
Quantitative Measurement , Wide-Angle X-Ray Diffraction and Scattering, Wide-
Angle Diffraction, Wide-Angle Scattering. Problem on XRD (Calculation of d values,
assigning planes, calculation of crystal parameters)
3. Transmission Electron Microscopy (4 L)
Instrumentation, Electron Sources, Thermionic Emission Gun, Field Emission Gun,
Electromagnetic Lenses, Specimen Stage, Specimen Preparation, Prethinning, Final
Thinning, Electrolytic Thinning, Ultramicrotomy, Image Modes (Mass–Density
Contrast, Diffraction Contrast, Phase Contrast), Selected-Area Diffraction (SAD),
Selected-Area Diffraction Characteristics.
4. Scanning Electron Microscopy (4 L)
Instrumentation, Optical Arrangement, Signal Detection, Detector, Probe Size and
Current Contrast Formation, Electron–Specimen Interactions, Topographic Contrast,

M.Sc. I Chemistry
Compositional Contrast, Operational Variables, Working Distance and Aperture Size,

Acceleration Voltage and Probe Current, Astigmatism, Specimen Preparation,
Preparation for Topographic examination.
References
1. Nanotechnology: Principles and Practices, S. K. Kulkarni, Third Ed. Springer,

2015.
2. Essentials of inorganic materials biosynthesis, C.N.R. Rao, Kanishka Biswas,
Wiley, 2015.
3. Materials Characterization Introduction to Microscopic and Spectroscopic
Methods, Yang Leng, Second Ed. Wiley-VCH,2013.
4. Introduction to Instrumental Analysis, R. D. Braun, Second Ed. Pharma med
press, 2016.
5. Solid State Chemistry - an Introduction. Elaine A. Moore, Lesley E. Smart Fourth
Ed. CRC Press, 2012.

M.Sc. I Chemistry


COURSES
ANNEXURE - A

4) Name of the course title : Inorganic Chemistry Practical-I
6) Type of Courses : Practical
SYLLABUS (AUTONOMOUS COLLEGE) FOR TWO YEARS M. Sc. DEGREE

COURSE UNDER CHOICE BASE CREDIT SYSTEM (CBCS )
Name of Subject: General Chemistry Practical – I (Inorganic Chemistry

Practical)
Course Code: CHG-190
Objective:
1. Students are expected to learn the basic application and recent development in
the practicals which is related to industrial approach.
2. Understand the knowledge of various inorganic techniques used in
characterization of compounds such as spectrometric, titrometric, complexmetric,
precipitation etc.
3. To improve their practical skills which will help them in metal industry.
4. To develop practical skills such as qualitative and quantitative analysis of ore,
alloy and complexes.

To understand ore and quantitative
1 Ore Analysis estimation of inorganic elements such as Fe,
Si, Pb and Al etc. from ore.

M.Sc. I Chemistry
It is useful to find out percentage composition

2 Alloy Analysis of metals present in alloy such as Fe, Cr, Sn
etc.
3 Thermochemistry thermochemistry and its application to find
lattice energy by heat of dissolution.
It is helpful to aware of different methods
used for synthesis of Ag and Zn
Synthesis of solid state
4 nanomaterials and characterization of
materials/ nanomaterials
nanomaterials by instrumental techniques
such as XRD, SEM and TEM.
Applications of Solid state It is helpful to study kinetics of photo catalytic
5
Materials dyes and their degradation.
Innovative
Un Total Digital Tools/
Methods to be Expected
it Lectu Film show and Project
used/ teaching Outcome
No re AV Application
aids
Collection of
different ores
https://mineral from local To understand
1 18 seducationcoa region and ore and checking
lition.org quantitative purity of ore.
estimation of
ores.
Collection of
different alloy
It is helpful to
from local
understand alloy
2 12 market and
https://study.c and checking
quantitative
om › academy purity of alloy.
All practicals estimation of
are performed › lesson alloy.
by microscale
techniques.
https://ocw.mit
It is useful to
.edu ›
understand
chemistry › 5-
thermochemistry,
3 12 60-
- lattice energy and
thermodynami
heat of
cs-kinetics-
neutralization.
spring-2008
Synthesis of Understand the

https://www.fr nanoparticle of nanoparticles,
4 12 ontiersin.org › different non- synthesis and
articles › toxic metals by characterization
fbioe.2019.00 co -precipitation by instrumental

M.Sc. I Chemistry
287 method and techniques XRD,

characterization SEM and TEM.
of nanoparticle.
To get awareness
about solid states
https://youtu.b
materials for
5 12 e/bPF- -
photo
hH0IRnI
degradation
purpose.
References :
Sr. Name of
No. Author/s
3rd edition New Jersey
Text book of Quantitative
1 A. I. Vogel John Wiley United
Analysis
& Sons States
Experimental Inorganic Mounir
2 Horwood House New Delhi
Chemistry A. Malati
Principles of 3rd edition United
3 S. K. Kulkarni
Nanotechnology Springer States
Date :
Place :

M.Sc. I Chemistry
ANNEXURE – B
Semester-I
CHG-190, Section-II Inorganic Chemistry Practical-I
Inorganic Material Analysis, Synthesis and Applications
Part-I: Ore Analysis (any three) (Ref. -1)
1. Determination of silica and manganese from pyrolusite ore.
2. Determination of aluminum and silica from Bauxite ore.
3. Determination of silica and iron from hematite ore.
4. Determination of copper and Sulphide from Chalcopyrite ore.
Part-II: Alloy Analysis (any two ) (Ref. -1)
5. Determination of tin and lead from solder alloy.
6. Determination of iron and chromium from stainless steel alloy.
7. Determination of copper and nickel from cupranickel alloy.
Part-III: Thermochemistry (compulsory)
8. Lattice energy of binary salt by heat of dissolution, systems such as CaCl 2, NaCl
and KCl.
9. Determination of heat of neutralization of strong acid and strong base.
Part- IV : Synthesis of solid state materials / nano-materials ( any two)
10. Synthesis of Fe2O3 nanoparticles sol-gel/coprecipitation/hydrothermal (any one
method)
11. Synthesis of ZnO from zinc oxalate - precursor method and determine band gap
by absorption spectroscopy
12. ZnO, TiO2, Fe2O3 nanoparticles powder XRD, SEM, TEM (at least one spectral
analysis should be done)
Part-V: Applications of Solid State Materials (compulsory)
13. Removal and kinetics of photocatalytic dyes, degradation (methylene blue) by
ZnO, TiO2 photocatalysis (Ref-2)
14. Study of adsorption of phosphate ion on alfa-Fe2O3 (Ref-2)
References:
1) Text book of Quantitative Analysis by A.I. Vogel, 3rded (1963).
2) Experimental Inorganic Chemistry by Mounir A. Malati, Horwood House, New
Delhi.
3) Nanotechnology by S. K. Kulkarni, 3rd edition, springer

M.Sc. I Chemistry

FORMAT FOR FRAMING SYLLABUS FOR FIRST YEAR PGCHEMISTRY
AUTONOMOUS COURSES
ANNEXURE - A

4) Name of Course Title : Basic Chemistry Practical-I
5) Year & Semester : M.Sc. I (Semester-I)
SYLLABUS (AUTONOMOUS COLLEGE) FOR TWO YEARS M. Sc. DEGREE

Name of Subject: Basic Practical Chemistry-I

Course Code: CHP-127 Section I (Physical Chemistry Practical)
Objectives:
1) To understand the fundamentals, principles, mathematical concepts and recent
development in the subject area.
2) The practical course is in relevance to the theory courses to improve the
understandings of the concepts.
3) It would help in development of practical skills of the students.
4) To inspire and boost the interest of the students towards physical chemistry.
5) To develop interdisciplinary approach of the subjects for students opting for good
position in industries at latter stages of post-graduation.
6) To carry out, and interpret measurements within the context of the fundamental
technological problems with which they are presented.
1 Statistical treatment of To get awareness about Statistical treatment of

M.Sc. I Chemistry
experimental data experimental data

To understand basic concepts of chemical
2 Chemical Kinetics kinetics with research and industrial level
application
To understand basic techniques of
determination of physical entities based on
3 Non-Instrumental
techniques like separation and properties of
liquid solutions.
To understand basic instrumental techniques of
spectroscopy for simultaneous determination of
4 Colorimetry and
Spectrophotometry inorganic ions and compounds. To study the
process of adsorption.
To get instrumental operating experience with
5 Surface Tension understanding of basic concepts with research
and industrial level applications.
Innovative
Methods Digital Tools/
Unit Total to be Film show and
Project Expected Outcome
No Lecture used/ AV
Teaching Application
aids
To get
awareness
1 6 - - -
about Statistical
treatment
Determine the Understand the
- https://youtu.be/a rate of reaction concept of
2 18
5J0jGBcb60 of some organic dilatometry and
reactions Kinetic concepts
https://youtu.be/v
CjpDF88JIc Determination of
https://youtu.be/6 molecular Training of simple
3 18 - weight of
8bo-h3Kf7s lab techniques
different organic
https://youtu.be/9 liquids
0b5DS6ARzE
Adsorption study Training of
- https://youtu.be/4 of some
4 24 operating lab
zchWu5dYb4 activated
charcoal Instruments

M.Sc. I Chemistry
Determination of Training of
https://youtu.be/q surface tension measurements of
5 6 -
vUyVrUb8Fo of some organic Properties of
liquids liquids
References:
Sr. Publication/Publis
Title of Books Name of Author/s Place
No her
Longmans, Green
Practical physical A. Findlay, T.A.
1 and Co,Sixth London
chemistry Kitchner
edition.
J.M. Wilson, K.J.
Experiments in Newcombe, A.R.
2 Pergamon Press -
Physical Chemistry Denko. R.M.W.
Richett
Senior Practical B.D.Khosla and
3 R. Chand and Co. New Delhi
Physical Chemistry V.S. Garg,IV edition.
Mc. Growhill,
Experimental
4 D. P. Shoemaker 7thEdition -
Physical Chemistry
2003
Physical (2001)
5 Wien -
chemistry
Advance
Physical Gurtu and Gurtu,VI (Meerut)
6 Pragati Publication
Chemistry edition.
Experiment
Experiments in Himalaya New
7 D. V. Jahagidar
Chemistry Publishing House Delh
Practical physical B. Vishwanathan and
8 Viva Books -
Chemistry P. S. Raghwan
Systematic
Anjali Publication
Experimental Auranga
9 Rajbhoj. S.W - 3rd ed. 2013
Physical bad
Chemistry

Date :
Place :

M.Sc. I Chemistry
Annexure- B
Semester-I
CHP-107 Basic Practical Chemistry-I
SECTION- I : Physical Chemistry Practical
Total 11 practical to be conducted
1) Statistical treatment of experimental data (calculation of mean and standard
deviation for given data and least square method for calibration curve method)
(compulsory)
Part-I: Chemical Kinetics: (Any three)
2) Kinetic decomposition of diacetone alcohol by dilatometry.
3) Determination of an order of a reaction.
4) Brönsted primary salt effect.
5) Kinetics of oxidation of ethanol by K2Cr2O7
Part-II: Non-Instrumental: (Any Three)
6) Determination of surface excess of amyl alcohol or TX-100 surfactant by Capillary
rise method.
7) Determination of molecular weight by steam distillation.
8) Glycerol radius by viscosity.
9) Partial Molar Volume (Polynometry) Determination of the densities of a series of
solutions and to calculate the molar volumes of the components.
Part-III: Colorimetry and Spectrophotometry (Any four)
10) Simultaneous determination of Ni and Co by spectrophotometry (Ref-1)
11) Simulations determination of KMnO4 and K2Cr2O7 by spectrophotometry(Ref-7).
12) To study the adsorption of certain dyes such as methyl violet, picric acid or
malachite green on charcoal. (Ref-2)
13) To determine the indicator constant of bromocresol purple by half height method
(Ref-8)
14) Estimation of Cu (II) by titration with Na2 EDTA by colorimetry.
15) A. Determination of energy of n to Π*transition in acetone and study of effect of
solvent on energy of this transition by recording absorbance spectra in n- hexane
and water. B. To study the effect of the extended conjugation on the λmax of p-nitro
phenol by recording spectrum in acidic and alkaline medium (Ref-8).
Part -IV: Surface Tension: (Any one)
16) Determination the surface tension of a liquid by stalagmometer method. (Ref-9)

M.Sc. I Chemistry
17) Determine the surface tension of methyl acetate, ethyl acetate, hexane and
chloroform and hence calculate the atomic parachors of C, H and Cl (Ref-9).
References:
1. Practical physical chemistry, A. Findlay, T. A. Kitchner (Longmans, Green and
Co.) 6th Edition, London.
2. Experiments in Physical Chemistry, J.M. Wilson, K.J. Newcombe, A.r. Denko.
R.M.W. Richett (Pergamon Press), New York.
3. Senior Practical Physical Chemistry, B.D.Khosla and V.S. Garg 4th Edition (R.
Chand and Co New Delhi.).
4. Experimental Physical Chemistry by D. P. Shoemaker, Mc. Growhill, 7 th Edition,
2003.
5. Physical chemistry by Wien (2001)
6. Advance Physical Chemistry Experiment, Gurtu and Gurtu, Pragati Publication
(Meerut),
7. Experiments in Chemistry, D. V. Jahagirdar, Himalaya Publishing House
8. Practical physical Chemistry, B. Vishwanathan and P. S. Raghwan, VivaBooks
9. Systematic Experimental Physical Chemistry Rajbhoj. S. W - 3rd ed. Aurangabad
Anjali Publication 2013

M.Sc. I Chemistry


COURSES
ANNEXURE - A
Name of Faculty : Science

Name of B.O.S : Chemistry
Name of Subject : Chemistry
Name of Course Title : Basic Practical Chemistry I
Year & Semester : M.Sc. I, Semester I
Type of Courses : Practical

Name of Subject: Basic Practical Chemistry-I

Course Code: CHP-107 Section II (Organic Chemistry Practical)
Objectives:
1. To develop practical skills such as separation, purification and identification of

chemical compound formed.
2. To improve their practical skills which will help them in industry or while doing
research in medicinal chemistry for Drug development.
Unit
No
Purification The students should apply these skills while performing the
1
Techniques organic compound synthesis
To perform the organic synthesis. Monitor the completion of
Single stage reaction by TLC. To separate and purify the chemical
2
Preparations compound formed. To record yield and physical constant of
the compound.

M.Sc. I Chemistry
Innovative
Methods
Digital Tools/ Film
Unit Total to be
show and AV Project Expected Outcome
No Lecture used/
Application
Teaching
aids
1 6 - - Perform The course includes
the synthesis of some
2 6 - -
experiment derivatives and
https://www.youtu with organic compounds,
3 6 - be.com/watch?v= different which will help them
3CWa7w8zZNM starting while working in
4 6 - - material research laboratory in
5 6 - - - future. Making
derivatives of organic
6 6 - - -
compounds will help
7 6 - - Perform them in industry or
the while doing research
8 6 - -
experiment in medicinal chemistry
9 6 - - with for Drug development
https://www.youtu different
10 6 - be.com/watch?v= starting
4Nv-ZAvqGII material
11 6 - - -
References:
Sr.
No
London
Practical organic F.G. Mann and B.C. Pearson,
1 and New
chemistry Saunders 1974
York
Text book of
2 practical organic Arthur I. Vogel Pearson,1974 London
chemistry
The systematic, Ralph L. Shriner, Christine
New
3 identification of K.F. Hermann, Terence C. Wiley
York
organic compounds Morrill and David Y. Curtin
Date :
Place :

M.Sc. I Chemistry
ANNEXURE – B
Semester-I
CHP-107 Basic Practical Chemistry-I
SECTION- II (Organic Chemistry Practicals)
Part-I: Purification Techniques (1 Experiment)
1. Purification of organic solids by recrystallization using solvents other than water
2. Thin Layer Chromatography technique two mixtures
Part-II: Single stage Preparations (Any 10)
1. Preparation of 1-formyl-2- methoxy naphthalene from 2-Methoxy naphthalene
2. Preparation of Benzyl alcohol and benzoic acid from benzaldehyde
3. Preparation of p-Nitroacetanilide from acetanilide
4. Preparation of Benzimidazole from o-Phenylene diamine
5. Preparation of Benzilic acid from benzoin
6. Preparation of 4-Chlorotoluene from p-toluidine
7. Preparation of Cyclohexane + Phenyl hydrizene (Fisher Indole Synthesis)
8. Preparation of Benzquinoxaline from o-Phenylene diamine
9. Preparation of Vanillyl alcohol from vanillin (using NaBH4)
10. Preparation of 2,4-dintro chlorobenzene from Chlorobenzene
11. Preparation of p-Nitro Phenyl acetic acid from p-Nitro Benzyl cyanide
12. Preparation of m-nitroaniline from m-di-nitrobenzene
13. Preparation of ethyl benzoate from Benzoic acid
Reference:
1. Practical organic chemistry, F.G. Mann and B.C. Saunders, 4th edition, Pearson
2009, London and New York.
2. Text book of practical organic chemistry, Arthur I. Vogel, L. Songman group, 1974,
London.
3. The systematic identification of organic compounds, Ralph L. Shriner, Christine K.
F. Hermann,Terence, C. Morrill and David Y. Curtin, 7th edition, Wiley, 1998.

M.Sc. I Chemistry
Semester- II

M.Sc. I Chemistry


COURSES
ANNEXURE - A

4) Name of Course Title : Physical Chemistry - Paper II
5) Year & Semester : M.Sc. I, Semester II

Name of subject: Molecular Spectroscopy and Nuclear Chemistry
No. of Credit: 04 Credit
Objectives:
1) To understand the fundamental, basic concept, principles, and recent

developments in the subject area.
2) To inspire and boost interest of the students towards chemistry as the main
subject.
3) To create foundation for research and development in Chemistry.
4) Students are expected to know physical chemistry, importance laws and
applications in chemistry.
5) The students are expected to know importance principles, concept, definition and
significance.
Unit
No
It is useful to understand types of molecule on the basis
Microwave
1 of moment of inertia and rotational spectra of di- and
Spectroscopy
poly-atomic molecules.

M.Sc. I Chemistry
It is helpful to study harmonic and Anharmonic

Infra-red oscillator, breakdown of the Born-Oppenheimer
2
Spectroscopy approximation, Fourier transform spectroscopy and its
advantages, The carbon dioxide laser, Applications.
It is helpful to study Quantum and classical theory of
Raman
3 Raman effect, structure determination from Raman and
Spectroscopy
Infra-red spectroscopy, applications.
It is useful to understand Born- Oppenheimer
Electronic approximation, Vibrational coarse structure, Frank-
4 Spectroscopy of Condon principle, dissociation energy and dissociation
molecules product, The fortrat diagram, Pre-dissociation,
molecular photoelectron spectroscopy.
ESR and
It is useful to understand Principle, applications and
5 Mossbauer
problems.
spectroscopy
It is useful to understand types of radioactive decay,
6 Radioactivity general characteristics of radioactive decay, decay
kinetics, Internal conversion and the Auger effect.
It is helpful to study interaction of γ radiation with
Elements of
7 matter, units for measuring radiation absorption,
Radiation
Radiation dosimetry.
It is useful to understand natural uranium reactor,
Reactor power., Critical size of thermal reactor, excess
reactivity & control, the Breeder reactor, The Indians
8 Nuclear Reactor
nuclear energy programme, Recovery of Uranium &
Plutonium, Nuclear waste management, Natural nuclear
reactor.
Applications of It is helpful to study physic-chemical research,
9
Radioactivity Analytical applications, and Medical applications.
Innovative
Unit Total
to be Film show and Project Expected Outcome
No Lecture
used/Teac AV Application
hing aids
The students are expected
https://shodhg
to understand types of
1 03 - anga.inflibnet. -
molecule on the basis of
ac.in/
moment of inertia.
harmonic and Anharmonic
https://epgp.inf oscillator, breakdown of the
2 05 - -
libnet.ac.in/ Born-Oppenheimer
approximation, Fourier
transform spectroscopy and

M.Sc. I Chemistry
its advantages, The carbon

dioxide laser, Applications.
https://epgp.inf to understand Quantum and
3 05 - -
libnet.ac.in/ classical theory of Raman
effect, applications.
to understand electronic
Ppt related to
spectra of diatomic molecules
ESR
- The Born- Oppenheimer
4 07 - spectroscopy -
approximation,Frank Condon
https://epgp.inf
principle,The fortrat diagram,
libnet.ac.in/
Pre-dissociation, molecular
photoelectron spectroscopy.
The students are familiar
https://ndl.iitkg
5 04 - - with Principle, applications
p.ac.in/
and problems
to understand types of
http://cec.nic.i radioactive decay, general
6 04 - -
n/ characteristics of radioactive
decay Internal conversion
and the Auger effect.
Interaction of radiation with
matter, interaction of γ
https://ndl.iitkg
7 06 - - radiation with matter, units for
p.ac.in/
measuring radiation
absorption, Radiation
dosimetry.
to understand Natural
uranium reactor, the four
factor formula- The
reproduction factor K,Critical
https://epgp.inf size of thermal reactor,
8 06 - -
libnet.ac.in/ excess reactivity & control,
the Breeder reactor, The
Indians nuclear energy
programme, Nuclear waste
management, Natural nuclear
reactor.
ppt related to
to understand Typical
applications of
reaction involved in the
9 08 - radioactivity -
preparation of radioisotopes,
https://epgp.inf
physic-chemical research,
libnet.ac.in/
Analytical applications.

M.Sc. I Chemistry
References:
Sr.
No.
Elements of Nuclear New Age International
1 H.J.Arnikar India
Chemistry (P) Ltd
D. Van Nostrand
Source book of S. Glasstone and
2 Company, Incorporated, India
Atomic energy D. Van
1946
Chemical applications
3 H.J.M. Brown Methuen young books India
of radioisotopes
Fundamentals of
C.N.Banwell and New Delhi [etc].
4 molecular India
E.M.McCash McGraw-Hill Education
spectroscopy
Date:
Place

M.Sc. I Chemistry
Annexure- B
Semester-II
CHP-210 Physical Chemistry-II
SECTION - I (2 Credits, 24 L, 6T)
Molecular Spectroscopy
1) Microwave Spectroscopy (03 L)
Types of molecule on the basis of moment of inertia and rotational spectra of di- and
poly-atomic molecules.
2) Infra-red Spectroscopy (05 L)
The vibrating diatomic molecule, harmonic and Anharmonic oscillator, The diatomic
vibrating rotator, breakdown of the Born-Oppenheimer approximation, The vibrations
of polyatomic molecule, Fourier transform spectroscopy and its advantages, The
carbon dioxide laser, Applications.
3) Raman Spectroscopy (05 L)
Quantum and classical theory of Raman effect, pure rotational Raman spectra,
vibrational Raman spectra, polarization of light and Raman effect, structure
determination from Raman and Infra-red spectroscopy, applications.
4) Electronic Spectroscopy of molecules (07 L)
Electronic spectra of diatomic molecules - The Born- Oppenheimer approximation,
Vibrational coarse structure, Frank- Condon principle, dissociation energy and
dissociation product, Rotational fine structure of electronic-vibration transition, The
fortrat diagram, Pre-dissociation, molecular photoelectron spectroscopy.
5) ESR and Mossbauer spectroscopy: Principle, applications and problems. (4L)
References:
1. Fundamentals of molecular spectroscopy: C.N. Banewell and E. Mc. Cash (Fourth
edition).
2. Molecular Spectroscopy: P.S. Sindhu, New Age international Publication. (Second
edition)
3. Molecular Spectroscopy: Suresh Chandra, Narosa Publication House (200
SECTION – II (2 Credits, 24 L, 6T)
Nuclear and Radiation Chemistry
1) Radioactivity (04 L)
Types of radioactive decay, general characteristics of radioactive decay, decay
kinetics, general expression for the activity of a daughter nuclide, Geiger- Nuttalis

M.Sc. I Chemistry
law, and α-decay: A problem in classical physics, Internal conversion and the Auger
effect.
2) Elements of Radiation (06 L)
Chemistry: Interaction of radiation with matter, interaction of γ radiation with matter,
units for measuring radiation absorption, Radiation dosimetry, Radiolysis of water,
free radicals in water radiolysis, Radiolysis of some aqueous solutions.
3) Nuclear Reactor (06 L): -
The fission energy, The Natural uranium reactor, the four factor formula- The
reproduction factor K, the classification of reactor, Reactor power., Critical size of
thermal reactor, excess reactivity & control, the Breeder reactor, The Indians nuclear
energy programme, Reprocessing of spent fuel Recovery of Uranium & Plutonium,
Nuclear waste management, Natural nuclear reactor.
4) Applications of Radioactivity (08 L)
Typical reaction involved in the preparation of radioisotopes, The Szillard- Chalmers
reaction, Radiochemical principles in the use of tracers, Isotopes in elucidating
reaction mechanism and structure determination, physic-chemical research - The
solubility of a sparingly soluble substances, surface area of a powder or precipitate
rates of diffusion, Analytical applications- Isotope dilution analysis, Neutron activation
analysis, Radiometric titrations, Medical applications-Thyroiditis, Assessing the
volume of blood in a patient, Industrial applications thickness measurements and
control, friction and wear out, gamma radiography.
References:
1) Elements of Nuclear Chemistry by H.J.Arnikar, New Age International (P)Ltd.
2) Source book of Atomic energy by S. Glasstone and D. Van Nostrand Company,
Incorporated, 1946
3) Chemical applications of radioisotopes by H.J.M. Brown, Methuen young books.
4) Fundamentals of molecular spectroscopy by C.N.Banwell and E.M.McCash,
McGraw-Hill Education.

M.Sc. I Chemistry

FORMAT FOR FRAMING SYLLABUS FOR TWO YEAR PG AUTONOMOUS

COURSES
ANNEXURE - A

4) Name of the course title : Inorganic Chemistry-II
5) Year & Semester : M.Sc. I, Semester-II

Name of subject: Coordination and Bioinorganic Chemistry
Course Code: CHI-230
No. of Credit: 04 Credit (48L + 12T)
Objective:
1.Students are expected to understand term symbols, microstates, Hund’s rules of

maximum multiplicity, orgel diagram, TS diagram and microstate table.
2.Understand the spectrum of d1-10 configuration, spectrochemical series,
nephelauxetic ratio and rachae parameter.
3.Understand the correlations diagram for Td an Oh ligand field and learn d-d
transition, d-p mixing, charge transfer spectra.
4.Learn the concept of magnetochemistry and magnetic properties of d block
elements.
Unit
No
Concept and scope of It is helpful to understand f microstates, term
1
ligand fields symbol and Hund’s rules of maximum multiplicity
Ligand field theory of It is helpful to study free ion terms in weak and
2 coordination strong field, correlation diagram in oh and td field.
complexes
Electronic spectra of It is useful to draw spectrum of d1-10 system.
3
transition metal

M.Sc. I Chemistry
complexes
Magnetic properties of
magnetism, A, E, T ground states magnetic
4 coordination
properties, Zemman effect, stark effect and orbital
complexes
contribution to magnetic moment
It is helpful to understand inorganic
5 Inorganic spectroscopy spectroscopy of 19F,11B,31P nuclei, Mossbauer
spectroscopy and EPR.
Overview of It is helpful to understand biochemistry, role of
6
Bioinorganic Chemistry different metals in biomolecules.
Concepts of Inorganic To understand the thermodynamic and kinetic
7 Chemistry in aspects in biological system.
Bioinorganic Chemistry
Functions and It is helpful to understand the mechanism and
Transport of Alkali and functions of alkali and alkaline metals in transport
8
Alkaline Earth Metal of electrolytes.
Ions
Choice, uptake and It is useful to know uptake of various inorganic
assembly of metal elements in biological system.
9
containing units in
Biology
It is helpful to know role of Ca in blood
Biochemistry of Ca, Mn
10 coagulation, Mn in photosynthesis and Fe in iron
and Fe
sulphur in proteins.
Innovative
Methods
Digital Tools/ Film
Unit Total to be
show and AV Project Expected Outcome
No Lecture used/
Application
teaching
aids
Lecture related to
coordination
It is helpful to know
complexes
basic of ligand field
1 4 swayam.gov.in -
theory, term symbol
IIT- Bombay
and microstate table.
https://youtu.be/MHl
Use of wp_7kxbM
Videos related to
model box
spectrum of
complexes, To understand orgel
magnetochemist-ry diagram, TS diagram
2 6 -
byProf. D. Ray and correlation
(IIT-Kharagpur) diagram.
https://youtu.be/BZ_t
Y88o0oI

M.Sc. I Chemistry
To understand
spectrochemical and
https://youtu.be/- nephelauxetic series
3 5 -
EKoIxoqf3Y along with electronic
spectra of d1-10
configuration.
To familiar with
https://youtu.be/jduv
4 5 - magnetic property of
WbIpeF0
d- block elements.
To find out structure of
5 4 - molecules by inorganic
spectroscopy.
It is helpful to
understand current
swayam.gov.in relevance of
6 2 - bioinorganic
noc19-cy26-lec01 chemistry and role of
metals in biological
systems.
Students are expected
to learn
7 8 noc19-cy26-lec02 - thermodynamic and
kinetic aspects in
biological system.
Use of Students are expected
periodic noc19-cy26-lec03 to know transport of
8 4 Table - alkali and alkalline
noc19-cy26-lec04 earth elements in
biological system.
Students are
expected to familiar
with information of the
9 4 noc19-cy26-lec06 -
metal containing
units and their uptake
in biological system.
Student are expected
to understand the role
of Ca Mn, Fe, S in
10 6 noc19-cy26-lec07 - blood coagulation,
photosynthesis, blood
transport , protein
synthesis respectively.

M.Sc. I Chemistry
References :
Sr. Title of Books Name of Author/s Publication Place

No.
Ligand field theory and B. N. Figgis and New
1) Wiley- VCH
its applications M. A. Hitachman York
4th edition
New
2) Inorganic Chemistry Shriver and Atkins Oxford University York
Press
Advanced Inorganic F. A. Cotton, 6th edition New
3)
Chemistry G. Wilkinson, Wiley York
Inorganic Electronic 2nd edition New
4) A. B. P. Lever
spectroscopy Elsevier York
Concise Inorganic 4th edition New
5 J. D. Lee
Chemistry Chapman & Hall York
NMR spectroscopy in Oxford University Englan
6 J. A. Iggo
Inorganic Chemistry press d
Mossbauer Spectroscopy P. Gutlich, R. Link,
United
7 and Transition Metal A. Trautwien, Alfred Springer
States
Chemistry X.
1st edition Vikas
Concise Coordination R. Gopalan and New
8
Chemistry Vimala Ramalingam Publishing Delhi
Principles of United
S. J. Lippard & J.M
9 BioinorganicChemistry Mill Valley States
Berg
University science Books
Bioinorganic Chemistry:
Inorganic elements in the W. Kaim, 2ndedition United
10
Chemistry of life: An B. Schwederski Wiley States
introduction and guide
Ligand field theory and B. N. Figgis and New
11 Wiley- VCH
its applications M. A. Hitachman York
4th edition
New
12 Inorganic Chemistry Shriver and Atkins Oxford University York
Press
Date :
Place :

M.Sc. I Chemistry
ANNEXURE – B
CHI-230 Inorganic Chemistry II
SECTION-I (2 Credit 24L,6T)

Coordination Chemistry
1) Concept and Scope of Ligand Fields: (04 L)
Quantum numbers, Free ion Configuration, Terms and States, Energy levels
of transition metal ions, free ion terms, microstates, term wave functions, spin-
orbits coupling.
2)Ligand Field Theory of Coordination Complexes (06L)
Effect of ligand field on energy levels of transition metal ions, weak cubic
ligand field effect on Russell- Saunders terms, Orgel diagrams, strong field effect,
correlation diagrams, Tanabe-Sugano Diagrams, Spin-Pairing energies.
3)Electronic spectra of Transition Metal Complexes (05 L)
Introduction, band intensities, band energies, band width and shapes,

transition metal spectra of 1st, 2ndand 3rd row ions and complexes, electronic
spectra of Lanthanide and Actinide, spectro chemical and nephelauxetic series,
charge transfer and luminescence spectra, calculations of Dq, B, β parameters.
4) Magnetic Properties of Coordination Complexes (05 L)

Origin magnetism, types of magnetism, Curie law, Curie-Weiss Law, Magnetic
properties of complexes-Para magnetism, 1stand 2nd Ordered Zeeman effect
,quenching of orbital angular momentum by Ligand fields, Magnetic properties of A,
E and T ground terms in complexes.
5)Inorganic spectroscopy (04L)
NMR: Structure determination of inorganic systems having19 F,11B,31P nuclei.

Mossbauer spectroscopy: Basic principle, instrumentation, spectral parameters
&display, application.
EPR: introduction, principle and application.
SECTION-II (2 Credit 24 Lectures 6T)
Bioinorganic Chemistry
1) Overview of Bioinorganic Chemistry (02L)
Historical Background and current relevance, role of Cu, Fe, Mn and Mo in

metalloprotein, and metalloenzymes.
2) Concepts of Inorganic Chemistry in Bioinorganic Chemistry (08L)

M.Sc. I Chemistry
Thermodynamic aspects - HSAB concept, chelate effect and Irving-William

series, pKa values of coordinated ligands, Tuning of redox potential,
Biopolymer effects. Kinetic aspects- Electron transfer reaction, Electronic
substitution reaction. reactions of coordinated ligands and Template effect,
concept of spontaneous self-assembly model compounds.
3) Functions and Transport of Alkali and Alkaline Earth Metal Ions (04L)
Importance of alkali and alkaline earth metals, Distribution of cationic and
anionic electrolytes in blood plasma and intracellular fluid, Ionophores: Natural
and Synthetic, Application of ionophores, Different mechanism involved in
exchange of ions across cell wall,Na+/K+-ATPase ion pump for active transport
of Na+ and K+.
4) Choice, uptake and assembly of metal containing units in Biology (04L)
5) Biochemistry of following Elements (6L)
(a) Ca in Blood coagulation.
(b) Mn in photosystem I & II
(c) Iron in Ferritin, Transferrin, Fe-S clusters, Porphyrin based system.
References:
1. Ligand field theory & its application: B. N. Figgis& M. A. Hitchman, Wiely VCH
publ.
(2000), Chapters 5, 6, 8,9,11.
2. Inorganic Chemistry: D. F. Shriver & P. W. Atkins, Oxford (1999).
3.Advanced Inorganic Chemistry: F. A. Cotton, G. Wilkinson,C. A. Murollo, M.
Bochmann, 6th edn. (2003).
4.Inorganic Electronic spectroscopy: A. B .P. Lever, 2 nd edn Elsevier Science
Publishers,New York, (1984).
5. Concise inorganic Chemistry, J. D. Lee 4th edition (Chapman and Hall )
6. NMR spectroscopy in Inorganic Chemistry, J. A. Iggo, Oxford University press
(2001).
7. Mössbauer Spectroscopy and Transition Metal Chemistry, P. Gütlich,R. Link,
A. Trautwien, Springer-Verlag (1978).
8. Concise Coordination Chemistry, R. Gopalan and Vimala Ramalingam (2016)
9. Principles of Bioinorganic Chemistry: S. J. Lippard & J.M Berg, University science
books, Mill Valley, California (1994), Chapters- 1,2,3,5,6,7,8.
10.Bioinorganic Chemistry: Inorganic elements in the Chemistry of life: An
introduction and guide: W. Kaim, B. Schwederski VCH,(1991).

M.Sc. I Chemistry


COURSES
ANNEXURE - A

4) Name of Course Title : Organic Chemistry- II
5) Year & Semester : M.Sc. I, Semester- II

Name of subject– Organic Chemistry- II (Photochemistry, Pericyclic Reactions

and Organic spectroscopy)
Course Code: CHO-250
Objectives:
1) Students should able to understand free radicals’ formation, stability and reactivity
and should also be able to use the basic understanding in writing probable reaction
mechanisms
2) Students should able to write MO diagram for various olefinic compounds and
should able to predict the products, the stereochemistry as well as should able to
understand the preferred reaction pathways.
3)Students should able to correlate IR bands with functional groups using numerical
data as well as spectral data.
4) Students should able to solve 1H-NMR problems and should also able to draw the
1H-NMR spectrum for simple organic compounds mentioning multiplicity pattern and
coupling constant Should able to predict and analyse the multiplicity patterns.
5) Students should able to use 13C-NMR data to interpret the structure NMR
problems.

M.Sc. I Chemistry
6) Students should know various key factors responsible for the spectroscopic data
acquisition and should able to solve Problems based on IR, 1H-NMR,13C-NMR, MS,
Unit
No
It is useful to understand free radicals’ formation,
1 Photochemistry stability and reactivity and the basic understanding in
writing probable reaction mechanisms.
It is useful to understand MO diagram of olefinic
2 Pericyclic reactions
compounds should able to predict the products.
It is useful to understand correlation of IR bands with
3 IR Spectroscopy functional groups using numerical data as well as
spectral data.
It is useful to understand how to solve 1H-NMR
4 1H-NMR problems and should also able to draw the 1H-NMR
spectrum for simple organic compounds.
It is useful to understand how to solve 13C-NMR
5 13C-NMR problems and their data interpretation for simple
organic compounds.
It is useful to understand how to solve problems and
6 Mass spectrometry their data interpretation for simple organic
compounds using Mass spectrometry.
Innovative
Methods to Digital Tools/
Unit Total
be used/ Film show and Project Expected Outcome
No Lecture
Teaching AV Application
aids
Student will be able to
understand the concepts
1 12 - - - in free radical reactions,
mechanism and the
stereo chemical outcomes
understand
https://epgp.inf
MOT and will be able to
libnet.ac.in/Ho
2 12 - - extend this in predicting
me/ViewSubje
reaction mechanism and
ct?catid=5
stereochemistry of
electrocyclic reactions.
Use of
Model box
https://epgp.inf understand basic principle
for
libnet.ac.in/Ho of IR spectroscopy and
3 4 understand -
me/ViewSubje their applications in
ing IR
ct?catid=5 structure elucidation of
stretching
organic compounds
vibrations

M.Sc. I Chemistry
Use of
Model box
understand basic principle
for
of 1H NMR spectroscopy
4 12 understand - -
and their applications in
ing
structure elucidation of
coupling
organic compounds
constants
https://epgp.inf
of 13C NMR
libnet.ac.in/Ho
5 4 - - spectroscopy and their
me/ViewSubje
applications in structure
ct?catid=5
elucidation of organic
compounds
of Mass spectrometry and
6 4 - - -
their applications in
structure elucidation of
organic compounds
References:
Sr.
No.
Pericyclic Reactions United
1 Ian Fleming OUP Oxford
(2 edition) Kingdom
Pericyclic Reactions by
A Mechanistic and Sunil Kumar Vinod Academic
2 Cambridge
Problem-Solving Kumar S.P. Singh Press
Approach
Orbital Symmetry: A
R. E. Lehr and A. P. Academic
3 problem solving Cambridge
Marchand Press
approach
Excited states in
J.A. Barltrop and
4 Organic Chemistry Springer New York
J.D.Coyle
1977 edition
Advanced Organic
A. Carey and R.J.
5 Chemistry (Part A) Springer New York
Sundberg
(5th Edition)
D. L. Pavia, G.M. Stamford, C T: Stamford, C
Introduction to
6 Lampman, G. S. Cengage T
Spectroscopy
Kriz,JamesR.Vyvyan Learning.[2015] USA
Spectrometric
R. M. Silverstein, F.
7 identification of organic Wiley New York
X. Webster
compounds(6thEd)
Spectroscopic methods D. H. Williams and I.
8 Mc Graw Hill New York
in organic chemistry Flemming
Spectroscopy of New Age
9 Dr. P. S. Kalsi Delhi
Organic Compounds International

M.Sc. I Chemistry
(7th Ed)
Nuclear Magnetic Springer-
10 Resonance – Basic Atta-Ur-Rehman Verlag (1986). New York
Principles
One and Two
Elsevier Amsterdam,
11 dimensional NMR Atta-Ur-Rehman
(1989). Netherlands
Spectroscopy
NMR Spectroscopy,
Basic Principles,
12 Concepts and Harald Gunther Wiley New York
Applications in
Chemistry (3rd Ed.)
Organic Spectroscopy: Alpha Science
13 Principles and Jagmohan International New Delhi
Applications Limited (2004)
Date :
Place :

M.Sc. I Chemistry
ANNEXURE - B
Semester-II
CHO – 250, Organic Chemistry-II
SECTION-I (2 Credits, 24 L, 6T)
Photochemistry and Pericyclic Reactions
1) Photochemistry [12 L]
Principles of Photochemistry, photochemistry of carbonyl compounds, alkenes,
dienes, and aromatic compounds, photo rearrangements, Barton reaction
2) Pericyclic reactions: [12 L]
Analysis by correlation diagrams, FMO approach and examples of electrocyclic,
cycloaddition, sigmatropic reactions and ene reactions and 1,3-dipolar additions,
cheletropic reactions and applications of pericyclic reactions.
SECTION-II (2 Credits, 24 L, 6T)
Spectroscopic Methods in Structure Determination of Organic Compounds
1. IR Spectroscopy [04L]
IR spectra of important functional groups 1. With and without conjugation, 2. Ring
size effect 3. Effect of H-bonding, 4. Resonance effect,5. Inductive effect. Problems
on IR Spectroscopy
2. 1H-NMR [12L]
Understanding of basic principle, chemical and magnetic nonequivalence, chemical
shifts and factors influencing chemical shift: electronegativity, NMR solvent polarity,
temperature, anisotropic effect, chemical shifts of acidic protons, D2O exchange,
Multiplicity patterns and Coupling Constants: Pascal’s triangle, understanding of tree
diagram, complex splitting patterns in aromatic, vinylic, saturated monocyclic
compounds.
Problems: complex problems based on multiple coupling constants should be
discussed and drawing of expected 1H-NMR spectrum along with complex
multiplicity patterns and coupling constants. Drawing of multiplicity patterns and
determination of coupling constants of complex multiplets should be discussed.
3. 13C-NMR [04L]
Basic of 13C-NMR: Chemical shift and factors affecting chemical shifts in 13C NMR,
off resoanance and proton decoupled spectra. Simple problems on 13C-NMR.
4. Mass spectrometry (MS) [04L]

M.Sc. I Chemistry
Basic principle of MS, significance of M+ (m/z) in determination of molecular formula,

Rule of 13. Genesis of m/z fragments: alkanes (cyclic and acyclic), alkenes, alkynes
Problems: Based on 2-3 fragments of abovementioned functional groups should be
discussed. Combined problems: Problems based on IR, 1H-NMR, 13C-NMR, MS
should be solved.
References:
1. Pericyclic Reactions by Ian Fleming (2nd edition), Oxford University Press, 2015.
2. Pericyclic Reactions by A Mechanistic and Problem-Solving Approach by Sunil
Kumar Vinod Kumar S.P. Singh, Academic Press, Cambridge.
3. Advanced Organic Chemistry (Part A) –by A. Carey and R.J. Sundberg, Springer,
New York.
4. Orbital Symmetry: A problem solving approach- R. E. Lehr and A. P. Marchand,
Academic Press, Cambridge
5. Excited states in Organic Chemistry by J.A. Barltrop and J.D.Coyle, Springer, New
York.
6. Introduction to Spectroscopy – D. L. Pavia, G.M. Lampman, G. S. Kriz, R.Vyvyan,
(5thEdition), Stamford, C T: Cengage Learning.
7. Spectrometric identification of organic compounds R. M. Silverstein, F. X.
Webster,6th Ed.John Wiley and Sons.
8. Spectroscopic methods in organic chemistry - D. H. Williams and I. Flemming Mc
Graw Hill
9. Spectroscopy of Organic Compounds (7 th Ed), by P. S. Kalsi, New Age
International Publication, New Delhi.
10. Nuclear Magnetic Resonance – Basic Principles- Atta-Ur-Rehman, Springer-
Verlag (1986).
11. One and Two dimensional NMR Spectroscopy – Atta-Ur-Rehman, Elsevier
(1989).
12. NMR Spectroscopy- Basic Principles, Concepts and Applications in Chemistry
(3rd Edition) Harald Gunther, Wiley, New York
13. Organic Spectroscopy: Principles and Applications, Jagmohan, Alpha Science
International Limited (2004), New Delhi

M.Sc. I Chemistry

AUTONOMOUS COURSES
SECTION: I
ANNEXURE - A

4) Name of Course Title : General Chemistry II

Name of subject– General Chemistry II (Organometallic and Inorganic Reaction
Mechanism)
Course Code: CHG – 290
Objectives:
1.Students should able to understand basic concepts of Organometallic and

Inorganic Reaction Mechanism.
2. Students should be introduced with interdisciplinary study.
3. To get awareness of allied courses of Chemistry
4. To understand detailed study of Organometallic Reactions and Catalysis,
Coordination Compounds, Reactions and Mechanism.
Unit
No
1. Introduction to Bonding To understand bonding in Molecules.
To study the organic ligands, Nomenclature and
Organometallic
2. bonding between metal atoms and organic pi
Chemistry
system.
Organometallic Reactions To get detailed information of Reactions involving
3.
and Catalysis gain and loss of ligands and organometallic

M.Sc. I Chemistry
catalysis: Hydroformylation, Monsanto acetic acid

process, Wacker Process, Hydrognation by
Willkinsons catalyst.
To get information of History and principles,
Coordination
Substitution reactions: Inert and labile complexes,
4. Compounds: Reactions
mechanism of substitution. Kinetics
and Mechanism
Consequences of reaction pathway.
Innovative Digital Tools/

Unit Total
Methods to be Film show and Project Expected Outcome
No Lecture
used AV Application
Use of models PPT To understand bonding
1 3 -
and charts presentation in molecules.
To study the organic
ligands,Nomenclature
Use of models PPT
2 5 - and bondingbetween
and charts presentation
metalatoms and organic
pi system.
To get detailed
information of Reactions
involving gain and loss
of ligands and
Use of models PPT organometallic catalysis:
3 8 -
and charts presentation Hydroformylation,
Monsanto acetic acid
process, Wacker
Process, Hydrognation
by Willkinsons catalyst.
To get information of
History and principles,
Use of models PPT Substitution reactions:
4 8 -
and charts presentation Inert and labile
complexes, mechanism
of substitution.
References :
Sr. No Title of Books Name of Author/s Publication Place
Concise Inorganic Wiley India

1 J. D. Lee -
Chemistry. 2011,Fifth Edition.
Gary Miessler and
2 Inorganic Chemistry Third Ed., Pearson -
Donald A. Tarr.
IUPAC Nomenclture
of Organometallic
3 Salzer - -
Compounds of
Transition Metals.

M.Sc. I Chemistry
Date :
Place

M.Sc. I Chemistry
Annexure B
Semester-II
CHG – 290, General Chemistry II (4 Credits)
SECTION-I: Theory Course (2 Credits, 24 L, 6T)
Organometallic and Inorganic Reaction Mechanism
1. Introduction to bonding ( Ref.1) (03L)

Types of bonds, Transitions between the main types of Ionic bonds, Covalent bonds,
Oxidation, Numbers, Coordinate bonds, Double and triple bonds, Metallic bonds and
metallic structures.
2. Organometallic Chemistry ( Ref.1) (05L)

Organic ligands and nomenclature, 18 electron rule: counting electrons, ligands
having extended pi system, bonding between Metal Atoms and organic pi systems:
linear pi system, cyclic pi system.
3. Organometallic Reactions and Catalysis (Ref-2) (08L)
Reactions involving gain and loss of ligands: ligand dissociation and substitution,
oxidative addition, reductive elimination, nucleophelic displacement,reactions
involving modification of ligands: insertion, carbonyl insertion, 1-2 insertion, hydride
elimination, abstraction, organometallic catalysis: Hydroformylation, Monsanto acetic
acid process, Wacker Process, Hydrognation by Willkinsons catalyst, Olefin
metathesis, heterogeneous catalysis: Ziegler Natta Polymerization, Water
gasreduction.
4. Coordination Compounds: Reactions and Mechanism (Ref-2) (08L)
History and principles, Substitution reactions: Inert and labile complexes, mechanism
of substitution, Kinetics Consequences of reaction pathway: dissociation,
interchange, association, Experimental evidences in Octahedral Substitution:
dissociation, linear free energy relationship, associative mechanism, the conjugate
base mechanism, the kinetic chelate effect, Stereochemistry of reactions:
substitution in trans complexes, substitution in cis complexes, isomerisation of
chelate rings, substitution reactions in Sq. Pl.Complexes.
References :
1) Concise Inorganic Chemistry, J. D. Lee, Wiley India 2011 ,Fifth Edition.

M.Sc. I Chemistry
2) Inorganic Chemistry: Gary Miessler and Donald A. Tarr, Third Ed., Pearson
(Chapter-12, 13 and14 pages: 422 to561).
3) IUPAC Nomenclture of Organometallic Compounds of Transition Metals by Salzer
http://publications.iupac.org/pac/1999/71_08_pdf/7108salzer_1557.pdf

M.Sc. I Chemistry

AUTONOMOUS COURSES
SECTION: I
ANNEXURE - A

4) Name of Course Title : General Chemistry Practical -II

Name of subject– General Chemistry Practical – II (Physical Chemistry
Practical - II)
Course Code: CHG – 290, Section- II
1) To understand the fundamentals, principles, mathematical concepts and recent

development in the subject area.
2) To improve the practical concept which is relevance to the theory courses.
3) To develop the practical skills of the students.
4) To inspire and boost interest of the students towards chemistry as the main
subject.
5) To develop interdisciplinary approach of the subjects for students opting for good
position in industries at latter stages of post-graduation.
6) To enable students to carry out, and interpret measurements within the context of
the fundamental technological problem with which they are presented
Unit
No
1 Conductometry To understand basic conductometry techniques for

M.Sc. I Chemistry
determination of dissociation constant and

thermodynamic entities. To study the process of
hydrolysis.
To understand basic concepts of chemical reactions
2 Spectrophotometer and Complex study with research and industrial
level application
To understand basic techniques of determination of
3 Potentiometry
analytical entities by Potentiometry
To understand basic instrumental techniques like
pH-meter for acid and base dissociation constant,
4 pH Metry
Hammett constant. To study the process of titration
to predict the best indicator.
To get awareness about Statistical treatment of
5 Table Work analysis of powder XRD data, Cyclic voltagram and
interpretation of Raman spectra
Innovative
Digital Tools/
Methods to
Unit Total Film show and
be used/ Project Expected Outcome
No Lecture AV
Teaching
Application
aids
Physicochem-ical Training of
https://youtu.be handling lab
1 18 - analysis of soil
/iQFQVuicW74
samples instruments
Determination Training of
of stability
- https://youtu.be handling lab
2 6 constant for
/4zchWu5dYb4 Sophisticated
different complex
reaction instruments
Analysis of Training of basic
https://youtu.be/
- paracetamol from lab instrumental
3 18 _PGAHJGCvUs pharmaceutic-al
formulation techniques
Physicochemi-cal Training of
- https://youtu.be
4 12 analysis of water handling lab
/dn9rDIJTHh8
samples instruments
To get awareness
Synthesis of
https://youtu.be about Statistical
- nanoparticles
5 12 /5NHhZ5Zk-oQ treatment of
and it’s
advanced
characterizati-on
techniques

M.Sc. I Chemistry
References:
Sr. Nameof Publication/
Title of Books Place
No. Author/s Publisher
Practical physical A. Findlay, T.A. Longmans, Green
1 London
chemistry Kitchner and Co.6th Edition
J.M. Wilson, K.J.
Experiments in Newcombe, A.r.
2 Pergamon Press New York
Physical Chemistry Denko. R.M.W.
Richett
R. Chand
Senior Practical B.D.Khosla and
3 and Co.4th New Delhi
Physical Chemistry V.S. Garg
Edition
Experimental Physical Mc. Grow hill,
4 D. P. Shoemaker 7thEdition 2003 New Delhi
Chemistry
5 Physical Chemistry Wien (2001) -
Advance Physical Pragati
Gurtu and
6 Chemistry Publication Meerut
Gurtu,.
Experiment 4th Edition
Himalaya
Experiments in
7 D. V. Jahagirdar Publishing New Delhi
Chemistry
House
B.Vishwanatha
Practical physical Viva
8 and -
Chemistry Books
P. S. Raghwan
Systematic Anjali
Rajbhoj .S.W- 3rd
9 Experimental Publication Aurangabad
ed.
Physical Chemistry 2013
Potentiometric and
Gupta Med chem 6: 047-
10 pH metric Studies of --
SRN 052. (2016)
Paracetamol

Date:
Place:

M.Sc. I Chemistry
Annexure- B
SEMESTER II
CHG -290: General Chemistry Practical - II
SECTION-II: Practical Course (2 Credits, 48 L + 12T)
Physical Chemistry Practical - II
Part-I: Conductometry: (Any three)

1) Hydrolysis of NH4Cl or CH3COONa or aniline hydrochloride.
2) Determination of λ0 or λα and dissociation constant of acetic acid.
3) Hydrolysis of ethyl acetate by NaOH.
4) Determination of ΔG, ΔH, and ΔS of silver benzoate by Conductometry.
5) Determination of critical micellar concentration (CMC) and ΔG of micellization of
sodium Lauryl Sulphate /Detergent
Part-II: Spectrophotometer (Any one)
6) Determination stability constant of complex formed between Fe2+ ion and 5- SSA
at pH 2 and pH-3 by spectrophotometric method.
7) Investigate the reaction between potassium per sulphate and potassium iodide by
spectrophotometric method. (Ref-9)
Part-III: Potentiometry: (Any three)
8) Stability Constant of a complex ion.
9) Solubility of a sparingly soluble salt
10) To determine the ionic product of H2O.
11) Determine the amount of Paracetamol by potentiometric titration
Part-IV: pH Metry (Any two)
12) Determination of the acid and base dissociation constant of an amino acid and
hence the isoelectric point of the acid.
13) Determine the Hammett constant of a given substituted benzoic acid by pH
measurement. (Ref-9)
14) Construct pH curve for titration of strong base – strong acid, strong base - weak
acid and predict the best indicator in these titrations (methyl orange, methyl orange,
bromocresol green, phenolphthalein, etc.)
Part-V: Table Work (Any two)
15) Analysis of powder XRD of SrTiO3 and Ag metal or any two compounds
(Calculation d, lattice constant, crystal volume and density, and assigning planes to
peaks using JCPDS data)

M.Sc. I Chemistry
16) Cyclic voltagram of K3Fe(CN)6 in KCl/H2O / Ferrocene inTEAP//MeCN

17) Detailed interpretation of Raman spectra of diatomic molecules.
References:
1) Practical physical chemistry, A. Findlay, T.A. Kitchner (Longmans, Green and Co.
6th Edition, London.
2) Experiments in Physical Chemistry, J.M. Wilson, K.J. Newcombe, A.r. Denko.
R.M.W. Richett (Pergamon Press), New York.
3) Senior Practical Physical Chemistry, B.D. Khosla and V.S. Garg 4th Edition (R.
Chand and Co, New Delhi.)
4)Experimental Physical Chemistry by D. P. Shoemaker, Mc. Growhill, 7 th Edition,
2003.Physical chemistry by Wien (2001)
5) Advance Physical Chemistry Experiment, Gurtu and Gurtu, Pragati Publication
(Meerut)
6) Experiments in Chemistry, D. V. Jahagirdar, Himalaya Publishing House
7) Practical physical Chemistry, B. Vishwanathan and P. S. Raghwan, Viva Books
8) Systematic Experimental Physical Chemistry Rajbhoj S.W - 3rd ed. - Aurangabad
Anjali Publication 2013
9) Gupta SRN, Potentiometric and pH metric Studies of Paracetamol. Med chem 6:
047-052. (2016)

M.Sc. I Chemistry


COURSES
ANNEXURE - A

4) Name of the course title : Basic practical Chemistry-II
5) Year & Semester : M.Sc. I, Semester-II

Name of subject: Basic Practical Chemistry – II (Inorganic Chemistry practical -

II)
Course Code: CHP-227
No. of Credit: 2 (48L + 12T)
Objective:
1.Students are expected to learn the fundamental of practicals and relevance to
industrial application.
2.Understand the knowledge of spectrometric and instrumental techniques which are
helps to find out quantitative estimation and purity of coordination complexes.
3.To improve their practical skills this will help in dyes industry.
4. To develop skill for column chromatography technique.
Unit
No
Synthesis of
It is useful to understand the concept of complexes and
1 coordination
purity of complexes.
complexes
It is helpful to aware of verify the Debye Huckel theory,
Inorganic
2 stability constant and solubility product.
Conductometry
It is also helpful to find structure of metal.
Inorganic Understand equilibrium constant and spectrum of
3
characterization complexes.

M.Sc. I Chemistry
techniques
Inorganic Kinetics Understand the effect of UV/sunlight on complexes and
4
Experiment rate of reaction.
Ion- Exchange It is helpful to aware of column chromatography and
5
Chromatography separation of cations by column chromatography.
Teaching Methodology
Innovative
Unit Total to be Film show
Project Expected Outcome
No Lecture used/ and AV
teaching Application
aids
Understand the
Prepare synthesis of
https://youtu.b different novel complexes and basic
1 18 e/ykkIP0RJXu complexes and of complexes such as
k characterize it. geometry, magnetic
property etc.
To study of Understand concept of
stability strong electrolyte and
https://youtu.b constant of verify Debye Huckel
2 18 e/668HBVYP- different novel theory and find out
All 8k metals stability constant of Fe
practicals
combined with + Sulphosalicylic acid/
are
ligands. salicylic acid.
performed
To aware of
at To prepare
equilibrium constant
microscal different
and colorimetric study
e complexes and
3 18 of complexes such as
technique spectroscopic
splitting parameter
s study of
(10Dq), Rachae
complexes.
parameter etc.
https://youtu.b Understand
4 6 e/Wn6PS- - photochemistry of
oTSyM complexes.
Seperation of Student should
https://youtu.b heavy metals prepare the column,
5 6 e/YPt5R83I_8 by column run the column,
Q chromatograph separate the cations
y. and quantify it.
References :
Sr.
No. Title of Books Name of Author/s Publication Place
Text book of 3rd edition New

1 A. I. Vogel
Quantitative Analysis John Wiley Jersey

M.Sc. I Chemistry
& Sons United

States
Experimental Inorganic Mounir
2 Horwood House New Delhi
Chemistry A. Malati
4th edition
Experiments in
3 D. V. Jahagirdar Himalaya Mumbai
Chemistry
Publishing House
General Chemistry
4 Anil. J Elias University Press Cambridge
Experiments
Practical physical B.Vishwanathan & Viva Book
5 New Delhi
Chemistry P. S. Raghwan Publishing
Signature of HoD/ Chairman

BOS
Date:
Place:

M.Sc. I Chemistry
Annexure- B
Semester- II
CHP-227: Basic Practical Chemistry-II
SECTION- I: Inorganic Chemistry Practical-II (2 Credits, 48 L, 12T)
Part-I: Synthesis of coordination complexes (any three) (Ref. 2)

1. Synthesis and Purity of Potassium tri-oxalato aluminate (III) trihydrate
2. Synthesis and Purity of Chloropentaamminecobalt (III) chloride.
3. Synthesis and Purity of Nitro pentaamminecobalt(III) chloride.
4.Synthesis and Purity of ammonium tetrathiocyanato-diammine chromate(III),
Reinecke's salt .
Part-II: Inorganic Conductometry (any three)
4. Structural determination of metal complexes by conductometric measurement.
(Ref-3)
5. To study complex formation between Fe(III) with sulfosalicylic acid by
conductometry (Ref-3)
6. To verify the Debye Huckel theory of ionic conductance for strong electrolytes KCl,
BaCl2, K2SO4 and [K3Fe(CN)6] . (Ref-3)
7. Determination of Pb(II) in solution with Na2SO4 solution and determination of
solubility product of PbSO4 (Ref-4)
Part-III: Inorganic characterization techniques (any three)
8. Determination of equilibrium constant of M – L systems Fe (III) - Sulphosalicylic
acid by Job’s continuous variation method. (Ref.-3, 5)
9. Determination of equilibrium constant of M – L systems Fe (III)- Salicylic acid by
Job’s continuous variation method. (Ref.-3, 5)
10. Solution state preparation of [Ni(en)3]S2O3, [Ni(H2O)6]Cl2, [Ni(NH3)6 ]Cl2. Record
absorption spectra in solution of all three complexes and calculate 10 Dq. Arrange
three ligands according to their increasing strength depending on your observations.
(Ref. -5)
11. Determination of magnetic susceptibility (χg and χm) of mercury tetracyanato
cobalt or Fe(acac)3 or Ferrous ammonium sulfate by Faraday or Gouy method. (Ref.
-3, 5)
Part-IV: Inorganic Kinetics Experiment (any one)
12. Synthesis and photochemistry of K3[Fe(C2O4)3].3H2O. (Ref-4)

M.Sc. I Chemistry
13. Kinetics of formation of Cr (III)-EDTA complex (Ref-3)

Part-V: Ion- Exchange Chromatography (Compulsory) (Ref. -1 and 3)
14. Separation of mixture of Zn(II) and Mg(II) using Amberlite IRA 400 anion
exchanger and quantitative estimation of separated ions Zn(II) and Mg(II)
References:
1. Vogel’s Textbook of Inorganic quantitative analysis
2. Experimental Inorganic Chemistry, Mounir A. Malati, Horwood Series in Chemical
Science (Horwood publishing, Chichester) 1999.
3. Experiments in Chemistry, D. V. Jahagirdar, Himalaya Publishing House
4. General Chemistry Experiments, Anil. J Elias, University Press (2002)
5. Practical physical Chemistry, B. Vishwanathan and P. S. Raghwan, Viva Books
690.

M.Sc. I Chemistry


COURSES
ANNEXURE - A

4) Name of Course Title : Basic Practical Chemistry-II
SYLLABUS (AUTONOMOUS COLLEGE) FOR TWO YEARS M.Sc.

DEGREE COURSE UNDER CHOICE BASE CREDIT SYSTEM (CBCS)
Name of subject – Basic Practical Chemistry-II (Organic Chemistry Practical -

II)
Objectives:
1. The objective of this course is to suggest modifications of the hazardous

Laboratory Experiments, currently practiced by the students in the present syllabus.
2. To enhance the use of alternative reagents which are not only eco-friendly but
also be easily available anywhere in the country in bulk quantities at very cheap
price. They should not preferably involve the use of organic solvents (like ether,
petroleum ether or ethyl acetate); ethanol and methanol are mostly preferred.
3. To avoid tedious experimental procedure like longer reaction time, reaction at high
temperature etc.
4. To recognize the energy requirements for their environmental and economic
impacts and should be minimized.
5. To conduct the synthetic methods at ambient temperature and pressure.
6. Conduct all the organic chemistry experiments (preparation, separation of mixture
of compounds, identification of functional groups etc.) in semi-micro or micro-scale.

M.Sc. I Chemistry
7. Use of Catalytic reagents (as selective as possible) as they are superior to

stoichiometric reagents.
8. To choose substances and the forms of the substance used in chemical reaction
so as to minimize the potential of chemical accidents, including releases, explosions,
and fires.
Unit
No Unit Title Purpose skills to be developed
Use of Chemistry software Student able to draw the chemical structure

1) like MOPAC, ISIS draw, using software like chemdraw
Chem office
Student will able to perform practicals with
alternative reagents and avoid solvents which
2) Green chemistry Practicals
minimizes the hazardous effects of the
chemical synthesis.
Innovative Digital Tools/ Film

Unit Total Expected
Methods show and AV Project
No Lecture Outcome
to be used Application
https://www.youtube.co 1. Students are
1) 6 - m/watch?v=1cxXAeQn made aware of
-M4 safety
https://www.youtube.co techniques and
2) 6 - m/watch?v=Na-x- - handling of
dBi4cg chemicals.
3) 6 - - Perform the 2. Students are
experiment made aware of
4) 6 - - with different carrying out
starting different types of
5) 6 - - material reactions and
https://www.youtube.co their workup
6) 6 - m/watch?v=0Hx- - methods.
jrAzmxc
3. This practical
7) 6 - - - course is
https://www.youtube.co designed to
8) 6 - m/watch?v=2r9eWd8f4 Perform the make student
BI experiment aware of green
with different chemistry and
9) 6 - - starting role of green
material chemistry in
10) 6 - -
pollution
https://www.youtube.co reduction.
11) 6 - m/watch?v=aTyqUU2Y -
UMo&t=90s

M.Sc. I Chemistry
References:
Sr. Name of
No. Author/s
V.K. Ahluwalia
Comprehensive Practical Sangam Books Hyderabad
1) and Renu
Organic Chemistry Limited (Telangana)
Aggarwal
Monograph on Green
Task Force
Chemistry Laboratory
Committee,
2) Experiments by Green - India
DST
Chemistry TaskForce
Committee, DST
Oxford Science
Green Chemistry: Theory P. Anastas and
3) Publications London
and Practice J. C. Warner,
Oxford, 1998
Date :
Place :

M.Sc. I Chemistry
ANNEXURE - B
Semester-II
CHP-227- Basic Practical Chemistry -II
SECTION- II Organic Chemistry Practical- II (2 Credits, 48 L, 12T)
Introduction to Green Chemistry
Concept of green chemistry, twelve principals of green chemistry, applications of
green chemistry for sustainable development, Atom economy, monitoring of reaction
using TLC.
Use of Chemistry software like MOPAC, ISIS draw, Chem office (1
Experiments)
Green Chemistry Preparations (10 Experiments)
1) Preparation of Schiff's bases in aqueous medium.
2) Preparation of dihydropyrimidinone under solvent free conditions
3) Preparation of acetanilide from aniline and acetic acid using Zn dust
4) Base catalyzed aldol condensation using LiOH.H2O as a Catalyst.
5) Bromination of trans-stilbene using sodium bromide and sodium bromate
6) [4+2] cycloaddition reaction in aqueous medium at room temperature
7) Benzil Benzilic acid rearrangement under solvent free condition
8) Clay catalyzed solid state synthesis of 7-hydroxy-4-methylcoumarin
9) Ecofriendly nitration of phenols and its derivatives using Calcium nitrate
10) Bromination of acetanilide using ceric ammonium nitrate in aqueous medium
11) Green approach for preparation of benzopinacolone from bezopinacol using
iodine catalyst,
12) Preparation of 1, 1-bis-2-naphthol under grinding at room temperature.
13) Solvent free aldol condensation between 3,4-dimethoxybenzaldehyde and 1-
indanone
14) Preparation of azlactone from hippuric acid
15) Preparation of thioamide from benzaldehyde in water.
References:
1. Comprehensive Practical Organic Chemistry by V.K. Ahluwalia and Renu
Aggarwal 2. Monograph on Green Chemistry Laboratory Experiments by Green
Chemistry Task Force Committee, DST
3. Green Chemistry: Theory and Practice, P. Anastas and J. C. Warner, Oxford
Science Publications Oxford, 1998

M. Sc. I Chemistry Syllabus (10!05!2020)

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S. N. Arts, D. J. Malpani Commerce and B. N.

Prin. Dr. Keshav K. Deshmukh

Structure of M. Sc. I Chemistry Course

Total Credits for M. Sc. I year 40

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 2

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 3

SANGAMNER NAGARPALIKA ARTS, D.J. MALPANI COMMERCE & B.N.

FORMAT FOR FRAMING SYLLABUS FOR FIRST YEAR PG AUTONOMOUS

1) Name of Faculty : Science

SYLLABUS (AUTONOMOUS COLLEGE) FOR TWO YEARS M.Sc. DEGREE

Name of subject: Physical Chemistry-I (Fundamentals of Physical Chemistry)

Course Code: CHP- 110

No. of Credit: 04 Credit (48L & 12T)

1. To understand the fundamental, basic concept, principles, and recent

Unit No Unit Title Purpose skills to be developed

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 4

work, chemical potential of a substance

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 5

heat and phase expected to understand

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 6

Fermi-Dirac and Bose-

Signature of HoD/ Chairman BOS

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 7

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 8

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 9

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 10

SANGAMNER NAGARPALIKA ARTS, D.J. MALPANI COMMERCE & B.N.

FORMAT FOR FRAMING SYLLABUS FOR FIRST YEAR UG / PG AUTONOMOUS

1) Name of faculty : Science

SYLLABUS (AUTONOMOUS COLLEGE) FOR TWO YEARS M.Sc. DEGREE

Name of subject: Inorganic Chemistry-I (Molecular Symmetry and Chemistry

Course Code: CHI-130

No. of Credit: 04 Credit (48L & 12T)

1. Student should imagine the molecules in three dimensions.

Unit No Unit Title Purpose skills to be developed

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 11

Innovative Digital Tools/

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 12

model box find out MO for pi bonding.

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 13

Signature of HoD/ Chairman BOS

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 14

1) Molecular Symmetry and Symmetry Groups (10L)

1. Hydrogen and its compounds (02L)

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 15

3. Boron Group (04L)

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 16

6. Instrumental analysis – By Douglas A.Skoog, F. James Holler, Stanley R. Crouch

Signature of HoD/ Chairman BOS

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 17

SANGAMNER NAGARPALIKA ARTS, D.J. MALPANI COMMERCE & B.N.

FORMAT FOR FRAMING SYLLABUS FOR FIRST YEAR PG AUTONOMOUS

1) Name of Faculty : Science

SYLLABUS (AUTONOMOUS COLLEGE) FOR TWO YEARS M.Sc. DEGREE

Name of subject– Organic Chemistry I (Basic Organic Chemistry)

Course Code: CHO-150

No. of Credit – 4 (48L + 12T)

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 18

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 19

ac.in/Home/ViewSu rearrangement reaction

Signature of HoD/ Chairman BOS

S. N. Arts, D. J. Malpani Commerce and B. N. Sarda Science College, Sangamner 20

1. Structure and Reactivity: (04 L)