Standardization /chemical Volume (mL) Equivalence Point

Na2CO3 21.462
Na2CO3-2 19.848
BHK Na2CO3-3 19.584
0.05 NaOH 5.4365
0.05 NaOH-2 4.905
0.05 NaOH-3 5.204
NaHCO3 10.48
NaHCO3-2 10.386
NaHCO3-3 10.493
HCL 9.95
HCL-2 9.857
HCL-3 9.821

moles BHK=moles de NaOH

M NaOH
Moles of BHK= 0.0002448 0.0450
PM BHK=204,22 g/mol
Moles of BHK= 0.0002448 0.0499
PM BHK=204,22 g/mol
Moles of BHK= 0.000244834002546 0.0470
PM BHK=204,22 g/mol
[NaOH] 0.0473
CAC7
Boehm tritation mean
Na2CO3
Na2CO3-2
Na2CO3-3
NaOH 11.324
NaOH-2 10.505
NaOH-3 10.388
NaHCO3
NaHCO3-2
NaHCO3-3
HCL 10.225
HCL-2 9.747
HCL-3 9.639

STANDARDIZATION CALCULATIONS
10 Sample+30 mL water= 40mL 10 Sample+30 mL water= 40mL
moles NaOH=moles de HCl M HCl Titration Moles de HCL=Moles NaHCO3
Moles HCl1= 0.47096 0.011773974819 Moles NaHCO31=
Moles HCl2= 0.46656 0.011663926612 Moles NaHCO32=
Moles HCl3= 0.46485 0.011621327306 MolesNaHCO33=
M HCl v1*C1=v2*c2 (40*C1=10*C2) M NaHCO3 v1*C1=v2*c2 (40*C1=10*C
0.0470959
0.04665571
0.04648531
[HCl] 0.0467 [NaHCO3]
 10 Sample+30 mL water= 40mL 10 Sample+30 mL water= 40mL
Moles de HCL=Moles NaHCO3 M NaHCO3 Titration 2 Moles de HCL=Moles Na2CO3 M Na2CO3 Titration
0.48989 0.012247357239 Moles Na2CO31= 0.50163 0.0125406861193
0.48550 0.012137504989 Moles Na2CO32= 0.46390 0.0115975928663
0.49050 0.012262549571 MolesNa2CO33= 0.45773 0.0114433322598
M NaHCO3 v1*C1=v2*c2 (40*C1=10*C2) MNa2CO3 v1*C1=v2*c2 (40*C1=10*C2)
0.048989428955495 0.050162744477
0.048550019955322 0.046390371465
0.049050198285306 0.045773329039
0.0489 [Na2CO3] 0.0474
 Boehm Titration:
HCl Titration
MHCl 0.0467
Titrating Agent NaOH
Mtit
: 0.0473

Muestra CAG(g) N°
1
R-A 0.100 2
3

Boehm Titration:
NaOH Titration
CNaOH 0.0473 M
Titrating Agent HCl
Ctit: 0.0467 M

Muestra CAG(g) N°
1
R-A 0.100 2
3

Boehm Titration:
NaHCO3 Titration
CNaHCO3 0.0489 M
Titrating Agent HCl
Ctit: 0.0467 M Ctit2:

Muestra CAG(g) N° Aliquot NaHCO3 (mL) Vol. HCl (mL)

1 10
R-A 0.100 2 10
3 10

Conc. Total Conc. Carboxilic

SAMPLE Basicity Conc. Total Acidity Acids Groups
(mmol/g)
(mmol/g) (mmol/g)

R-A -3.498 -8.390 13.040

 volume correction

Prepared Volume Samp

Aliquot HCl (mL) Vol. NaOH (mL) mmol NaOH mmol Inicial

10 12.290 0.58 0.467

10 11.492 0.54 0.467
10 11.384 0.54 0.467

volume correction

Prepared Volume Samp

Aliquot NaOH (mL) Vol. HCl (mL) mmol HCl mmol Inicial

10 16.066 0.75 0.47

10 13.946 0.65 0.47
10 13.848 0.65 0.47

volume correction Vi.Ci=C2.V2

mmol*40 ml / 10
Prepared Volume Sa 4

mmolHCl mmol Iniciales mmol consumidas mmol/g

0.00 0.4890 1.9560 19.56
0.00 0.4890 1.9560 0.00
0.00 0.4890 1.9560 19.56

Conc. Lactonics Groups Conc. Total grupos

(mmol/g) Fenolicos (meq/g)

9.480 -11.950
Vi.Ci=C2.V2
mmol*40 ml / 10
4

Conc. Total Basicity

mmol consumed mmol/g (mmol/g)
-0.46 -4.57
-0.31 -3.06 -3.498
-0.29 -2.86

Vi.Ci=C2.V2
mmol*40 ml / 10
4

Conc. Total Acidity

mmol consumed mmol/g (mmol/g)
-1.10912880 -11.0913
-0.71311280 -7.1311 -8.390
-0.69480640 -6.9481

Conc. Carboxilic Acids

Groups (mmol/g)

13.040
 Boehm Titration:
Na2CO3 Titration
CNa2CO3 0.0474 M
Titrating Agent HCl
Ctit: 0.0467 M Ctit2:

Muestra CAG(g) N° Aliquot Na2CO3 (mL) Vol. HCl (mL) mmol HCl

1 10 0.00
R-A 0.100 2 10 0.00
3 10 0.00
volume correction Vi.Ci=C2.V2
mmol*40 ml / 10
Prepared Volume Sample 4

Conc. Lactonics
mmol Inicial mmol consumed mmol/g Groups (mmol/g)
0.47 1.90 9.48
0.47 1.90 9.48 9.4800
0.47 1.90 9.48