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Introduction
The ideas about the physics of processes occurring in welding arcs, especially
about the mechanism of cathode processes, in the existing scientific literature
are based on numerous hypotheses, which have not yet been sufficiently
confirmed by experiments. Therefore, this book briefly discusses only the
main hypotheses.
A distinctive feature of welding processes is that they are thermal and usually
come with the introduction of thermal or thermomechanical energy to the
processing site. If only mechanical energy is introduced, then to a large
extent the effect of its conversion to thermal form is used.
Since the forms of energy input are the most common and essential features
of welding processes, these features form the basis of their classification
proposed in this book.
A strong covalent bond with an energy of the order of 105 J / mol determines
the high melting point and crystal strength. The covalent bond determines the
structure of the so-called atomic crystals: diamond, silicon, germanium, gray
tin, etc.
It is important for welders to bear in mind that strong covalent bonds are
established not only in atomic crystals, but also when metals are combined
with metalloids, metal oxides, as well as semiconductors or intermetallic
compounds with semiconductor properties. Intermetallic compounds are
compounds of typical metals with metals having weak metallic properties.
With the direct connection of metals with ceramics containing acid oxides,
coordination covalent bonds are more easily formed when a thin layer of
lower basic oxides with donor properties is created on the metal surface.
The ionic bond is also strong with an energy of about 105-107 J / mol. A
feature of the ionic bond is the lack of saturation and spatial orientation.
The notions of purely covalent and purely ionic bonds are largely idealized. If
in an ionic bond one atom completely gives up an electron to another, and in
a covalent bond each electron belongs equally to both bound atoms, then in
intermediate cases bonds with any percentage of ionicity are possible.
In addition to the two most typical chemical bonds, covalent and ionic,
molecular bonds are distinguished by the universal forces of Van der Waals
and metal bonds.
Van der Waals forces act between any atoms and molecules, but they are very
small - on the order of 103 J / mol. Therefore, molecular crystals, solid inert
gases, oxygen, nitrogen molecules, etc., due to these forces, have a very low
melting point. The formation of strong structures is mainly due to strong,
typically chemical bonds, such as covalent bonds, and the van der Waals
forces are only a small addition. The forces of Van der Waals are usually
associated with adhesive bonds when bonding, wetting solids with liquids,
etc.
Metallic bonds form structures through the interaction of positive lattice ions,
atomic residues, and delocalized, socialized electrons. They essentially do not
belong to chemical ones, and the concept of a metal bond can be considered
qualitative, since metals usually do not have a molecular structure, and their
atoms combine into crystalline formations. This type of connection
determines the high strength, ductility and electrical conductivity of metals.
The binding energy is about 105 J / mol. A strong metal bond is observed
during the formation of intermetallic compounds and some solid solutions.
One of its features is the lack of saturation, determined by the valency of the
corresponding atoms.
The metallic bond, by its nature, has significant similarities to the covalent
bond. In both cases, the electron orbits merge, but in the metal there is a
generalization not of individual, but of all valence electron orbits. In this
case, the general energy levels are established in the entire volume of the
crystal. The number of levels will be of the same order as the number of
atoms in a given volume of metal. The levels are very close to each other and
form energy bands, which are sometimes considered as splitting of valence
levels - orbits of individual atoms.
Since there is a cloud of generalized electrons in a metal, a metal bond allows
a greater displacement of atoms than other types of bonds. This determines
the high plasticity of metal crystals in comparison with valence or ionic
crystals.
All four types of bonds in crystals: atomic, ionic, molecular and metallic,
rarely exist in their pure form. Usually there are combinations of different
bonds at the same time, and, as noted above, molecular bonds are weak
compared to the other three. It should also be noted that the surfaces of solids
under atmospheric conditions are usually inert, since the valencies of their
atoms are saturated with a bond with the atoms of the environment. An
example of saturation is the oxidation of substances in a gaseous medium. On
the surface, processes such as physical adsorption, due to the forces of Van
der Waals, can also occur.
In fact, even in the ideal case, energy is required to connect surfaces. The fact
is that any stable state of the system corresponds to a certain minimum
energy per atom. Each atom is, as it were, in a potential well and the
transition from one stable state to another is possible only by overcoming the
energy barrier.
Inside the crystal, each atom is held by symmetrically directed binding
forces. On the free surface of a crystal or liquid, an atom is unbalanced due to
the absence of a bond on one side or due to its weakening. This causes an
increase in the energy of the surface layer of the crystal. If an atom needs a
certain energy to move inside the body, then an atom needs even more energy
to exit into the environment. Therefore, to connect two single crystals into
one, deformation or thermal energy is required externally.
Now let's talk about the fact that the welding process takes place in two
stages. Experimental material and theoretical analysis show that welding and
soldering can be attributed to the class of so-called topochemical reactions,
which are distinguished by the two-stage process of the formation of strong
bonds between the atoms of the substances being joined. At the same time,
two-stage is characteristic only for microareas of the connected surfaces.
At the first stage, physical contact develops, that is, the substances to be
joined are brought closer to the distances required for interatomic interaction,
and surfaces are also prepared for interaction. In the second stage, the stage
of chemical interaction, the process of formation of a strong compound ends.
When welding in the liquid phase (fusion welding and soldering), the atoms
of solid bodies come together by wetting the surfaces of the bodies with
liquid material (solder, melt), and the surface of a solid material is activated
by communicating thermal energy to its particles. Liquid material can spread
over the entire surface of the body and provide contact and adhesion of its
molecules and the surface layer of solids.
Upon solidification of the molten material, weak adhesive bonds are replaced
by strong chemical bonds corresponding to the nature of the materials being
joined and their type of crystal lattice. When welding in the liquid phase, the
input energy must ensure the melting of the main and filler materials, the
fusion of the joint, heating of the edges, etc. In this case, enhanced diffusion
of the components in the molten and solid materials, their mutual dissolution
occurs. These processes, as well as crystallization of the molten metal of the
weld pool or solder, provide a shear structure of the weld zone, which usually
increases the strength of the welded joint.
In the case of the rapid formation of physical contact of a solid with a melt,
for example, during welding by melting one of the materials to be joined, at
first a peak of interfacial energy will be observed at the interface between the
solid and liquid phases, since the transition of the atomic system to a new
state does not occur to be welded have microroughnesses even with careful in
thousands of angstroms. Therefore, when combining instantaneously, but for
some finite time interval. The duration of the retardation of the peak of the
interface, as this delay period is called, can be calculated approximately as
the lifetime of the atom in front of the potential barrier or determined
experimentally. Based on these data, it is possible to determine the
permissible duration of contact between the solid and liquid phases and the
optimum temperature for welding or soldering.
When welding in the solid state, the approach of atoms and the activation of
surfaces are achieved due to the joint elastic-plastic deformation of the
materials being joined in contact, often simultaneously with additional
heating.
The calculations are based on the ideas about the seizure of materials as a
result of creep on contact surfaces and the formation of strong chemical
bonds at the places of exit and movement of vacancies, dislocations, and their
clusters. The exit of dislocations to the contact surface activates it by
breaking saturated bonds, which leads to the formation of active centers.
However, it is generally accepted that when metals are combined in the solid
state, not only setting, but also sintering is important. Sintering is a complex
of diffusion processes that occur in time at elevated temperatures. Setting is a
diffusionfree phenomenon, the union of crystal lattices in contact of bodies as
a result of their joint plastic deformation. The relative role of setting and
sintering in different methods of joining metals is different and is determined
mainly by the temperature, time and pressure in the contact. For example,
diffusion welding with a long exposure time can be considered based on the
sintering phenomenon. In all other cases, the setting is primary, and the
diffusion and recrystallization processes, if they occur at all, are secondary.
Now let's talk about soldering and bonding. Soldering is usually called the
process of joining materials without melting them, using solder. Welding and
brazing processes are often difficult to distinguish, for example, when
welding dissimilar metals, in combinations of steel and copper, tungsten and
molybdenum and others, when only one of the most low-melting metals is
melted. Therefore, in the future, when analyzing energy sources, it is
advisable to combine welding and soldering with one term - welding.
Soldering can be performed using the same energy processes as welding.
To carry out chemical wetting during soldering, heating of parts and solder is
necessary, as well as surface activation. The latter is achieved by heating in
vacuum, in special environments or by surface treatment with flux.
Bonding can occur with little or no energy introduced into the joint due to the
adhesion forces between the liquid glue and the molecules of the surface
layers of the solid and chemical reactions. The ability of the adhesive to
connect products is also explained by the forces of residual chemical affinity
between the molecules of glue and the material to be bonded on the surface.
These forces are approximately 10-100 times less than the basic chemical
bonding forces in simple molecules. For example, they give rise to the
phenomenon of surface tension in liquids, the ability to wet or not wet the
surfaces of various materials. In the case of high molecular weight
compounds, where a monomer molecule repeats a macromolecule in the
polymer thousands of times, the adhesion forces increase in proportion to the
increase in molecular weight. These forces, having an electrical nature,
largely depend on the chemical structure of the adhesive and the material to
be bonded.
Now let's talk about the thermodynamic definition of the welding process. An
analysis of the physicochemical characteristics of the production of welded
and soldered joints allows us to establish the presence in the welding zone of
two main physical phenomena associated with an irreversible change in the
state of energy and matter: introduction and conversion of energy; motion
(transformation) of matter.
The type, intensity and nature of the conversion of the input energy is the
main thing that determines the type of welding process. Moreover, the
introduction of energy is always a necessary condition for the welding
process, since without this it is impossible to activate the connected surfaces.
The introduction of the substance is necessary only in some cases of fusion
welding and soldering, and energy in these cases can also be introduced with
the molten material.
The nature of the movement of the substance in the weld zone can vary
greatly from process to process. The movement is significant when welding
in the liquid phase and soldering, especially in the presence of filler material.
In pressure welding with heating, the material in the joint zone experiences
insignificant transformations and only the movement of the material through
the joint as a result of diffusion is significant. Cold welding is realized
practically without the movement of substances, if you do not take into
account the movement of dislocations and their exit to the surface.
Based on the foregoing, we can give the following thermodynamic definition
of the welding process. Welding is the process of obtaining a monolithic
compound of materials due to the introduction of irreversible thermodynamic
conversion of energy and matter at the junction.
Electric arc welding is performed with the obligatory use of a high current
source, which at the same time has a low voltage. Such voltage is
simultaneously supplied both to the welding electrode (one contact) and to
the workpiece to be welded (second contact). As a result of the interaction of
the workpiece and the electrode, an electric arc is formed between them, it is
due to it that the edges of the connected parts melt. The use of such an arc,
which is necessary for converting electric current energy into heat, allows one
to obtain a temperature of the order of 5000 degrees in the zone of electric arc
welding, which is quite enough to melt any of the metals known to mankind.
Submerged Arc Welding
The principle of laser welding is reduced to the fact that the laser radiation is
sent to the focus, where a beam is created from it, which gets onto the parts to
be welded. The beam enters the metal, is absorbed by it, heats the metal, as a
result of which melting occurs and a weld occurs.
The pressure of the energy flow - a beam or arc - on the weld pool will
certainly also have a very large effect on the formation of the joint. However,
in the energy balance, the influence of the energy of pressure forces is small.
Resistance welding applies only to metals. The main source of energy is the
heat released by electric current in the contact zone of the connected parts,
the electrical resistance of which is higher than the resistance of the base
metal. The pressure compressing the parts forms a welded joint, which takes
only a few percent of the total input energy.
The essence of the gas-pressure welding process is that the edges or ends of
the parts to be joined are heated by the flame of a special multi-nozzle torch
to a plastic or molten state and then connect them using compressive force.
Induction Welding
Friction welding is commonly used for bar products. During welding, one
part of the product remains stationary, and the other rotates. When both parts
are reduced and axial force is applied due to friction forces, heating and
plastic deformation of the metal occurs. The molten and heated metal is
partially squeezed out of the joint. Welding is used both for metals and for
plastics.
Ultrasonic Welding
Explosion Welding
Vacuum setting welding can be done with the least energy and even
theoretically with the release of energy at the junction. The setting of metals
is possible under high vacuum, subject to careful fitting and contact of parts
on a significant surface. A little pressure is also practically necessary, as a
perfect fit is difficult to achieve. Oxide films and contaminants in a vacuum
evaporate and clean surfaces come into contact.
When choosing an energy source for welding specific products, one should
take into account the technical feasibility of using this source, process
efficiency, energy and economic, as well as the number and reliability of the
compounds obtained.
Conclusion
I hope that this brief physical basis and classification of welding processes
will be useful for you. I plan to write some more books for Welding
Knowledge series. The main purpose of these books is to promote reader’s
competence in welding. I may bring to you some simple knowledge but this
knowledge is a foundation for any good welding engineer or welder. My
main aim is to bring qualified welders to this world, who would have a deep
understanding of the process.