Title: Chapter 12 new quiz

Started: January 16, 2010 2:20 PM

Submitted: January 16, 2010 3:04 PM
Time spent: 00:44:52
Total score: 9.05/10 = 90.5% Total score adjusted by 0.0 Maximum possible score: 10
1

Calculate the weight percent of a solution made by mixing 72.1 g of sucrose, C12H22O11, in 495.65 g
of water. Submit your answer to 2 decimal places.

Student Response Value Correct Answer

Answer: 12.70 100% 12.70
Units: % 0.0% %
Score: 1/1

Calculate the weight percent of a solution made by mixing 5.00 g of urea, (NH2)2CO in 67.02 g of
water. Submit your answer to 2 decimal places.

Student Response Value Correct Answer

Answer: 6.94 100% 6.94
Units: % 0.0% %
Score: 1/1

Calculate the mole fraction of a solution made by mixing 32.9 g of sucrose, C12H22O11, in 136.86 g of
water. Submit your answer to 3 decimal places.

Student Response Value Correct Answer

Answer: 0.012 100% 0.012
Score: 1/1

Calculate the molality of a solution made by mixing 15.2 g of urea, (NH2)2CO in 393.95 g of water.
Submit your answer to 3 decimal places.

Student Response Value Correct Answer

Answer: 0.642 95% 6.42E-1 (6.42 × 10-1)
 Student Response Value Correct Answer
Units: m 5.0% m
Score: 1/1

Calculate the molality of a solution made by mixing 14.8 g of urea, (NH2)2CO in 459.18 g of water.
Submit your answer to 3 decimal places.

Student Response Value Correct Answer

Answer: 0.537 95% 0.537
Units: m 5.0% m
Score: 1/1

You are given an aqueous 20.0 m solution of ammonia, NH3. What is the weight percent of the
solution?

Student Response Value Correct Answer

Answer: 25.4% 100% 25.4
Score: 2/2

You are given a 89.0% solution of sulfuric acid, H2SO4. What is the molality of this solution? The
density of the H2SO4 solution is 1.610 g/mL.

Student Response Value Correct Answer

Answer: 82.5 95% 82.5
Units: m 5.0% m
Score: 2/2

Calculate the molality of ions in a solution made by mixing 6.32 g of KBr, MW=119.00, in 60.44
mL of water at 37.0°C. The density of water at this temperature is 0.9933 g/cm-3 Submit your answer
to 2 decimal places.

Student Response Value Correct Answer

Answer: 0.88 0% 1.77
 Student Response Value Correct Answer
Units: m 5.0% m
Score: 0.05/1

Title: Chapter 13 new quiz

Started: April 16, 2010 6:42 PM
Submitted: April 16, 2010 7:03 PM
Time spent: 00:20:31
Total score: 8/10 = 80% Total score adjusted by 0.0 Maximum possible score: 10
1

A reaction with the activation energy Ea= 219.00 kJ/mol, has a rate constant k = 1.400 x 102 at
988.00 Kelvin. Determine the rate constant when the temperature is changed to 238.00 Kelvin. R =
8.314 J K-1mol-1

Student Response Correct Answer

Answer: 4.56E-35 4.56E-35 (4.56 × 10-35)
General Rearrange the two-temperature Arrhenius equation as shown on p507 of MF 3rd Edition
Feedback: and solve for k2
Score: 2/2

Calculate the half life of a first order reaction having a rate constant of 5.16 x 10-4. Enter your
answer to 3 sig figs.

Student Response Correct Answer

Answer: 1.34E3 1.34E3 (1.34 × 103)
Score: 1/1

The rate constant for the decomposition of dinitrogen pentoxide to form nitrogen dioxide and
oxygen gas has the rate constant 1.7 x 10-3 s-1. This is a first order reaction. How long would it take
for for the reaction to be 89.00% to complete? Enter your answer to 1 decimal place even if that is
more sig figs that you are entitled to report.

Student Response Correct Answer

Answer: 1298.4 1,298.4
 General Apply the first order integrated rate equation rearranged to solve for t, with the initial
Feedback: concentration as [A]o and the final concentration as [A]t.
Score: 1/1

The rate constant for the decomposition of dinitrogen pentoxide to form nitrogen dioxide and
oxygen gas has the rate constant 1.7 x 10-3 s-1. This is a first order reaction. If the initial
concentration of dinitrogen pentoxide was 1.318 mol/L, how many seconds will it take for the
concentration to reach 0.461 mol/L?

Student Response Correct Answer

Answer: 617.9 618
General Apply the first order integrated rate equation rearranged to solve for t, with the initial
Feedback: concentration as [A]o and the final concentration as [A]t.
Score: 1/1

In a certain decomposition reaction, dinitrogen pentoxide decomposes to form nitrogen dioxide gas
and oxygen gas. It was found that at 189 seconds the concentration of oxygen gas was 0.296 mol/L
and at 764.8 seconds the concentration of oxygen gas was 0.625 mol/L. What is the rate of
decomposition of dinitrogen tetroxide over the specified time period in this reaction?

Student Response Correct Answer

Answer: 1.14E-3 -1.14E-3 (-1.14 × 10-3)
General The rate of a reaction is the rate of change of some species. In this case we are measuring
Feedback: the change in concentration with time. To solve this, we divide the change in
concentration by the time taken for the change to occur. The units are M/s. See page 475
of your textbook.
Score: 0/1

In a certain decomposition reaction, dinitrogen pentoxide decomposes to form nitrogen dioxide gas
and oxygen gas. It was found that at 399 seconds the concentration of oxygen gas was 0.420 mol/L
and at 715.4 seconds the concentration of oxygen gas was 0.967 mol/L. What is the rate of
formation of nitrogen dioxide over the specified time period in this reaction?

Student Response Correct Answer

Answer: 3.46E-3 6.92E-3 (6.92 × 10-3)
General The rate of a reaction is the rate of change of some species. In this case we are measuring
 Feedback: the change in concentration with time. To solve this, we divide the change in
concentration by the time taken for the change to occur. The units are M/s. See page 475
of your textbook.
Score: 0/1

The second order rate constant for a reaction is 3.2100 x 102 M-1s-1. If the initial reagent
concentration is 0.93100 mol/L, determine the time (in seconds) required for the reagent
concentration to reach 0.34600 mol/L.

Student Response Correct Answer

Answer: 5.66E-3 0.01
General Apply the second order integrated rate equation rearranged to solve for t .
Feedback:
Score: 1/1

Determine the activation energy Ea in kJ/mol for a reaction who's rate constant k1 = 4.400 x 10-6 at
471.00 Kelvin changes to k2 = 7.500 x 10-2 when the temperature is changed to 625.00 Kelvin. R =
8.314 J Enter your answer in kJ.K-1mol-1

Student Response Correct Answer

Answer: 1.55E2 1.55E2 (1.55 × 102)
General Rearrange the two-temperature Arrhenius equation as shown on p507 of MF 3rd Edition
Feedback: and solve for Ea.
Score: 1/1

A reaction with the activation energy Ea= 92.00 kJ/mol, has a rate constant k = 8.500 x 10-4 at 379.00
Kelvin. Determine the temperature required to increase the rate constant 5 times . R = 8.314 J K-
1
mol-1

Student Response Correct Answer

Answer: 4.01E2 4.01E2 (4.01 × 102)
General Rearrange the two-temperature Arrhenius equation as shown on p507 of MF 3rd Edition
Feedback: and solve for T2
Score: 1/1
Chapter 14 new quiz
Started: February 22, 2010 9:43 PM
Submitted: February 22, 2010 10:03 PM
Time spent: 00:20:32
Total score: 10/10 = 100% Total score adjusted by 0.0 Maximum possible score: 10
1.
The reaction

2 B(aq) + D(aq) A(aq) + 2 F(aq)

is currently found, in some aqueous mixture at 22oC, to be at equilibrium. Placing the reaction
vessel in ice water causes an increase in B and D concentration, thus:

Student Response Correct Answer

A. the reaction shown must be endothermic.
B. the rate of the forward reaction must be less than the rate of the reverse
reaction.
C. the concentration of A must be equal to the concentration of D.
D. the rate of the forward reaction must be exactly equal to the rate of the
reverse reaction.
E. The reaction must be exothermic.
Score: 1/1

2.
The reaction

2 B(aq) + D(aq) A(aq) + 2 F(aq)

may be, in some aqueous mixture at 22oC, at equilibrium. If Q < K, you could definitely say that:

Student Response Correct Answer

A. the reaction shown must be endothermic.
B. the rate of disappearance of B is exactly one-half the rate of gain of A.
C. the rate of the forward reaction must be exactly equal to the rate of the
reverse reaction.
D. the rate of the forward reaction is not equal the rate of the reverse
reaction.
 Student Response Correct Answer
E. the concentration of A must be equal to the concentration of D.
Score: 1/1

3.
A mixture of 0.100 mol of CO2, 0.050 mol of H2, and 0.100 mol of H2O is placed in a 1.00 L vessel
and reacts according to the reaction shown below.

CO2 + H2 --> CO + H2O (all are gaseous)

At equilibrium the container is found to contain 0.0916 M CO2. What is the equilibrium constant,
Kc, for the reaction?

Student Response Correct Answer

Answer: 0.24 0.239
Score: 1/1

4.
The chemical reaction

2 D(g) + F(g) 2 B(g)

for which Kp = 14.83 and Ho = 22.6 kJ/mol, is initially at equilibrium in a sealed 3.000 L
adjustable volume vessel at 25oC. Altering conditions may cause the reaction to shift in order to
reach a new equilibrium. What kind of adjustment is expected of the reaction if the following
changes are made? (The answers are listed as effect of A; effect of B)

A. increased the volume of the vessel

B. decreased the temperature of the system ?

Student Response Correct Answer

A. shift right; shift right
B. shift left; shift left
C. shift ldft; shift right
D. shift right; shift left
E. no shift; shift left
Score: 1/1

5.
Initially, .500 atm of H2 and .500 atm I 2 are mixed in an evacuated 1.0 L flask. The system is
 allowed to come to equilibrium and it is found tocontain 0.320 atm HI. What is the equilibrium
partial pressure of I2 for the reaction shown below?

H2 + I2 --> 2 HI

Student Response Correct Answer

Answer: 0.340 0.340
Score: 1/1

6.
The reaction

A(s) + 2 B(g) 2 D(g)

exhibits Kc = 0.0277 at 342 K. If the standard enthalpy change for this reaction is 10.0 kJ/mol, what
is the value of Kc for the following reaction ?

D(g) B(g) + 1/2 A(s)

Student Response Correct Answer

Answer: 6.01 6.01
Score: 1/1

7.
A mixture of A(aq) and B(aq) associated with the reaction

A(aq) 2 B(aq)

for which the numerical value of Kc is 4.26, is initially prepared to contain [A] = 0.500 M and [B]
= 1.81 M. As this system progresses toward equilibrium, we can confidently predict

Student Response Correct Answer

A. the concentrations of both A and B will decrease.
B. the concentration of A will increase, while the concentration of B will
decrease.
C. no change will occur in the concentration of either A or B.
D. the concentrations of both A and B will increase.
E. the concentration of A will decrease, while the concentration of B will
increase.
Score: 1/1
8.
Given the chemical reaction

3 A(g) + 2 B(s) 2 D(g)

What is the equilibrium constant, Kp, expression for the reverse reaction?

Student Response Correct Answer

A.

B.

C.

D.

E.

Score: 1/1

9.
Under a set of unspecified conditions, the reaction

H2(g) + O2(g) + Cl2(g) 2 HOCl(g)

has Kp = 0.0698. What is the value of Kp for the reverse reaction ?

Student Response Correct Answer

Answer: 14.3 14.3
Score: 1/1

Kp = 0.233 for the following reaction at 470° C.

A (g) + B (s) = 2 C (g)

What is the correct value of Kc? Enter your answer to 4 decimal places. e.g. 0.0025

Student Response Correct Answer

Answer: 0.0038 0.0038
 Score: 1/1

Title: Chapter 16 new quiz

Started: April 16, 2010 7:04 PM
Submitted: April 16, 2010 7:26 PM
Time spent: 00:22:16
Total score: 8/10 = 80% Total score adjusted by 0.0 Maximum possible score: 10
1. Buffer Calculation 1
Calculate the pH of a buffer solution made by mixing 34 ml of a 0.11 M potassium
acetate solution with 65 ml of a 0.10M acetic acid solution. Give the pH to two decimal
places.

Student Response Value Correct Answer

Answer: 4.50 100% 4.50
Score: 1/1

2. Buffer Conceptual 2
Which of the following combonations will result in the creation of a buffer? Select all
that apply.

Student Correct
Value Feedback
Response Answer
A. mixing 50% good!
0.50 mol
NaOH
with 1.0
mol
HOBr
B. mixing 50% Good!
0.25 mol
HCl with
1.0 mol
CH3NH2
C. mixing
0.50 mol
HCl with
1.0 mol
HOBr
D. mixing
1.0 mol
HCl with
0.50 mol
NH3
 Student Correct
Value Feedback
Response Answer
E. mixing
0.50 mol
NaOH
with 0.50
mol
HOBr
Score: 1/1

3. Buffer Conceptual 1
Which of the following combonations will result in the creation of a buffer? Select all
that apply.

Student Correct
Value Feedback
Response Answer
A. mixing 50% good!
0.50 mol
HCl with
1.0 mol
NH3
B. mixing
0.50 mol
HCl with
0.50 mol
NH3
C. mixing
1.0 mol
HCl with
0.50 mol
NH3
D. mixing
0.50 mol
HCl with
1.0 mol
NH4Cl
E. mixing 50% Good!
0.25 mol
NaOH
with 1.0
mol HF
Score: 1/1

4. Buffer Mixture 2
Calculate the pH of a buffer solution made by mixing 31.1 g of potassium formate into
 1 L of a 0.09 M solution of formic acid. Give the pH to two decimal places.

Student Response Value Correct Answer

Answer: 4.36 100% 4.35
Score: 1/1

5. Buffer of pH 4
Which of the following sets of conjugate pairs would you select to make a buffer with a
pH of 3.35?

Student Correct
Value Feedback
Response Answer
A. nitrous acid
and sodium
nitrite
B. lactic acid
and sodium
lactate
C. hydrazine 0%
and
hydrazinium
+1
D. benzoic acid
and sodium
benzoate
E. arsenious
acid and
sodium
arsenate
Score: 0/1

6. Buffer of pH 1
Which of the following sets of conjugate pairs would you select to make a buffer with a
pH of 9.22? Select one answer.

Student Correct
Value Feedback
Response Answer
A. arsenious 0%
acid and
sodium
arsenate
B. benzoic acid
and sodium
benzoate
 Student Correct
Value Feedback
Response Answer
C. ammonia
and
ammonium
chloride
D. nitrous acid
and sodium
nitrite
E. hydrazine
and
hydrazinium
+1
Score: 0/1

7. Equivalence point
Calculate the volume of .025 M HCl required to titrate 50.0 mL of 0.046M NaOH
solution to the equivalence point. State your answer to one decimal place in mL.

Student Response Value Correct Answer

Answer: 92.0 100% 92.0
Score: 1/1

8. SA/SB titration 2
Calculate the pH of a solution resulting from the titration of 50mL of 0.044M HBr with
25 mL of 0.102M KOH. Give your answer to two decimal places.

Student Response Value Correct Answer

Answer: 11.67 100% 11.67
Score: 1/1

9. WA SB Titration pKa pt
What is the pH of a solution resulting from the titration of 50 mL of 0.050 M formic
acid solution, HCOOH, with 25 mL of 0.050 M NaOH solution? Calculate your answer
to two decimal places.

Student Correct
Value Feedback
Response Answer
A. pH = 2.90
B. pH = 3.74 100% easy, wasn't it!
C. pH = 2.60
D. pH = 6.01
 Student Correct
Value Feedback
Response Answer

Title: Chapter 17 new quiz

Started: April 3, 2010 12:59 PM
Submitted: April 3, 2010 1:06 PM
Time spent: 00:07:23
Total score: 8.02/10.02 = 80.0399% Total score adjusted by 0.0 Maximum possible score: 10.02
1. Question 107
Under which of the following conditions would one mole of Ne have the highest entropy, S?

Student
Value Correct Answer Feedback
Response
A.
27 C
and 25 L
B.
137 C
and 25 L
C.
27 C
and 35 L
D. 100%
137 C
and 35 L
Score: 1/1

2. Question 103
The following pictures represent three equilibrium mixtures for the interconversion of A, B, and C
molecules (unshaded spheres) into X, Y, and Z molecules (shaded spheres), respectively. What is

the sign of G for each of the three reactions?

Student
Value Correct Answer Feedback
Response
A.
G

(1) =
 Student
Value Correct Answer Feedback
Response

-; G

(2) =

+; G

(3) =
0
B. 100%
G

(1) =

-; G

(2) =

0; G

(3) =
+
C.
G

(1) =

0; G

(2) =

-; G

(3) =
+
D.
G

(1) =

+; G

(2) =

0; G

(3) =
-
 Score: 1/1

3. Question 096
Consider the reaction 2A(g) A2(g). The following pictures represent two possible initial states and
the equilibrium state of the system.

What are the signs (+ or -) of H, S, and G when the system goes

from initial state 2 to the equilibrium state?

Student
Value Correct Answer Feedback
Response
A.
H=

+, S=

+, G
=+
B. 0%
H=

+, S=

+, G
=-
C.
H = -,

S = -,

G=+
D.
H = -,

S = -,

G=-
Score: 0/1

4. Question 085
In figure (1) below oxygen molecules, represented by unshaded spheres, and chlorine molecules,
represented by shaded spheres, are in separatecompartments. Figure (2) shows the equilibrium state
of the system after the stopcock separating the two compartments is opened. Assuming the oxygen
 and the chlorine behave as ideal gases, what are the signs (+, -, or 0) of H, S, and G
for this process?

Student
Value Correct Answer Feedback
Response
A.
H=

+, S=

-, G=
+
B. 100%
H=

0, S=

+, G
=-
C.
H=

0, S=

-, G=
+
D.
H = -,

S = +,

G=-
Score: 1/1

5. Question 081

If G is small and positive,

Student
Value Correct Answer Feedback
Response
A. the forward
reaction is
spontaneous
 Student
Value Correct Answer Feedback
Response
and the
system is far
from
equilibrium.
B. the forward
reaction is
spontaneous
and the
system is
near
equilibrium.
C. the reverse
reaction is
spontaneous
and the
system is far
from
equilibrium.
D. the reverse 100%
reaction is
spontaneous
and the
system is
near
equilibrium.
Score: 1/1

6. Question 071
If Q increases

Student
Value Correct Answer Feedback
Response
A.
G
increases
and the
reaction
becomes
more
spontaneous.
B. 100%
G
increases
and the
reaction
 Student
Value Correct Answer Feedback
Response
becomes less
spontaneous.
C.
G
decreases
and the
reaction
becomes
more
spontaneous.
D.
G
decreases
and the
reaction
becomes less
spontaneous.
Score: 0.34/0.34

7. Question 069

G= G for a reaction

Student
Value Correct Answer Feedback
Response
A. if Q = K.
B. if Q = 1. 100%
C. at STP.
D. at the start
of the
reaction.
Score: 0.34/0.34

8. Question 040
During perspiration,

Student
Value Correct Answer Feedback
Response
A. the
entropy of
the water
evaporated
 Student
Value Correct Answer Feedback
Response
decreases
and the
entropy of
the body
decreases.
B. the
entropy of
the water
evaporated
decreases
and the
entropy of
the body
increases.
C. the 100%
entropy of
the water
evaporated
increases
and the
entropy of
the body
decreases.
D. the
entropy of
the water
evaporated
increases
and the
entropy of
the body
increases.
Score: 0.34/0.34

9. Question 026
Under which of the following conditions would one mole of Ne have the highest entropy, S?

Student
Value Correct Answer Feedback
Response
A.
27 C
and 25 L
B.
137 C
and 25 L
 Student
Value Correct Answer Feedback
Response
C.
27 C
and 35 L
D. 100%
137 C
and 35 L
Score: 0.5/0.5

1
Question 030

Which should have the highest standard molar entropy at 25 C?

Student
Value Correct Answer Feedback
Response
A. Al(s)
B. Al(l)
C. Al(g) 100%
D. All three
should
have a
standard
molar
entropy of
zero.
Score: 0.5/0.5

1
Question 041

A hot penny is dropped into cold water inside a polystyrene foam cup. Assuming negligible heat
loss to the atmosphere and the cup,

Student
Value Correct Answer Feedback
Response
A. the 0%
decrease
in entropy
of the
penny is
equal to
the
increase in
 Student
Value Correct Answer Feedback
Response
entropy of
the water.

| Spenny

|=|
Swater |
B. the
decrease
in entropy
of the
penny is
less than
the
increase in
entropy of
the water.

| Spenny

|<|
Swater |
C. the
decrease
in entropy
of the
penny is
more than
the
increase in
entropy of
the water.

| Spenny

|>|
Swater |
D. the
entropy of
both the
penny and
the water
increases.
Score: 0/1

1 Question 105
 What is the entropy change associated with the expansion of one mole of an ideal gas from an
initial volume of V to a final volume of 6.50V at constant temperature?

Student
Value Correct Answer Feedback
Response
A.
S=
-6.50 R ln
(Vf/Vi)
B. 100%
S=R
ln 6.50
C.
S=
6.50 R ln
(Vf/Vi)
D.
S=
-R ln 6.50
Score: 1/1

1
Question 099

Consider the following gas-phase reaction of A2 (shaded spheres) and B2 (unshaded spheres):

Which of the above reaction mixtures is G of reaction = G ?

Student
Value Correct Answer Feedback
Response
A. (1)
B. (2)
C. (3) 100%
D. (4)
Score: 1/1

Title: Chapter 15 new quiz

Started: March 7, 2010 2:39 PM
Submitted: March 7, 2010 3:01 PM
Time spent: 00:21:29
Total score: 8.5/10 = 85% Total score adjusted by 0.0 Maximum possible score: 10
1

Consider the following generic weak acid reaction.

HA + H2O <==> H3O+ + A -

If a 0.0031M solution of HA has a pH of 3.08, calculate Ka for the acid HA.

Enter your answer with two sig figs in the form: 2.3E-6 for 2.3 x 10-4

Student Response Value Correct Answer

Answer: 3.1E-4 100% 3.1E-4 (3.1 × 10-4)
Score: 1.5/1.5

Ka = 2.0 x 10-9 for HOBr. Calculate the pH of a 0.1171M HOBr solution. Round the pH to two
decimal places.

Student Response Value Correct Answer

Answer: 4.82 100% 4.82
Score: 1.5/1.5

Calculate the pH of a 2.38 x 10-4 M hydrazine solution. Show your answer to two decimal places and
use Kb = 8.9 x 10-7.

Student Response Value Correct Answer

Answer: 9.16 100% 9.16
Score: 1.5/1.5

Hypochlorous acid, HOCl, is a weak acid with a Ka of 3.50x10-8. What is the pH of a 0.38M solution
of KOCl? Use two decimal places in your answer.
 Student Response Value Correct Answer
Answer: 3.94 0% 10.52
Score: 0/1.5

Refer to Appendix C, Tables C.1 and C.3 to decide which of the following salt solutions will
produce a basic solution? You may select more than one answer.

Student
Value Correct Answer Feedback
Response
A. C5H5NHBr
B. KI
C. LiOBr 50%
D. NaCH3CO2 50%
E. NH4Cl
Score: 2/2

Refer to Appendix C, Tables C.1 and C.3 to decide which of the following salt solutions will
produce a acidic solution? You may select more than one answer.

Student
Value Correct Answer Feedback
Response
A. LiOBr
B. NaCH3CO2
C. NH4Cl 50%
D. C5H5NHBr 50%
E. KI
Score: 2/2