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MODEL 2350A

GAS CHROMATOGRAPH
CONTROLLER
__________________________________________

USER GUIDE
H2S CEM APPLICATION

Applies to both:
Daniel Danalyzer Gas Chromatographs
Rosemount Analytical Process Gas Chromatographs

Part Number 3-9005-006

Revision B
OCTOBER 2005
MODEL 2350A GAS CHROMATOGRAPH CONTROLLER O C T 2005

USER GUIDE H2S CEM


MODEL 2350A GAS CHROMATOGRAPH
CONTROLLER APPLICATION

NOTICE
DANIEL M EASUREMENT AND CONTROL, INC. AND ROSEMOUNT ANALYTICAL, INC. (COLLECTIVELY,
“SELLER”) SHALL NOT BE LIABLE FOR TECHN ICAL OR EDITORIAL ERRORS IN THIS MANUAL OR
OMISSIONS FROM THIS MANUAL. SELLER M AKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING THE IMPLIED W ARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR
PURPOSE W ITH RESPECT TO THIS MANUAL AND, IN NO EVENT, SHALL SELLER BE LIABLE FOR ANY
SPECIAL OR CONSEQUENTIAL DAMAGES INCLUDING, BUT NOT LIMITED TO, LOSS OF PRODUCTION,
LOSS OF PROFITS, ETC.

PRODUCT NAMES USED HEREIN ARE FOR MANUFACTURER OR SUPPLIER IDENTIFICATION ONLY AND
MAY BE TRADEMARKS/REGISTERED TRADEMARKS OF THESE COMPANIES.

THE CONTENTS OF THIS PUBLICATION ARE PRESENTED FOR INFORMATIONAL PURPOSES ONLY, AND
W HILE EVERY EFFORT HAS BEEN MADE TO ENSURE THEIR ACCURACY, THEY ARE NOT TO BE
CONSTRUED AS W ARRANTIES O R GUARANTEES, EXPRESSED OR IMPLIED, REGARDING THE
PRODUCTS OR SERVICES DESCRIBED HEREIN OR THEIR USE OR APPLICABILITY. W E RESERVE THE
RIGHT TO M ODIFY OR IMPROVE THE DESIGNS OR SPECIFICATIONS OF SUCH PRODUCTS AT ANY TIME.

SELLER DOES NOT ASSUME RESPONSIBILITY FOR THE SELECTION, USE OR MAINTENANCE OF ANY
PRODUCT. RESPONSIBILITY FOR PROPER SELECTION, USE AND M AINTENANCE OF ANY SELLER
PRODUCT REMAINS SOLELY W ITH THE PURCHASER AND END-USER. DANIEL AND THE DANIEL LOGO
ARE REGISTERED TRADEMARKS OF DANIEL INDUSTRIES, INC. THE ROSEMOUNT AND ROSEMOUNT
ANALYTICAL LOGO THE ARE REGISTERED TRADEMARKS OF ROSEMOUNT ANALYTICAL, INC. THE
EMERSON LOGO IS A TRADEMARK AND SERVICE MARK OF EMERSON ELECTRIC CO.

COPYRIGHT © 2005
BY DANIEL MEASUREMENT AND CONTROL, INC.,
HOUSTON, TEXAS,
U.S.A.

All rights reserved. No part of this work may be reproduced or


copied in any form or by any means - graphic, electronic, or
mechanical — without first receiving the written permission of
Daniel Measurement and Control, Inc. Houston, Texas, U.S.A.

PREFACE i
SEP 2005 MODEL 2350A GAS CHROMATOGRAPH CONTROLLER

WARRANTY
1. LIM ITED W ARRANTY: Subject to the limitations contained in Section 2 herein and except as otherwise expressly
provided herein, Daniel M easurement and Control, Inc. and Rosemount Analytical, Inc., (collectively “Seller”) warrants
that the firmware will execute the programming instructions provided by Seller, and that the Goods manufactured or
Services provided by Seller will be free from defects in materials or workmanship under normal use and care until the
expiration of the applicable warranty period. Goods are warranted for twelve (12) months from the date of initial
installation or eighteen (18) months from the date of shipment by Seller, whichever period expires first. Consumables
and Services are warranted for a period of 90 days from the date of shipment or completion of the Services. Products
purchased by Seller from a third party for resale to Buyer ("Resale Products") shall carry only the warranty extended by
the original manufacturer. Buyer agrees that Seller has no liability for Resale Products beyond making a reasonable
commercial effort to arrange for procurement and shipping of the Resale Products. If Buyer discovers any warranty
defects and notifies Seller thereof in writing during the applicable warranty period, Seller shall, at its option, promptly
correct any errors that are found by Seller in the firmware or Services, or repair or replace F.O.B. point of manufacture
that portion of the Goods or firmware found by Seller to be defective, or refund the purchase price of the defective
portion of the Goods/Services. All replacements or repairs necessitated by inadequate maintenance, normal wear and
usage, unsuitable power sources, unsuitable environmental conditions, accident, misuse, improper installation,
modification, repair, storage or handling, or any other cause not the fault of Seller are not covered by this limited
warranty, and shall be at Buyer's expense. Seller shall not be obligated to pay any costs or charges incurred by Buyer
or any other party except as may be agreed upon in writing in advance by an authorized Seller representative. All costs
of dismantling, reinstallation and freight and the time and expenses of Seller's personnel for site travel and diagnosis
under this warranty clause shall be borne by Buyer unless accepted in writing by Seller. Goods repaired and parts
replaced during the warranty period shall be in warranty for the remainder of the original warranty period or ninety (90)
days, whichever is longer. This limited warranty is the only warranty made by Seller and can be amended only in a
writing signed by an authorized representative of Seller. Except as otherwise expressly provided in the Agreement,
THERE ARE NO REPRESENTATIONS OR W ARRANTIES OF ANY KIND, EXPRESSED OR IMPLIED, AS TO
MERCHANTABILITY, FITNESS FOR PARTICULAR PURPOSE, OR ANY OTHER MATTER W ITH RESPECT
TO ANY OF THE GOODS OR SERVICES. It is understood that corrosion or erosion of materials is not covered
by our guarantee.

2. LIMITATION OF REMEDY AND LIABILITY: SELLER SHALL NOT BE LIABLE FOR DAMAGES CAUSED
BY DELAY IN PERFORMANCE. THE SOLE AND EXCLUSIVE REMEDY FOR BREACH OF W ARRANTY
HEREUNDER SHALL BE LIMITED TO REPAIR, CORRECTION, REPLACEM ENT OR REFUND OF PURCHASE
PRICE UNDER THE LIMITED W ARRANTY CLAUSE IN SECTION 1 HEREIN. IN NO EVENT, REGARDLESS
OF THE FORM OF THE CLAIM OR CAUSE OF ACTION (WHETHER BASED IN CONTRACT, INFRINGEMENT,
NEGLIGENCE, STRICT LIABILITY, OTHER TORT OR OTHERW ISE), SHALL SELLER'S LIABILITY TO
BUYER AND/OR ITS CUSTOMERS EXCEED THE PRICE TO BUYER OF THE SPECIFIC GOODS
MANUFACTURED OR SERVICES PROVIDED BY SELLER GIVING RISE TO THE CLAIM OR CAUSE OF
ACTION. BUYER AGREES THAT IN NO EVENT SHALL SELLER'S LIABILITY TO BUYER AND/OR ITS
CUSTOMERS EXTEND TO INCLUDE INCIDENTAL, CONSEQUENTIAL OR PUNITIVE DAMAGES. THE
TERM "CONSEQUENTIAL DAMAGES" SHALL INCLUDE, BUT NOT BE LIMITED TO, LOSS OF
ANTICIPATED PROFITS, LOSS OF USE, LOSS OF REVENUE AND COST OF CAPITAL.

ii PREFACE
MODEL 2350A GAS CHROMATOGRAPH CONTROLLER SEP 2005

TABLE OF CONTENTS

New Functionality . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Automatic Validation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Manual Validation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

Modbus Status Registers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Validation Stream Sequence . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Numeric Entries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

Streams 1 and 4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

Streams 2 and 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

Validation Sequence . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Validation Streams within Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Low Stream Validation Failure (Calibration Correctable) . . . . . . . . . . . . . . . . . . . . . . . . 10
High Stream Validation Failure (Calibration Correctable) . . . . . . . . . . . . . . . . . . . . . . . 10
Low Stream Validation Failure (A Condition Uncorrectable by Calibration) . . . . . . . . . 11
High Stream Validation Failure (A Condition Uncorrectable by Calibration) . . . . . . . . 13

Modbus Register Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

PREFACE iii
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iv PREFACE
MODEL 2350A GAS CHROMATOGRAPH CONTROLLER SEP 2005

H2S CEM APPLICATION

The H2S CEM (Continuous Emissions Monitoring) application is based on the standard 2350A mode
1 application, v1.75, enhanced as described below.

New Functionality:

Automatic Validation

The validation sequence is automatically run once a day at the time specified by the variable named
'ValStartTime' (Validation Start Time). Use the Application>User Defined>Numeric menu to access
the 'ValStartTime' variable.

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The default Validation Start Time is 600 (6:00 a.m. or 0600 in 24-hr time). The 'ValStartTime' is
calculated ((Hours*100)+Minutes). If a validation is needed to run at 7:30 a.m. every day the
operator would calculate the time by:

7*100 = 700
then
700 + 30 = 730.

The value '730' would then be entered into the 'ValStartTime' Value field.

If using 24-hour time, and the validation process was to start at 14:25 in the afternoon, the time
would then be calculated by:

14*100=1400
then
1400+25=1425

The value 1425 would then be entered into the 'ValStartTime' Value field.

Manual Validation

Start the validation process manually at any time by setting the Option field of the 'StartVal'
variable. Use the Application>User Defined>Selection menu to access the StartVal dialog.

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StartVal - 1 = IDLE, 2 = START - manually starts the validation sequence. When the application
detects START, it sets 'Discrete Input #5' to ON, which then initiates the auxiliary stream sequence
for the validation.

Click the start option and then click the OK button to apply the change.

Whichever method is used to start the Validation process, Manual or Timed, the Switch field, of
'Digital Input #5', labeled 'Run_Aux_Seq' is set to ON, triggering the Validation Process.

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Modbus Status Registers

Sim2251 Register 8017 (StartVal) R/W - 1 = IDLE, 2 = START -

Use the Application>User Defined>Selection menu to access the Validation Start process or from
writing the integer '2' to this register. When the application detects a manual 'Start' from the 'StartVal'
variable in the Application>User Defined>Selection menu, this register is set to 2 - (Start), the
application then sets 'Discrete Input #5' to ON which initiates the validation process by running the
'Auxiliary Stream Sequence'.

Sim2251 Register 8018 (Validation Failure Flag) RO - “1" indicates that the last validation
sequence failed. Location #1 from Application>Discrete Alarms menu shows the location of the
failure. Discrete Outputs 1 through 3 may be assigned to this alarm at location #1.

Sim2251 Register 8019 (Operational status) RO - 0 = idle, 1 = maintenance mode, 2 = analysis, 3


= calibration, 4 = validation.

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Validation Stream Sequence

The validation process is controlled by the 'Auxiliary Stream Sequence'. Use the Application>System
menu to access the Systems dialog. This application, is set up to run in the following stream order:
2,2,2,3,3,3,1.

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Numeric Entries:

To access the User Defined Numerics Entries dialog use the Application>User Defined>Numeric
menu.

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This is where the variables listed below are assigned values.

ValStartTime - Validation Start Time. ((hrs * 100) + mins) The time each day the validation
sequence will begin. If invalid, validation sequence will not be run.

ValLoStrm - Validation Low Stream. The stream number for the low H2S concentration stream (2
for this application)

ValHiStrm - Validation High Stream. The stream number for the high H2S concentration stream (3
for this application)

ValCalStrm - Validation Calibration Stream. The calibration stream number for the validation
process to re-calibrate either Stream 2 or 3 when out of limits(3 for this application).

ValAnlStrm - Validation Analysis Stream. The analysis stream number used for determining the
CDT that will have the response factor of H2S updated after the validation calibration run is
completed (1 for this application).

ValToFail - Validation To Fail. The number of times the validation sequence will run when a
validation calibration fails, before the validation process is aborted and the validation failure alarm
is set (1 for this application).

ValLoConc - Validation Low Concentration. Nominal concentration of ValLoStrm (30 ppm for this
application)

ValLoDevLim - Validation Low Deviation Limit. Allowable percentage from nominal concentration
(±10% for this application)

ValHiConc - Validation High Concentration. Nominal concentration of ValHiStrm (240 ppm for
this application)

ValHiDevLim - Validation High Deviation Limit. Allowable percentage from nominal


concentration (±10% for this application)

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Streams 1 and 4

Both Streams 1 and 4, run on Component Data Table 1 and Timed Event Table 1. Stream 1 is the
standard analysis stream. Stream 4 is the standard calibration stream for Component Data Table 1.
Stream 4 is periodically run on a calibration gas bottle and updates the component retention times
and response factors of CDT1 after normal calibrations.

Stream 1 is also the 'ValAnlStrm' (Validation Analysis Stream), the stream used to determine on
which component data table the H2S response factor will be updated when the validation calibration
process on Stream 3 is run.

For this application, Stream #1 is assigned to Component Data Table #1. The response factor for
H2S on Component Data Table #1 will be updated when the validation calibration process on Stream
#3 is run.

Streams 2 and 3

Streams 2 and 3 are assigned to Component Data Table #2.

Stream #2 for this application, is the H2S low concentration stream, 'ValLoStrm' (Validation Low
Stream).

Stream #3 for this application, is the H2S high concentration stream 'ValHiStrm' (Validation High
Stream).

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Validation Sequence

Validation Streams within Limits

When a validation process has been started manually from the Application>User Defined> Selection
menu or automatically by the 'StartValTime' setting, 'Discrete Input #5' is set to ON which initiates
the 'Auxiliary Stream Sequence'. The validation process which is being controlled by the 'Auxiliary
Stream Sequence' in the 'System' submenu begins. Running in order the streams 2,2,2,3,3,3,1.

The SIM2251 Modbus bus register 8019 (Operational Status) is set to 4 (Validation). If the
validation process was started manually by setting the 'StartVal' Option field in the
Application>User Defined>Selection menu to 'Start', SIM2251 Modbus Register 8017 (StartVal)
will be set to 2 (Start). Modbus Register 8017 is not changed if the validation process was a time
validation.

On the last run of Stream2, the 'ValLoStrm', the calculated Mole % of H2S on Stream 2 running the
low H2S calibration bottle is compared to the 'ValLoConc' value assigned to Stream 2 in the numeric
submenu. For this application, the Default 'ValLoConc' value is 30 ppm.

If the above calculated Mole % of H2S on the 'ValLoStrm' (Stream 2) is within the 'ValLoConc'
limits specified by the variable 'ValLoDevLim' (±10% for this application, between 27 ppm and 33
ppm), then the 'ValHiStrm' (Stream 3) is run.

On the last run of Stream3, the 'ValHiStrm', the calculated Mole % of H2S on Stream 3 from the
High H2S calibration bottle is compared to the 'ValHiConc' value assigned to Stream 3, in the
Numeric submenu. For this application, the 'ValHiConc' value is 240ppm.

If the above calculated Mole % of H2S on the 'ValHiStrm' (Stream 3) is within the 'ValHiConc' limits
specified by the variable 'ValHiDevLim' (±10% for this application, between 216 ppm and 264 ppm),
the controller goes to 'Idle' for a short period of time. 'Discrete Input #5' is returned to OFF, Sim2251
Modbus registers 8017 (StartVal) is set to 1 (Idle), if it was a manual start. Register 8019 is set to
2 (Analysis), and the 2350A Controller resumes normal analyses on Stream 1.

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Low Stream Validation Failure (Calibration Correctable)

The validation process is initiated. 'Discrete Input #5' is set to 'ON'. SIM2251 Modbus bus register
8019 (Operational Status) is set to 4 (Validation). Register 8017 (StartVal) is set to 2 (Start) if the
validation process was started manually, otherwise register 8017 remains at 1 (Idle). The validation
process begins running the 'Auxiliary Stream Seq'.

On the last run of Stream2, the 'ValLoStrm', the calculated Mole Percent of H2S on Stream 2 running
the low H2S calibration bottle is compared to the 'ValLoConc' value assigned to Stream 2 in the
Numeric submenu. For this application the default 'ValLoConc' value is 30ppm.

If the above calculated Mole% of H2S on the 'ValLoStrm' (Stream 2) is found to be out of the
'ValLoConc' limits specified by the variable 'ValLoDevLim' (±10% for this application, between 27
ppm and 33 ppm), then the validation sequence is 'Halted'. The system goes to 'Idle' for a short period
of time. Then a calibration sequence is run on the 'ValHiStrm' (Stream 3).

At the end of the calibration sequence on the 'ValHiStrm', if the new calculated response factors fall
within the component data table's 'Response Factor % Dev' limits, then the H2S response factor will
be updated in both component data tables.

At this time the validation process is repeated, the calculated H2S Mole % for the 'ValLoStm' is
checked against the 'ValLoConc' limits. The calculated H2S Mole % for the ValHiStrm' is checked
against the 'ValHiConc' Limits, and if both are found to be in Range, the Controller goes to 'Idle' for
a short Period. 'Discrete Input #5' is returned to OFF, Sim2251 Modbus registers 8017 (StartVal)
is set to 1 (Idle), if the validation process was a manual start. Register 8019 is set to 2 (Analysis), and
the 2350A Controller resumes normal analyses on Stream 1.

High Stream Validation Failure (Calibration Correctable)

The validation process is initiated. 'Discrete Input #5' is set to ON. SIM2251 Modbus bus register
8019 (Operational Status) is set to 4 (Validation). Register 8017 (StartVal) is set to 2 (Start) if the
validation process was started manually, otherwise register 8017 remains at 1 (Idle). The validation
process begins running the 'Auxiliary Stream Seq'.

On the last run of Stream2, the 'ValLoStrm', the calculated Mole % of H2S on Stream 2 running the
Low H2S calibration bottle is compared to the 'ValLoConc' value assigned to Stream 2 in the
Numeric submenu. For this application, the Default 'ValLoConc' value is 30ppm.

If the above calculated Mole % of H2S on the 'ValLoStrm' (Stream 2) is within the 'ValLoConc'
limits specified by the variable 'ValLoDevLim' (±10% for this application, between 27 ppm and 33
ppm), then the 'ValHiStrm' (Stream 3) is run.

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On the last run of Stream 3 in the validation process, If the calculated Mole % of H2S on the
'ValHiStrm' (Stream 3) is found to be out of the 'ValHiConc' limits specified by the variable
'ValHiDevLim' ±10% for this application, between 216 ppm and 264 ppm), then the validation
sequence is 'Halted'. The system goes to 'Idle' for a short period. Then a calibration sequence is run
on the 'ValHiStrm' (Stream 3).

At the end of the calibration sequence, if the new calculated response factors fall within the
component data table's 'Response Factor % Dev' limits, then the H2S response factor will be updated
in both component data tables.

At this time the validation process is repeated, the calculated H2S Mole % for the 'ValLoStm' is
checked against the 'ValLoConc' limits. The calculated H2S Mole % for the ValHiStrm' is checked
against the 'ValHiConc' limits, and if both are found to be in range, the controller goes to 'Idle' for
a short period pf time. 'Discrete Input #5' is returned to OFF, Sim2251 Modbus registers 8017
(StartVal) is set to 1 (Idle) if the validation process was manually started. Register 8019 is set to 2
(Analysis), and the 2350A Controller resumes normal analyses on Stream 1.

Low Stream Validation Failure (A Condition Uncorrectable by Calibration)

The validation process is initiated. 'Discrete Input #5' is set to 'ON'. SIM2251 Modbus bus register
8019 (Operational Status) is set to 4 (Validation). Register 8017 (StartVal) is set to 2 (Start) if the
validation process was started manually, otherwise register 8017 remains at 1 (Idle). The validation
process begins running the 'Auxiliary Stream Seq'.

On the last run of Stream2 during the validation process, the 'ValLoStrm', the calculated Mole % of
H2S on Stream 2 running the Low H2S calibration bottle is compared to the 'ValLoConc' value
assigned to Stream 2 in the Numeric submenu. For this application the default 'ValLoConc' value is
30 ppm.

If the above calculated Mole % of H2S on the 'ValLoStrm' (Stream 2) is found to be out of the
'ValLoConc' limits specified by the variable 'ValLoDevLim' (+/-10% for this application, between
27 ppm and 33 ppm), then the validation sequence is 'Halted'. The system goes to 'Idle' for a short
period. Then a calibration sequence is run on the 'ValHiStrm' (Stream 3).

At the end of the calibration sequence on the 'ValHiStrm', if the new calculated response factors are
outside the component data table's 'Response Factor % Dev' limits, the H2S Response Factor for the
component data tables will not be updated. The active 'Excess Response Factor Deviation' alarm will
be set. The validation process is then repeated.

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Before setting the validation failure alarm, the validation process will be repeated the number of
times specified by the value assigned to the 'ValToFail' variable in the User Defined Numerics
submenu. For this application, the default repeat value is 1.

When this validation process has completed, the controller goes to 'idle' for a short period, and if the
out of range condition is found to still exist, the following events take place:

1) The active 'H2S Validation Check Failed' alarm is set.

2) If a discrete output has been assigned to the validation alarm In the Discrete Alarms
submenu, it will be activated.

3) Sim2251 Modbus Register 8017 (StartVal) returns to 1 (Idle) if the validation process was
manually started.

4) Sim2251 Modbus register 8018 (Validation Failure Flag) is set to '1' (Failed).

5) Sim2251 Modbus registers 8019 (Operational Status) is set to '2' (Analysis).

6) 'Discrete Input #5' is reset to OFF.

7) The controller resumes running Stream 1 analyses.

The active 'H2S Validation Failure' alarm can be cleared in MON. But SIM2251 Modbus register
8018 (Validation Failure Flag) and the 'Discrete Output', if one has been assigned to the validation
alarm in the Discrete Alarms submenu, will remain set.

The Modbus register 8018 (Validation Failure Flag) and the discrete output will only be cleared
when the conditions causing the validation failure has been cleared and the validation process passes.

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High Stream Validation Failure (A Condition Uncorrectable by Calibration)

The validation process is initiated. 'Discrete Input #5' is set to ON. SIM2251 Modbus bus register
8019 (Operational Status) is set to 4 (Validation). Register 8017 (StartVal) is set to 2 (Start) if the
validation process was started manually, otherwise register 8017 remains at 1 (Idle). The validation
process begins running the 'Auxiliary Stream Seq'.

On the last run of Stream2 (the VAlLoStrm) during the validation process, the calculated Mole %
of H2S on Stream 2 running the Low H2S calibration bottle is compared to the 'ValLoConc' value
assigned to Stream 2 in the Numeric submenu, for this application the default 'ValLoConc' value
is 30 ppm.

If the above calculated Mole % of H2S on the 'ValLoStrm' (Stream 2) is within the 'ValLoConc'
limits specified by the variable 'ValLoDevLim' (±10% for this application, between 27 ppm and 33
ppm), then the validation process begins on the 'ValHiStrm' (Stream 3).

On the last run of Stream 3 in the validation process, If the calculated Mole % of H2S on the
'ValHiStrm' (Stream 3) is found to be out of the 'ValHiConc' limits specified by the variable
'ValHiDevLim' (±10% for this application, between 216 ppm and 264 ppm), then the validation
sequence is 'Halted'. The system goes to 'Idle' for a short period. Then a calibration sequence is run
on the 'ValHiStrm' (Stream 3).

At the end of the calibration sequence on the 'ValHiStrm', if the new calculated response factors are
outside the component data table's 'Response Factor % Dev' limits, the H2S response factor for the
component data tables will not be updated. The active 'Excess Response Factor Deviation' alarm will
be set. The validation process is then repeated.

Before setting the validation failure alarm, the validation process will be repeated the number of
times specified by the value assigned to the 'ValToFail' variable in the User Defined Numerics
submenu. For this application the default repeat value is 1.

When this validation process has completed, the controller goes to 'idle' for a short period, and if the
out of range condition is found to still exist, the following events take place:

1) The active 'H2S Validation Check Failed' alarm is set.

2) If a discrete output has been assigned to the validation alarm in the 'Discrete Alarms'
submenu, it will be activated.

3) Sim2251 Modbus Register 8017 (StartVal) returns to 1 (Idle) if the validation process was
manually started.

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4) Sim2251 Modbus register 8018 (Validation Failure Flag) is set to '1' (Failed).

5) Sim2251 Modbus registers 8019 (Operational Status) is set to '2' (Analysis).

6) 'Discrete Input #5' is reset to 'OFF'.

7) The controller resumes running Stream 1 analyses.

The active 'H2S Validation Failure' alarm can be cleared in MON. But SIM2251 Modbus register
8018 (Validation Failure Flag) and the 'Discrete Output', if one has been assigned to the Validation
Alarm in the Discrete Alarms submenu, will remain set.

The Modbus register 8018 (Validation Failure Flag) and the discrete output will only be cleared
when the conditions causing the validation failure has been cleared and the validation process
passes.

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Modbus Register Definitions:

(SIM2251) (User-Modbus)
Field Strm Component
8007 ValStartTime R/W Cus_Cmp_Data-Field2 1 3
8008 ValLoStrm R/W Cus_Cmp_Data-Field3 1 3
8009 ValHiStrm R/W Cus_Cmp_Data-Field4 1 3
8010 ValCalStrm R/W Cus_Cmp_Data-Field5 1 3
8011 ValAnlStrm R/W Cus_Cmp_Data-Field1 1 4
8012 ValToFail R/W Cus_Cmp_Data-Field2 1 4
8013 ValLoConc RW Cus_Cmp_Data-Field3 1 4
8014 ValLoDevLim RW Cus_Cmp_Data-Field4 1 4
8015 ValHiConc RW Cus_Cmp_Data-Field5 1 4
8016 ValHiDevLim RW Cus_Cmp_Data-Field1 1 5
8017 StartVal RW Cus_Cmp_Data-Field2 1 5
8018 Validation failure flag RO Cus_Cmp_Data-Field3 1 5
8019 Operational status RO Cus_Cmp_Data-Field4 1 5
8020 Last mod date for 8007 RO Cus_Cmp_Data-Field5 1 5
8021 Last mod time for 8007 RO Cus_Cmp_Data-Field1 2 1
8022 Last mod date for 8008 RO Cus_Cmp_Data-Field2 2 1
8023 Last mod time for 8008 RO Cus_Cmp_Data-Field3 2 1
8024 Last mod date for 8009 RO Cus_Cmp_Data-Field4 2 1
8025 Last mod time for 8009 RO Cus_Cmp_Data-Field5 2 1
8026 Last mod date for 8010 RO Cus_Cmp_Data-Field1 2 2
8027 Last mod time for 8010 RO Cus_Cmp_Data-Field2 2 2
8028 Last mod date for 8011 RO Cus_Cmp_Data-Field3 2 2
8029 Last mod time for 8011 RO Cus_Cmp_Data-Field4 2 2
8030 Last mod date for 8012 RO Cus_Cmp_Data-Field5 2 2
8031 Last mod time for 8012 RO Cus_Cmp_Data-Field1 2 3
8032 Last mod date for 8013 RO Cus_Cmp_Data-Field2 2 3
8033 Last mod time for 8013 RO Cus_Cmp_Data-Field3 2 3
8034 Last mod date for 8014 RO Cus_Cmp_Data-Field4 2 3
8035 Last mod time for 8014 RO Cus_Cmp_Data-Field5 2 3
8036 Last mod date for 8015 RO Cus_Cmp_Data-Field1 2 4
8037 Last mod time for 8015 RO Cus_Cmp_Data-Field2 2 4
8038 Last mod date for 8016 RO Cus_Cmp_Data-Field3 2 4
8039 Last mod time for 8016 RO Cus_Cmp_Data-Field4 2 4
8040 Last mod date for 8017 RO Cus_Cmp_Data-Field5 2 4
8041 Last mod time for 8017 RO Cus_Cmp_Data-Field1 2 5
8042 Last mod date for 8018 RO Cus_Cmp_Data-Field2 2 5
8043 Last mod time for 8018 RO Cus_Cmp_Data-Field3 2 5

H2S CEM APPLICATION 15


SEP 2005 MODEL 2350A GAS CHROMATOGRAPH CONTROLLER

8044 Last mod date for 8019 RO Cus_Cmp_Data-Field4 2 5


8045 Last mod time for 8019 RO Cus_Cmp_Data-Field5 2 5
8046 Stream 1 Comp 1 mole% RO Cus_Cmp_Data-Field1 3 1
8047 Stream 1 Comp 2 mole% RO Cus_Cmp_Data-Field2 3 1
8048 Stream 1 Comp 3 mole% RO Cus_Cmp_Data-Field3 3 1
8049 Stream 1 Comp 4 mole% RO Cus_Cmp_Data-Field4 3 1
8050 Stream 1 Comp 5 mole% RO Cus_Cmp_Data-Field5 3 1
8051 Stream 1 Comp 6 mole% RO Cus_Cmp_Data-Field1 3 2
8052 Stream 1 Comp 7 mole% RO Cus_Cmp_Data-Field2 3 2
8053 Stream 1 Comp 8 mole% RO Cus_Cmp_Data-Field3 3 2
8054 Stream 1 Comp 9 mole% RO Cus_Cmp_Data-Field4 3 2
8055 Stream 1 Comp 10 mole% RO Cus_Cmp_Data-Field5 3 2
8056 Stream 1 Comp 11 mole% RO Cus_Cmp_Data-Field1 3 3
8057 Stream 1 Comp 12 mole% RO Cus_Cmp_Data-Field2 3 3
8058 Stream 1 Comp 13 mole% RO Cus_Cmp_Data-Field3 3 3
8059 Stream 1 Comp 14 mole% RO Cus_Cmp_Data-Field4 3 3
8060 Stream 1 Comp 15 mole% RO Cus_Cmp_Data-Field5 3 3
8061 Stream 1 Comp 16 mole% RO Cus_Cmp_Data-Field1 3 4
8062 Stream 1 Comp 17 mole% RO Cus_Cmp_Data-Field2 3 4
8063 Stream 1 Comp 18 mole% RO Cus_Cmp_Data-Field3 3 4
8064 Stream 1 Comp 19 mole% RO Cus_Cmp_Data-Field4 3 4
8065 Stream 1 Comp 20 mole% RO Cus_Cmp_Data-Field5 3 4
8066 Stream 1 BTU RO Cus_Cmp_Data-Field1 3 5
8067 Stream 1 rel dens RO Cus_Cmp_Data-Field2 3 5
8068 Stream 1 unnorm conc RO Cus_Cmp_Data-Field3 3 5
8069 Spare RO Cus_Cmp_Data-Field4 3 5
8070 Spare RO Cus_Cmp_Data-Field5 3 5
8071 Stream 2 H2S mole % RO Cus_Cmp_Data-Field1 4 1
8072 Stream 2 BTU RO Cus_Cmp_Data-Field2 4 1
8073 Stream 2 rel dens RO Cus_Cmp_Data-Field3 4 1
8074 Stream 2 unnorm conc RO Cus_Cmp_Data-Field4 4 1

8075 Spare RO Cus_Cmp_Data-Field5 4 1


8076 Stream 3 H2S mole % RO Cus_Cmp_Data-Field1 4 2
8077 Stream 3 BTU RO Cus_Cmp_Data-Field2 4 2
8078 Stream 3 rel dens RO Cus_Cmp_Data-Field3 4 2
8079 Stream 3 unnorm conc RO Cus_Cmp_Data-Field4 4 2
8080 Spare RO Cus_Cmp_Data-Field5 4 2
8081 Stream 1 date RO Cus_Cmp_Data-Field1 4 3
8082 Stream 1 time RO Cus_Cmp_Data-Field2 4 3
8083 Stream 2 date RO Cus_Cmp_Data-Field3 4 3

16 H2S CEM APPLICATION


MODEL 2350A GAS CHROMATOGRAPH CONTROLLER SEP 2005

8084 Stream 2 time RO Cus_Cmp_Data-Field4 4 3


8085 Stream 3 date RO Cus_Cmp_Data-Field5 4 3
8086 Stream 3 time RO Cus_Cmp_Data-Field1 4 4

Note: last modification dates are IEEE floating point numbers formatted as YYMMDD, such YY
is the last two digits of the year, MM is the month (1 - 12), and DD is the day of the month. The last
modification times are stored as HHMMSS where HH is hour (0 - 23), MM is minutes, and SS is
seconds.

H2S CEM APPLICATION 17


SEP 2005 MODEL 2350A GAS CHROMATOGRAPH CONTROLLER

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18 H2S CEM APPLICATION


NOTES
NOTES
WARRANTY CLAIM PROCEDURES

To make a warranty claim, you, the Purchaser, must:

1. Provide Daniel Measurement Services (DMS), a division of Emerson Process Management,


with proof of the Date of Purchase and proof of the Date of Shipment of the product in
question.

2. Return the product to DMS within twelve (12) months of the date of original shipment of the
product, or within eighteen (18) months of the date of original shipment of the product to
destinations outside of the United States. The Purchaser must prepay any shipping charges.
In addition, the Purchaser is responsible for insuring any product shipped for return, and
assumes the risk of loss of the product during shipment.

3. To obtain Warranty service or to locate the nearest DMS office, sales, or service center call
(713) 827-6314, Fax (713) 827-6312 write to:

Daniel Measurement Services


a division of Emerson Process Management
11100 Brittmoore Park Drive
Houston, Texas 77041

Or contact DMS via the following site:

www.emersonprocess.com/daniel

4. When contacting DMS for product service, the Purchaser is asked to provide information
as indicated on the following page entitled "Customer Repair Report".

5. For product returns from locations outside the United States, it will be necessary for you to
obtain the import consignment address so that DMS’s customs broker can handle the
importation with the U.S. Customs Service.

6. DMS offers both on call and contract maintenance service designed to afford single source
responsibility for all its products.

7. DMS reserves the right to make changes at any time to any product to improve its design and
to insure the best available product.
CUSTOMER REPAIR REPORT

FOR SERVICE, COMPLETE THIS FORM, AND RETURN IT ALONG WITH THE AFFECTED EQUIPMENT TO CUSTOMER
SERVICE AT THE ADDRESS INDICATED BELOW.

COMPANY NAME:

TECHNICAL CONTACT: PHONE:

REPAIR P. O. #: IF WARRANTY, UNIT S/N:

INVOICE ADDRESS:

SHIPPING ADDRESS:

RETURN SHIPPING METHOD:

EQUIPMENT MODEL #: S/N: FAILURE DATE:

DESCRIPTION OF PROBLEM:

WHAT WAS HAPPENING AT TIME OF FAILURE?

ADDITIONAL COMMENTS:

REPORT PREPARED BY: TITLE:

IF YOU REQUIRE TECHNICAL ASSISTANCE, PLEASE FAX OR WRITE THE CUSTOMER SERVICE DEPARTMENT AT:

DANIEL MEASUREMENT SERVICES


DIVISION OF EMERSON PROCESS MANAGEMENT PHONE: (713) 827-6314
ATTN: CUSTOMER SERVICE FAX: (713) 827-6312
11100 BRITTMOORE PARK DRIVE
HOUSTON, TEXAS 77041

FOR FASTEST SERVICE CONTACT DMS VIA OUR WEBSITE:


www.emersonprocess.com/daniel
Daniel Measurement and Control, Inc., Daniel Measurement Services, Inc.,
and Rosemount Analytical, Inc., Divisions of Emerson Process Management
reserve the right to make changes to any of its products or services
at any time without prior notification in order to improve that product or
service and to supply the best product or service possible.
www.emersonprocess.com/daniel

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